Since social networks (SNs) have become a global phenomenon in almost every industry, including airlines and banking, their security has been a major concern to most stakeholders. Several security techniques have been invented towards this but information security awareness (hereafter “awareness”) remains the most essential amongst all. This is because users, an important component of awareness, are a big problem on the SNs regardless of the technical security implemented. For SNs to improve on their awareness techniques or even determine the effectiveness of these security techniques, many measurement and evaluation techniques are in place to ascertain that controls are working as intended. While some of these awareness measurement techniques are inexpensive, effective and efficient to some extent, they are all incident-driven as they are based on the occurrence of (an) incident(s). In addition, these awareness measurement techniques may not present a true reflection of awareness, since many cyber incidents are often not reported. Hence, they are generally adjudged to be post mortem and risk-permissive. These limitations are major and unacceptable in some industries such as insurance, airlines and banking, where the risk tolerance level is at its lowest. This study therefore aims to employ a technical method to develop a non-incident statistics approach of measuring awareness efforts. Rather than evaluating the effectiveness of awareness efforts by the success of attacks or occurrence of an event, password cracking is presented and implemented to proactively measure the impacts of awareness techniques in SNs. The research encompasses the development and implementation of an SN – sOcialistOnline, the literature review of the past related works, indirect observation (available information), survey (as a questionnaire in a quiz template), and statistical analysis. Consequently, measurement of awareness efforts is shifted from detective and corrective paradigms to preventive and anticipatory paradigms, which are the preferred information security approaches going by their proactive nature. / Engineering, Science & Technology / D. Phil (Computer Science)

Climate change is predicted to have a global effect on temperatures and precipitation rates throughout the world. The UK Climate projections expect that in the United Kingdom this will lead to warmer, drier summers and wetter winters, where events of extreme rainfall are more common. These changes are expected to impact on slope hydrology, and concurrently slope stability. In the United Kingdom this impact is expected to be negative, whereas in other countries, such as Italy and France it could lead to slopes being more stable. Infrastructure slopes in the UK range in age and construction quality, they are susceptible to serviceability problems, characterised by heterogeneous material properties and can fail unexpectedly due to progressive reduction in soil shear strength. In this thesis the effects of climate change on a highway cutting in the south of England are modelled, using numerical methods. A finite element model is created and developed in the software package GeoStudio VADOSE/W. The model has been validated against observed pore water pressure trends and magnitudes and is shown to be able to accurately replicate the behaviour. By incorporating the effects of desiccation cracking on the soil s material properties, by the means of bimodal soil water characteristic curve and hydraulic conductivity function, the replication of these trends is improved even further. A series of future climate series were created using the UKCP09 Weather Generator 2.0. These series were implemented with the VADOSE/W model as climate boundary conditions and models were run, and the results compared to control, current climate results. The results were investigated by the means of statistical analyses which revealed that climate change will have some significant effects on the slope s hydrology, increasing magnitudes of evapotranspiration greatly which can have further significant effects on the magnitude of suctions developing in the slope throughout the summer. It is thought that the results suggest that climate change will not have significant negative effects on slope stability. However it is important to remember that the results only apply with certainty to the specific slope and climate change scenario investigated here. The methods used and developed within this thesis can be extended to other locations, in the UK and internationally, analysing the effects of different climate change scenarios.

The influence of catalyst characteristics, i.e., acidity and porosity on the product distribution in the cracking of triglyceride-rich biomass under fluid catalytic cracking (FCC) conditions is reported. It has found that the degradation degree of triglyceride molecules is strongly dependent on the catalysts’ acidity. The higher density of acid sites enhances the conversion of triglycerides to lighter products such as gaseous products and gasoline-range hydrocarbons. The formation of gasolinerange aromatics and light olefins (propene and ethene) is favored in the medium pore channel of H-ZSM-5. On the other hand, heavier olefins such as gasoline-range and C4 olefins are formed preferentially in the large pore structure of zeolite Y based FCC catalyst (Midas-BSR). With both catalysts, triglyceride molecules are mainly converted to a mixture of hydrocarbons, which can be used as liquid fuels and platform chemicals. Hence, the utilization of the existing FCC units in conventional petroleum refineries for processing of triglyceride based feedstock, in particular waste cooking oil may open the way for production of renewable liquid fuels and chemicals in the near future. / Bài báo trình bày kết quả nghiên cứu khả năng tích hợp sản xuất nhiên liệu sinh học và hóa phẩm từ nguồn nguyên liệu tái tạo sinh khối giầu triglyceride bằng công nghệ cracking xúc tác tấng sôi (FCC) trong nhà máy lọc dầu. Kết quả nghiên cứu cho thấy xúc tác có ảnh hưởng mạnh đến hiệu quả chuyển hóa triglyceride thành hydrocarbon. Tính acid của xúc tác càng mạnh thì độ chuyển hóa càng cao và thu được nhiều sản phẩm nhẹ hơn như xăng và các olefin nhẹ. Xúc tác vi mao quản trung bình như H-ZSM-5 có độ chọn lọc cao với hợp chất vòng thơm thuộc phân đoạn xăng và olefin nhẹ như propylen và ethylen. Với kích thước vi mao quản lớn, xúc tác công nghiệp FCC dựa trên zeolite Y ưu tiên hình thành C4 olefins và các olefin trong phân đoạn xăng. Ở điều kiện phản ứng của quá trình FCC, triglyceride chuyển hóa hiệu quả thành hydrocarbon mà có thể sử dụng làm xăng sinh học cho động cơ và olefin nhẹ làm nguyên liệu cho tổng hợp hóa dầu.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: Plastic shrinkage cracking (PSC) is the cracking caused by the early age shrinkage of concrete within the first few hours after the concrete has been cast. It results in unsightly surface cracks that serve as pathways whereby corroding agents can penetrate the concrete which shortens the expected service life of a structure. PSC is primarily a problem at large exposed concrete surfaces for example bridge decks and slabs placed in environmental conditions with high evaporation rates. Most precautionary measures for PSC are externally applied and aimed to reduce the water loss through evaporation. The addition of a low dosage of polymeric fibres to conventional concrete is an internal preventative measure which has been shown to reduce PSC. The mechanisms involved with PSC in conventional and low volume fibre reinforced concrete (LV-FRC) are however not clearly understood. This lack of knowledge and guidance leads to neglect and ineffective use of preventative measures. The objective of this study is to provide the fundamental understanding of the phenomena of PSC. To achieve the objective, an in depth background study and experiments were conducted on fresh conventional concrete and LV-FRC. The three essential mechanisms required for PSC are: 1→ Capillary pressure build-up between the particles of the concrete is the source of shrinkage. 2→ Air entry into a concrete initiates cracking. 3→ Restraint of the concrete is required for crack forming. The experiments showed the following significant findings for conventional and LV-FRC: PSC is only possible once all the bleeding water at the surface has evaporated and once air entry has occurred. The critical period where the majority of the PSC occurs is between the initial and final set of concrete. Any preventative measure for PSC is most effective during this period. The bleeding characteristics of a mix have a significant influence on PSC. Adding a low volume of polymeric fibres to concrete reduces PSC due to the added resistance that fibres give to crack widening, which increases significantly from the start of the critical period. The fundamental knowledge gained from this study can be utilized to develop a practical model for the design and prevention of PSC in conventional concrete and LV-FRC. / AFRIKAANSE OPSOMMING: Plastiese krimp krake (PSK) is die krake wat gevorm word a.g.v. die vroeë krimping van beton binne die eerste paar ure nadat die beton gegiet is. Dit veroorsaak onooglike oppervlak krake wat dien as kanale waardeur korrosie agente die beton kan binnedring om so die dienstydperk van die struktuur te verkort. Dit is hoofsaaklik ʼn probleem by groot blootgestelde beton oppervlaktes soos brug dekke en blaaie wat gegiet is in klimaat kondisies met hoë verdamping tempo’s. Meeste voorsorgmaatreëls vir PSK word ekstern aangewend en beperk die water verlies as gevolg van verdamping. Die byvoeging van ʼn lae volume polimeriese vesels is ʼn interne voorsorgmaatreël wat bekend is om PSK te verminder. Die meganismes betrokke ten opsigte van PSK in gewone beton en lae volume vesel versterkte beton (LV-VVB) is vaag. Die vaagheid en tekort aan riglyne lei tot nalatigheid en oneffektiewe aanwending van voorsorgmaatreëls. Die doel van die studie is om die fundamentele kennis oor die fenomeen van PSK te gee. Om die doel te bereik is ʼn indiepte agtergrond studie en eksperimente uitgevoer op gewone beton en LV-VVB. Die drie meganismes benodig vir PSK is: 1→ Kapillêre druk tussen die deeltjies van die beton is die hoof bron van krimping. 2→ Lugindringing in die beton wat krake inisieer. 3→ Inklemming van die beton is noodsaaklik vir kraakvorming. Die eksperimente het die volgende noemenswaardige bevindinge opgelewer: PSK is slegs moontlik indien al die bloeiwater van die beton oppervlakte verdamp het en indien lug die beton ingedring het. Die kritiese periode waar die meerderheid van die PSK plaasvind is tussen die aanvanklike en finale set van die beton. Enige voorsorgmaatreël vir PSK is mees effektief gedurende die periode. Die bloei eienskappe van ʼn meng het ʼn noemenswaardige effek op die PSK. Die byvoeging van ʼn lae volume polimeriese vesels tot beton verminder die PSK deur die addisionele weerstand wat die vesels bied teen die toename in kraakwydte. Die weerstand vergroot noemenswaardig vanaf die begin van die kritiese periode. Die fundamentele kennis wat in die studie opgedoen is, kan gebruik word vir die ontwikkeling van ʼn praktiese model vir die ontwerp en verhoed van PSK in gewone beton en LV-VVB.

Thesis (MScEng)--Stellenbosch University, 2013. / Durability and impermeability in a water-retaining structure are of prime importance if the structure is to fulfill its function over its design life. In addition, serviceability cracking tends to govern the design of water retaining structures. This research concentrates on load-induced cracking specifically that due to pure bending and to direct tension in South African reinforced concrete water retaining structures (WRS). As a South African design code for WRS does not exist at present, South African designers tend to use the British codes in the design of reinforced concrete water-retaining structures. However, with the release of the Eurocodes, the British codes have been withdrawn, creating the need for a South African code of practice for water-retaining structures. In updating the South African structural design codes, there is a move towards adopting the Eurocodes so that the South African design codes are compatible with their Eurocode counterparts. The Eurocode crack model to EN1992 (2004) was examined and compared to the corresponding British standard, BS8007 (1989). A reliability study was undertaken as the performance of the EN1992 crack model applied to South African conditions is not known. The issues of the influence of the crack width limit and model uncertainty were identified as being of importance in the reliability crack model.

Thesis (MScEng)-- Stellenbosch University, 2013. / ENGLISH ABSTRACT: Macro synthetic fibre reinforced concrete (SynFRC) is a relatively new concrete for the purpose of being used in structural elements which only require minimum reinforcement and are supported continuously by sub-layers. One structural element that is of particular interest is slabs-on-grade which is supported by a subgrade/sub-base and requires minimum reinforcement to control the shrinkage strains which may result in cracking. The aim of this project is to investigate the potential use of macro SynFRC in the application of controlling drying shrinkage cracking (DSC) in concrete slabs-on-grade. The focus is on the use of concrete slabs-on-grade that is intended for industrial floors. The SynFRC material parameters of interest were characterised first with the aid of various experimental tests. These are: flexural tests, compression tests, friction tests between the SynFRC and wooden surfaces used for full scale testing, and the shrinkage of the concrete. Next the post-cracking tensile behaviour of the SynFRC was determined by way of an inverse analysis. These tensile responses were subsequently used to perform a series of different finite element analyses. These analyses were performed on specific slabs-on-grade to determine the effects of the added tensile behaviour of the SynFRC on the DSC. The results obtained concerned: the spacing of cracks, the maximum and average crack width, and the difference in crack width between the normal concrete (NC) and the SynFRC. These changes take place in accordance to the concrete age. From the analyses it was determined that the addition of fibres gives the concrete a ductility that allows the concrete to crack more than NC, yet does not allow the cracks to propagate. This applies to low fibre contents of less than 0.4% by volume and a slab thickness of 200mm, as well as to fibre contents that have Re,3 values of 0.51 and higher. Moreover, it results in improvements seen when adding fibres if the friction is sticky, meaning when the maximum friction between the slab and the subgrade is reached with a very small amount of movement. With a stickier friction though smaller crack widths occur within both the NC and the SynFRC. / AFRIKAANSE OPSOMMING: Makro sintetiese vesel versterkte beton (SynFRC) is 'n relatiewe nuwe beton. Dit het ten doel om gebruik te word in strukturele elemente wat minimale versterking benodig en wat deurlopend deur sublae ondersteun word. Een spesifieke strukturele element van belang is grondvloere wat deur 'n sublaag ondersteun word en wat minimale ondersteuning benodig om die krimping vervorming te beheer wat moontlike krake kan veroorsaak. Die doel van die projek was om die potensiële gebruik van makro sintetiese vesels te ondersoek tydens die beheer van die uitdroog krimp kraking van 'n beton grondvloer. Die fokus was op die gebruik van betonvloere vir fabrieksdoeleindes. Die eienskappe van SynFRC materiale is vooraf vasgestel vir die doel van verskeie eksperimentele toetse. Hierdie toetse sluit in buigbaarheidstoetse, druktoetse, krimping van beton en toets van wrywing tussen die SynFRC en hout oppervlaktes wat gebruik is vir volskaalse toets. Die trek gedrag van SynFRC na kraking is vasgestel deur inverse analise. Hierdie trek gedrag is dan gebruik om 'n reeks eindige element analises uit te voer. Hierdie analises is uitgevoer op spesifieke grondvloere om die effek te bepaal van verhoogde trek gedrag van SynFRC op die uitdroog krimp kraking. Volgens die uitslae sodoende verkry was die kraakspasiëring, die maksimum en gemiddelde kraakwydte en die verskil in die kraakwydte tussen normale beton en die SynFRC as ‘n funksie van beton oudedom. Vanuit die analises het dit duidelik geblyk dat die byvoeging van vesels die beton se smeebaarheid verhoog het en dit het tot gevolg gehad dat die beton meer krake vorm, maar dat die krake nie vergroot nie. Dit is waargeneem by 'n lae vesel inhoud van minder as 0.4% per volume en 'n betonblad met 'n dikte van 200mm. Dit is ook waargeneem by 'n hoër vesel volume wat Re,3 waardes van 0.51 en hoër het. Kleiner kraakwydte is waargeneem waar vesel volume verhoog is indien die wrywing hoër is, bedoelende dat die maksimum wrywing tussen die betonblad en die sublaag bereik is met baie min beweging. Daar het wel kleiner kraakwydtes in beide die normale beton en die SynFRC voorgekom waar daar hoër wrywing was.

Premature concrete deterioration due to alkali-silica reaction (ASR) and delayed ettringite formation (DEF) is a significant problem all over the world. In cases where these mechanisms were not initially prevented, mitigation is critical to halt expansion and cracking. The main objectives of the research presented herein were to study the effect of ambient relative humidity (RH) on rates of concrete expansion, to determine RH thresholds below which expansion due to ASR and/or DEF may be suppressed, and to evaluate coatings intended to lower the internal RH of concrete and thus minimize future potential for damage. Results from testing showed that the RH threshold for ASR was below 82%, the RH threshold for DEF was below 92%, and the RH threshold for combined ASR and DEF could be about 83% for the materials tested. Furthermore, it was shown that some coatings are effective in reducing ASR- and DEF-related expansion by lowering the internal RH of concrete. / text

This thesis describes the metallurgical and environmental factors that influence hydrogen embrittlement of super duplex stainless steels and presents a model to predict the rate at which embrittlement occurs. Super duplex stainless steel has an austenite and ferrite microstructure with an average fraction of each phase of approximately 50%. An investigation was carried out on the metallurgical and environmental factors that influence hydrogen embrittlement of super duplex stainless steels. Tensile specimens of super duplex stainless steel were pre-charged with hydrogen for two weeks in 3.5% NaCl solution at 50º C at a range of applied potentials to simulate the conditions that exist when subsea oilfield components are cathodically protected in seawater. The pre-charged specimens were then tested in a slow strain rate tensile test and their susceptibility to hydrogen embrittlement was assessed by the failure time, reduction in cross-sectional area and examination of the fracture surface. The ferrite and austenite in the duplex microstructures were identified by analysing their Cr, Ni, Mo and N contents in an electron microscope, as these elements partition in different concentrations in the two phases. It was shown that hydrogen embrittlement occurred in the ferrite phase, whereas the austenite failed in a ductile manner. An embrittled region existed around the circumference of each fracture surface and the depth of this embrittlement depended on the hydrogen charging time and the potential at which the charging had been carried out. The depth of embrittlement was shown to correlate with the rate of hydrogen diffusion in the alloy, which was measured electrochemically using hydrogen permeation and galvanostatic methods. A two-dimensional diffusion model was used to calculate the hydrogen distribution profiles for each experimental condition and the model could be employed to provide predictions of expected failure times in stressed engineering components.

Lors de leur construction, les structures massives (ex. les enceintes de confinement des centrales nucléaires) sont soumises à des déformations dues à l’hydratation du béton. En effet, d’une part la réaction chimique du ciment avec l’eau est exothermique et thermo activée, ce qui induit des déformations de dilatation puis de contraction. D’autre part une dépression capillaire étant créée par la consommation d’eau due à l’hydratation du ciment, des déformations de contraction se produisent. Lorsqu’elles sont empêchées par la partie de la structure déjà construite, ces déformations volumiques induisent des contraintes de compression puis de traction pouvant causer une fissuration traversante augmentant alors sensiblement la perméabilité du béton. Mon travail de thèse a consisté à caractériser le comportement au jeune âge du matériau que l’on utilise (basé sur la formulation utilisée lors de la construction d’une enceinte) puis à mettre au point un essai permettant d’étudier la fissuration d’une éprouvette de béton soumise à des déformations empêchées lors de son durcissement. Ce nouvel essai est en fait une évolution de l’essai à l’anneau de retrait gêné permettant de prendre également en compte les déformations d’origine thermique. Les essais de caractérisation concernent essentiellement, d’un point de vue macroscopique, le retrait (endogène et thermique), le fluage (propre et thermique transitoire) et l’évolution des caractéristiques mécaniques (résistance à la compression, à la traction et module d’élasticité). La campagne d’essais réalisée avec ce nouveau dispositif, appelé essai à l’anneau thermique actif, et l’analyse numérique de ces essais par des simulations aux éléments finis (basées sur un modèle viscoélastique endommageable introduisant un couplage entre le fluage et l’endommagement) a permis d’évaluer ce couplage, d’identifier la diminution de résistance en traction due à une reprise de bétonnage et de quantifier l’effet des armatures sur le comportement du béton. Des mesures de transfert d’air sec à travers une éprouvette fissurée ont également été réalisées sur ce dispositif. Finalement, des simulations numériques d’ouvrages massifs ont mis en exergue l’influence des conditions de restriction du retrait sur le faciès d’endommagement et l’influence du couplage fluage fissuration sur le calcul des ouvertures de fissures. / At early-age, massive concrete structures (ex. nuclear power plant) are submitted to strains due to the hydration reaction. If they are restrained, crossing cracks can occurs. This cracking may increase significantly the concrete wall permeability. The objectives of this work was to characterize the early age concrete behavior (thermal and endogenous shrinkage, basic and thermal transient creep, mechanical characteristic evolution) as well as develop a new device to study the early age cracking of a concrete structure submitted to restrained shrinkage.The experimental campaign achieved with this new device (called thermal active ring test) and the numerical analysis of the test thanks to finite element simulations allows us to evaluate the coupling betwwen creep and damage, to identify the tensile strength decrease due to construction joints and to quantify the effect of reinforcement on the concrete behaviour. Moreover, with this device, permeability measurements have been performed on a cracked specimen. Finally, numerical simulations of massive structures highlight the influence of boundary conditions for restrained shrinkage and the influence of the coupling between creep and damage on the damage pattern.

Le travail de thèse effectué a porté sur l'applicabilité et la compréhension d’un système catalytique bifonctionnel acide et hydro/déshydrogénante sur l'hydroconversion et l’hydrotraitement d'un Résidu Sous Vide. En amont de ce travail, il est rappelé qu'au-delà de 400 °C (régime thermique), la forte conversion du RSV conduit à des phénomènes indésirables de précipitation et d’instabilité, liés à l'augmentation de la polarité des asphaltènes. L’objectif de la thèse était donc de favoriser les réactions de craquage et d’hydrogénolyse à plus faible température (370 °C), grâce à la fonction acide du catalyseur, et d’étudier la nature des structures asphalteniques résultantes. Des catalyseurs modèles, de formulation NiMo, supportés sur des aluminosilicates préparés par greffage de silicium à la surface d'une alumine, ont été utilisés. Ces catalyseurs développent une acidité faible, apportée par le support. Cette acidité a été quantifiée et caractérisée sur les aluminosilicates synthétisés, comme sur le catalyseur fini. La phase hydrogénante, ainsi que la texture des solides, ont aussi été caractérisées en détail. Des catalyseurs, dont les trois paramètres précités ont pu être modifiés indépendamment, ont ainsi été obtenus.Les performances catalytiques ont ensuite été évaluées en hydroconversion d’un RSV Safaniya, en réacteur batch. Les résultats révèlent un impact limité de l’acidité sur les grandeurs globales du test. Les modifications successives des phases hydrogénantes, et l’apport de macroporosité, n’ont pas permis d’améliorer cet impact par la suite. L’analyse détaillée conduite sur les asphaltènes après conversion a mis en relief des modifications de structures moléculaires nettes. Celles-ci ont pu être illustrées via une méthode de reconstitution moléculaire. L'introduction d’acidité a ainsi favorisé les réactions de craquage des chaines aliphatiques ou naphténique des asphaltènes, sans pour autant augmenter l'aromaticité de la molécule. / The aim of this work was to study and investigated bifunctional sulfided and acidic catalyst for the hydroconversion and the hydrotraitment of a Vacuum Residue. Upstream works have already demonstrate that high level of residue conversion, at high temperatures ( > 400 °C), leads to create carbonaceous sediments (sediments), link to asphaltenes polarity and aromaticity. Thus, our objective was to promote hydrocracking reactions at lower temperatures (370 °C), by enhancing acidity of conventional sulfided catalysts. Structures of consequent asphaltenes, modified by acidity, were also studied. Model NiMo catalysts were obtained by grafting silica on the surface of alumina carriers. Characterization on carriers and sulfided catalysts reveal the improvement of a weak acidity. Hydrogenating phase and textures properties have also been characterized in this work. In the end, we have obtained catalysts with same texture, same hydrogenating power, but also different level of acidity strength. Catalytic performances were evaluated in batch reactor, for the hydroconversion reaction of a Safaniya Vacuum Residue. Results reveal no changes in hydroconversion or hydrotraitment reactions parameters with acidity. No improvement was observed by enhancing the hydrogenating power or by adding macroporosity on textures with acidic sulfided catalysts. Nonetheless, combinated asphaltenes analysis and molecular reconstructions methods have shown that acidity can modify asphaltènes structures and properties. Acidity enhances cracking reactions of aliphatic chains and naphthenic units, without improving the aromaticity of the molecules.