The possibilities of environmental pollution control are increasing and more advanced wastewater treatment methods are being emphasized, as well as more specific control of contaminants presence in treated waters. That is why it becomes relevant to perform not only chemical analysis but also ecotoxicological bioassays as the means of evaluation of biological effects caused by wastewater discharges to ecosystems. No wastewater treatment plant is able to treat the water perfectly – it can only decrease the pollution level to an acceptable value. Therefore it is important to find out if the treatment process is sufficient to provide a satisfactory decrease of ecotoxicity and also what effects to the organisms in recipient will be caused by wastewater discharges. The thesis is focused on the evaluation of wastewater ecotoxicity. In the experimental part of the thesis, wastewater samples were collected at four wastewater treatment plants in the Czech Republic. At one of them also the sludge samples were taken. The aim was to evaluate the efficiency of wastewater treatment by selected ecotoxicological bioassays. The results have shown that the efficiency of wastewater treatment plants with secondary treatment is sufficient to reduce acute toxic effects to the minimum. Average toxicity removal was over 80 % at three of four evaluated wastewater treatment plants. At the fourth WWTP it was 41 %, however, at this WWTP high efficiency of treatment is not necessary.

The thesis deals with energy demands of wastewater treatment plants. The content is focused on inclusion of membrane modules to the wastewater treatment process. Two possible options of wastewater treatment are compared; first, convetional mechanical-biological wastewater treatment plants with activation and installable tank; on the other hand, plants with activation with membrane module. In the practical part, three possible options of intensification are suggested. In the first part, new mechanisms for the plant are projected, in the second part, the energy demands of this tecnological equipment are treated, and in the last point, the item bugget is processed. The comparison of investment and operating costs is made in the conclusion of the thesis.

The aim of the Diploma Thesis is to propose an assessment of energy-consuming criteria of wastewater treatment plant. We focus on formation of energy questionnaire that is used to evaluate the wastewater treatment plant according to the criteria, and subsequently indicate which processes increase energy consumption. Verification of proposed energy-consuming criteria was carried out with the data of an existing wastewater treatment plant.

This thesis deals with possible options for solving drainage in the village Větřní - Frymburk st. and School st. and adjacent villages Lužná, Dolní Němče and Dobrné. The first part describes the current state of sanitation of Větřní and its adjacent area. It also includes assessment of the condition of the current sewer system in the village Větřní, which is connected with some newly proposed sewerages. The following chapter deals with the technical description of the possible variants of the drainage sites including economic evaluation. Then there is a recommendation of choices of variant and evaluation of overall investment and operating costs. In conclusion of the chapter there are summarized advantages and disadvantages of variants of drainage.

Diploma thesis deals with issues related to final treatment sludge. Sewage sludge is an inevitable product of wastewater treatment. Also, most of them concentrated pollution. Most of pollution are concentrated in to them. And because it contains a large percentage of combustibles. Before thermal utilization, it is necessary to appropriately adjust the sludge. Thermal sludge utilization offers the most effective method of energy recovery. It is an energy conversion in the sludge, to heat and electricity. In the vast majority, if not the co-firing, it is necessary to modify the sludge and so it is dried. This is the optimal use of modern technology. There are several variations possible use. Unfortunately it is not in general able to propose the most appropriate technology or methodology, how to make best use of sewage sludge. Specific assignment usually have their own characteristics. In my work I will therefore first try to outline possible technology and in the second part to suggest sludge terminal for WWTP Hodonín.

This study aims to detect how many microplastics and what kind are released from the wastewater treatment plant (WWTP) Skebäck, in Örebro. The study was limited to the analysis of three filters with 50 μm mesh size and one filter with 300 μm mesh size. The samples were taken at different times, two in the fall of 2019 and one in the spring of 2020. Visual characterization was used for the quantification of microplastics, and a lower and upper bound was used. The lower bound represents particles that were deemed identifiable as plastic with high certainty, while the upper bound also includes particles that may have been microplastic. An additional ATR-FTIR analysis was performed on selected microplastics >300 μm.  The presence of microplastics in the effluent from Skebäcks WWTP could be confirmed. The quantity of microplastics per m​3​ (MP/m​3​) trapped on the 50 μm filters were quantified in a range between 0 MP/m​3​ to 291 MP/m​3​ for the lower bound, and 72 MP/m​3​ to 435 MP/m​3​ for the upper bound. The 300 μm filter had considerably less microplastics than the 50 μm filter with 1.8 MP/m​3​. The quantification of fibers on the 50 μm filter and 300 μm filters was not possible due to high blank contaminations. According to the concentration of 63 MP/m​3​ of the lower bound count on the 50 μm filters and the amount of water flowing through Skebäck in 2019, 17 818 935 m​3​, 1.1 billion microplastic particles were released into Svartån that year. In comparison the highest value of the upper bound count, 435 MP/m​3​, gave a release of 7.7 billion microplastic particles. Using the concentration of the 300 μm filter 1.8 MP/m​3​, 32 million microplastics/year were released from Skebäck in 2019. The amount of spheres 50-300 μm released in the effluent from Skebäck was estimated to be 3.7 kg in 2019.

The use of treated wastewater (TWW) for crop irrigation is how many governments are looking to feed their large population due to urbanisation. Here, we outline and analyse the benefits of using TWW and the drawbacks of such practices in line with existing regulations. The review begins by highlighting the history of wastewater reuse in agriculture. The approach used in the write-up is outlined after the background. There is an in-depth look at three main areas: the uptake of heavy metals and pharmaceuticals on crop irrigation, plant yield, and the impact of regulations on these practices. Results demonstrate the presence of several pharmaceuticals, triclosan, acetaminophen, diazepam in lettuce, meprobamate, atenolol in celery, and carbamazepine, triclosan, and triclocarbon in soybean. Trace metals (Cd, Pb) are present in the edible part of the vegetable and arsenic is found in the ryegrass roots and maise. Some benefits derived from using TWW in crop irrigation include nutrient supply, water resource protection and food security, whereas the drawbacks are exposure of contaminants to food and humans.

Historically, water, energy and agricultural resources have been naturally scarce in Jordan, but current economic, demographic, geopolitical and environmental conditions are aggravating the situation. The influxes of refugees are increasing the already high natural population growth; better economic conditions and living standards are changing consumption and production patterns; surrounding conflicts affect the supply of resources; and negative effects associated to climate change can be noticed already. Therefore, nexus thinking as a basis for integrated and cross-sectorial natural resources management is essential to achieve water, energy and food security, and eventually to move towards a sustainable development of the country. To that end, understanding the existing nexus interlinkages is crucial. This document constitutes a first nexus approach focused on water, energy and agriculture (WEA) sectors in Jordan. The research has adopted a case study method based on literature review to consider different contextual factors, and three levels of study were regarded: national level, Lower Jordan River Basin within Jordanian borders level, and As-Samra WWTP level, which has constituted the case study. Based on an extensive literature review that has resulted in an updated analysis of the current Jordanian context, the main WEA nexus interlinkages have been identified at every level of study. Thirteen future alternative pathways have been proposed, their potential impacts on WEA nexus sectors have been investigated, and related indicators to evaluate these impacts have been suggested. Additionally, three combined pathways have been analyzed in detail. In general, results show that interdependencies between WEA sectors at all levels are strong and projected to intensify in the future, and highlight the critical situation of Jordan in terms of resource management. Inefficiencies and unsustainable uses of natural resources stand out as decisive problems that urge to be solved, and future pathways appear to be potentially harmful for the Jordanian system unless they are included in an integrated nexus-based planning. / Historiskt sett har vatten-, energi- och jordbruksresurser varit naturligt begränsade i Jordanien, men de nuvarande ekonomiska, demografiska, geopolitiska och miljöbetingade förhållandena förvärrar situationen. Inkommande flyktningar ökar den redan höga populationsökningen; bättre ekonomiska förutsättningar och levnadsstandarder ändrar konsumtion- och produktionsmönster; kringliggande konflikter påverkar utbudet av resurser; och negativa effekter associerade med klimatförändringar är redan tydliga. På denna grund så är Nexus en god grund för integrerad och tvärsektoriell förvaltning av naturresurs och vital för att säkerställa resurser för vatten, energi och mat och eventuellt gå mot en hållbar utveckling inom landet. För att åstadkomma det ovannämnda så är förståelse för nuvarande nexus samband avgörande. Denna studie utgör ett tillvägagångssätt för en nexus studie med fokus på vatten, energi och jordbruk (WEA) sektorerna i Jordanien. Arbetet utgår från en fallstudie och baseras på en litteraturstudie som är gjord på tre olika nivåer: nationell, Lower Jordan River Basin inom gränserna av Jordanien och As-Samra vattenreningsverk, sistnämnda utgör fallstudien. Baserat på en omfattande litteraturstudie som resulterat i en uppdaterad analys av Jordaniens situation, så har de huvudsakliga WEA nexus sambanden identifierats för varje nivå. Tretton framtida alternativa utfall har föreslagits, deras potentiella påverkan på WEA sektorerna har undersökts och relaterade indikatorer har föreslagits för att utvärdera deras påverkan. Vidare, tre kombinerade utfall har utvärderats i detalj. Överlag så visar resultaten på starkt ömsesidigt beroende mellan WEA sektorerna på alla nivåer och är beräknad att intensifieras i framtiden, vilket betonar den kritiska situationen Jordanien befinner sig i med avseende på naturresurshantering. Ineffektivt och ohållbart utnyttjande av naturresurser står ut som ett stort problem som kräver en lösning, och framtida utfall tycks vara potentiellt skadliga för Jordanien om de inte inkluderas i en integrerad planering baserat på ett nexus tillvägagångssätt.

Membrane bioreactors (MBRs) have proven to be an extremely effective wastewater treatment process combining ultrafiltration with biological processes to produce high-quality effluent. However, one of the major drawbacks to this technology is membrane fouling – an inevitable process that reduces permeate production and increases operating costs. The prediction of membrane fouling in MBRs is important because it can provide decision support to wastewater treatment plant (WWTP) operators. Currently, mechanistic models are often used to estimate transmembrane pressure (TMP), which is an indicator of membrane fouling, but their performance is not always satisfactory. In this research, existing mechanistic and data-driven models used for membrane fouling are investigated. Data-driven machine learning techniques consisting of random forest (RF), artificial neural network (ANN), and long-short term memory network (LSTM) are used to build models to predict transmembrane pressure (TMP) at various stages of the MBR production cycle. The models are built with 4 years of high-resolution data from a confidential full-scale municipal WWTP. The model performances are examined using statistical measures such as coefficient of determination (R2), root mean squared error, mean absolute percentage error, and mean squared error. The results show that all models provide reliable predictions while the RF models have the best predictive accuracy when compared to the ANN and LSTM models. The corresponding R2 values for RF when predicting before, during, and after back pulse TMP are 0.996, 0.927, and 0.996, respectively. Model uncertainty (including hyperparameter and algorithm uncertainty) is quantified to determine the impact of hyperparameter tuning and the variance of extreme predictions caused by algorithm choice. The ANN models are most impacted by hyperparameter tuning and have the highest variability when predicting extreme values within each model’s respective hyperparameter range. The proposed models can be useful tools in providing decision support to WWTP operators employing fouling mitigation strategies, which can potentially lead to better operation of WWTPs and reduced costs. / Thesis / Master of Applied Science (MASc)

Organohalogen compounds are formed in swimming pool waters when natural organic matter, such as hair, urine or sweat etc., react with the used disinfectant (usually chlorine). Many of the organohalogen compounds are persistent and hazardous for human health and aquatic ecosystems. Backwash water from swimming pool facilities is often released to the sewer and contain these compounds. The connected wastewater treatment plant receives this water, where some of these compounds escapes the treatment process, into the recipient. It is therefore important to minimize the levels of organohalogen compounds in the influent water to the wastewater treatment plant. In this study, potential treatment techniques for organohalogen compounds at the swimming pool facility have been investigated. The main focus have been on an experimental column test with four filter materials applied (granular activated carbon, natural zeolites, PoloniteR and Zugol). Real backwash water was used. Furthermore, other techniques have been theoretically investigated as well. The activated carbon directly showed the most efficient removal efficiency (above 95 %), but all filter materials had a removal to a certain degree and became more efficient by time. The results further suggest that the more lipophilic organohalogen compounds are bound to particulate matter and highly affected by physical filtration. Another important conclusion is that the specific activated carbon used in the study is not suitable for the purpose, because it released very high levels of phosphorus in the beginning of the column test as well as showing some practical problems. However, other types of activated carbon exists. Next step recommended is to determine the lifetime of the filters. / När människor badar i bassänger hamnar vanligtvis naturligt organiskt material i dem, såsom urin, svett, hår och hudflagor. Desinfektionsmedlet som tillsätts (oftast klor) har som syfte att avlägsna mikroorganismer, men när naturligt organiskt material hamnar i vattnet kommer också oavsiktliga reaktioner ske och halogenerade organiska föreningar bildas. Dessa föreningar kan kvantifieras via AOX måttet (adsorberbar organisk halogen), vilket är den samlade förekomsten av alla bundna organiska halogener i ett prov. AOX består således av flera hundra olika föreningar, varav vissa är mer lipofila och benämns EOX (extraherbar organisk halogen). Många av de föreningar inkluderade i AOX är bioackumulativa, persistenta och giftiga för akvatiska organismer, även i låga koncentrationer. Förutom att vara miljöfarliga för akvatiska ekosystem, kan de också vara skadliga för människans hälsa. Filtret som renar badvattnet i simhallar behöver backspolas regelbundet och backspolvattnet, som innehåller AOX, skickas vanligen till spillvattennätet. Vid avloppsreningsverket är det visat i ett tidigare examensarbete samt i andra rapporter att en del av de inkommande AOX ämnena även följer med det utgående, renade, vattnet ut i recipienten. Det är därmed av vikt att minimera ämnena redan vid källan, det vill säga på badanläggningen. I denna masteruppsats har behandlingstekniker för halogenerade organiska föreningar undersökts. Huvudfokus har varit på experimentella kolonntester för fyra filtermaterial (granulerat aktivt kol, naturliga zeoliter, PoloniteR och Zugol), men även andra tekniker har studerats teoretiskt. I testerna användes äkta backspolvatten från en simhall. Alla material reducerade AOX till viss del och visade på effektivare reducering efter hand. Det var dock tydligt att det aktiva kolet var mest effektivt och hade hög reducering redan i första mätningen, AOX-reduceringen låg på över 95 % (jämfört med det obehandlade backspolvattnet). Vad som dock var problematiskt med det aktiva kolet var att det släppte höga halter fosfor i början av kolonntestet, vilket också bekräftades med ett skaktest. Dessutom uppvisade materialet praktiska problem. Ur ett realistiskt perspektiv med dessa problem i åtanke, blir det inte hållbart i längden att använda detta specifika kol. Det finns dock många olika typer av aktivt kol, vilka förmodligen är mer lämpliga och som inte uppvisar dessa problem, och kan användas för detta ändamål. Vidare antyder det erhållna resultatet att de mer lipofila föreningarna av AOX (EOX) är bundet till partikulärt organiskt material och därmed påverkas väsentligt av mekanisk filtrering. Det är dock viktigt med en aktiv bindning. Projektet har påverkats av covid-19 pandemin med lägre antal folk på badhusen samt mindre tillgång till laboratoriet vid KTH. En föreslagen förbättring av metoden är att ha en kontinuerlig omblandning i förvaringskärlet med det obehandlade vattnet innan det tillförs kolonnerna. Vidare nämns det att modifierade zeoliter verkar lovande samt att nästa viktiga steg för projektet är att bestämma livstiden för filtermaterialen.