Orientador: Liliane Maria Ferrareso Lona / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química / Made available in DSpace on 2018-08-07T08:12:19Z (GMT). No. of bitstreams: 1 Bufo_MoacirJose_D.pdf: 987875 bytes, checksum: 8fa242d4879a20b9592f76cbbb4e5681 (MD5) Previous issue date: 2006 / Resumo: Águas residuárias urbanas e industriais, cujo destino final em nível mundial é o rio, sempre apresentam imiscíveis na forma de película e gotas, sejam de óleos comestíveis ou óleos lubrificantes ou solventes petroquímicos. A grande dificuldade em separar estes imiscíveis está no diâmetro de gotas inferior a 40 microns. A melhor tecnologia, hoje, produz água tratada ainda com gotas de 20 microns e com teor de imiscível igual a 10 mg/litro. O autor do presente trabalho, em 1984, acidentalmente criou um coalescedor a filme, e realizou ensaios numa instalação em escala piloto, para encontrar uma solução para um problema de imiscível em água, de uma indústria petroquímica. Os ensaios qualitativos realizados mostraram que a tecnologia é eficiente para separar imiscíveis em água. Os estudos, naquela época, não tiveram continuidade. O regime de operação da instalação piloto era contínuo. A aparelhagem da piloto era totalmente em vidro. O controle destes ensaios foi por meio visual que é bastante significativo pelo fato de ser um controle simnão, isto é, ou tem turbidez ou não tem turbidez. A água residuária entrando no coalescedor era homogênea e na saída do coalescedor havia a formação de duas camadas distintas com uma interface de separação. A camada inferior apresentava uma turvação e a camada superior não apresentava turvação. Este fato mostra de forma inquestionável de que ocorreu um processo de aglutinação de partículas ou coalescência. Desta forma, o objetivo deste trabalho é dar continuidade ao trabalho iniciado em 1984, visando desenvolver uma metodologia para explicar o fenômeno da coalescência neste tipo de coalescedor e também desenvolver um modelo para o seu dimensionamento, visto que o fluxograma do processo já está estabelecido. Este trabalho é assim definido como teórico, uma vez que já existe o trabalho experimental realizado em 1984. A consulta em literatura tem três enfoques: O primeiro é conhecer o fenômeno da coalescência em termos científico. O segundo enfoque foi conhecer o estado da arte da tecnologia de coalescedor. O terceiro foi uma compilação de todos aqueles conhecimentos científicos e tecnológicos julgados pertinentes para a condução deste estudo. Adotouse, neste trabalho, o método de dedução indutiva e a antiga técnica da equação da proporcionalidade para propor um mecanismo e uma equação cinética da coalescência em filme de líquido. Também foi usada a equação da continuidade de NavierStokes para determinar o perfil de concentração das gotas ao longo do filme, visando gerar um modelo de dimensionamento para o coalescedor proposto. Foi constatado que o comportamento de imiscível em água é específico para cada espécie química e também depende da intensidade de energia aplicada ao meio. Por este motivo, a consolidação da tecnologia de separação de gotas de imiscível proposta só poderá ser realizada mediante um estudo numa instalação em escala industrial. Qualquer estudo em escala piloto vem somente confirmar o que já foi realizado e no máximo fornecer valores isolados de concentração de gotas de imiscível / Abstract: Urban and industrial wastewaters always have immiscible chemicals. These immiscibles are chemicals such as edible oils, lubricant oil and petrochemical solvents. The final destinations of these wastewaters is the river. It is very difficult to separate immiscibles with diameter drop less than 40 µm from the wastewater. The best separation technology available today still produces clean water with drops below 20 microns and with immiscible content of 10 mg/l. In 1984 the author of this work accidentally created one coalescence film equipment. The pilot scale test results were successful in separating immiscibles from wastewater in a petrochemical plant. The glass pilot plant operated continuously. The kind of control plant it is visual to detect the turbidity. The homogenous liquid wastewater is fed to the top of the coalescence equipment. The liquid issue. the bottom of equipment had two phases. The lower phase was turbid and the upper phase was not. Unfortunately the investigation was stopped at the time. Based on the research developed in 1984, the objective of this work is to study the phenomena of coalescence of the liquid film and to develop a kinetic coalescence model and a design model for a coalescence equipment. This present work is theoretical based on the experimental date (process flowsheet and design equipment) obtained in 1984. There are three main objectives: the first objective is to understand the coalescence phenomena; the second is to understand the development of coalescer technology; the third is to compile all relevant scientific and technological knowledge for this research. The investigation used the inductive deduction method and the old proportional equation technique to suggest a mechanism and kinetic equation to describe the film coalescence phenomenon. The NavierStokes equation was used to determine the drop concentration profile in the film, in order to produce a way to design the equipment. One conclusion is that each immiscible chemical behave differently in water. The applied energy also plays a role. Another pilot plant will only confirm what has been done and give isolated immiscible products drop concentration / Doutorado / Desenvolvimento de Processos Químicos / Mestre em Engenharia Química

abstract: This study explores how bulk composition and oxygen fugacity (fO2) affect the partitioning of sulfur between the molten mantle and core of an early planetesimal. The model can be used to determine the range of potential sulfur concentrations in the asteroid (16) Psyche, which is the target of the National Aeronautics and Space Administration/Arizona State University Psyche Mission. This mission will be our visit to an M-type asteroid, thought to be dominantly metallic. The model looks at how oxygen fugacity (fO2), bulk composition, temperature, and pressure affect sulfur partitioning in planetesimals using experimentally derived equations from previous studies. In this model, the bulk chemistry and oxygen fugacity of the parent body is controlled by changing the starting material, using ordinary chondrites (H, L, LL) and carbonaceous chondrites (CM, CI, CO, CK, CV). The temperature of the planetesimal is changed from 1523 K to 1873 K, the silicate mobilization and total melting temperatures, respectively; and pressure from 0.1 to 20 GPa, the core mantle boundary pressures of Vesta and Mars, respectively. The final sulfur content of a differentiated planetesimal core is strongly dependent on the bulk composition of the original parent body. In all modeled cores, the sulfur content is above 5 weight percent sulfur; this is the point at which the least amount of other light elements is needed to form an immiscible sulfide liquid in a molten core. Early planetesimal cores likely formed an immiscible sulfide liquid, a eutectic sulfide liquid, or potentially were composed of mostly troilite, FeS. / Dissertation/Thesis / Masters Thesis Geological Sciences 2020

<p>Electrostatic spray is a spray that is induced by an interaction between the surface charge on the liquid meniscus and the externally applied electrical field that forms a conical shape known as the Taylor Cone. Electrostatic spray can be seen in a variety of different fields in modern times, such as, agriculture, combustion, space propulsion, and medical applications. The experimental setup for any electrostatic spray consists of the following components: a syringe pump filled with an ionic fluid, a high voltage power supply, and a ground source. The orientation of the nozzle, set to a horizontal or vertical orientation, and the interface that is examined, liquid/air or liquid/liquid interface are two parameters that can vary from one setup to another while still using the same components to form the electrostatic spray. In this experimental study, the characteristic of the electrostatic spray of two immiscible fluids, liquid/liquid interface, with a horizontal nozzle orientation, was analyzed. The two immiscible fluids that were chosen for this experiment were olive oil, the ambient fluid, and pure ethanol, the working fluid. A set range of 0 – 5 kV with an increment of 0.5 kV was applied to the working fluid with a flowrate of 0.1 mL/min. The distance between the nozzle and the copper disk was also altered for three different distances, 22.09, 14.6 and 10.33 mm. Different patterns and trajectories were captured and analyzed using both a high-speed camera and a long exposure camera. Formation of vortices was recorded in the induced flow. The general trend was found was an increase in the droplets’ velocity with the increase of the applied voltage. Additionally, there was an increase in the droplets’ velocity was recorded as the copper disk was moved closer to the nozzle. A dimensional number, Jowaiser’s number Jo, has been proposed where it relates the electric forces to the inertial forces. It can be used to predicts the phase that the flow experiences. The four phases that a flow can experience are the droplet phase, transition phase, spray phase, and the shorting phase.  </p>

<p> The separation of a mixture of carbon tetrachloride in water was studied in a 2 inch diameter glass hydrocyclone. First, the effect of a mixing valve and of oil/water ratio on the volume/surface diameter of the dispersion in the feed to the hydrocyclone was studied using a statistical experiment design. Secondly, the effect of feed drop size distribution, oil/water ratio, and overflow/underflow split on the separation in the hydrocyclone was determined, again using a statistical experiment design. In both designs, five levels of each variable were studied. Flow rate, design shape, and temperature were kept constant. The range of variables was: </p> <p> 1. Mixing Value Pressure Drop 17.95 to 88.25 mm. Hg </p> <p> 2. Oil/Water Ratio 0.132 to 0.211 </p> <p> 3. Overflow/Underflow Split 4/1 to 8/1 </p> <p> From the first part of the work it was found that oil/water ratio had no significant effect on the volume/surface diameter, and that there was a linear relationship between the volume/surface diameter and mixing valve pressure drop. </p> <p> From the second part of the work it was found that volume split had most significant effect on hydrocyclone separation for the range of variables studied. The oil/water ratio had the next most significant effect on separation, and finally, drop size distribution was also found to be significant, but was the least important of the three variables. The interactions of the variables were no significant. The hydrocyclone separation could be predicted. The prediction of the overflow drop-size distribution agreed very well with the distribution observed photographically. Both predictions required assumptions that short-circuit flow and drop-drop coalescence was negligible. </p> / Thesis / Master of Engineering (ME)

L'objectif de cette thèse est l'étude du problème de Cauchy pour les solutions faibles de trois problèmes (systèmes paraboliques dégénérés et fortement couplés) modélisant des écoulements diphasiques et compressibles en milieu poreux. La motivation de ce travail est un "benchmark" du GNR MoMaS pour l'étude de l'impact de l'écoulement du gaz d\^{u} à la corrosion des matériaux ferreux dans un site de stockage de déchets radioactifs. Cette thèse est divisée en trois chapitres indépendants. Premièrement, on s'intéresse à l'analyse mathématique d'un problème modélisant l'écoulement de deux phases immiscibles et en considérant qu'une phase est compressible et l'autre est incompressible (eau/gaz). Deuxièmement, on traite le cas général du déplacement de deux fluides compressibles et immiscibles dans un milieu poreux. Enfin, le dernier chapitre est consacré à la construction et à la convergence de la méthode des volumes finis pour le système eau-gaz sous l'hypothèse que la densité du gaz est une fonction de la pression globale.

No description available.

Multiphase flow and transport in fractured rock is of importance to many practical and engineering applications. In the field of groundwater hydrology an issue of significant environmental concern is the release of dense non-aqueous phase liquids (DNAPLs) which can cause long-term groundwater contamination in fractured aquifers. This study deals with two fundamental processes – fluid displacement and interphase mass transfer – concerning the behavior of the multiphase contaminants in fractured media. The focus of this work has been placed on improving the current understanding of small-scale (single fracture) physics by a combined effort of numerical modeling analysis, laboratory experiments and model development. This thesis contributes to the improved understanding through several aspects. Firstly, the effect of aperture variability, as characterized by geostatistical parameters such as standard deviation and correlation length, on the DNAPL entrapment, dissolution and source-depletion behaviors in single fractures was revealed. Secondly, a novel, generalized approach (adaptive circle fitting approach) to account for the effect of in-plane curvature of fluid-fluid interfaces on immiscible fluid displacement was developed; the new approach has demonstrated good performance when applied to simulate previously published experimental data. Thirdly, the performance of a continuum-based two-phase flow model and an invasion percolation model was compared for modeling fluid displacement in a variable-aperture fracture and the dependence of fracture-scale capillary pressure – saturation relationships on aperture variability was studied. Lastly, through experimental studies and mechanistic numerical modeling of DNAPL dissolution, kinetic mass transfer characteristics of two different entrapment configurations (residual blobs and dead-end pools) were investigated. The obtained understanding from this thesis will be useful for predictive modeling of multiphase contaminant behavior at a larger (fracture network) scale. / Flerfasflöde och ämnestransport i sprickigt berg är av betydelse för många praktiska och tekniska problem. Tunga, svårlösliga organiska vätskor (engelska: dense non-aqueous phase liquids: DNAPLs; t.ex. klorerade lösningsmedel) kan orsaka långvarig förorening av vattenresurser, inklusive akviferer i sprickigt berg, och utgör ett viktigt miljöproblem inom grundvattenhydrologin. Denna studie behandlar två fundamentala processer för spridning av flerfasföroreningar i sprickiga medier – utbredning av den organiska vätskan och massöverföring mellan organisk vätska och vatten. Arbetet har fokuserat på att förbättra nuvarande kunskap om de fysikaliska processerna på liten skala (enskilda sprickor) genom en kombination av numerisk modellering, laboratorieexperiment och modellutveckling. Avhandlingen har bidragit till utökad processförståelse i flera avseenden. För det första har arbetet belyst effekterna av sprickaperturens variabilitet, uttryckt med geostatistiska parametrar som standardavvikelse och rumslig korrelationslängd, på fastläggning och lösning av organiska vätskor i enskilda sprickor, samt utmattningsbeteendet hos dessa källor till grundvattenförorening. För det andra har en ny, generell metod (adaptiva cirkelpassningsmetoden) för att ta hänsyn till effekten av krökningen av gränsytan mellan organisk vätska och vatten i sprickplanet utvecklats; denna metod har visats fungera väl i simuleringar av tidigare publicerade experimentella data. För det tredje, har en jämförelse gjorts mellan en kontinuumbaserad tvåfasflödesmodell och en invasions-perkolationsmodell med avseende på hur väl de kan simulera tvåfasflöde i en spricka med varierande apertur. Här studerades även hur relationen mellan kapillärtryck och mättnadsgrad på sprickplansskala beror av variabiliteten i sprickapertur. Till sist undersöktes lösning av den organiska vätskan i grundvatten för två fastläggningsscenarier (fastläggning i immobila droppar och ansamling i fällor – ”återvändssprickor”) både genom experiment och mekanistisk numerisk modellering. Kunskapen som tagits fram i denna avhandling bedöms vara användbar även för att modellera spridningen av flerfasföroreningar på större (spricknätverks-) skalor.

This thesis focuses on the lattice-Boltzmann method (LBM) and its ability to simulate immiscible two-phase flow. We introduce the main lattice-Boltzmann-based approaches for analyzing two-phase flow: the color-fluid model by Gunstensen, the interparticle-potential model by Shan and Chen, the free-energy model by Swift and Orlandini, and the mean-field model by He. The first objective is to assess the ability of these methods to maintain continuity at the interface of two fluids, especially when the two fluids have different viscosities or densities. Continuity issues have been mentioned in the literature but have never been quantified. This study presents a critical comparison of the four lattice-Boltzmann-based approaches for analyzing two-phase flow by analyzing the results of the two-phase Poiseuille flow for different viscosity ratios and density ratios. The second objective is to present the capability of the most recent version of the color-fluid model for simulating 3D flows. This model allows direct control over the surface tension at the interface. We demonstrate the ability of this model to simulate surface tension effects at the interface (Laplace bubble test), stratified two-phase flows Poiseuille two-phase flow), and bubble dynamics (the free rise of a bubble in a quiescent viscous fluid).

[pt] A eficiência do processo de injeção de água, o método de recuperação secundária mais comum na indústria do petróleo, é limitada por seu padrão de varredura não uniforme, originado da formação de caminhos preferenciais devido à alta razão de mobilidade entre água e óleo, e a elevada saturação de óleo residual, associada aos efeitos capilares. A fim de melhorar a recuperação de petróleo, diferentes abordagens têm sido sugeridas na literatura, com algumas delas baseadas no bloqueio de poros e consequente desvio de água, varrendo assim uma área maior do reservatório e deslocando mais do óleo aprisionado por capilaridade. O bloqueio de poros pode ser realizado com diferentes métodos, sendo um deles a injeção de emulsão, com a fase dispersa, composta por gotas de óleo, atuando como o agente responsável pela diminuição da mobilidade da fase aquosa. Neste trabalho, os mecanismos fundamentais do processo de injeção de emulsão foram estudados experimentalmente, visualizando-se o escoamento em escala de poros em um dispositivo micro-fluídico de vidro composto por uma rede de canais constritos, que modela as principais características de um meio poroso. Os resultados mostram o efeito do tamanho da gota e do número de capilaridade no padrão do escoamento, no tamanho dos gânglios do óleo aprisionado e na recuperação de óleo residual. / [en] The efficiency of water flooding, the most common secondary recovery method in the oil industry, is limited by its non-uniform sweep pattern, originating from the formation of preferential paths because of the high mobility ratio between water and oil, and the high residual oil saturation, associated with capillary oil trapping. In order to improve oil recovery, different approaches have been suggested in the literature, with some of them based on pore blocking and consequent water diversion, thus sweeping a bigger area of the reservoir and displacing more of the trapped oil. Pore blockage can be performed with different methods, one of which is emulsion flooding, with the disperse phase, composed by oil drops, acting as the agent responsible for the decreased water phase mobility. In this work, the fundamental mechanisms of emulsion flooding process was studied experimentally, by visualizing the pore-scale flow in a glass microfluidic device composed of a network of constricted channels, that models the main features of a porous media. The results show the effect of drop size and capillary number on the flow pattern, trapped oil ganglia size and residual oil recovery.

This theses deals with flow of two immisible fluid in horizontal pipeline. First part teoretically describes immisible flow. What follows is experimental measurement in wich experimental track was adjusted for inlet of oil from the top. Water and corn germ oil were used as fluids. There were observed many modes of flow on the track. After that PIV was described and measured. PIV was done for measurement of values of velocity vectors. Simulation of one chosen mode was developed in the last chapter. This simulation was done in Ansys Fluent with help of VOF method. Simulation was done both in 3D and 2D pipeline. In the end these simulation were compared with experiment measurement and were critically evaluated.