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Image-based Material EditingKhan, Erum 01 January 2006 (has links)
Photo editing software allows digital images to be blurred, warped or re-colored at the touch of a button. However, it is not currently possible to change the material appearance of an object except by painstakingly painting over the appropriate pixels. Here we present a set of methods for automatically replacing one material with another, completely different material, starting with only a single high dynamic range image, and an alpha matte specifying the object. Our approach exploits the fact that human vision is surprisingly tolerant of certain (sometimes enormous) physical inaccuracies. Thus, it may be possible to produce a visually compelling illusion of material transformations, without fully reconstructing the lighting or geometry. We employ a range of algorithms depending on the target material. First, an approximate depth map is derived from the image intensities using bilateral filters. The resulting surface normals are then used to map data onto the surface of the object to specify its material appearance. To create transparent or translucent materials, the mapped data are derived from the object's background. To create textured materials, the mapped data are a texture map. The surface normals can also be used to apply arbitrary bidirectional reflectance distribution functions to the surface, allowing us to simulate a wide range of materials. To facilitate the process of material editing, we generate the HDR image with a novel algorithm, that is robust against noise in individual exposures. This ensures that any noise, which would possibly have affected the shape recovery of the objects adversely, will be removed. We also present an algorithm to automatically generate alpha mattes. This algorithm requires as input two images--one where the object is in focus, and one where the background is in focus--and then automatically produces an approximate matte, indicating which pixels belong to the object. The result is then improved by a second algorithm to generate an accurate alpha matte, which can be given as input to our material editing techniques.
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The Search for Truth in the Digital Cinematic Space and Green Screen PerformancesDalton, Kade 01 January 2014 (has links)
With the advent of the blockbuster and its visual effects, film has grown to accept these effects and the technology behind them, namely green screen mattes, as cornerstones to the post-production process. The propensity of green screen in all types of productions, especially those involving actors and their performances, raises questions about the methodology and workflow behind its common practice. Using real-life environments and people to create narrative scenes, this project explores the utilization of matte backgrounds to inform the rehearsal and performance aspects of cinematic story-telling.
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Posibilidades artísticas de la imagen electrónica: el Chroma-keyFurió Vita, Dolores 13 October 2008 (has links)
Esforzados en reproducir una realidad más real que la propia realidad, hace años
que las tecnologías de la imagen emplean recursos cada vez más sofisticados con
los que elaborar y construir un lenguaje propio.
Resulta evidente el desarrollo en estos últimos treinta años de aplicaciones que
integran la técnica de chroma-key como un elemento más de su discurso. Este
recurso unido a los diferentes medios que lo emplean (Cine,
Televisión,Videoarte) supone una ampliación formal y expresiva del lenguaje
audiovisual.
Realizar un estudio sobre las diferentes aplicaciones que se le ha dado al uso
del chroma-key, intentando indagar detrás de la tecnología para ver las
necesidades que ha llevado a los autores a escogerla y qué uso hacen de ella y
cómo la integran en su discurso.
Hemos podido observar que existen diferencias manifiestas en la manera que
tienen de aplicar el Cine, la Televisión y el Videoarte estos recursos.
En el caso del Cine, nos interesa por su uso casi imperceptible del chroma-key
ya en la década de los sesenta. En la Televisión, observamos que en los últimos
veinte años se ha incorporado una nueva forma de representación: el decorado
virtual. El Videoarte desde su nacimiento (años sesenta) emplea el chroma-key
de una manera mucho más evidente, priorizando lo experimental que tiene el
medio frente a la ilusión de realidad propia del Cine. A partir de la
revolución informática en los noventa, observamos que muchas prácticas
artísticas se engloban dentro de lo que se denomina "interactivas". Aquí
también hemos encontrado algún ejemplo de utilización del chroma-key, que
permite esta interactividad entre los espectadores y la propia obra.
El objetivo de este estudio pretende un análisis formal de estas prácticas con
chroma-key, con el fin de establecer el uso expresivo que se deriva del empleo
de este recurso. / Furió Vita, D. (2008). Posibilidades artísticas de la imagen electrónica: el Chroma-key [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/3343
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Forêt en construction : Identité subjective d'un espace et recherche infinie de l'histoireMatte, Stéphanie 15 May 2024 (has links)
357641\u Ce texte se veut une excroissance théorique de mon exposition de fin de maîtrise Les météores présentée à la galerie du RAB –Lieu de diffusion et d’expérimentation de la maitrise en arts visuels en septembre 2019. J’y traite de ce qui me fascine, m’intrigue et me fait réfléchir en tant que réceptrice du monde extérieur et comment certains de ces éléments influencent mon travail d’émettrice, de créatrice.
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Le figure dell’invenzione negli inediti di Francesco Orlando : teoria, prospettive, applicazioni / Les figures de l'inventio dans les inédits de Francesco Orlando : théorie, perspectives et applications / Figures of Invention in Francesco Orlando’s Unpublished Works : theory, perspectives, implementationsSturli, Valentina 26 March 2019 (has links)
La thèse est née de la possibilité qui nous a été donnée d’analyser en exclusivité une partie des travaux inédits du critique italien et théoricien de la littérature, Francesco Orlando (1934- 2010), qui portent sur le thème de l’invention littéraire. Les perspectives contenues dans ces inédits, dûment contextualisées, sont autant de contributions au débat sur les instruments et les méthodes de recherche dans le domaine critico-thématique. Cette matière première, qui se compose de fiches de notes et d’un corpus consistant de leçons et d’interventions intégralement enregistrés à l’aide d’un appareil audio, permet de grands développements interprétatifs; elle se prête parfaitement à une recherche qui a pour point de départ le cadre de la proposition théorique et s’ouvre ensuite, dans une seconde phase de notre travail, à l’application des résultats à l’analyse comparée des œuvres de deux auteurs de la littérature italienne, Walter Siti, et française, Michel Houellebecq, que rapprochent d’importantes convergences aussi bien thématiques, formelles que du point de vue des figures utilisées. / The thesis considers previously unpublished works by Italian literary critic and theoretician Francesco Orlando (1934-2010) concerning the subject of literary invention. The ideas expressed in these works, with due contextualization, provide interesting contributions in the debate about methodologies and tools of research in the field of thematic criticism. The material I consider consists in notes and in the audio tapes of a consistent corpus of lectures and conferences, and leaves room for further interpretative developments. My research considers Orlando’s material as a theoretical frame for an analysis of Italian author Walter Siti and French author Michel Houellebecq, who share important common features both thematically and stylistically.
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Separação e pré-concentração de metais : uma transferência do meio aquoso para fase sólida ou líquidos orgânicosSouza, Rodrigo Papai de January 2018 (has links)
Orientadora: Profa. Dra. Ivanise Gaubeur / Tese (doutorado) - Universidade Federal do ABC, Programa de Pós-Graduação em Ciência e Tecnologia/Química, Santo André, 2018. / Dois novos procedimentos de extração que utilizam materiais
extratores não-convencionais são apresentados nesta tese. A utilização de
cera de parafina derretida como um extrator químico permitiu agregar as
principais vantagens da extração em fase líquida (homogeneidade do extrato,
curto tempo de extração e simplicidade de operação) na extração em fase
sólida, delineando um procedimento inovador. O papel matte foi outro
material estudado nesse trabalho e mostrou-se interessante como extrator
químico, especialmente pelo baixo custo dessa fase sólida. Como prova de
conceito, o íon metálico cobre (II) em solução aquosa foi utilizado para o
desenvolvimento da metodologia. O extrato resultante de ambos os
procedimentos de extração foi analisado diretamente por Espectrometria de
Emissão Óptica com Plasma Induzido por LASER (LIBS). Os fatores que
afetam a reação de complexação, a extração e a detecção do analito na fase
sólida foram otimizados num estudo univariado. Nas melhores condições
encontradas, foram construídas curvas de calibração numa faixa linear de
0,50 até 10,00 mg L-1 e alcançados limites inferiores de detecção de 0,12 mg
L-1 e 0,08 mg L-1 de cobre (II) em solução aquosa, para os procedimentos com
cera de parafina e com o papel matte, respectivamente. A precisão de ambos
os métodos propostos mostrou-se inferior a 5% e a exatidão foi avaliada por:
(i) análise de material de referência certificado de soro sanguíneo humano;
(ii) ensaios de adição e recuperação do analito em amostras líquidas de
composição química distintas (água mineral, água do mar, água de torneira,
cachaça, refrigerante e urina humana) e (iii) comparação dos resultados
obtidos com os fornecidos pelo método de Espectrometria de Absorção
Atômica com Forno de Grafite. Ambos os procedimentos se destacaram pela:
(i) elevada eficiência no processo de extração (>94%); (ii) facilidade de
execução; (iii) baixo custo e inocuidade dos extratores; (iv)
microhomogeneidade das fases sólidas obtidas; (v) possibilidade de préconcentração
de íons metálicos e (vi) superação das dificuldades intrínsecas
na análise de líquido por LIBS. / Two new extraction procedures that use non-conventional extractant
materials are described in this thesis. The use of melted paraffin wax as a
chemical extractant allowed to aggregate the main advantages of the liquid
phase extraction (homogeneity of the extract, short extraction time and
simplicity of operation) in solid phase extraction, delineating an innovative
procedure. The matte paper was another material studied in this work and
was interesting as a chemical extractant, especially for the low cost of this
solid phase. As proof of concept, the copper (II) ion in aqueous solution was
applied for the development of the methodology. The extract obtained from
both extraction procedures was analyzed directly by LASER-Induced
Breakdown Spectroscopy (LIBS). The parameters that affecting the
complexation reaction, extraction and analyte detection in the solid phase
were optimized in a univariate approach. Under the best conditions,
calibration curves were constructed in a linear range of 0.50 to 10.00 mg L-1
and lower detection limits of 0.12 mg L-1 and 0.08 mg L-1 of copper (II) in
aqueous solution were obtained, for the procedures with paraffin wax and
matte paper, respectively. The precision of both methods was less than 5%
and accuracy was assessed by: (i) analysis of certified reference material of
human blood serum; (ii) spike and recovery analyte in liquid samples of
different chemical compositions (seawater, tap water, mineral water,
cachaça, soft drink and human urine) and (iii) comparison of the results
obtained with those provided by the Graphite Furnace Atomic Absorption
Spectrometry. Both procedures were highlighted by: (i) high efficiency in the
extraction process (> 94%); (ii) ease of execution; (iii) low cost and safety of
extractants; (iv) microhomogeneity of the solid phases obtained; (v) the ability
of preconcentration metal ions and (vi) overcoming the intrinsic drawbacks
in liquid analysis by LIBS.
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Effect of lime additions and bulk chromium content on chromium deportment in smelter matte-slag systemsDu Preez, Rudolph C. 03 1900 (has links)
Thesis (MScEng) –Stellenbosch University, 2010 / ENGLISH ABSTRACT: More mining houses are turning their attention to the processing of ore mined
from the UG2 reef. This is mainly due to the depletion of the Merensky reef
or the low availability of ore from the Platreef. With the higher UG2 ore
concentration in the process feed, companies experience more problems with
the processing of the ore due to its high chrome content. Although there are
various possible solutions to the problems experienced in the processing of UG2
ore, very little of thise solutions are actually implemented in the industry.
When smelting chrome-bearing ore, the chrome can go to any of three
phases: matte phase, spinel phase or glass phase. If it reports to the furnace
matte phase it can lead to problems in the down stream processing. When
chrome forms part of the spinel phase it forms a solid, refractory-like material
which, to an extent, is an unwanted material inside the furnace. Lastly the
chrome can report to the glass phase (liquid phase) which is the more desireable
phase to which chrome should report to since it will have little or no impact
on downstream processing.
There were four main objectives for this research project namely to conduct
a literature review to understand the problem of chrome in the smelting
process, to do an experimental simulation of a matte and slag phase in one
crucible, to interpret the experimental results and compare the experimental
results to thermodynamic predictions obtained using FactSageTM.
From literature the following aspects were found to be important:
Silica structures
Research has shown that silica incorporates different metal ions into its
structures. When the metal ions are incorporated into the silica structures
they are seen as part of the glass phase. By incorporating cations such as
chromium into the silica structure the structure is able to maintain its neutral
electrical charge.
Basicity of slag
Oxides once melted will either donate or accept oxide ions. The group of
oxides that are in excess will determine whether that specific slag is acidic or
non acidic. This is important to our study since the basicity can determine
the stability of the spinel phase. Partial pressures
The partial pressure of the system is important since it forms part of the
equilibrium constant calculations - meaning that partial pressures determine
the stability of certain species. Currently different arguments exist as to how
the sulphur pressure inside a molten bath is maintained. What is important,
however, is that for the system in this research project a log oxygen partial
pressure of -8 and a log sulphur partial pressure of -3.5 was chosen. These
values were based on previous research done on PGM and copper smelting
processes.
Chrome deportment
Previous research on chrome deportment shows a relationship between temperature
and the amount of chromium dissolving into the glass phase as well as
an increased chromium(II)oxide solubility (when compared to chromium(III)oxide)
in a silicate melt. Regarding slag chemistry and chrome deportment very little
work has been published for the system found in the PGM industry but it is
mentioned that by adjusting certain slag additives (alumina, lime and silica)
the chrome deportment can be manipulated.
The scope of this project was to investigate the effect of chromium, lime
and silica on chrome deportment. More specifically, the effect of lime. The
reason being that lime was originally added as 10%wt of the feed stream in the
processing of Merensky ore to act as a fluxing agent. With the new furnace
design and higher power densities the slag are maintained at 200oC to 350oC
higher than when Merensky ore was smelted. With these higher slag temperatures
fluxing agents will play a smaller role meaning that lime additions
become less important. Literature studies also showed that additional lime in
a slag system can stabilize the spinel structure (which is an unwanted phase).
Removing lime would be advantageous out of a chrome presepective as well as
an economic point of view.
The research was conducted in three sections namely the determination of
the time required for this particular system to reach equilibrium, the investigation
of different additives on chrome deportment using a controlled atmosphere
and synthetic slags and, lastly, a comparison of the experimental results obtained
to thermodynamic predictions.
For the equilibration studies reaction time periods of 4,7,11 and 16 hours
were used. From the results it was found that the alumina crucible dissolved
into the glass phase continually. This indicated that equilibrium was not
reached. However, a reaction time, rather than an equilibrium time, was chosen
where the species and phases had enough time to react. This was based
on literature, on observations of species diffusing between the matte and slag
phase as well as on two-point analysis (diffusion gradients). A reaction time
of nine hours was chosen With the reaction time fixed, the effect of different slag additives on chrome
deportment was investigated. For the addition of chrome it was seen that an
1.5%wt increase in the starting material increased the chrome content of the
slag phase by 0.025%wt. For the same increase in chromium in the starting
materials the chrome content of the spinel phase increased by 2.1% indicating
that chromium has a tendency to report to the spinel phase. The increase
in chromium had a minor effect on the chrome content of the matte phase,
however, since the chrome content only increased from 0.025%wt to 0.028%wt.
Plotting the results showed that increasing the lime in the starting material
decreases the chromium content in the glass phase. For the 39%wt silica system
the chromium content in the glass phase decreased from 0.75%wt to 0.46%wt
for an increase in the lime content from 1.7%wt to 7.3%wt. The same trend was
seen for the 33%wt silica system. For the spinel phase an increase of 1.27%wt
was seen when the lime content of the starting materials was increased from
1.7%wt to 10.1%wt for a 33%wt silica system. The same increase in lime
increased the chrome content of the matte phase from 0.03%wt to 0.06%wt for
a 33%wt silica system.
Silica also proved to affect chrome deportment. Increasing the silica content
of the starting materials from 25%wt to 39%wt increased the amount of
chromium in the glass phase from 0%wt to 0.46%wt for a 10%wt lime system.
The same effect is seen for a lower lime content except that more chromium
were incorporated into the silica structure. A silica increase from 32.4%wt
to 39%wt resulted in a chromium decrease from 5.2%wt to 0% in the spinel
phase for a 10%wt lime system. The same trend was seen for the 1.5%wt lime
system. An increase in the silica levels lead to an increase in the chrome level
of the matte phase. When silica is increased from 32%wt to 39%wt the chrome
content of the matte phase increased from 0.06%wt to 0.07%wt.
The last part of the research project entailed the comparison of the trends
observed with the experimental results to trends obtained from thermodynamic
predictions. FactSageTM is a program that uses model equations to predict
the Gibbs free energies for different phases. The program is therefore also able
to predict the amount of different phases present at equilibrium. This is called
thermodynamic ”optimization”.
In section 6 trends that were observed from FactSageTM results are compared
to the trends found in the experimental results. It is important to note
that it is only trends that are evaluated and not actual values since FactSageTM
calculations are for a system that is at equilibrium and (as explained above)
this system is not at complete equilibrium. The comparison however was good.
Several trends found in the experimental results were confirmed by the results
from FactSageTM. These included the relationships of chromium fed versus
chromium spinel, lime fed versus chromium spinel, lime fed versus chromium
in glass, silica fed versus chromium in glass, silica fed versus chromium in
spinel and silica fed versus chromium in matte. To conclude, slag additions can be used to manipulate chrome deportment
to an extent. Secondly, FactSageTM can be used for thermodynamic predictions
but a proper understanding as well as some form of validation of the
specific system investigated is still needed.
Due to time constraints and the difficulty of experimentally simulating this
multi-phase system in the lab, only a few parameters were investigated. In
order to obtain a more complete understanding of the system the effect of
partial pressures and temperature should also be investigated.
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Leaching of Ni-Cu-Fe-S Peirce Smith converter matte : effects of the Fe-endpoint and leaching conditions on kinetics and mineralogy.Van Schalkwyk, R. F. 12 1900 (has links)
Thesis (MScEng)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: In a first stage atmospheric leach at the Lonmin Marikana base metals refinery,
nickel-copper-iron-sulphur Peirce Smith converter matte is leached in recycled
electrolyte from the electrowinning section. The electrolyte contains sulphuric acid,
copper and nickel sulphates, and a small amount of iron sulphate. The converter
matte contains mostly nickel, copper and sulphur (typically 48 %, 28 % and 23 %,
respectively), but also minor amounts (<5 %) iron and cobalt. The matte also
contains platinum group elements (PGEs) and other precious metals totalling 0.2 –
0.7 % (platinum, palladium, iridium, rhodium, ruthenium, osmium and some gold).
The predominant mineral phases are heazlewoodite, chalcocite and a nickel-copper
alloy phase, as well as some entrained slag and spinel minerals. The purpose of the
first stage leach is to extract nickel, while simultaneously precipitating copper and
PGEs contained in the recycled electrolyte. Nickel, cobalt and iron are leached by
acid and oxygen. Copper is precipitated by a redox reaction in which copper ions
oxidise nickel from the matte. The purpose of this study was to determine the effects
of key variables on the performance of the first stage leach (specifically on the
removal of PGEs and copper from solution and the overall extraction of nickel) and
to improve fundamental understanding of these effects.
Batch leaching tests were carried out to investigate the effects of the following
factors: availability of oxygen, initial acid concentration, initial copper concentration,
iron endpoint (iron content of the matte), solids/liquid ratio and stirring rate. Liquid
samples were analysed with Atomic Absorption Spectroscopy (AA) to determine
leaching kinetics. Characterisation of solid samples from leach tests by quantitative
X-Ray diffraction (XRD) and scanning electron microscopy with an energy dispersive
system (SEM-EDS) helped to improve understanding of the leaching mechanism.
The oxidative leaching mechanism entails an initial period in which the alloy phase is
leached by acid and oxygen, while copper reacts with the nickel-copper-alloy and
heazlewoodite phases (which react galvanically with each other) to form a chalcocite
precipitate. In a second reaction period, heazlewoodite was transformed to millerite
by acid leaching and the particle structure became more porous. The rate of copper precipitation and nickel extraction were faster during the second reaction period than
the first reaction period. Some copper leaching occurred once the leachable nickel
(60 – 70 %) had been dissolved, provided that the solution was strongly acidic (pH < 2).
The non-oxidative leaching mechanism entails a galvanic interaction, between the
nickel-copper-alloy and heazlewoodite phases, in which nickel is leached from both
phases and copper is precipitated as chalcocite. Leaching by acid was negligible in
most non-oxidative tests. An initial fast period of copper precipitation was followed
by a second slower period. The decrease in reaction rate can probably be linked to
the decreasing availability of the nickel-copper-alloy phase. During non-oxidative
leaching, the particle structure remained mostly intact. Copper precipitation kinetics
under non-oxidative conditions was found to be slower than under oxidative
conditions. The faster copper precipitation kinetics under oxidative conditions is
most likely caused by an increase in porosity and reaction area as nickel is leached
from the matte by acid and oxygen.
The initial acid concentration, solids/liquid ratio and Fe-endpoint were the most
important factors determining reaction kinetics under oxidative conditions. Low initial
acid concentrations (37 g/L) and a high solids/liquid ratio improved the extent of
copper precipitation. Nickel extraction was enhanced by low solids/liquid ratios and
high initial acid concentrations (74 g/L). Nickel extraction was significantly less
(56 % less in one instance) when leaching high iron mattes (5.7 % Fe) rather than
low iron mattes (< 1 % Fe). Copper precipitation was initially faster when leaching a
high iron matte, but slower nickel leaching from high iron mattes led to an excess of
available acid, which resulted in copper being leached. The results suggest that high
iron mattes will lead to poor copper and PGE precipitation in the first stage leach and
also to lower nickel extractions. Consequently, Peirce Smith converting at the plant
must be carefully controlled to avoid high iron mattes.
Under non-oxidative conditions, the solids/liquid ratio and Fe-endpoint were the most
important factors. The rate of copper precipitation was faster when a high iron matte
was leached, so that a higher percentage copper was precipitated and more nickel
was extracted from the matte. / AFRIKAANSE OPSOMMING: As ‘n eerste stap in die Lonmin Marikana basis-metale veredelingsaanleg word
nikkel-koper-yster-swawel Peirce-Smith-converter-mat geloog in elektroliet wat
hersirkuleer word vanaf die aanleg se koper-elektroplaterings-afdeling. Die loging
word by atmosferiese druk uitgevoer. Die elektroliet bevat swawelsuur, koper- en
nikkel-sulfate en ‘n klein hoeveelheid ystersulfaat. Die mat bevat hoofsaaklik nikkel,
koper en swawel (tipies 48 %, 28 % en 23 %), maar ook klein hoeveelhede (< 5 %)
yster en kobalt. Verder maak Platinum Groep Elemente (PGE’s) en ander
waardevolle metale (platinum, palladium, iridium, rhodium, ruthenium, osmium en
goud) 0.2 % tot 0.7 % van die massa van die mat uit. In terme van minerale bestaan
die materiaal hoofsaaklik uit heazlewoodite, chalcocite en ‘n nikkel-koper allooi fase,
asook slak en spinel minerale, wat tydens Peirce-Smith-converting weens
meesleuring in die mat rapporteer. Die doel van die eerste stadium loog is om nikkel
op te los, terwyl koper en PGE’s wat in die elektroliet voorkom presipiteer moet word.
Nikkel, kobalt en koper word geloog in reaksies met suurstof en swawelsuur. Koper
word presipiteer deur middel van ‘n redoks reaksie waarin koper-ione nikkel in die
mat oksideer. Die doel van hierdie studie was om die effekte van
sleutelveranderlikes op die proses te bepaal (spesifiek hoe nikkel-loging en koper
presipitasie affekteer word) en om fundamentele begrip van die veranderlikes en hul
effekte te verkry.
Lot loogtoetse is uitgevoer op ‘n laboratorium-skaal en die effekte van die volgende
faktore is ondersoek: beskibaarheid van suurstof, begin suurkonsentrasie, yster
eindpunt (die ysterinhoud van die mat), vastestof/vloeistof verhouding en die
roertempo. Vloeistof monsters geneem tydens loogtoetse is geanaliseer met behulp
van Atoom Absorpsie Spektroskopie (AA) om kinetika te bepaal. Vastestof monsters
is ook geneem tydens loogtoetse en kwantitatiewe X-straal diffraksie (XRD), asook
skanderings-elektron-mikroskopie met ‘n energie dispersie sisteem (SEM-EDS) is
gebruik om die materiaal te karakteriseer en die logingsmeganisme te verduidelik.
Die oksidatiewe logingsmeganisme behels ‘n aanvanklike periode waartydens die
allooi fase geloog word deur suur en suurstof, terwyl koper presipiteer om chalcocite te vorm as gevolg van ‘n reaksie waarin galvanise interaksie tussen die nikkel-koperallooi
en heazlewoodite fases ‘n belangrike rol speel. In ‘n tweede reaksie periode is
heazlewoodite geloog deur suur om millerite te vorm. Tydens hierdie tweede fase
het die partikel struktuur meer porieus geword. Die tempo van koper presipitasie en
nikkel loging was vinniger tydens die tweede reaksie periode as tydens die eerste.
Koper is geloog indien die oplossing baie suur was (pH < 2) en die loogbare nikkel
(60 – 70 %) reeds opgelos het.
Die nie-oksidatiewe logingsmeganisme behels galvaniese interaksie tussen die
nikkel-koper-allooi en heazlewoodite fases, wat lei tot koper presipitasie as
chalcocite. Loging deur swawelsuur was onbeduidend. ‘n Aanvanklike vinnige
periode van koper presipitasie tydens nie-oksidatiewe toetse is gevolg deur ‘n
tweede stadiger periode. Die afname in reaksietempo kan waarskynlik verklaar word
deur die afnemende beskikbaarheid van die nikkel-koper-allooi fase. Tydens nieoksidatiewe
loging het die partikel struktuur redelik onveranderd gebly. Koper
presipitasie kinetika in nie-oksidatiewe toetse was stadiger as in oksidatiewe toetse.
Die belangrikste faktore wat kinetika in oksidatiewe toetse beïnvloed het was die
suurkonsentrasie, vastestof/vloeistof verhouding en die yster-eindpunt. Lae beginsuurkonsentrasies
(37 g/L) en ‘n hoë vastestof/vloeistof verhouding het gelei daartoe
dat meer koper uit die elektroliet herwin is. Nikkel ekstraksie was hoër indien die
vastestof/vloeistof verhouding laag was en die begin suurkonsentrasie hoog (74 g/L).
Nikkel ekstraksie was beduidend laer (56 % laer in een geval) wanneer hoë-yster
mat (5.7 % Fe) geloog is, eerder as lae yster mat (< 1 % Fe). Wanneer ‘n hoë yster
mat geloog is, was koper presipitasie aanvanklik vinniger, maar weens stadige
nikkel-ekstraksie-tempos was ‘n oormaat van suur beskikbaar sodat koper uiteindelik
geloog is. PGE presipitasie is ook nadelig beïnvloed wanneer koper geloog is en
veral tydens toetse met hoë yster mat.
Die mees belangrike faktore wat nie-oksidatiewe loging beïnvloed het was die
vastestof/vloeistof verhouding en die yster-eindpunt. Die tempo van koper
presipitasie was vinniger in toetse met ‘n hoë yster mat, sodat ‘n hoër persentasie
koper presipiteer het en meer nikkel opgelos het wanneer ‘n hoë yster mat geloog is.
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Rééclairage par génération de cartes de normales en composition vidéo numériqueBergeron, Nicolas January 2006 (has links)
Mémoire numérisé par la Direction des bibliothèques de l'Université de Montréal.
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Studium možností zmatňování povrchu pro účely 3D skenování / Study of surface coating possibilities for 3D scanning purposesFranke, Jakub January 2020 (has links)
This diploma thesis deals with matte coatings for 3D scanning purposes. The coatings are made with spray gun which uses a vibrating membrane atomizer and air blow gun. A suspension of titanium dioxide and alcohol is used as a coating material. This thesis describes the effect of the spray gun process parameters on the deposited coatings. These include, for example type of the coating suspension or setup of the blow gun. Phase Doppler Anemometry was used to measure spray characteristics. Deposited coatings were measured with profilometer and scanned with 3D scanner to study their thickness and effect on the results of 3D reconstruction. The result of this work was the coating with thickness below 1 µm with good optical properties for 3D scanning purposes. Standard deviation of the captured point cloud from the reference plane was below 0.0011 mm.
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