Rammed earth is a monolithic construction formed by compacting processed soil in progressive layers. Rammed earth is used for the construction of load bearing walls, floors, sub base material in roadways, airport runways, taxiways, aprons, foundations and earthen bunds. Soil, sand, cement and water are the ingredients used for the preparation of cement stabilized rammed earth (CSRE) specimens. The cracking in a rammed earth structure is due to the development of tensile stresses. The tensile stresses are generated due to various causes like unequal settlement of foundation, eccentric loading and / or lateral loading such as wind pressure and earthquake on an earth structure. The cracking in a rammed earth structure causes the failure of its intended function. For example formation of crack may lead to the instability of an embankment slope. And earthen dam can be destroyed gradually by erosion of soil at the crack surface (Harison et al. 1994). Hence, it becomes important to understand the fracture behaviour of cement-stabilized rammed earth structures. Well focused studies in understanding the fracture behaviour of CSRE structures are scanty. The present work attempts to address some issues on the fracture behaviour of CSRE including size effect. Through an experimental programme material properties viz. compressive strength, tensile strength and stress-strain relationships are generated for two chosen densities, 17 and 18.5 kN/m3 of CSRE both in dry and saturated condition. Soil composition, density, cement content and moisture content of the specimen during testing influence the characteristics of CSRE. In the present investigation keeping the cement at 10%, the density is varied choosing a soil-sand mixture having optimum grading limits. The basic raw materials used are soil, sand, cement and water in the ratio of 1 : 1.5 : 0.25 : 0.34 by weight. The strength properties studied alone are inadequate to predict the mechanics of fracture due to the presence of microscopic flaws, cracks, voids and other discontinuities. Therefore, some linear elastic fracture parameters such as mode I fracture toughness (KIc), critical energy release rate (GIc), net section strength (f net) and notch sensitivity are calculated, presuming that CSRE is still a brittle material because it is yet to be confirmed that CSRE is a quasibrittle material. In fact, in the present work, it is shown that CSRE has significant amount of softening. A comprehensive experimental work has been undertaken to test CSRE beam specimens for two densities, three sizes of beam and three notch to depth ratios under three point bending (TPB) in a closed loop servo-controlled machine with crack mouth opening displacement control. Results indicate that the CSRE in dry condition exhibits a greater resistance to fracture than the saturated specimen. The variation of net section strength with the notch depth is not significant. Therefore the CSRE material is notch insensitive, implying that it is less brittle. An experimental program was undertaken to determine the nonlinear fracture parameters of beam specimens both in dry and saturated condition. The influence of moisture content, density, size of the specimen as well as notch to depth ratio of the specimen on RILEM fracture energy (G F ) are presented. The GF values increase with increase in density and size of the specimen, while they decrease with increase in notch to depth ratio. Results clearly show that the total energy absorbed by the beams (W OF ) and RILEM fracture energy (G F ) for all specimens tested in dry state are higher compared to the specimens tested in saturated state, indicating that the dry specimen offers higher resistance to the crack propagation. The RILEM fracture energy GF , determined from TPB tests, is said to be size dependent. The assumption made in the work of fracture is that the total strain energy is utilized for the fracture of the specimen. The fracture energy is proportional to the size of the fracture process zone (FPZ), which also implies that size of FPZ increases with increase in the un-cracked ligament (d - a) of beam. This also means that FPZ is proportional to the depth d for a given notch to depth ratio, because for a given notch/depth, (d - a) which is also is proportional to d because is a constant. This corroborates the fact that fracture energy increases with size. Interestingly, the same conclusion has been drawn by Karihaloo et al. (2006). They have plotted a curve relating fracture process zone length and overall depth the beam. In the present study a new method namely Fracture energy release rate method proposed by Muralidhara et al. (2013) is used. In the new method the plot of GF /(d - a) versus (d - a) is obtained from a set of experimental results. The plot is found to follow power law and showed almost constant value of GF /(d - a) at larger ligament lengths. This means the fracture energy reaches a constant value at large ligament lengths reaffirming that the fracture energy from very large specimen is size-independent. This Fracture energy release rate method is used to determine size-independent fracture energy GRf , based on the relationship between RILEM fracture energy and the un-cracked ligament length. The experimental results from the present work agree well with the proposed new method. Similarly, the method is extended to determine nominal shear strength τv for large size beam. Results show that for both densities GRf decrease in saturated condition, while in dry condition as the density is increased from 17 to 18.5 kN/m3 the GRf decrease by 7.58%, indicating that the brittleness increases with higher density. The τv for large size beam increases with density both in dry and saturated condition. The size effect method for evaluating material fracture properties proposed by Bazant (1984) is applied to cement stabilised rammed earth. By measuring the peak loads of 2D geometrically similar notched beam specimens of different sizes, nonlinear fracture parameters such as fracture energy (Gf ), fracture toughness (KIc), effective length of the fracture process zone (Cf ), brittleness number (β), characteristic length (l 0) and the critical crack tip opening displacement (CT ODc) are determined for both dry and saturated conditions. The crack growth resistance curves (R-curve) are also developed for dry and saturated specimens. In the size effect method, for both densities 18.5 and 17 kN/m3 the values of nonlinear fracture properties, namely G f , Cf , KIc, CT ODc and l 0 are lower for the saturated specimen compared to those of the dry specimen. In dry condition as the density is increased from 17 to 18.5 kN/m3 the Gf decreases to 13.54%, indicating that the brittleness increase with higher density. The areas under the load-displacement and load-CMOD curves are a measure of the fracture energy and these areas are low for saturated specimens. The crack growth resistance curves (R-curve) plotted using the size-effect law from peak loads are the measure of resistance against crack growth R. The value of R is high for dry specimen compared to that of the saturated specimens. During aggregate pullout or the opening of crack, the interlock or friction between the crack surfaces may cause the energy dissipation through friction and bridging across the crack. Therefore the wet friction in case of saturated specimen must be smaller resulting in more brittleness compared to the larger dry friction for dry specimen. In the present investigation the Digital Image Correlation (DIC) technique is used to study the FPZ properties in cement stabilised rammed earth. The MATLAB package written by Eberl et al. (2006) is suitably modified and used for image correlation to suit our requirements. CMOD measured using DIC technique is validated by comparison with the CMOD measured using clip gauge. The FPZ properties such as the development of FPZ and crack opening displacements at different loading points as well as the influence of notch/depth ratio on FPZ length (lFPZ ) are evaluated for both dry and saturated conditions. At peak load the lFPZ are about 0.315 and 0.137 times the un-cracked ligament length respectively for specimens tested under dry and saturated conditions. In dry and saturated states the FPZ length decreases as the ratio increases. Lower values of lFPZ in saturated specimen indicates that it is relatively more brittle compared to dry specimen.

Fly ash and blast furnace slag are the two major industrial solid by-products generated in most countries including India. Although their utilization rate has increased in the recent years, still huge quantities of these material remain unused and are stored or disposed of consuming large land area involving huge costs apart from causing environmental problems. Environmentally safe disposal of Fly ash is much more troublesome because of its ever increasing quantity and its nature compared to blast furnace slag. Bulk utilization of these materials which is essentially possible in civil engineering in general and more particular in geotechnical engineering can provide a relief to environmental problems apart from having economic benefit. One of the important aspects of these waste materials is that they improve physical and mechanical properties with time and can be enhanced to a significant level by activating with chemical additives like lime and cement. Class-C Fly ashes which have sufficient lime are well utilized but class-F Fly ashes account for a considerable portion that is disposed of due to their low chemical reactivity. Blast furnace slag in granulated form is used as a replacement for sand to conserve the fast declining natural source. The granulated blast furnace slag (GBS) is further ground to enhance its pozzolanic nature. If GBS is activated by chemical means rather than grinding, it can provide a good economical option and enhance its utilization potential as well. GGBS is latent hydraulic cement and is mostly utilized in cement and concrete industries. Most uses of these materials are due to their pozzolanic reactivity. Though Fly ash and GGBS are pozzolanic materials, there is a considerable difference in their chemical composition. For optimal pozzolanic reactivity, sufficient lime and silica should be available in desired proportions. Generally, Fly ash has higher silica (SiO2) content whereas GGBS is rich in lime (CaO) content. Combining these two industrial wastes in the right proportion may be more beneficial compared to using them individually. The main objective of the thesis has been to evaluate the suitability of the class-F Fly ash/GGBS mixtures with as high Fly ash contents for Geotechnical and Geo-environmental applications. For this purpose, sufficient amount of class-F Fly ash and GGBS were collected and their mixtures were tested in the laboratory for analyzing their mechanical behavior. The experimental program included the evaluation of mechanical properties such as compaction, strength, compressibility of the Fly ash/GGBS mixtures at different proportions with GGBS content varying from 10 to 40 percent. An external agent such as chemical additives like lime or cement is required to accelerate the hydration and pozzolanic reactions in both these materials. Hence, addition of varying percentages of lime is also considered. However, these studies are not extended to chemically activate GBS and only GGBS is used in the present study. Unconfined compressive strength tests have been carried out on various Fly ash/ GGBS mixtures at different proportions at different curing periods. The test results demonstrated rise in strength with increase in GGBS content and with 30 and 40 percent of GGBS addition, the mixture showed higher strength than either of the components i.e. Fly ash or GGBS after sufficient curing periods. Addition of small amount of lime increased the strength tremendously which indicated the occurrence of stronger cementitious reactions in the Fly ash/GGBS mixtures than in samples containing only Fly ash. Improvement of the strength of the Fly ash/GGBS mixtures was explained through micro-structural and mineralogical studies. The microstructure and mineralogical studies of the original and the stabilized samples were investigated by scanning electron microscopy (SEM) and X-Ray diffraction techniques respectively. These studies together showed the formation of cementitious compounds such as C-S-H, responsible for imparting strength to the pozzolanic materials, is better in the mixture containing 30 and 40 percent of GGBS content than in individual components. Resilient and permanent deformation behavior on an optimized mix sample of Fly ash and GGBS cured for 7 day curing period has been studied. The Resilient Modulus (Mr) is a measure of subgrade material stiffness and is actually an estimate of its modulus of elasticity (E). The permanent deformation behavior is also important in predicting the performance of the pavements particularly in thin pavements encountered mainly in rural and low volume roads. The higher resilient modulus values indicated its suitability for use as subgrade or sub-base materials in pavement construction. Permanent axial strain was found to increase with the number of load cycles and accumulation of plastic strain in the sample reduced with the increase in confining pressure. Consolidation tests were carried on Fly ash/GGBS mixtures using conventional oedometer to assess their volume stability. However, such materials develop increased strength with time and conventional rate of 24 hour as duration of load increment which requires considerable time to complete the test is not suitable to assess their volume change behavior in initial stages. An attempt was thus made to reduce the duration of load increment so as to reflect the true compressibility characteristics of the material as close as possible. By comparing the compressibility behavior of Fly ash and GGBS between conventional 24 hour and 30 minutes duration of load increment, it was found that 30 minutes was sufficient to assess the compressibility characteristics due to the higher rate of consolidation. The results indicated the compressibility of the Fly ash/GGBS mixtures slightly decreases initially but increase with increase in GGBS content. Addition of lime did not have any significant effect on the compressibility characteristics since the pozzolanic reaction, which is a time dependent process and as such could not influence due to very low duration of loading. Results were also represented in terms of constrained modulus which is a most commonly used parameter for the determination of settlement under one dimensional compression tests. It was found that tangent constrained modulus showed higher values only at higher amounts of GGBS. It was also concluded that settlement analysis can also be done by taking into account the constrained modulus. The low values of compression and recompression indices suggested that settlements on the embankments and fills (and the structures built upon these) will be immediate and minimal when these mixtures are used. In addition to geotechnical applications of Fly ash/GGBS mixture, their use for the removal of heavy metals for contaminated soils was also explored. Batch equilibrium tests at different pH and time intervals were conducted with Fly ash and Fly ash/GGBS mixture at a proportion of 70:30 by weight as adsorbents to adsorb lead ions. It was found that though uptake of lead by Fly ash itself was high, it increased further in the presence of GGBS. Also, the removal of lead ions increased with increase in pH of the solution but decreases at very high pH. The retention of lead ions by sorbents at higher pH was due to its precipitation as hydroxide. Results of the adsorption kinetics showed that the reaction involving removal of lead by both the adsorbents follow second-order kinetics. One of the major problems which geotechnical engineers often face is construction of foundations on expansive soils. Though stabilization of expansive soils with lime or cement is well established, the use of by-product materials such as Fly ash and blast furnace slag to achieve economy and reduce the disposal problem needs to be explored. To stabilize the soil, binder comprising of Fly ash and GGBS in the ratio of 70:30 was used. Different percentages of binder with respect to the soil were incorporated to the expansive soil and changes in the physical and engineering properties of the soil were examined. Small addition of lime was also considered to enhance the pozzolanic reactions by increasing the pH. It was found that liquid limit, plasticity index, swell potential and swell pressure of the expansive soil decreased considerably while the strength increased with the addition of binder. The effect was more pronounced with the addition of lime. Swell potential and swell pressure reduced significantly in the presence of lime. Based on the results, it can be concluded that the expansive soils can be successfully stabilized with the Fly ash-GGBS based binder with small addition of lime. This is also more advantageous in terms of lime requirement which is typically high when Fly ash, class-F in particular, is used alone to stabilize expansive soils. Based on the studies carried out in the present work, it is established that combination of Fly ash and GGBS can be advantageous as compared to using them separately for various geotechnical applications such as for construction of embankments/fills, stabilization of expansive soils etc. with very small amount of lime. Further, these mixtures have better potential for geo-environmental applications such as decontamination of soil. However, it is still a challenge to activate GBS without grinding.

This thesis presents the implementation of the upper bound limit analysis in combination with finite elements and linear optimization for solving different stability problems in geomechanics under plane strain conditions. Although the nonlinear optimization techniques are becoming quite popular, the linear optimization has been adopted due to its simplicity in implementation and ease in attaining the convergence while performing the analysis. The objectives of the present research work are (i) to reduce the computational effort while using an upper bound finite element limit analysis with linear programming in dealing with geotechnical stability problems, and (ii) to obtain solutions for a few important geotechnical stability problems associated with reinforced earth, unsupported tunnels and a group of anchors. It is also intended to examine the developments of the failure patterns in all the cases. For carrying out the analysis for different stability problems, three noded triangular elements have been used throughout the thesis. The nodal velocities are treated as basic unknown variables and the velocity discontinuities are employed along the interfaces of all the elements. The soil mass is assumed to obey the Mohr-Coulomb’s failure criterion and an associated flow rule. The Mohr-Coulomb yield surface is linearized by means of an exterior regular polygon circumscribing the actual yield circle so that the finite element formulation leads to a linear programming problem. A simple technique has been proposed for reducing the computational effort while solving any geotechnical stability problem by using the upper bound finite element limit analysis and linear optimization. In the proposed method, the problem domain has been discretized into a number of different regions in which a particular order (number of sides) of the polygon has been specified to linearize the Mohr-Coulomb yield criterion. A greater order of the polygon needs to be chosen only in that part of the domain wherein the rate of the plastic strains becomes higher. The computational effort required to solve the problem with this implementation reduces considerably. By using the proposed method, the bearing capacity has been computed for smooth as well as rough strip footings and the results obtained are found to be quite satisfactory. The ultimate bearing capacity of a rigid strip footing placed over granular, cohesive-frictional and purely cohesive soils, reinforced with single and a group of two horizontal layers of reinforcements has been determined. The necessary formulation has been introduced to incorporate the inclusion of reinforcement in the analysis. The efficiency factors, and , to be multiplied with Nc and Nγ for finding the bearing capacity of reinforced foundations, have been established. The results have been obtained (i) for different values of soil friction angles in case of granular and cohesive-frictional soils, and (ii) for different rates at which the cohesion increases with depth for purely cohesive soil under undrained condition. The optimum positions of the reinforcements' layers corresponding to which and becomes maximum, have been established. The effect of the length of the reinforcements on the results has also been analyzed. As compared to cohesive soil, the granular soils, especially with greater values of frictional angle, cause much more predominant increase in the bearing capacity. The stability of a long open vertical trench laid in a fully cohesive and cohesive-frictional soil has been determined with an inclusion of single and a group of two layers of horizontal reinforcements. For different positions of the reinforcement layers, the efficiency factor (ηs), has been determined for several combinations of H/B, m and where H and B refer to height and width of the trench, respectively, and m accounts for the rate at which the cohesion increases linearly with depth for a fully cohesive soil with = 0. The effect of height to width of the long vertical trench on the stability number has been examined for both unreinforced and reinforced soils. The optimal positions of the reinforcements layers, corresponding to which becomes maximum, have been established. The required length of reinforcements to achieve maximum efficiency factor corresponding to optimum depth of reinforcement has also been determined. The magnitude of the maximum efficiency factor increases continuously with an increase in both m and . The effect of pseudo-static horizontal earthquake body forces on the stability of a long unsupported circular tunnel (opening) formed in a cohesive frictional soil has been determined. The stability numbers have been obtained for various values of H/D (H = tunnel cover, D = diameter of the tunnel), internal friction angle of soil, and the horizontal earthquake acceleration coefficient The computations revealed that the values of the stability numbers (i) decreases quite significantly with an increase in , and (ii) become continuously higher for greater values of H/D and . The failure patterns have also been drawn for different combinations of H/D, and . The geometry of the failure zone around the periphery of the tunnel becomes always asymmetrical with an inclusion of horizontal seismic body forces. The interference effect on the stability of two closely spaced parallel (twin) long unsupported circular tunnels formed in fully cohesive and cohesive-frictional soils has been evaluated. The variation of the stability number with S/D has been established for different combinations of H/D, m and ; where D refers to the diameter of each tunnel, S is the clear spacing between the tunnels, and is the internal friction angle of soil and m accounts for the rate at which the cohesion increases linearly with depth for a soil with = 0. On account of the interference of two tunnels, the stability number reduces continuously with a decrease in the spacing between the tunnels. The minimum spacing between the two tunnels required to eliminate the interference effect increases with (i) an increase in H/D and (ii) a decrease in the values of both m and . The failure patterns have also been generated for a few cases with different values of S/D. The size of the failure zone is found to become smaller for greater values of m and . The horizontal pullout capacity of a group of two vertical strip anchors embedded, along the same vertical plane in sand, at shallow depths has been determined. At collapse, it is assumed that the anchor plates are subjected to the same uniform horizontal velocity without any bending or tilt. The pullout resistance increases invariably with increases in the values of embedment ratio, friction angle of the sand mass and anchor-soil interface friction angle. The effect of spacing (S) between the anchors on their group collapse load is examined in detail. For a given embedment ratio, the total group failure load becomes maximum corresponding to a certain optimal spacing (Sopt). The values of Sopt increases with an increase in the value of , but the changes in the value of H/B and do not have any significant effect on Sopt. The vertical uplift capacity of a group of two horizontal strip plate anchors with the common vertical axis buried in purely cohesive as well as in cohesive frictional soil has been computed. The variation of the uplift factors Fc, Fq and F , due to the contributions of soil cohesion, surcharge pressure and unit weight, respectively, has been evaluated for different combinations of S/B and H/B. As compared to a single isolated anchor, the group of two anchors generates significantly greater magnitude of Fc. On the other hand, the factors Fq and F , for a group of two anchors are found to become almost equal to that of a single isolated anchor as long as the levels of the lower plate in the group and the single isolated anchor are kept the same. For the group of two horizontal strip plate anchors in purely cohesive soil, an increase of cohesion of soil mass with depth and the effect of self weight of the soil have been incorporated. The uplift factor Fcy both due to cohesion and unit weight of the soil has also been computed for the anchors embedded in clay under undrained condition. For given embedment ratios, the factor Fcy increases linearly with an increase in the normalized unit weight of soil mass upto a certain value before attaining a certain maximum magnitude. The computational results obtained for different research problems would be useful for design.

No description available.

Soft soil deposits of coastal regions and lowland areas pose many geotechnical problems but it is indispensable to utilize these grounds to meet the growing demand for infrastructure with ever increasing urbanization and industrial development. Soft soils are generally associated with high compressibility and low strength characteristics which augment the risk of huge settlements and foundation failure. It is essential to understand the complex behaviour of the ground consisting of soft clays as construction and maintenance of infrastructure in these areas is challenging. Marine sediments mostly possess open microstructure irrespective of the differences in their mineral composition and sedimentation environment. Also this particular microstructure in marine sediments is generally accompanied by the presence of a great amount of organic residues and fragments of marine organisms. Formation of pyrite is also possible because of the presence of decomposable organic matter, dissolved sulfate and reactive iron minerals. These soils due to their inherent mineralogy and microstructure have high void ratios and consequently high water holding capacity which explains the reason for their low shear strength and high compressibility characteristics. And often the formation environment is conducive for incorporation of organic content in the soft clay deposits which further aggravates the problem. A complete characterization of the soil can enhance the understanding of soil behavior and therefore can play a crucial role in suggesting suitable and sustainable ground improvement method. Soft clay deposits of Kuttanad area in Kerala, India extending to varying depths below the ground level, present a challenge as a foundation soil due to low bearing capacity and high settlement. Geologically Kuttanad is considered as a recent sedimentary formation. In the geological past, the entire area was a part of the Arabian Sea. Presently Kuttanad area covers an area of about 1,100 km2. Many intriguing reports of distresses to structures founded on this soil are available. An over view of specific characteristics of soft clays along with the comprehensive description of soft clays from various parts of the world is presented in the introductory Chapter. Deep soil mixing and mass stabilization methods are found to be relatively advantageous in reducing differential settlements and in achieving expeditious construction. A more detailed review of literature on Kuttanad soil problems and various ground improvement methods adopted are presented. The different ground improvement techniques attempted are soil reinforcement, stone columns, preloading etc. Soil mixing can be relatively advantageous over the other conventional ground improvement methods. Laboratory studies carried out earlier with different binders such as cement, lime and lime fly ash combinations did not exhibit appreciable improvement in soil strength. It is reasoned that the lack of understanding of the soil characteristics is responsible for the limited success of these attempts. Based on the review of literature the detailed scope of the work is presented at the end of Chapter 1. The method of collection of the soil from Kuttanad region, methods adopted for characterization of soil, characteristics of various binders used and testing procedures adopted for assessing the geotechnical behavior with and without binders are described in Chapter 2. In order to characterize the soil for understanding its behaviour under different conditions as well as to gauge its response to different stabilizers, a detailed physico¬chemical, mineralogical, morphological and fabric studies are carried out and presented in Chapter 3. An attempt has been made to explain the role of components of soils such as organic substances, pyrite and sesquioxides for variations in its properties with change in water content. The high water holding capacity of the soil reflected in its Liquid limit along with relatively low plasticity characteristics of the soil has been explained as due to the presence of minerals such as metahalloysite and gibbsite, the flocculated fabric, porous organic matter and water filled diatom frustules (amorphous silica). Based on the study conducted on the plasticity characteristics of Kuttanad soil under different conditions of drying and treatment, it was brought about that the organic content plays a dominant role in particle cementation and aggregation causing a substantial reduction in plasticity upon drying. Further, the presence of minerals such as pyrite and iron oxides also account for the plasticity changes. The significant changes in soil properties upon drying have also been successfully explained in Chapter 4. Attempts made to stabilize the soil using conventional chemical stabilizers are described in Chapter 5. The effect of binders on the strength improvement of soil has been explained based on the changes occurring in the composition, fabric and physico-chemical characteristics of soil upon addition of the binders. Lack of strength development in soil with lime has been attributed to the inherent composition of the soil hindering the formation of pozzolanic compounds and unfavourable modification of the fabric. On the other hand the soil responded well to cement stabilisation. The influence of various parameters such as Water/Cement (W/C) ratio, Initial water content, curing period and additive dosage on the strength development of cement treated soil has been examined. Cement improved the strength of the soil by binding the soil particles without depending on the interaction with the soil. It was observed that the role of initial water content is insignificant and the strength improved with reducing W/C ratio. The dependence of strength development with cement addition on the fabric at different W/C ratios has been assessed. Also the role of other additives such as Lime, Sand, Fly Ash, Ground granulated blast furnace slag, Silica fume and Sodium silicate to enhance the strength of cement treated soil has been analysed in Chapter 5. It was shown that only Sodium Silicate (NS) along with cement meets with good success. The studies on the undrained shear strength and compressibility characteristics of cemented soil carried out to understand the strength and deformation behaviour of the cemented soil are presented in Chapter 6. It is clear from the compressibility characteristics of the cemented soil that there is a well defined yield stress demarcating the least compressible pre-yield zone and more compressible post yield zone. Generally the yield stress increases with reducing water cement ratio. It is interesting to note that the post yield compressibility of the cemented soil is controlled more by the fabric of soil than by cementation effect. The study on the undrained shear behavior of cemented soil revealed that the cohesion intercept and angle of internal friction increases with addition of cement. However the impact of cementation is reflected more as increase in cohesion intercept with increasing cement content. The uniqueness of failure envelope observed for the cemented soil irrespective of whether the confining stress is above or below the yield stress has been explained in detail. A case study on the performance of embankment founded on Kuttand soil improved with Deep mixed cement columns (DMCC) has been evaluated through numerical simulations using FLAC 2D and this forms the subject matter of Chapter 7. For this work the soil properties of the Kuttanad soil determined by experimental investigations have been used. The simulation results showed that the introduction of DMCC columns improved the factor of safety against failure and reduced settlements. This study clearly endorses the analysis and the results of the test carried out on Kuttanad soil. The final chapter summarizes the details of the work carried out which brings out the importance of characterization of the soil in terms of soil components, physico-chemical environment as well as the micro structure of the soil in predicting the behaviour of the soil in changing environment and to understand the stabilization response of the soil with different binders which intern helps to select appropriate binder and or binder combinations.

Hazardous waste substances are solid, semi-solid or non-aqueous liquids that exhibit characteristics of corrosivity, reactivity, ignitability, toxicity and infectious property. Major available options for management of hazardous waste include direct disposal into landfill or chemical treatment/stabilization of wastes prior to landfill disposal. Hazardous wastes are accepted for direct disposal in engineered landfills if they conform to the chemical concentration limit criterion (determined by water leach test followed by estimation of the concentration of the contaminant) and compressive strength (the material should have compressive strength > 50 kPa) criterion. Lead is classified as extremely toxic metal. Elevated levels of lead in water (surface and ground water) primarily arise from industrial discharges, and aerial deposition. During its residence in surface water bodies, the lead may interact detrimentally with aquatic life or be abstracted into public water supplies. According to National drinking water standards, the permissible limit of lead in drinking water is 0.05 mg/l. Deposition of air-borne lead, disposal of sewage sludge on land and disposal of industrial effluents on lands are major sources of lead contamination of soils. When incorporated in soil, lead is of very low mobility. Lead retained in soils can be slowly leached to the groundwater thereby impacting human health if consumed for potable needs. Alternatively lead deposited in soils can be absorbed by vegetation (crops/trees) and can impact human health on their consumption. Given the negative impacts of lead contamination on human health, the strong affinity of soils to retain deposited lead and the possible release for human consumption, this thesis focuses on characterization and chemical stabilization of artificially lead contaminated soils in the context of their disposal in hazardous waste landfills. The main objectives of the thesis are: characterize artificially lead contaminated soils for water leachability of lead and undrained strength characteristics as per CPCB (Central Pollution Control Board) guidelines in the context of disposal criteria in hazardous waste landfills. Artificially lead contaminated soils in compacted and slurry states are used in the thesis. Red soil (from Bangalore District, Karnataka) and river sand are used in the preparation of compacted and slurry specimens. The red soil and red soil-sand specimens are artificially contaminated in the laboratory by employing aqueous lead salt solutions as remolding fluids. Lead concentrations of 160 to 10000 mg/l are used in this study. The results of characterization studies with artificially lead contaminated soils help identify contaminated soil materials that require chemical stabilization prior to disposal into engineered landfills. Based on the results of characterization studies with artificially lead contaminated soils, lime stabilization coupled with steam curing technique is resorted to immobilize lead in the red soil-sand slurry specimens and mobilize adequate undrained strength to meet the criteria for disposal of lead contaminated soils in hazardous landfills. After this first introductory chapter, a detailed review of literature is performed towards highlighting the need to undertake chemical stabilization of artificially lead contaminated soils in Chapter 2. Chapter 3 presents a detailed experimental program of the study. Chapter 4 presents the physico-chemical and mechanical characterization of the artificially lead contaminated soils. The ability of artificially contaminated soils to release (artificially added) lead during water leaching is explained using lead speciation results performed using the Visual MINTEQ program. Experimental results illustrated that contamination of compacted red soil and red soil + sand specimens with significant lead concentrations (21 to 1300 mg/kg) resulted in major fractions of the added lead being retained in the precipitated state. Results of water leach tests revealed that lead concentrations released in the water leachates are far less than (0.0011 to 0.48 mg/l) limits prescribed by CPCB (2 mg/l) for direct disposal of lead contaminated materials into hazardous waste landfills. Unconfined compressive strengths developed by the lead contaminated red soil and red soil-sand specimens were significantly higher (100-2700 kPa) than the strength requirement (> 50 kPa) for direct disposal of hazardous wastes in engineered landfills. Lead contamination did not affect the unconfined compression strengths of the specimens as matric suction prevalent in the unsaturated compacted soils had an overriding influence on the cementation bond strength created by the lead precipitates. Visual Minteq tool was helpful in predicting the amount of added lead that was converted to insoluble precipitate form. However the amounts of water leachable lead determined experimentally and predicted by Visual Minteq were very different-Visual Minteq predicted much higher amounts of water leachable lead than experimentally determined. Experimental results revealed that the levels of lead released by the red soil-sand slurries in water leach tests were in excess (13 to 36 mg/l) of the permissible lead concentration (2 mg/l) for direct disposal of hazardous waste in landfills. Owing to water contents generally being in excess of their liquid limit water contents (w/wL ratio > 1) the slurry specimens exhibited undrained strengths below 1 kPa. Lime stabilization and steam curing of the contaminated slurry specimens was therefore resorted to control the leachibility of lead and increase undrained strengths to acceptable limits. Chapter 5 deals with lime stabilization of artificially contaminated slurries that do not meet the leachate quality (lead concentration in water < 2 mg/l) or compressive strength (> 50 kPa). Procedures are evolved for lime stabilization of such artificially contaminated soils to meet both the water leachate quality and compressive strength criteria. Lime stabilization together with steam curing of the lead contaminated slurry specimens effectively immobilized the added lead (2500 mg/kg) and imparted adequate compressive strengths to the contaminated red soil-sand slurry specimens. The lime stabilized contaminated specimens released marginal lead concentrations (0.03 to 0.45 mg/l) in the water leach; these values are much lower than permissible limit (2 mg/l) for disposal in hazardous landfills or values exhibited by the unstabilized specimens (13 to 38 mg/l). Lime addition rendered the contaminated specimens strongly alkaline (pH values ranged between 10.68 and 11.66). Combination of the experimental and Visual Minteq results suggested that precipitation of lead as hydrocerrusite in the alkaline environments (pH 10.68 to 11.95) is not the sole factor for marginal release of lead in water leach tests of the 4, 7 and 10 % lime stabilized contaminated specimens. It is possible that fraction of lead ions are entrapped within the cemented soil matrix. Water leach tests performed at range of pH values (pH 2.5 to 9.6) with 7 % lime stabilized specimens suggested that immobilization of lead as hydrocerrusite or as entrapment in the cemented soil mass in the lime stabilized specimens is practically irreversible even on exposure to extreme pH conditions. The lime stabilized contaminated specimens developed unconfined compressive strengths ranging from 100 kPa (4 % lime stabilized 40 % red soil-60 % sand specimen) to 1000 kPa (10 % lime stabilized 100 % red soil specimen). The significant growth of compressive strength upon lime stabilization is attributed to growth of inter-particle cementation bonds by the CAH (calcium aluminate hydrate) and CSH (calcium silicate hydrate) compounds formed by lime-clay reactions, slight reduction in void ratios and growth of strong inter-particle cementation bonds the during steam curing at 800C. The results of this thesis bring out a procedure to immobilize high concentrations of lead and develop adequate compressive strength of lead contaminated slurry specimens by lime stabilization + steam curing technique. The red soil acted as pozzolana in reactions with lime, while, steam curing accelerated the lime-soil reactions. The procedure can be extended to non-organic slurry wastes that are devoid of pozzolanic material (example, lead contaminated smelting sands). In slurry wastes devoid of pozzolana, materials such as fly ash can be added and the reactions between lime and fly ash would immobilize lead + develop adequate compressive strength. Also, similar to the methodology being adaptable for any non-organic slurries, it can also be extended to other toxic metal bearing wastes, example, zinc, cadmium and nickel.

The objective of this thesis was to identify the mechanisms associated with the recurrence of rock-slope instability along the R518 and R523 roads in Limpopo. Advanced geotechnical methods and ASTER imagery were used for the purpose while a predictive rockfall hazard rating matrix chart and rock slope stability charts for unsaturated sensitive clay soil and rock slopes were to be developed. The influence of extreme rainfall on the slope stability of the sensitive clay soil was also evaluated. To achieve the above, field observations, geological mapping, kinematic analysis, and limit equilibrium were performed. The latter involved toppling, transitional and rotational analyses. Numerical simulation was finally resorted to. The following software packages were employed: SWEDGE, SLIDE, RocData, RocFall, DIPS, RocPlane, and Phase 2. The simulation outputs were analyzed in conjunction with ASTER images. The advanced remote sensing data paved the way for landslide susceptibility analysis. From all the above, rockfall hazard prediction charts and slope stability prediction charts were developed. Several factors were also shown by numerical simulation to influence slope instability in the area of study, i.e. sites along the R518 and R523 roads in the Thulamela Municipality. The most important factors are extreme rainfall, steep slopes, geological features and water streams in the region, and improper road construction. Owing to the complexity of the failure mechanisms in the study area, it was concluded that both slope stability prediction charts and rock hazard matrix charts are very useful. They indeed enable one to characterize slope instability in sensitive clay soils as well as rockfall hazards in the study area. It is however recommended that future work is undertaken to explore the use of sophisticated and scientific methods. This is instrumental in the development of predictive tools for rock deformation and displacement in landslide events. / Electrical and Mining Engineering / D. Phil. (Mining Engineering)

Tesis por compendio / [ES] Esta tesis englobada dentro del programa de doctorado en ingeniería de la construcción sigue la línea de investigación en sostenibilidad y gestión de la construcción. Las investigaciones se han centrado en el desarrollo de cementos de activación alcalina (CAA) obtenidos a partir de residuos con el fin de reducir tanto el coste económico como medioambiental. Este hecho implicaría la reducción en el uso tanto de materias primas, en el caso de los precursores, como de reactivos químicos en el caso de los activadores. La tesis doctoral que se presenta estudia el uso de diferentes mezclas de residuos como precursores: cerámica sanitaria, catalizador gastado de craqueo catalítico, escoria de alto horno y ceniza volante de central térmica en la preparación de morteros. Así mismo, utiliza también CAA, obtenidos a partir de residuos en la estabilización de suelos. En este último caso también se han usado residuos en la preparación de activadores como son las cenizas obtenidas en la combustión de biomasa. Los resultados obtenidos ponen de manifiesto la viabilidad en el uso de residuos para la preparación de CAA, y la posibilidad incluso de ser usados en contextos de subdesarrollo. / [CA] Aquesta tesi englobada dins del programa de doctorat en enginyeria de la construcció segueix la línia d'investigació en sostenibilitat i gestió de la construcció. Les investigacions s'han centrat en el desenvolupament de ciments d'activació alcalina (CAA) obtinguts a partir de residus amb la finalitat de reduir tant el cost econòmic com mediambiental. Aquest fet implicaria la reducció en l'ús tant de matèries primeres, en el cas dels precursors, com de reactius químics en el cas dels activadors. La tesi doctoral que es presenta estudia l'ús de diferents mescles de residus com a precursors: ceràmica sanitària, catalitzador gastat de craqueig catalític, escòria d'alt forn i cendra volant de central tèrmica en la preparació de morters. Així mateix, utilitza també CAA, obtinguts a partir de residus en l'estabilització de sòls. En aquest últim cas també s'han usat residus en la preparació d'activadors com són les cendres obtingudes en la combustió de biomassa. Els resultats obtinguts posen de manifest la viabilitat en l'ús de residus per a la preparació de CAA, i la possibilitat de ser usats fins i tot en contextos de subdesenvolupament. / [EN] This doctoral thesis encompassed within the doctoral program in construction engineering follows the research line in sustainability and construction management. The research has focused on the development of alkaline activated cements (AAC) obtained from waste to reduce the economic and environmental cost. This fact would imply a reduction in the use of raw materials in the case of precursors, and chemical reagents in the case of activators. The doctoral thesis that is presented studies the use of different waste mixtures as precursors: sanitary ceramics, spent fluid cracking catalyst, blast furnace slag and fly ash from thermal power plants in the preparation of mortars. Likewise, also is used CAA obtained from residues in soil stabilization. In the latter case, residues have also been used in the activators preparation, such as the ashes obtained in the combustion of biomass. The results obtained show the viability in the use of residues for CAA preparation, and the possibility of being used even in underdeveloped contexts. / Agradecer al Ministerio de Ciencia e Innovación por el soporte a mi investigación, mediante los fondos del proyecto APLIGEO BIA2015-70107-R y los fondos FEDER. También a las empresas: Ideal Standard por suministrar residuos de cerámica sanitaria, Omya Clariana S.A. por suministrar catalizador gastado del craqueo catalítico, a Balalva S.L. por suministrar cenizas volantes, a Cementval por suministrar escorias de alto horno, a Heineken España S.A. por el suministro de residuo del filtrado de cerveza (tierras diatomeas), a DACSA GROUP por la ceniza de cáscara de arroz, y a PAVASAL por suministrar suelo de tipo dolomítico. Támbien al servicio de Microscopía electrónica y al Instituto de Ciencia y Técnología del Hormigón de la Universitat Politècnica de València. / Cosa Martínez, J. (2022). Utilización de mezclas de residuos para la obtención de cementos de activación alcalina: aplicación en morteros y suelos estabilizados [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/185221 / Compendio

The subject of this master’s thesis is a solution of chosen parts of building construction project. The project solves industrial hall that contains productions and administrative space. This thesis includes technological regulations for substructure, study of performing the main technological stages, design of using machines, checking and testing plans. Other phrases parts are time schedules, budget, calculations, design of site equipment including engineering report and report for performing access road. Starting materials, which were used for this thesis, were engineering report also including working drawings.