Ce mémoire s’intéresse au système binaire massif CV Serpentis, composé d’une Wolf- Rayet riche en carbone et d’une étoile de la séquence principale, de type spectral O (WC8d + O8-9IV). D’abord, certains phénomènes affectant les étoiles massives sont mentionnés, de leur passage sur la séquence principale à leur mort (supernova). Au cours du premier cha- pitre, un rappel est fait concernant certaines bases de l’astrophysique stellaire observa- tionnelle (diagramme Hertzsprung-Russell, phases évolutives, etc...). Au chapitre suivant, un des aspects les plus importants de la vie des étoiles massives est abordé : la perte de masse sous forme de vents stellaires. Un historique de la découverte des vents ouvre le chapitre, suivi des fondements théoriques permettant d’expliquer ce phénomène. Ensuite, différents aspects propres aux vents stellaires sont présentés. Au troisième chapitre, un historique détaillé de CV Ser est présenté en guise d’introduc- tion à cet objet singulier. Ses principales caractéristiques connues y sont mentionnées. Finalement, le cœur de ce mémoire se retrouve au chapitre 4. Des courbes de lumière ultra précises du satellite MOST (2009 et 2010) montrent une variation apparente du taux de perte de masse de la WR de l’ordre de 62% sur une période orbitale de 29.701 jours. L’analyse des résidus permet de trouver une signature suggérant la présence de régions d’interaction en corotation (en anglais corotating interaction regions, ou CIR) dans le vent WR. Une nouvelle solution orbitale est présentée ainsi que les paramètres de la région de collision des vents et les types spectraux sont confirmés. / This thesis focuses on the massive binary CV Serpentis, consisting of a carbon-rich Wolf-Rayet star and a main-sequence O-type star (WC8d + O8-9IV). First off, different phenomena linked to massive stars throughout their existence - from main sequence to the supernova explosion - are mentioned. The first chapter offers a brief overview of some of the basics of observational stellar astrophysics (Hertzsprung- Russell diagram, evolution, etc...). The next chapter covers one of the most important aspects of massive stars : mass loss through stellar winds. The chapter opens with a chronology of the discovery of stellar winds, followed by the foundations of stellar wind theory. Finally, different processes involved in wind ejection are presented. The third chapter reviews chronologically the main studies carried out on CV Ser and helps introduce this peculiar system. Its main characteristics are given in this chapter. Finally, chapter 4 is the central part of this work. MOST light curves taken in 2009 and 2010 show what appears to be a 62% increase of the mass-loss rate over one or- bital period (29.701d). There also seems to be evidence for the presence of corotating interaction regions (CIR) in the WR wind. Indeed, the analysis of the residuals yields a CIR-like signature. A new orbit is derived, as well as the wind-collision zone parame- ters, while the spectral types of both stars are confirmed.

Made available in DSpace on 2016-06-02T19:32:04Z (GMT). No. of bitstreams: 1 4733.pdf: 3640369 bytes, checksum: 241bde399e7bf5d34363759fa6ab1025 (MD5) Previous issue date: 2012-05-23 / Financiadora de Estudos e Projetos / The macrophytes are essential for the development and maintenance of food webs, to carbon dynamics and nutrient cycling in tropical aquatic systems. After senescence and plant death, decomposition of organic detritus depends heavily on their elemental compositions. Thus, the present study aimed to evaluate the effect of seasonality and trophic state of reservoirs and Vigário Lajes on the mass losses of detritus of Salvinia auriculata, Pistia stratiotes, Eichhornia crassipes, Sagittaria montevidensis and Brachiaria subquadripara, the influence of elemental composition of debris on the coefficients decay of carbon, nitrogen and phosphorus, and the stoichiometric ratios between these elements during the decomposition process. Over 120 days, the richest detritus in nutrients and less refractory (S. montevidensis and P. stratiotes) showed a biphasic pattern of decay and the greater decay of carbon (70-90%), phosphorus (90-96%) and nitrogen (68-94%). The poorest and refractories detritus (S. auriculata and E. crassipes) had lower rates of decay, with monophasic and biphasic patterns and lower mass loss in carbon-based (20-34%), phosphorus-based (26%), and nitrogen-based (10- 37%). As for the difference between the environments, the total mass loss of carbon was up to 70% higher during the rainy season (Sept/10 to Jan/11) and 27% higher in the dry season (may/11 to Sep/11) for detritus S. auriculata incubated in the reservoir Vigário; for the detritus of B. subquadripara total mass loss was also greater in this reservoir, reaching 58% in the rainy season and 36% during the dry season. The minor differences between the environments occurred in the mass loss of carbon detritus of S. montevidensis, (ca. 1.3% and 0.3% in rainfall in the dry season) and P. stratiotes (ca. 5.3% in the rainy season and 5.5% in the dry season). Yet these detritus showed the greatest losses of phosphorus (90-95%) and nitrogen (68-94%) in both experiments. The minor differences between the environments occurred in the mass loss of carbon detritus of S. montevidensis, (ca. 1.3% and 0.3% in the rainy season in the dry season) and P. stratiotes (ca. 5.3% and 5.5% in the rainy season in the dry season). Yet these detritus showed the greatest losses of phosphorus (90-95%) and nitrogen (68-94%) in both experiments. The ratio between carbon and nitrogen was higher in detritus of S. auriculata and E. crassipes in oligotrophic reservoir, and lower in detritus of S. montevidensis and P. stratiotes, whose mass loss coefficients (k) were higher. / As macrófitas são essenciais para o desenvolvimento e manutenção das cadeias tróficas, para a dinâmica do carbono e ciclagem de nutrientes de sistemas aquáticos tropicais. Após senescência e morte das plantas, a decomposição dos detritos orgânicos depende muito das suas composições elementares. A temperatura, a concentração de nutrientes inorgânicos no meio, as relações estequiométricas entre os organismos decompositores e os detritos podem afetar as taxas de decomposição, embora no caso da relação estequiométrica isso nem sempre ocorra. Nesse sentido, esse estudo teve como objetivo avaliar o efeito da sazonalidade e da condição de trofia dos reservatórios de Lajes e de Vigário sobre as perdas de massa dos detritos de Salvinia auriculata, Pistia stratiotes, Eichhornia crassipes, Sagittaria montevidensis e Brachiaria subquadripara; a influência da composição elementar dos detritos sobre os coeficientes de decaimento de carbono, nitrogênio e fósforo; e as relações estequiométricas entre esses elementos durante o processo de decomposição. Ao longo de 120 dias, os detritos mais ricos em nutrientes e menos refratários (S. montevidensis e P. stratiotes) apresentaram padrão bifásico de decaimento, além dos maiores decaimentos de carbono (70 a 90%), fósforo (90 a 96%) e nitrogênio (68 a 94%). Os detritos mais pobres e refratários (S. auriculata e E. crassipes) apresentaram menores coeficientes de decaimento, com padrões monofásico e bifásico e as menores perdas de massa em base de carbono (20 a 34%), de fósforo (26%) e de nitrogênio (10 a 37%). Quanto à diferença entre os ambientes, a perda de massa total de carbono foi até 70% maior no período das chuvas (set/10 a jan/11) e 27% maior no período seco (mai/11 a set/11) para detritos de S. auriculata incubados no reservatório de Vigário; para os detritos de B. subquadripara a perda de massa total também foi maior neste reservatório, chegando a 58% no período das chuvas e 36% no período seco. As menores diferenças entre os ambientes ocorreram na perda de massa de carbono dos detritos de S. montevidensis , (ca. 1,3% nas chuvas e 0,3% na seca) e de P. stratiotes (ca. 5,3% nas chuvas e 5,5% na seca) .Contudo, esses detritos apresentaram as maiores perdas de fósforo (90 a 95%) e de nitrogênio (68 a 94%) nos dois experimentos. A razão entre carbono e nitrogênio foi mais alta nos detritos de S. auriculata e E. crassipes, no ambiente oligotrófico, e mais baixa nos detritos de S. montevidensis e P. stratiotes, cujos coeficientes de perda de massa (k) foram maiores.

A ce jour il n'est toujours pas possible de prédire avec exactitude le phénomène d'érosion par cavitation. La raison principale est qu'il est difficile de caractériser l'agressivité de l'écoulement. Cette thèse propose d'utiliser une méthode inverse pour estimer l'agressivité de l'écoulement à partir de l'observation des cratères (pits) imprimées sur la surface dans les premiers instants de l'érosion de cavitation. Trois matériaux ont été testés dans la veine d'écoulement PREVERO disponible au LEGI de Grenoble dans les mêmes conditions expérimentales. La géométrie des pits laissés sur la surface est précisément mesurée à l'aide d'une méthode systématique permettant de s'affranchir de l'effet de rugosité. Supposant que chaque pit a été généré par une bulle unique dont le champ de pression est assimilé à une forme Gaussienne, des calculs par éléments finis permettent d'estimer le chargement qui a créé l'empreinte résiduelle. On montre que la distribution des chargements suit une loi universelle indépendante du matériau testé; le matériau le plus tendre (alliage d'aluminium) mesurant les plus faibles impacts tandis que le matériau le plus résistant (Acier inoxydable) donne accès aux plus grandes pressions d'impact. On en conclu que le matériau peut être utilisé comme capteur de pression mesurant le niveau d'agressivité de l'écoulement. La méthode inverse repose sur une caractérisation mécanique des matériaux prenant en compte la sensibilité de la contrainte à la vitesse de déformation. On montre que les essais de nanoindentation sont mieux adaptés que les essais de compression pour déterminer les paramètres de la loi de comportement, notamment pour l'alliage d'aluminium pour lequel la microstructure est très hétérogène. Des essais de compression à haute vitesse par barres de Hopkinson complètent la loi de comportement en donnant la sensibilité à la vitesse de déformation. Des simulations prenant en compte la dynamique du chargement montrent que des impacts de fort amplitude mais appliqués sur un temps court ne laissent pas d'empreinte résiduelle si la fréquence est plus élevée que la fréquence naturelle du matériau assimilé à un oscillateur amorti. Un mécanisme d'accumulation dynamique de la déformation plastique pouvant conduire à la rupture par fatigue est proposé. Finalement, la courbe de perte de masse est simulée en appliquant aléatoirement sur un maillage 3D, la population d'impacts estimée par la méthode inverse. / Numerical prediction of cavitation erosion requires the knowledge of flow aggressiveness, both of which have been challenging issues till-date. This thesis proposes to use an inverse method to estimate the aggressiveness of the flow from the observation of the pits printed on the surface in the first moments of the cavitation erosion. Three materials were tested in the same experimental conditions in the cavitation tunnel PREVERO available LEGI Grenoble. The geometry of the pits left on the surface is precisely measured using a systematic method to overcome the roughness effect. Assuming that each pit was generated by a single bubble collapse whose pressure field is treated as a Gaussian shape, finite element calculations are run for estimating the load that created each residual imprint. It is shown that the load distribution falls on a master curve independent of the tested material; the softer material (aluminum alloy) measuring the lowest impacts while the most resistant material (duplex stainless steel) provides access to the largest impact pressures. It is concluded that the material can be used as a pressure sensor measuring the level of aggressiveness of the flow. The inverse method is based on a material characterization taking into account strain rate effects. It is shown that nanoindentation tests are more suitable than compression tests to determine the parameters of the behavior law, particularly for the aluminum alloy for which the microstructure is very heterogeneous. High-speed compression tests with split Hopkinson pressure bars complement the constitutive law giving the sensitivity to the strain rate. Simulations considering the dynamic loading show that impacts of strong amplitude but applied in a short time do not leave any residual pit if the frequency is higher than the natural frequency of the material treated as a damped oscillator. A dynamic mechanism of plastic strain accumulation that could eventually lead to fatigue failure is proposed. Finally, the mass loss curve of cavitation erosion is simulated by applying randomly on a 3D mesh, the impact force population estimated by the inverse method.

No description available.

The diploma thesis deals with the observation of the values of selected parameters (especially the static modulus of elasticity) of light-weight concrete in compression before and after multiple cyclic loading. The deformation of test specimens during multiple cyclic loading were measured with resistive strain gauges. Test specimens (cylinders with a diameter of 150 mm and height of a 300 mm) were cyclically loaded and up to 4 500 loading cycles were performed. The aim of this thesis is assessment changes in the values of static modulus of elasticity depending on the number of loading cycles.

’African Bamboo PLC’ has the vision to become the first and the leading bamboo-based floorboard producer in Africa with export markets in Europe and America. African alpine bamboo (Yushania alpina), common in the highlands of Ethiopia, was used to develop woven strand board (WSB) products. Research on thermal modification was part of the product development. Samples were mainly collected in Tetechia (6°33‘ 34‘‘ N 38°32‘25‘‘ W, 2,650-2,700 m a.s.l.), located in the Sidama region. Three culms each of two, three, four and five years of age were harvested. Samples were taken from the middle of each internode to determine the moisture content and density. Samples used to assess the effects of thermal modification were cut next to them. Further test specimens from different areas and other species such as the lowland bamboo (Oxytenanthera abyssinica) were also investigated. The thermal treatment was applied in a kiln with steam as an inert blanket to reduce oxidative processes. Eight modifications were performed at temperatures of 160 °C, 180 °C, 200 °C and 220 °C, at durations of three or five hours each. Mass loss, sorption behaviour, impact resistance, resistance to indentation and contents of chemical components were analysed for the modified and unmodified samples. Yushania alpina is a thin-walled bamboo with a maximum diameter of 6 cm, moisture content of up to 150 % and densities of between 0.5 g/cm² and 0.8 g/cm². Moisture content, diameter and wall thickness decreased from the bottom to the top of the culms, whereas density increased. Two year old bamboo had the lowest and three year the highest density. The mass loss followed an exponential trend, with about 2 % loss at 160 °C and 16 % at 220 °C. This mainly reflected the degradation of hemicellulose, which was fully removed at 220 °C. Extractive contents, at less than 5 %, fluctuated. Lignin amounted to 30 % and increased appreciably. Cellulose reached contents of about 45 % and decreased slightly at high temperatures. The chemical change, which was based more on the temperature than on the duration of treatment, influenced the sorption behaviour and mechanical properties most of all. The equilibrium moisture content was reduced by between 10 % to 40 %, depending on the climate and modification temperature chosen. This reduction stabilised between temperatures of 200 °C and 220 °C. The impact resistance of untreated bamboo was 3.8 J/cm², compared to only 1.4 J/cm² for modified samples. Resistance also differed between samples from the outer and inner part of the culm in the transverse section. The resistance to indentation declined also. Unmodified samples had 47 N/mm², compared to only 20 N/mm² for strongly modified samples. The results of the analysis and the experience gained indicate that temperatures between 180 °C and 200 °C, held for three hours, lead to the best results for woven strand board production using Ethiopian highland bamboo. / ’African Bamboo PLC’ setzt sich zum Ziel, als erstes Unternehmen Holzwerkstoffe aus Bambus nach Europa und Amerika zu exportieren. Afrikanischer Hochgebirgsbambus (Yushania alpina), welcher vor allem im Hochland von Äthiopien vorkommt, wurde dazu verwendet ”woven strand boards” (WSB) zu entwickeln. Untersuchungen zur thermischen Modifizierung waren dabei Bestandteil der Produktentwicklung. Die dafür notwendigen Bambusproben wurden hauptsächlich in Tetechia (6°33‘34‘‘ N 38°32‘25‘‘ W, 2650-2700 m ü. NN), einem Dorf in Sidama, entnommen. Es wurden dazu je drei Bambushalme der Altersklassen zwei, drei, vier und fünf Jahre geerntet. Proben für die Bestimmung von Holzfeuchte und Dichte wurden in der Mitte jedes Internodiums entnommen. Diese spielten als Referenzprobe eine große Rolle. Neben den Referenzprobekörpern wurden die jeweiligen Stücke für die thermische Behandlung heraus gesägt, wobei dies nach einer bestimmten Systematik erfolgte. Neben den Proben aus Tetechia wurden für die Untersuchungen zudem Proben aus anderen Gebieten und von einer anderen Art, dem Tieflandbambus (Oxytenanthera abyssinica), hinzugefügt. Die thermische Modifizierung erfolgte unter Wasserdampf, welcher oxidative Prozesse verhinderte. Insgesamt erfolgten acht Modifizierungen bei Temperaturen von 160 °C, 180 °C, 200 °C und 220 °C und einer jeweiligen Haltezeit von drei oder fünf Stunden. In Anbetracht der unbehandelten und behandelten Proben wurden der Masseverlust, die Bruchschlagarbeit, der Eindruckswiderstand und die chemische Zusammensetzung analysiert. Yushania alpina ist ein dünnwandiger Bambus mit Durchmessern bis zu 6 cm, Holzfeuchten bis 150 % und Dichten zwischen 0,5 g/cm² und 0,8 g/cm². Holzfeuchte, Durchmesser und Wandstärke verringerten sich mit der Halmhöhe, wobei die Dichte hingegen anstieg. Zweijähriger Bambus hatte die geringsten und dreijähriger Bambus die höchsten Dichten. Der Masseverlust folgte einem expontiellem Verlauf mit Werten von 2 % bei 160 °C und 16 % bei 220 °C. Er widerspiegelte den Abbau der Hemicellulose, welche bei 220 °C schon nicht mehr vorhanden war. Exktraktgehalte fluktuierten mit Werten unter 5 %. Der Ligningehalt lag bei ungefähr 30 % und stieg merklich an. Der Cellulosegehalt erreichte Werte von etwa 45 %, wobei die Cellulose bei höheren Temperaturen leicht abgebaut wurde. Die chemischen Veränderungen, welche maßgeblich von der angewandten Temperatur statt der Behandlungsdauer beeinflusst wurden, wirkten sich auf das Sorptionsverhalten und mechanische Eigenschaften aus. Je nach ausgesetztem Klima und erfolgter Modifikation wurde die Ausgleichsfeuchte der Proben um 10 % bis 40 % reduziert. Die Abnahme der Ausgleichsfeuchte stabilisierte sich im Temperaturbereich von 200 °C bis 220 °C. Die Bruchschlagarbeit des unbehandelten Bambus betrug 3,8 J/cm², die des behandelten nur 1,4 J/cm². Die Bruchschlagarbeit variierte unabhängig von der Modifikation zwischen dem inneren und äußeren Abschnittes innerhalb des Halmquerschnitts. Der Eindruckswiderstand nahm mit der thermischen Behandlung ebenfalls ab. Unbehandelte Proben hatten 47 N/mm², während die modifizierten Proben nur noch 20 N/mm² aufwiesen. Anhand der Ergebnisse und erworbenen Erfahrungen lies sich schlussfolgern, dass Temperaturen zwischen 180 °C und 200 °C bei einer Haltezeit von drei Stunden für die thermische Modifizierung von Äthiopischem Hochlandbambus in Bezug auf die Entwicklung von ”woven strand boards” empfehlenswert waren.

An understanding of compartment fire behaviour is important for fire protection engineers. For design purposes, whether to use a prescriptive code or performance based design, life safety and property protection issues are required to be assessed. The use of design fires in computer modelling is the general method to determine fire safety. However these computer models are generally limited to the input of one design fire, with consideration of the complex interaction between fuel packages and the compartment environment being simplified. Of particular interest is the Heat Release Rate, HRR, as this is the commonly prescribed design parameter for fire modelling. If the HRR is not accurate then it can be subsequently argued that the design scenario may be flawed. Therefore the selection of the most appropriate fire design scenario is critical, and an increased level of understanding of compartment behaviour is an invaluable aid to fire engineering assumptions. This thesis details an experimental study to enhance the understanding of the impact and interaction that the size and location of pool fires within an enclosure have upon the compartment fire behaviour. Thirty four experiments were conducted in a reduced scale compartment (½ height) with dimensions of 3.6m long by 2.4m wide by 1.2m high using five typical ventilation geometries (fully open, soffit, door, window and small window). Heptane pool fires were used, located in permutations of three evenly distributed locations within the compartment (rear, centre and front) as well as larger equivalent area pans located only in the centre. This thesis describes the experimental development, setup and results of the experimental study. To assist in the classification of compartment fire behaviour during the experiments, a ‘phi’ meter was developed to measure the time dependent equivalence ratio. The phi meter was developed and configured to measure O₂, CO₂ and CO. The background development, calibration, and experimental results are reported. A review of compartment fire modelling using Fire Dynamics Simulator, has also been completed and the results discussed. The results of this experimental study were found to have significant implications for Fire Safety Engineering in that the size of the fire is not as significant as the location of the fire. The effect of a fire near the vent opening was found to have a significant impact on compartment fire behaviour with the vent located fuel source increasing the total compartment heat release rate by a factor of 1.7 to that of a centrally placed pool fire of the same total fuel area. The assumption that a fire located in the centre of the room provides for the highest heat release rate is not valid for post-flashover compartment fires. The phi meter was found to provide good agreement with the equivalence ratio calculated from total compartment mass loss rates, and the results of FDS modelling indicate that the use of the model in its current form can not be applied to complex pool fire geometries.

No description available.

[ES] El diseño de puentes, a diferencia de lo que ocurre con el diseño de edificios o con el diseño de túneles ha dejado de lado la consideración de la acción del fuego hasta la fecha. Este vacío normativo, combinado con la gran repercusión económica y social de colapsos de puentes en el pasado como consecuencia de incendios, ha motivado un rápido incremento del número de estudios relativos a la ingeniería frente al fuego en el ámbito de los puentes. Aunque la acción del fuego no resulta del todo desconocida en el ámbito de las estructuras, sí que existen una serie de singularidades que impiden la trasposición directa de recomendaciones o de modelos de fuego simplificados ya desarrollados en otros campos que ya incorporan la acción del fuego en el diseño. En este contexto, el trabajo que a continuación se expone parte de un incendio ocurrido en el estado de Alabama en 2002, cuyas consecuencias fueron la demolición de un puente mixto de 37 metros de vano central, para plantear y validar una metodología que aborda el problema de forma numérica mediante tres modelos acoplados secuencialmente: modelo de incendios, modelo térmico y modelo mecánico Realizada una validación a nivel general se descubre que, aunque la configuración geométrica final obtenida se ajustan bastante a la realidad, la definición del incendio ha supuesto un gran número de hipótesis. Es por ello que se decide, en una segunda parte, realizar una campaña experimental que permita registrar la potencia del fuego, las temperaturas del gas y del acero y las flechas en un puente construido ad-hoc en el campus de la Universitat Politècnica de València. Este puente experimental tenía un vano único de 6 m de luz y fue sometido a cargas de fuego de hasta 1.3 MW. Mediante el empleo de los registros realizados en la campaña experimental se ha validado el modelo de incendio, el modelo térmico y el modelo mecánico. Con todo ello se ha puesto en evidencia la importancia del viento en la acción del fuego, la magnitud de los gradientes térmicos espaciales y la urgencia de desarrollar procedimientos simplificados que permitan la incorporación del fuego como acción en el ámbito de los puentes Las validaciones específicas de cada modelo han permitido además llegar a una serie de conclusiones de gran interés para la realización de futuras campañas experimentales en puentes a mayor escala. / [CAT] El disseny de ponts, a diferència del que passa amb el disseny d'edificis o amb el disseny de túnels ha deixat de banda la consideració de l'acció del foc. Aquest buit normatiu, combinat amb la gran repercussió econòmica i social de col·lapses de ponts com a conseqüència d'incendis, ha motivat un ràpid increment del nombre d'estudis relatius a l'enginyeria del foc del foc en l'àmbit dels ponts. Encara que l'acció del foc no resulta del tot desconeguda en l'àmbit de les estructures, sí que hi ha una sèrie de singularitats que impedeixen la transposició directa de recomanacions o de models de foc simplificats ja desenvolupats en altres camps que ja incorporen l'acció del foc al disseny. En aquest context, el treball que a continuació s'exposa part d'un incendi ocorregut a l'estat d'Alabama en 2002 i que va provocar la demolició d'un pont mixt de 37 metres de va, per plantejar i validar una metodologia que aborda el problema de forma numèrica mitjançant tres models acoplats seqüencialment: model d'incendis, model tèrmic i model mecànic Realitzada una validació a nivell general es descobreix que, encara que la configuració geomètrica final obtinguda s'ajusta en gran mesura a la realitat, la definició de l'incendi ha suposat un gran nombre d'hipòtesis. És per això que es decideix, en una segona part, realitzar una campanya experimental que permeta registrar la potència del foc, les temperatures del gas i de l'acer i les fletxes en un pont construït ad hoc al campus de la Universitat Politècnica de València. Aquest pont experimental presenta un va únic de 6 m de llum i va ser sotmès a càrregues de foc de fins a 1.3 MW. Mitjançant l'ús dels registres realitzats a la campanya experimental s'ha validat el model d'incendi, el model tèrmic i el model mecànic. Amb tot això s'ha posat en evidència la importància del vent en l'acció del foc, la magnitud dels gradients tèrmics espacials i la urgència de desenvolupar procediments simplificats que permetin la incorporació del foc com a acció en l'àmbit dels ponts Les validacions específiques de cada model han permès a més arribar a una sèrie de conclusions de gran interès per a la realització de futures campanyes experimentals en ponts a major escala. / [EN] To date, the fire action has been left aside in the bridge design despite this action has been widely considered in other structures such as building and tunnels. This regulatory vacuum, combined with the great economic and social impact of bridge collapses in recent times as a result of fires, has led to a rapid increase in the number of studies related to fire engineering in the field of bridges. Although the action of fire is not entirely unknown in the field of structures, there are a number of singularities that prevent the direct transposition of recommendations or simplified fire models from such fields. In this context, the study started by using a real fire which occurred in the state of Alabama in 2002 and led to the demolition of the 37-meter main span of a composite concrete and steel bridge to introduce and validate a methodology that numerically addresses the problem by uncoupling the problem in three different models: fire model, thermal model and mechanical model. Once the validation was accomplished at a general level, it was discovered that, although the geometrical data were quite adjusted to reality, the definition of the fire had involved a large number of hypotheses. That is why carrying out an experimental campaign to record the power of the fire, the gas and steel temperatures and the vertical deflections of a bridge built ad-hoc on the campus of the Universitat Politècnica de València became a priority. This 6-meter single span experimental bridge was subjected to fire loads of up to 1.3 MW. Through the use of the information recorded during the experimental campaign, the fire model, the thermal model and the mechanical model were validated. Moreover, the importance of wind in the action of fire, the magnitude of spatial thermal gradients and the urgency of developing simplified procedures which allow the consideration of fire as an action in the field of bridges were also highlighted. Last but not least, the validation of the different models allowed the author to include useful guidelines in order to define future experimental campaigns with more powerful fires and longer span bridges. / Alós Moya, J. (2018). Análisis de la respuesta frente al fuego de puentes mixtos multijácena [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/116625 / TESIS

’African Bamboo PLC’ has the vision to become the first and the leading bamboo-based floorboard producer in Africa with export markets in Europe and America. African alpine bamboo (Yushania alpina), common in the highlands of Ethiopia, was used to develop woven strand board (WSB) products. Research on thermal modification was part of the product development. Samples were mainly collected in Tetechia (6°33‘ 34‘‘ N 38°32‘25‘‘ W, 2,650-2,700 m a.s.l.), located in the Sidama region. Three culms each of two, three, four and five years of age were harvested. Samples were taken from the middle of each internode to determine the moisture content and density. Samples used to assess the effects of thermal modification were cut next to them. Further test specimens from different areas and other species such as the lowland bamboo (Oxytenanthera abyssinica) were also investigated. The thermal treatment was applied in a kiln with steam as an inert blanket to reduce oxidative processes. Eight modifications were performed at temperatures of 160 °C, 180 °C, 200 °C and 220 °C, at durations of three or five hours each. Mass loss, sorption behaviour, impact resistance, resistance to indentation and contents of chemical components were analysed for the modified and unmodified samples. Yushania alpina is a thin-walled bamboo with a maximum diameter of 6 cm, moisture content of up to 150 % and densities of between 0.5 g/cm² and 0.8 g/cm². Moisture content, diameter and wall thickness decreased from the bottom to the top of the culms, whereas density increased. Two year old bamboo had the lowest and three year the highest density. The mass loss followed an exponential trend, with about 2 % loss at 160 °C and 16 % at 220 °C. This mainly reflected the degradation of hemicellulose, which was fully removed at 220 °C. Extractive contents, at less than 5 %, fluctuated. Lignin amounted to 30 % and increased appreciably. Cellulose reached contents of about 45 % and decreased slightly at high temperatures. The chemical change, which was based more on the temperature than on the duration of treatment, influenced the sorption behaviour and mechanical properties most of all. The equilibrium moisture content was reduced by between 10 % to 40 %, depending on the climate and modification temperature chosen. This reduction stabilised between temperatures of 200 °C and 220 °C. The impact resistance of untreated bamboo was 3.8 J/cm², compared to only 1.4 J/cm² for modified samples. Resistance also differed between samples from the outer and inner part of the culm in the transverse section. The resistance to indentation declined also. Unmodified samples had 47 N/mm², compared to only 20 N/mm² for strongly modified samples. The results of the analysis and the experience gained indicate that temperatures between 180 °C and 200 °C, held for three hours, lead to the best results for woven strand board production using Ethiopian highland bamboo. / ’African Bamboo PLC’ setzt sich zum Ziel, als erstes Unternehmen Holzwerkstoffe aus Bambus nach Europa und Amerika zu exportieren. Afrikanischer Hochgebirgsbambus (Yushania alpina), welcher vor allem im Hochland von Äthiopien vorkommt, wurde dazu verwendet ”woven strand boards” (WSB) zu entwickeln. Untersuchungen zur thermischen Modifizierung waren dabei Bestandteil der Produktentwicklung. Die dafür notwendigen Bambusproben wurden hauptsächlich in Tetechia (6°33‘34‘‘ N 38°32‘25‘‘ W, 2650-2700 m ü. NN), einem Dorf in Sidama, entnommen. Es wurden dazu je drei Bambushalme der Altersklassen zwei, drei, vier und fünf Jahre geerntet. Proben für die Bestimmung von Holzfeuchte und Dichte wurden in der Mitte jedes Internodiums entnommen. Diese spielten als Referenzprobe eine große Rolle. Neben den Referenzprobekörpern wurden die jeweiligen Stücke für die thermische Behandlung heraus gesägt, wobei dies nach einer bestimmten Systematik erfolgte. Neben den Proben aus Tetechia wurden für die Untersuchungen zudem Proben aus anderen Gebieten und von einer anderen Art, dem Tieflandbambus (Oxytenanthera abyssinica), hinzugefügt. Die thermische Modifizierung erfolgte unter Wasserdampf, welcher oxidative Prozesse verhinderte. Insgesamt erfolgten acht Modifizierungen bei Temperaturen von 160 °C, 180 °C, 200 °C und 220 °C und einer jeweiligen Haltezeit von drei oder fünf Stunden. In Anbetracht der unbehandelten und behandelten Proben wurden der Masseverlust, die Bruchschlagarbeit, der Eindruckswiderstand und die chemische Zusammensetzung analysiert. Yushania alpina ist ein dünnwandiger Bambus mit Durchmessern bis zu 6 cm, Holzfeuchten bis 150 % und Dichten zwischen 0,5 g/cm² und 0,8 g/cm². Holzfeuchte, Durchmesser und Wandstärke verringerten sich mit der Halmhöhe, wobei die Dichte hingegen anstieg. Zweijähriger Bambus hatte die geringsten und dreijähriger Bambus die höchsten Dichten. Der Masseverlust folgte einem expontiellem Verlauf mit Werten von 2 % bei 160 °C und 16 % bei 220 °C. Er widerspiegelte den Abbau der Hemicellulose, welche bei 220 °C schon nicht mehr vorhanden war. Exktraktgehalte fluktuierten mit Werten unter 5 %. Der Ligningehalt lag bei ungefähr 30 % und stieg merklich an. Der Cellulosegehalt erreichte Werte von etwa 45 %, wobei die Cellulose bei höheren Temperaturen leicht abgebaut wurde. Die chemischen Veränderungen, welche maßgeblich von der angewandten Temperatur statt der Behandlungsdauer beeinflusst wurden, wirkten sich auf das Sorptionsverhalten und mechanische Eigenschaften aus. Je nach ausgesetztem Klima und erfolgter Modifikation wurde die Ausgleichsfeuchte der Proben um 10 % bis 40 % reduziert. Die Abnahme der Ausgleichsfeuchte stabilisierte sich im Temperaturbereich von 200 °C bis 220 °C. Die Bruchschlagarbeit des unbehandelten Bambus betrug 3,8 J/cm², die des behandelten nur 1,4 J/cm². Die Bruchschlagarbeit variierte unabhängig von der Modifikation zwischen dem inneren und äußeren Abschnittes innerhalb des Halmquerschnitts. Der Eindruckswiderstand nahm mit der thermischen Behandlung ebenfalls ab. Unbehandelte Proben hatten 47 N/mm², während die modifizierten Proben nur noch 20 N/mm² aufwiesen. Anhand der Ergebnisse und erworbenen Erfahrungen lies sich schlussfolgern, dass Temperaturen zwischen 180 °C und 200 °C bei einer Haltezeit von drei Stunden für die thermische Modifizierung von Äthiopischem Hochlandbambus in Bezug auf die Entwicklung von ”woven strand boards” empfehlenswert waren.