The condition of no relative velocity of fluid past solid is termed as ‘no-slip boundary condition’. This condition is a general observation in fluid mechanics. However, several research groups have recently reported slip of water for surfaces with water repelling chemistry (referred to as hydrophobic surfaces). The effect has been attributed to disruption of H-bonding network of water molecules at such surfaces and resulting nucleation of dissolved gases and even reduced water density locally in absence of dissolved air. Slip of water on hydrophobic surfaces has been demonstrated to get amplified by high degree of roughness and patterning. Trapping of air in the surface asperities has been cited as the possible reason. The present work focuses on the study of effect of surface chemistry and roughness on flow behavior close to solid surfaces. Superhydrophobic surfaces have been generated by novel methods and wet-etching has been used to generate well-defined patterns on silicon surfaces. For flow characterisation, a micrometre resolution Particle Image Velocimetry (micro-PIV) facility has been developed and flow measurements have been carried out with a spatial resolution of less than 4 µm. It has been found from the experiments that flow of water on smooth surfaces, with or without chemical modification, conforms to the no-slip within the resolution limits of experiments. Deviation is observed in case of rough and patterned hydrophobic surfaces, possibly because of trapped air in asperities. Total Internal Reflection experiments, used to visualise the air pockets, confirmed the trapping of air at asperities. Diffusion of air out of the crevices seems to be the limiting factor for the utility of these surfaces in under-water applications.

The southern Patagonian Andes record the Late Cretaceous closure and inversion of the Late Jurassic – Early Cretaceous Rocas Verdes marginal basin, subsequent development of the Patagonian retroarc fold-thrust belt and the Neogene to present tectonic superposition of a left-lateral strike-slip plate margin defined by the Magallanes- Fagnano fault zone. In this dissertation, I present new geologic maps, cross sections and detailed macro- and microscopic structural analyses that describe the geometry and kinematic evolution of the fold-thrust belt and superposed strike-slip deformation over ~200 km along-strike between 53° and 55° S latitude. Results are discussed in the context of the regional tectonic development of the southernmost Andes and are relevant to the understanding of important tectonic processes including the development of a retroarc fold-thrust belt, the formation of a basal décollement below and toward the hinterland of a fold-thrust belt and the spatial distribution of deformation along a strike-slip plate margin. New maps and balanced cross-sections of the Patagonian fold-thrust belt show that it developed during two main phases of Late Cretaceous to Paleogene shortening that were partly controlled by the antecedent geology and mechanical stratigraphy of the Rocas Verdes basin. During the Late Cretaceous, a thin-skinned thrust belt developed above a décollement that formed first in relatively weak shale deposits of the Rocas Verdes basin and later deepened to <1 km below the basement-cover contact. Ramps that cut mechanically rigid volcanic rocks of the marginal basin link the two décollements. Basement-involved reverse faults that cut the early décollements and probably reactivate Jurassic normal faults reflect Paleogene shortening. Shortening estimates increase northwest to southeast from 26 to 37% over 100 km along-strike and are consistent with regional models of the fold-thrust belt. Structural data, kinematic analyses, and microstructural observations from the lower décollement show that it is defined by transposition of several generations of northeast-vergent noncylindrical folds, shear bands, and a quartz stretching lineation that are kinematically compatible with first-generation structures of the fold-thrust belt. Quartz microstructural data from the décollement are consistent with deformation temperatures that decrease from ~500-650° C to ~400-550° C over ~75 km in the transport direction, indicating that the décollement dipped shallowly (~6°) toward the hinterland. The décollement decoupled the underthrust continental margin from the fold- thrust belt and exemplifies the kinematic relationship between shortening that occurs coevally in a retroarc fold thrust-belt and its polydeformed metamorphic ‘basement’. Fault kinematic data and crosscutting relationships show kinematic and temporal relationships between populations of thrust, strike-slip and normal faults that occur in the study area. Thrust faults form an internally compatible population that shows subhorizontal northeast-trending shortening of the fold-thrust belt and is kinematically distinct from populations of normal and strike-slip faults. Both strike-slip and normal faults crosscut the fold-thrust belt, are localized near segments of the Magallanes- Fagnano fault zone, have mutually compatible kinematic axes and are interpreted to be coeval. Strike-slip faults form Riedel and P-shear geometries that are compatible with left-lateral slip on the Magallanes-Fagnano fault-zone. Strike-slip and normal faults occur in a releasing step-over between two overlapping left-lateral, left-stepping segments of the Magallanes fault zone and record a tectonic event defined by sinistral transtension that probably reflects changing plate dynamics associated with the opening of the Drake Passage during the Early Miocene. / text

The Valle de Catacamas forms a major basin along the central portion of the Guayape fault, the most prominent tectonic element of the Chortís block. The Guayape fault extends 290 km southwest from the Caribbean coast to the region of El Paraíso, Honduras, and may continue to the Pacific coast along a related prominent topographic feature, the Choluteca linear. Basins presently forming along the Guayape fault indicate that the fault is currently experiencing right-slip. The active features of the Valle de Catacamas displace older folds and reverse faults which apparently formed during an earlier period of sinistral shear. Thus, the Guayape fault has undergone at least two phases of movement, post-Cenomanian left-slip followed by the present right-slip. The geology of the valley suggests multiple stages of evolution. These include at least one period of thrust and reverse faulting, possibly associated with sinistral shear along the Guayape fault, and a recent episode of normal faulting associated with dextral shear on the Guayape fault. Thrusting of basement rocks over Jurassic strata on the south side of the valley was the earliest deformation to affect Mesozoic or Cenozoic rocks. The event can only be dated as post-Jurassic in age. The Cretaceous rocks of the Sierra de Agalta on the north side of the Valle de Catacamas are much more strongly deformed than similar rocks in central Honduras. In this range, the Aptian-Albian Atima Limestone commonly has a pervasive pressure solution cleavage which has not been reported from other locations on the Chortís block. The cleavage is apparently axial planar to the folds. The age of this deformation is constrained only as post-Cenomanian. SIR data indicate that these folds are deflected in sinistral shear near the Guayape fault. In addition, a major structural contact has a large left-lateral separation. The folds in the Sierra de Agalta are cut by the range-bounding normal fault of the Sierra de Agalta. Younger rocks are placed on older rocks by this normal fault, and fault slip data from small fault planes in the footwall block indicate normal faulting. The N 65° E strike of this normal fault, the N 35° E strike of the Guayape fault, and stress orientations inferred from fault slip data indicate that the present movement on the Guayape fault is right-slip. Fault slip data from the Guayape fault zone is heterogeneous as would be expected if two stage slip has occurred. / text

Ένα από τα κύρια προβλήματα που συναντώνται σε κτίρια ή γέφυρες που έχουν κατασκευασθεί πριν από το 1980, είναι η μειωμένη καμπτική αντοχή και πλαστιμότητα, το οποίο αρκετά συχνά οφείλεται στην έλλειψη περίσφιξης και στη παρουσία κοντών αναμονών που είχαν οι κατασκευές αυτές. Ο κύριος σκοπός της παρούσας διατριβής είναι να παρουσιάσει και να αξιολογήσει πέντε από τα διαθέσιμα στη βιβλιογραφία αναλυτικά μοντέλα προσδιορισμού του απαιτούμενου πάχους του εξωτερικά εφαρμοζόμενου μανδύα για την αποφυγή της αστοχίας των ματιζομένων οπλισμών των υποστυλωμάτων συμπεριλαμβανομένου και του αντίστοιχου μοντέλου το οποίο δίνεται στο Σχέδιο 1 και Σχέδιο 2 του ΚΑΝΕΠΕ. Τα αναλυτικά μοντέλα αξιολογούνται μέσω πειραματικών αποτελεσμάτων από τη βιβλιογραφία. Η αξιολόγηση γίνεται σε δύο επίπεδα. Στο πρώτο επίπεδο αξιολογείται η αξιοπιστία πρόβλεψης του απαιτούμενου πάχους του υλικού ενίσχυσης –χρησιμοποιώντας τις μέσες τιμές των υλικών- ενώ στο δεύτερο επίπεδο εξετάζεται η αντίστοιχη καταλληλότητα κάθε προσομοιώματος για το σχεδιασμό –χρησιμοποιώντας τις αντίστοιχες τιμές σχεδιασμού των υλικών-. Τροποποιημένες εξισώσεις βασιζόμενες στο προσομοίωμα του ΚΑΝΕΠΕ παρουσιάζονται. Η χρήση των τροποποιημένων εξισώσεων ελέγχεται μέσω διαθέσιμων πειραματικών αποτελεσμάτων και προκύπτει ικανοποιητική σύγκλιση με αυτά. / Reinforced concrete frames or bridges constructed in the early 80s or before, were usually designed and detailed to resist lower lateral forces than those required today. Building columns were commonly designed for compression only and as a result they do not have the adequate lateral strength to resist the imposed earthquake loads. One of the main deficiencies in these older structures is the limited flexural strength and ductility often due to short and lightly confined lap splices. The main aim of this thesis is to present and evaluate five of the proposed analytical models in order to rehabilitate reinforced concrete columns with short lap splices by external confinement, including and the confinement model given by the draft version of the Greek Retrofitting Code (GRECO). The above analytical models are validated against experimental results. The validation is performed in two levels. In the first level, the reliability of the prediction for the required jacket thickness given by the models, is examined, by using the average values of the materials. In the second level, the propriety for the design of each model is examined by using the design values of the materials. A modified equation based on the model given by GRECO is presented as well. By using the proposed modified equation a satisfactory agreement with the experimental results was accomplished.

The modern trends in lubrication aim at reducing the oil quantity in tribological applications. As a consequence, the film thickness in the contact zone decreases significantly and can reach the order of magnitude of a few nanometres. Hence, the surface separation is ensured by very few lubricant molecules. Atomistic simulations based on the Molecular Dynamics method are used to analyze the local behavior of these severely confined films. A particular attention is paid to the occurrence of wall slip: predictive models and analytical laws are formulated to quantify and predict this phenomenon as a function of the surface-lubricant pair or the local operating conditions in a contact interface. Then, the coupling between Molecular Dynamics simulations and macroscopic models is explored. The classical lubrication theory is modified to include slip effects characterized previously. This approach is employed to study an entire contact featuring a nano-confined lubricant in its center, showing a severe modification of the film thickness and friction. Finally, the lubricant quantity reduction is pushed to the limits up to the occurrence of local film breakdown and direct surface contact. In this scenario, atomistic simulations allow to understand the relationship between the configuration of the last fluid molecules in the contact and the local tribological behavior.

La dynamique granulaire amenant à l'état critique présente un intérêt dans la compréhension de la déstabilisation menant à l'avalanche. Son étude permet d'avoir des pistes de compréhension sur des mécanismes plus complexes telles les catastrophes géophysiques (séismes, glissements de terrain, éboulements). Ainsi, lorsqu'un milieu granulaire tridimensionnel sous gravité est quasi-statiquement incliné, des précurseurs sont observés à partir d'une dizaine de degrés avant l'avalanche. Ces précurseurs correspondent à des réarrangements collectifs de grains observés à la surface qui apparaissent pseudo-périodiquement avec l'angle d'inclinaison. Cette thèse fournit une caractérisation expérimentale des précurseurs détectés à la surface par méthode optique et dans le volume par méthodes acoustiques (linéaire et non linéaire). Tout d'abord, de bonnes corrélations sont trouvées entre les réarrangements à la surface et dans le volume. Dans un second temps, l'étude est poursuivie avec une liste non exhaustive de paramètres influant sur les propriétés des précurseurs. L'état de surface des grains est crucial pour la dynamique des précurseurs. Puis, une tentative de description de la déstabilisation est réalisée avec notamment la mesure de la variation des paramètres élastiques. Les précurseurs d'avalanches correspondent à des pertes successives de rigidité du système, suivies du renforcement de ce dernier.

In 2004, students at the University of Guelph designed and constructed an all-wheel-drive Formula SAE vehicle for competition. It utilized an electronically-controlled, hydraulic-actuated limited slip center coupling from Haldex Traction Ltd, to transfer torque to the front wheels. The initial control system design was not comprehensively conceived, so there was a need for a thoroughly developed control system for the all-wheel-drive actuator augmented with commonly available sensors and a low cost controller. This thesis presents a novel all-wheel-drive active torque transfer controller using a neural network estimated slip angle velocity. This controller specifically targets a racing vehicle by allowing rapid direction changes for maneuverability but damping slip angle changes for increased controllability. The slip angle velocity estimate was able to track the actual simulated value it was trained against with excellent phase matching but with some offsets and phantom spikes. Using the estimated slip angle velocity for control realized smooth control output, excellent stability, and a fast turn-in yaw response on par with rear-wheel-drive configurations. A full vehicle simulation with software-in-the-loop testing for control software was also developed to aid the system design process and avoid vehicle run time for tuning. This design flow should significantly decrease development time for controls algorithm work and help increase innovation within the team.

The upper 8-12 km of the Alpine Fault, South Island, New Zealand, accommodates relative Australia-Pacific plate boundary motion through coseismic slip accompanying large-magnitude earthquakes. Earthquakes occur due to frictional instabilities on faults, and their nucleation, propagation, and arrest is governed by tectonic forces and fault zone properties. A multi-disciplinary dataset is presented on the lithological, microstructural, mineralogical, geochemical, hydrological, and frictional properties of Alpine Fault rocks collected from natural fault exposures and from Deep Fault Drilling Project (DFDP-1) drillcore. Results quantify and describe the physical and chemical processes that affect seismicity and slip accommodation. Oblique dextral motion on the central Alpine Fault in the last 5-8 Myr has exhumed garnet-oligoclase facies mylonitic fault rocks from depths of up to 35 km. During the last phase of exhumation, brittle deformation of these mylonites, accompanied by fluid infiltration, has resulted in complex mineralogical and lithological variations in the fault rocks. Petrophysical, geochemical, and lithological data reveal that the fault comprises a central alteration zone of protocataclasites, foliated and nonfoliated cataclasites, and fault gouges bounded by a damage zone containing fractured ultramylonites and mylonites. Mineralogical results suggest that at least two stages of chemical alteration have occurred. At, or near, the brittle-to-ductile transition (c. >320 °C), metasomatic alteration reactions resulted in plagioclase and feldspar replacement by muscovite and sausserite, and biotite (phlogopite), hornblende (actinolite) and/or epidote replacement by chlorite (clinochlore). At lower temperatures (c. >120°C), primary minerals were altered to kaolinite, smectite and pyrite, or kaolinite, smectite, Fe-hydroxide (goethite) and carbonate, depending on redox conditions. Ultramylonites, nonfoliated and foliated cataclasites, and gouges in the hanging wall and footwall contain the high-temperature phyllosilicates chlorite and white mica (muscovite/illite). Brown principal slip zone (PSZ) gouges contain the low-temperature phyllosilicates kaolinite and smecite, and goethite and carbonate cements. The frictional and hydrological properties of saturated intact samples of central Alpine Fault surface-outcrop gouges and cataclasites were investigated in room temperature experiments conducted at 30-33 MPa effective normal stress (σn') using a double-direct shear configuration and controlled pore fluid pressure in a triaxial pressure vessel. Surface-outcrop samples from Gaunt Creek, location of DFDP-1, displayed, with increasing distance (up to 50 cm) from the contact with footwall fluvioglacial gravels: (1) an increase in fault normal permeability (k = 7.45 x 10⁻²⁰ m² to k = 1.15 x 10⁻¹⁶ m²), (2) a transition from frictionally weak (μ=0.44) fault gouge to frictionally strong (μ=0.50’0.55) cataclasite, (3) a change in friction rate dependence (a–b) from solely velocity strengthening to velocity strengthening and weakening, and (4) an increase in the rate of frictional healing. The frictional and hydrological properties of saturated intact samples of southern Alpine Fault surface-outcrop gouges were also investigated in room temperature double-direct shear experiments conducted at σn'= 6-31 MPa. Three complete cross-sections logged from outcrops of the southern Alpine Fault at Martyr River, McKenzie Creek, and Hokuri Creek show that dextral-normal slip is localized to a single 1-12 m-thick fault core comprising impermeable (k=10⁻²⁰ to 10⁻²² m²), frictionally weak (μ=0.12 – 0.37), velocity-strengthening, illite-chlorite and trioctahedral smectite (saponite)-chlorite-lizardite fault gouges. In low velocity room temperature experiments, Alpine Fault gouges tested have behaviours associated with aseismic creep. In a triaxial compression apparatus, the frictional properties of PSZ gouge samples recovered from DFDP-1 drillcore at 90 and 128 m depths were tested at temperatures up to T=350°C and effective normal stresses up to σn'=156 MPa to constrain the fault's strength and stability under conditions representative of the seismogenic crust. The chlorite/white mica-bearing DFDP-1A blue gouge is frictionally strong (μ=0.61–0.76) across a range of experimental conditions (T=70–350°C, σn'=31.2–156 MPa) and undergoes a stability transition from velocity strengthening to velocity weakening as T increases past 210°C, σn'=31.2–156 MPa. The coefficient of friction of smecite-bearing DFDP-1B brown gouge increases from μ=0.49 to μ=0.74 with increasing temperature and pressure (T=70–210°C, σn'=31.2–93.6 MPa) and it undergoes a transition from velocity strengthening to velocity weakening as T increases past 140°C, σn'=62.4 MPa. In low velocity hydrothermal experiments, Alpine Fault gouges have behaviours associated with potentially unstable, seismic slip at temperatures ≥140°C, depending on mineralogy. High-velocity (v=1 m/s), low normal stress (σn=1 MPa) friction experiments conducted on a rotary shear apparatus showed that the peak coefficient of friction (μp) of Alpine Fault cataclasites and fault gouges was consistently high (mean μp=0.69±0.06) in room-dry experiments. Variations in fault rock mineralogy and permeability were more apparent in experiments conducted with pore fluid, wherein the peak coefficient of friction of the cataclasites (mean μp=0.64±0.04) was higher than the fault gouges (mean μp=0.24±0.16). All fault rocks exhibited very low steady state coefficients of friction (μss) (room-dry mean μss=0.18±0.04; saturated mean μss=0.10±0.04). Three high-velocity experiments conducted on saturated smectite-bearing principal slip zone (PSZ) fault gouges had the lowest peak friction coefficients (μp=0.13-0.18), lowest steady state friction coefficients (μss=0.02-0.10), and lowest breakdown work values (WB=0.07-0.11 MJ/m²) of all the experiments performed. Lower strength (μ < c. 0.62) velocity-strengthening fault rocks comprising a realistically heterogeneous fault plane represent barrier(s) to rupture propagation. A wide range of gouges and cataclasites exhibited very low steady state friction coefficients in high-velocity friction experiments. However, earthquake rupture nucleation in frictionally strong (μ ≥ c. 0.62), velocity-weakening material provides the acceleration necessary to overcome the low-velocity rupture propagation barrier(s) posed by velocity-strengthening gouges and cataclasites. Mohr-Coulomb theory stipulates that sufficient shear stress must be resolved on the Alpine Fault, or pore fluid pressure must be sufficiently high, for earthquakes to nucleate in strong, unstable fault materials. A three-dimensional stress analysis was conducted using the average orientation of the central and southern Alpine Fault, the experimentally determined coefficient of friction of velocity-weakening DFDP-1A blue gouge, and the seismologically determined stress tensor and stress shape ratio(s). Results reveal that for a coefficient of friction of μ ≥ c. 0.62, the Alpine Fault is unfavourably oriented to severely misoriented for frictional slip.

A combined experimental and computational investigation of the deformation behavior of pure magnesium single crystal at the micron length scale has been carried out. Employing the recently exploited method of microcompression testing, uniaxial microcompression experiments have been performed on magnesium single crystals with [0001], [2-1-12], [10-11], [11-20] and [10-10] compression axes. The advantage of the microcompression method over conventional mechanical testing techniques is the ability to localize a single crystalline volume which is characterizable after deformation. The stress-strain relations resulting from microcompression experiments are presented and discussed in terms of orientation dependent slip activity, twinning mechanisms and an anisotropic size effect. Such a mechanistic picture of the deformation behavior is revealed through SEM, EBSD and TEM characterization of the deformation structures, and further supported by 3D discrete dislocation dynamics simulations. The [0001], [2-1-12], and [10-11] compression axes results show dislocation plasticity. Specifically, the deformation due to [0001] compression is governed by pyramidal slip and displays significant hardening and massive unstable shear at stresses above 500MPa. In the case of the two orientations with compression along an axis 45 degrees to the basal plane, unsurpringly it is found that basal slip dominates the deformation. In contrast, compression along the [11-20] and [10-10] directions show deformation twinning in addition to dislocation plasticity. In the case of compression along [11-20], the twinning leads to easy basal slip, while the twin resultant during compression along [10-10] does not lead to easy basal slip. In all cases, a size effect in the stress-strain behavior is observed; the flow stress increases with decreasing column diameter. Furthermore, the extent of the size effect is shown to depend strongly on the number of active slip systems; compression along the [0001] axis is associated with 12 slips systems and displays a saturation of the size effect at a diameter of 10μm, while the other orientations still show a significant size effect at this diameter. The experimental evidence of an orientation-dependent deformation behavior in flow stress has been investigated by 3D discrete dislocation dynamics simulations. Here, the code TRIDIS was modified for hcp structure and c/a ratio of Mg. By matching the simulation results to experimental results, some proper constitutive material parameters such as initial dislocation density, dislocation source length, the critical resolved shear stress were suggested. For the case of [0001] and [2-1-12] orientation, dislocation feature in the pillar during the deformation was exhibited and strain burst was discussed.

Baigiamajame magistro darbe atliekami eksperimentiniai gelžbetoninių sijų, sustiprintų pneumatiniu montažiniu pistoletu mechaniškai tvirtinama anglies pluošto juosta, elgsenos tyrimai, nagrinėjama jungių skaičiaus ir išdėstymo įtaka sijos elgsenai. Darbą sudaro: įvadas, trys pagrindiniai skyriai, pasiūlymai ir išvados, literatūros sąrašas. Įvade aptariama tiriamoji problema, darbo aktualumas ir naujumas, pristatomas darbo objektas, formuluojami tikslai ir uždaviniai, pateikiama tyrimų metodika. Pirmajame skyriuje pateikiamos bendros žinios apie sijų stiprinimą, apžvelgiama stiprinimo metodų raida, aptariamos statybiniams kompozitams gaminti naudojamos medžiagos ir aprašomi populiariausi metodai, naudojami statybiniais kompozitais sustiprintų sijų skaičiavimui. Antrajame skyriuje plačiau aptariamas sluoksnių skaičiavimo metodas, atliekama jo parametrinė analizė. Trečiajame skyriuje plačiai aprašomas bandinių paruošimas ir jų bandymo metodika, pateikiami eksperimentinių tyrimų rezultatai, jie palyginami su teoriniais skaičiavimais bei kitų autorių gautais rezultatais. Darbo pabaigoje pateikiami sijų stiprinimo pneumatiniu montažiniu pistoletu mechaniškai tvirtinama anglies pluošto juosta pasiūlymai, formuluojamos išvados. Darbo apimtis – 69 p. teksto be priedų, 33 paveikslai, 5 lentelės, 32 bibliografiniai šaltiniai. / This thesis presents the analysis based on experimental testing of reinforced concrete beams, strengthened by mechanically fastened fiber reinforced polymer strips, when high pressure air powered pinner was used to fasten the strips. The influence of the number and arrangement of fasteners is investigated. Thesis consists of introduction, three main chapters, recommendations and conclusions, literature list. The introduction presents an overview, objectives, scope, methodology and significance of thesis. The first chapter shows the development of beam strengthening, introduces composite materials and methods used for calculating beams strengthened using FRP strips. In the second chapter the chosen calculation method is described in detail and its parametric analysis is performed. Third chapter gives a detailed description on the test specimen preparation and the methodology of testing. Experimental results and their comparison with theoretically obtained values and values obtained by other researchers are given here. The recommendations on the technology of strengthening the beams using mechanically fastened fiber reinforced polymer strips are given and the conclusions are drawn. Thesis contains 69 pages. There are 33 pictures, 5 tables and 32 references in the thesis.