Portland clinker is thanks to its large-scale production a continuously studied topic. Clinker, or Portland cement, is used for construction purposes, or for insulation and special applications. One of these special applications could be shielding of different types of radiation by making use of the content of barium ions. The present master’s thesis examines the influence of barium oxide on the formation and properties of Portland clinker, which could be, by incorporation of barium ions into the system, used as a binder for buildings resistant to various types of radiation. Barium sulfate and barium carbonate were added to the raw meal in order to prepare clinkers with different content of barium oxide. The effect of barium on the formation of clinker phases was studied (by XRD – Rietveld analysis and by the microscopic point integration), as well as the effects on the variations of temperature of the phase formation (TG-DTA) and the rate of alite formation under isothermal conditions. Furthermore, the ability of barium to become a part of clinker minerals was studied by SEM with EDS, and the solubility of barium phases by ICP-OES. The hydration of clinker minerals containing barium was studied by isothermal calorimetry.

This thesis focuses on collecting all available data on mixing Portland cements and especially on Portland cements with limestone. In the experimental part are compare the rheological properities of mixing Portland cements with limestone, their compatibility with plasticizing additives, witch depends on the type of additives, dosage and time, then in experimental part they are summarized monitoring of physical-mechanical properties and volume changes of concrete.

Stockholm Vatten has decided to close down the Bromma waste water treatment plantand manage the waste water from Bromma together with the waste water from the formerEolshällsverket to Henriksdal’s waste water treatment plant. Henriksdals wastewater treatment plant will be expanded for higher purification requirements and loads,estimated to be finished until 2040. This entails extensive renovations and additionsto the existing treatment plant in and on Henriksdalsberget, as well as a major expansionof the Sickla plant.The purpose of the study is to investigate an environmentally friendly alternative tothe standard concrete that will be used for the expansion of the Sickla plant. The largestenvironmental villain in concrete is the cement. The aim of this study has beento replace the cement with environmentally friendly additives in the largest possibleamount, thus reducing the negative impact of the cement on the environment.In the present study, a review was made of obtained data with exposure classes, then aliterature study was performed to gain knowledge in the area. With help from experts,two fictitious recipes for each exposure class have been calculated for the standardconcrete and the green concrete. In this way, a careful comparison between the concretetypes was made of the cement’s impact on global warming. Thereafter, a study wascarried out on existing EPDs, which were incorporated into the One Click LCA (2015)software. An LCA in the mentioned software was carried out, which enabled data to becompiled and a comparison of the climate impact between the four different fictitiousrecipes has been done.Compiled and compared data from LCA and analysis of EPDs show that 70% of thestructure with exposure class XD2 gets a 47% reduction in global warming when usinggreen concrete instead of standard concrete. Furthermore, the results show that theremaining 30% of the structure with exposure class XF3/XC4 gets a 20% reductionwhen using green concrete instead of standard concrete. The total reduction in globalwarming when using green concrete instead of standard concrete for the expansion ofSickla treatment plant was calculated to be 40%. / Stockholm Vatten har beslutat att lägga ned Bromma reningsverk och leda avloppsvattnetfrån Bromma tillsammans med avloppsvattnet från det forna Eolshällsverkettill Henriksdals reningsverk. Henriksdals reningsverk ska byggas ut för högre reningskravoch belastningar beräknade till år 2040. Detta medför omfattande om- och tillbyggnationeri det befintliga reningsverket i och på Henriksdalsberget samt en storutbyggnad av Sicklaanläggningen.Syftet med detta arbete är att undersöka ett miljövänligare alternativ till standardbetongensom ska användas vid utbyggnaden av Sicklaanläggningen. Då den främsta”miljöboven” i betongen är cementet har målet med denna studie varit att ersätta cementetmed miljövänliga tillsatsmaterial i största möjliga mängd, i syfte att minskacementets negativa inverkan på miljön.I föreliggande arbete har en genomgång utförts på erhållna data med exponeringsklasser,därefter påbörjades en litteraturstudie i syfte att inhämta kunskaper inomområdet. Med hjälp av experter har två fiktiva recept för respektive exponeringsklassräknats fram för standardbetongen och den gröna betongen. Med denna metod genomfördesen noggrann jämförelse mellan de olika recepten avseende cementets inverkanpå den globala uppvärmningen. Därefter undersöktes existerande EPD:er, vilka infogadesin i programvaran One Click LCA (2015). En LCA i den nämnda programvaranutfördes, vilket möjliggjorde att data kunde sammanställas och en jämförelse av klimatpåverkanmellan de fyra olika fiktiva recepten kunde genomföras.Sammanställd och jämförd data från LCA och analys av EPD:er visar att 70% av konstruktionenmed exponeringsklass XD2 får en reducering på 47% på den globala uppvärmningenvid användning av grön betong istället för standardbetong. Vidare visarresultatet att resterande 30% av konstruktionen med exponeringsklass XF3/XC4 fåren reduktion på 20% vid användning av grön betong istället för standardbetong. Dentotala reduktionen på den globala uppvärmningen vid användning av grön betongistället för standardbetong för utbyggnaden av Sickla reningsverk beräknades till 40%.

The primary objective of this research was to quantify the improvement in service life of a flexible pavement constructed using full-depth reclamation (FDR) in conjunction with cement stabilization when specified reductions in the spatial variability of specific construction-related parameters are achieved. This study analyzed pavement data obtained through field and laboratory testing of a reconstruction project in northern Utah. Data analyses included multivariate regression, Monte Carlo simulation, and mechanistic-empirical analyses of a model pavement structure. The results of the research show a steadily increasing trend in 28-day unconfined compressive strength of the cement-treated base (CTB) layer with increasing reductions in variability for cement content, moisture content, and reclaimed asphalt pavement (RAP) content across each of five different reliability levels. The most significant increases in CTB strength occurred with reductions in the standard deviations of moisture content and RAP content. Decreasing the variability of cement content did not provide significant additional strength to the CTB layer. Therefore, when involved on FDR projects, members of the pavement industry should focus energy on reducing the variability of both moisture content and RAP content, which both significantly impact pavement life, to achieve high-quality, long-lasting pavements.

The heat development that occurs due to the hydration of cement is important to consider during casting of massive concrete structures. By using computer programs that are based on finite element methods (FEM), simulations can be performed on the heat- and strength development. In this project, a FE program called ConTeSt has been used in order to predict the temperature- and strain development in a massive concrete wall. If the potential risks in a concrete structure are evaluated before casting, economical savings, including a better casting plan could be obtained. The structure under investigation was a concrete wall behind one of the spillways in the hydro power dam of Storfinnforsen. Due to a re-construction of the wall, an opportunity occurred to develop a measurement plan of the casting and perform simulations on the wall. A sensitivity analysis was performed in order to investigate the effects on the temperature- and strain development, by varying the cement content, ambient temperature, wind speed and degree of restraint in translation. The results showed, that a higher cement content increased the rate of hydration and hence the temperature in the concrete. Higher wind speeds contributed to more cooling of the concrete which, in some cases, resulted in cracking due to contraction of the material. Cracking due to contraction also occurred when the ambient temperature was decreased. The ambient temperature did not have a significant impact on the rate of hydration, but instead the impact was larger from the initial temperature of the fresh concrete. A higher initial temperature of the fresh concrete increased the rate of hydration, which increased the temperature in the material. The degree of restraint could only be varied in translation in ConTeSt and hence the effect on the strain development was not that significant. A crack risk analysis was performed where the developed tensile stresses were compared with the tensile strength of the concrete. The same factors were varied as in the sensitivity analysis. The results showed that the tensile strength was exceeded for most of the cases and thus that the crack risk was high. The required equipment, in order to perform the measurements on site, consisted of 7 strain gauges of the module KM-100B from TML Tokyo Sokki Kenkyujo, 2 data loggers of the module Spider-8 from HBM, at least a 25 m ø9 mm 5-core shielded cable and a computer with the software Catman Easy. / Värmeutvecklingen som uppstår på grund av hydratationen av cement är viktig att beakta vid gjutning av massiva betongkonstruktioner. Detta brukar göras genom simuleringar av värmeutvecklingen och hållfasthetstillväxten med hjälp av olika finita element (FE) program. I detta projekt har programmet ConTeSt använts för att på förhand kunna förutse temperatur - och töjningsutvecklingen i en massiv betongvägg. I och med detta kan bl.a. gjutningen planeras bättre samtidigt som ekonomiska besparingar kan åstadkommas om eventuella risker kan kartläggas innan gjutningen påbörjas. En ledmur bakom ett av utskoven i Storfinnforsens kraftverk undersöktes närmare i samband med en ombyggnad. Möjligheten uppstod att planera en mätning av gjutningen av ledmuren samt att utföra simuleringar av väggen i ConTeSt. En känslighetsanalys utfördes för att undersöka effekterna på temperatur- och töjningsutvecklingen genom att variera cementhalten, omgivningstemperaturen, vindhastigheten och graden av tvång i förskjutningen i längdriktningen av väggen. Resultaten visade att högre cementhalter ökade graden av hydratation vilket ökade temperaturen i betongen. Högre vindhastigheter bidrog till snabbare kylning av betongen vilket i vissa fall lett till sprickor på grund av kontraktion av materialet. Sprickor till följd av kontraktion uppstod även då omgivningstemperaturen sänktes. Omgivningstemperaturen hade ingen större påverkan på hydratationen, utan istället var det temperaturen av den färska betongmassan som visade större påverkan. Högre temperatur av den färska betongmassan ökade graden av hydratation vilket ökade temperaturen i betongen. Graden av tvång kunde i ConTeSt endast varieras i förskjutningen i längdriktningen av väggen vilket inte hade någon större effekt på töjningsutvecklingen. En sprickrisk analys utfördes där den utvecklade dragspänningen jämfördes med draghållfastheten. Analysen utfördes genom att variera samma faktorer som varierades i känslighetsanalysen. Resultaten visade att draghållfastheten överskreds i de flesta fall och att därmed sprickrisken var hög. För att genomföra mätningen blev slutsatsen att det behövs 7 st töjningsgivare av modell KM-100B från TML Tokyo Sokki Kenkyujo, 2 st data logger av typ Spider8 från HBM samt minst en 25 m ø9 mm skärmad 5-kärnkabel, inklusive en dator med programvaran Catman Easy.

[pt] O presente estudo busca definir uma relação de mistura estável utilizando aditivos poliméricos à base de álcool polivinílico (PVOH) para controlar a perda de filtrado, antiespumante e dispersante, caracterizando a influência de cada adição na cinética de hidratação, propriedades mecânicas, físicas e reologia da mistura. Além disso, foi caracterizado o comportamento das pastas de cimento em condições de cura que simulam a situação do poço até 6100 m de profundidade, seguindo as recomendações da API, e o comportamento do material nos estados in situ, utilizando pressões confinantes para realizar os ensaios de compressão. Por fim, propôs-se a inclusão de microfibras de álcool polivinílico (PVA) para melhorar o desempenho mecânico das pastas cimentícias, avaliando diferentes tipos de carregamento e definindo os impactos da adição de fibras na viscosidade e tixotropia das misturas. Verificou-se que o uso de PVOH como aditivo de perda de filtrado não influencia na cinética de hidratação para concentrações de até 0,4% em peso de cimento, mas à medida que a quantidade de PVOH é aumentada na mistura, o processo de hidratação da pasta de cimento pode ser modificado por causa do mecanismo de absorção do PVOH. Além disso, novas fases de produtos de hidratação aparecem com o aumento da temperatura e pressão de cura: dellaite, hydroxyellestadite e alpha-C2SH. A última fase (alpha-C2SH) está relacionada à perda de capacidade de resistência das amostras curadas a 149°C, simulando o caso do poço de petróleo de 6100 m de profundidade. Para os ensaios triaxiais, a pressão de confinamento conferiu às amostras um comportamento diferente do caso uniaxial, implicando em uma considerável melhora da plasticidade no comportamento tensão-deformação. Embora se observe algum reforço por atrito devido a tensões de cisalhamento no plano das fissuras, o efeito mais importante do confinamento é suportar a deformação dúctil, mesmo para o caso da pasta de cimento reforçada com fibra de PVA. Finalmente, o estudo mostrou que as fibras de PVA conferem um leve aumento da viscosidade da pasta de cimento, uma fase plástica prolongada aparentemente sem perda de capacidade de carga em testes triaxiais e uma capacidade aprimorada de absorver energia ao avaliar cargas de tração e cisalhamento. / [en] The present study seeks to define a stable mixing ratio using powder Polyvinyl Alcohol (PVOH) based polymeric additives to control the loss of filtrate, defoamer, and dispersant, characterizing the influence of each addition on hydration kinetics, mechanical and physical properties, and rheology of the mix. The behavior of cement pastes under curing conditions that simulate the wellbore situation up to 6100 m depth was also evaluated, following API recommendations. Moreover, the behavior of the material under in situ states, using confining pressures to perform the compression tests, was characterized. Finally, the inclusion of Polyvinyl Alcohol (PVA) microfibers is proposed to improve the mechanical performance of cement pastes, evaluating different types of loading and defining the impacts of the fiber addition on the viscosity and thixotropy of the mixtures. It was found that the use of PVOH as a fluid loss additive does not influence hydration kinetics for concentrations up to 0.4% by weight of cement, but as the amount of PVOH is increased in the mixture, the hydration process of the cement paste may be modified because of the PVOH absorptive mechanism. Moreover, new hydration products phases appear with increasing curing temperature and pressure: dellaite, hydroxyellestadite, and alpha-C2SH. The last phase (alpha-C2SH) is related to the loss of strength capacity of the samples cured at 149°C, simulating a 6100 m depth wellbore. For the triaxial tests, the confining pressure gave the samples a behavior markedly different from the uniaxial case, implying a considerable improvement in the plasticity of the stress-strain behavior. Although some frictional reinforcement is observed due to shear stresses in the cracks surface, the most important effect of confinement is to withstand ductile deformation, even in the case of PVA fiber-reinforced cement paste. Finally, the study has shown that PVA fibers impart a slight viscosifying effect on the cement slurry, a prolonged plastic phase with apparently no loss of load-carrying capacity in triaxial tests, and an improved ability to absorb energy when evaluating tensile and shear loads.

Concrete is good as a construction material regarding fire and its properties regarding strength. However, the concrete expands and cracks due to fire resulting in structural damage. According to the literature the concrete usually loses its strength during and after fire exposure due to themechanical and physical changes.Concrete consists of cement, water, aggregates of different sizes, and usually some sort of plasticiser depending on its final use. Globally the concrete production releases about 4.5 billionmetric tons of carbon dioxide, which is about 8% of all the emissions of carbon dioxide in the world (Naturskyddsföreningen, 2022).The main components in cement are limestone and marlstone which are melted and turned to clinker. The clinker is mixed with sand and gypsum to make cement. Due to the high releases of carbon dioxide from the production of cement and the destruction of the environment mining of the raw materials, Sweden had a concrete-crisis in the summer of 2021, this was due to the government denied the main cement company Cementa AB to continue to mine limestone on the island of Gotland. Due to this decision new sustainable components to replace the components to produce concrete is critical. An alternative material called biochar may be suitable as a component in concrete. Biochar is a renewable product from pyrolysis of biomass. The favorable properties of biochar such as low density, high specific area and low thermal conductivity has the potential to lower the carbon footprint of concrete. This thesis evaluates the properties and performance for different biochar ratios mixed within concrete before and after exposure to fire in a furnace that followed the standard ISO 834 curve up to 650 ℃. In particular, experiments were conducted to observe how the mechanical properties (e.g., tensile and compressive strengths) are affected by exposure to fire that caused a temperature rise of up to 650 ℃. By analyzing the results from the experiments, it is seen that the workability of the concrete decreases with higher ratios of biochar due to the biochar’s water absorption properties. The compressive and tensile strength tests before fire exposure, for both aggregate and cement replaced samples, resulted in the average strength decreasing with higher ratios of biochar. Interestingly, iiithe results after fire exposure represented higher compressive strengths for both cement and aggregate replaced samples for all ratios of biochar. However, the tensile strength after fire exposure generally decreased with higher ratios of biochar. Differential scanning calorimetry and infrared spectroscopy were performed to gain an insight into the reason for the increase in compressive strength after fire exposure. Most probably, when the silica, present in the cement, was exposed to 650 °C under fire, it softened and fused the other components, which led to stronger compressive strengths.

This thesis investigates sustainability measures for quicklime and cement clinker production. It is the aim of this thesis to contribute to the effort of creating a more sustainable modus of industrial production. The methods used comprises process simulations through multicomponent chemical equilibrium calculations, fuel characterization and raw materials characterization through dynamic rate thermogravimetry. The investigated measures relate to alternative fuels, co-combustion, oxygen enrichment, oxyfuel combustion, mineral carbonation and optimizing raw material mixes based on thermal decomposition characteristics. The predictive multicomponent chemical equilibrium simulation tool developed has been used to investigate new process designs and combustion concepts. The results show that fuel selection and oxygen enrichment influence energy efficiency, and that oxyfuel combustion and mineral carbonation could allow for considerable emission reductions at low energy penalty, as compared to conventional post-combustion carbon dioxide capture technologies. Dynamic rate thermogravimetry, applied to kiln feed limestone, allows for improved feed analysis with a deeper understanding of how mixing of different feed materials will affect the production processes. The predictive simulation tool has proven to be of practical value when planning and executing production and full scale campaigns, reducing costs related to trial and error. The main conclusion of this work is that several measures are available to increase the sustainability of the industry.

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

This investigation centers on early concrete technology used in Seguin, Texas, during the mid-19th century. Over the course of fifty years, more than ninety concrete structures were built in Seguin. Over the last century, these have dwindled to twenty extant structures. Much of the previous Seguin concrete era research has focused on the historical narrative and architectural description. This study aims to answer questions that previous research has not — it investigated the raw materials used in making Seguin’s concrete. The results provide new information about the Seguin concrete structures, providing guidance for their long-term maintenance. The materials analysis uses instrumental techniques such as scanning electron microscopy, energy dispersive x-ray spectroscopy, and x-ray diffraction to determine the chemical composition and crystalline structure of the cement binder from several extant structures in Seguin. Gathering both qualitative and quantitative data for the binder allowed us to identify the raw materials used in the concrete and better understand the construction methods. Studying the materials and methods increased our understanding of these historic structures and will inform future preservation efforts. / text