Les actionneurs piézoélectriques font partie des outils les plus utilisés dans les applications à l'échelle micro/nano-métrique (micromanipulation, microassemblage, micropositionnement, etc…). Du point de vue fonctionnel, on distingue les actionneurs mono-axe (permettant d'obtenir la déflection suivant une direction) et les actionneurs multi-axes (pouvant fléchir suivant plusieurs directions). La notoriété des actionneurs piézoélectriques est due à un certain nombre de performances telles qu'une large bande passante (plus du kHz possible), une très bonne résolution (de l'ordre du nanomètre), une faible consommation en énergie électrique, une grande densité de force, une facilité d'alimentation et d'intégration, etc. Cependant, ces actionneurs sont caractérisés par des non-linéarités fortes (hystérésis et la dérive lente), des oscillations mal-amorties, et sont sensibles à la variation des conditions ambiantes (en particulier à la variation de la température). Pour les actionneurs multi-axes, il s'ajoute un problème des couplages entre les différents axes de l'actionneur. Cette thèse propose des stratégies innovantes de commande des actionneurs piézoélectriques multi-axes pour contrer les problèmes sus-mentionnés. Ces stratégies sont groupées en deux catégories. La première catégorie concerne les techniques de commande en boucle fermée. Ces techniques sont les plus adaptées pour garantir la robustesse et un niveau de précision élevé pour les actionneurs piézoélectriques. Cependant, à l'échelle micro/nano-métrique, ces techniques sont limitées par un manque d'espace suffisant pour installer des capteurs de position. La deuxième catégorie concerne la commande en boucle ouverte dont l'intérêt majeur est lié au fait qu'il n'y a pas besoin de capteurs pour la commande, ce qui constitue un avantage en terme de coût et facilité d'intégration. Dans cette thèse, nous proposons d'abord les techniques de modélisation et de commande en boucle ouverte multivariables. Ensuite, nous faisons une analyse des effets de la température sur les actionneurs piézoélectriques et nous proposons des techniques de commande en boucle ouverte et en boucle fermée de ces effets. Enfin, une stratégie de commande en boucle fermée par découplage, visant à obtenir des correcteurs d'ordre réduit pour les actionneurs multi-axes est proposée. Toutes ces techniques sont vérifiées et appliquées expérimentalement à un actionneur piézoélectrique de type tube. / Piezoelectric actuators are among the most used tools in many applications at micro/nano-scale (micromanipulation,microassembly, micropositioning, etc). From a functional perspective, there exist mono-axis actuators(which are made to bend in one direction) and multi-axis actuators (which provide deflections in different directions).The popularity of piezoelectric actuators is especially due to their high resolution (nanometric resolution),the large bandwidth (greater than 1kHz possible), the low electrical power consumption, the high force density,the ease of integration in positioning systems, etc. However, piezoelectric actuators are characterized by hysteresisand creep nonlinearities, badly damped vibrations and they are sensitive to the variation of ambient conditions(especially to the temperature variation). In addition, multi-axis actuators exhibit cross-couplings betweentheir axis. This thesis proposes novel strategies for modeling and control of multi-axis piezoelectric actuators,with the aim to counteract the aforementionned problems. These strategies are grouped into two categories.The first category concerns feedback control techniques. These techniques are the most suitable to ensurethe robustness and a high level of precision for piezoelectric actuators. However, at the micro/nanoscale, thesetechniques are limited by the lack of enough physical space to install feedback sensors. The second categoryconcerns the feedforward control techniques. The main advantage of these techniques is related to the factthat, in feedforward control schemes, feedback sensors are not needed for tracking. This allows to achieve ahigh degree of packageability and the cost reduction. In this thesis, we first propose multivariable modelingand feedforward control techniques. Then, we analyse the effects of temperature variation on piezoelectricactuators and we propose feedforward and feedback control techniques for these effects. Finally, a feedbackstrategy based on decoupling techniques with an aim to reduce the order of feedback controllers for multi-axispiezoelectric actuators, is proposed. All these modeling and control strategies are experimentally applied on apiezoelectric tube actuator.

Wheeled systems are energy efficient on prepared surfaces like roads and tracks. Legged systems are capable of traversing different terrains but can be lossy. At low speeds and on off-road surfaces, legged systems using dynamic walking can be energy efficient. Towards this objective, the dynamics of the walker needs to be modelled and controlled. In addition, the braking and ground impact losses need to be minimized. This thesis presents analysis and experiments on the dynamics and control of a rimless-spoked-wheel based mobile robot (Chatur ∗) that belongs to a category between wheeled and legged systems. This rolling rimless wheel is effectively a 2D dynamic walker that serves as a platform for investigating the dynamics and energetics of inverted pendulum walking with constant step angle. A pulsed actuation torque is proposed for the system resulting in four torque regimes defined by the ratio of energy losses to available actuator torque. Five physical constraints that impose fundamental limits on the choice of operating points of a generic inverted pendulum walker are expounded and a method for locating optimal operating points is discussed. Chatur’s hardware design is elaborated and a control topology is proposed for pulsed actuation of the dual brushless dc (BLDC) motor driven platform with wheel synchronization. Various actuator torque profiles can be used to achieve dynamic ‘walking’ in a hub-actuated rimless wheel. The proposed pulsed actuation torque gives rise to four torque regimes that achieve sustained walking and a fifth regime where the walker keeps slowing down with each step. The regimes can be identified based on the fraction of stance phase for which the actuator is energized. Theoretical analysis and experimental results are presented. A simple closed-form analytical solution, using hyperbolic functions, is proposed for the stance phase inverted pendulum dynamics considering planar motion. Ground impacts are assumed to cause abrupt drop in velocity. A constant braking torque that lumps together the effect of several loss phenomena is also considered. Based on whether the CoM is rising or falling and whether or not there is an actuating torque, a stance phase can have four types of sub-phases — actuated rise, unactuated rise, actuated fall, unactuated fall. These are concatenated in four different ways to form repeating cycles yielding the four regimes. The experimental set-up is a fixed step-angle walker constructed using two synchronized adjacent rimless wheels independently actuated at the hub. Varying the magnitude and duty ratio of the torque pulse, the four proposed regimes are experimentally shown. The mechanical power consumption and cost of transport are computed from measured motor currents for different average forward speeds. Videos of the walks are also taken. The space of operating points for an inverted pendulum based bipedal dynamic walker in terms of constraints and optimality is investigated. The operating point of the walker can be specified by the combination of initial mid-stance velocity (v0) and step angle (φm) chosen for a given walk. Not all operating points lead to a realizable steady-state gait. Using basic mechanics, a framework of physical constraints that limit the choice of operating points is proposed. The constraint lines thus obtained delimit the valid region of operation of the walker in the v0–φm plane. Within this allowable region, sub-regions that result in various regimes of walking are identified. A given average forward velocity vx,avg can be achieved by several combinations of v0 and φm. Only one of these combinations results in the minimum mechanical power consumption and can be considered the opti-mum operating point for the given vx,avg. A method is proposed for obtaining this optimal operating point based on tangency of the power and velocity contours. Putting together all such operating points for various vx,avg, a family of optimum operating points, called the optimal locus, is obtained. For the energy loss and internal energy models chosen, the optimal locus obtained has a largely constant step angle with increasing speed but tapers off at non-dimensional speeds close to unity. Thus, choosing the right step angle and keeping it fixed over a broad range of speeds could lead to an inverted pendulum walker that is close to optimal from a mechanical energy perspective. The complete hardware design for Chatur and the caveats associated with reliable performance of the mechanical and electrical subsystems are elaborated. In order to en-sure lateral stability, the system uses two contralateral wheels each driven by a separate BLDC hub motor. From a motor drive perspective, the mechanical load belongs to a unique class of dynamic loads whose reflected torque has a characteristic cyclic varia-tion that repeats several times within a mechanical revolution. The proposed control topology has two hierarchical levels, an inner loop for torque control of BLDC motor implemented using a standard proportional-integral controller, and an outer loop for torque reference generation that uses the information on the ground impact instants and the motor position feedback. Ground impacts of the spokes are detected by an accelerometer to initiate the application of torque. The torque pulse magnitude can be set internally or by a manual operator via radio control. The pulse duration is programmable and enables attainment of various torque regimes at different steady state speeds. The wheels are synchronized so that corresponding spokes on both wheels move in unison. This is achieved by including a wheel synchronization loop that compensates for any lag between the wheels. Lag is detected based on number of sector changes in the hall-effect position sensor data received from both motors. An improved BLDC motor drive is developed wherein non-commutating current feedback is used to reduce current spikes during sector transitions. Experimental waveforms for controller validation are shown.

L’utilisation de systèmes robotiques pour la navigation dans des zones confinées pose des défis intéressants sur les thèmes de conception, de modélisation et de commande, particulièrement complexes pour les applications médicales. Dans ce contexte, nous introduisons un nouveau concept de robots continus, fortement prometteurs pour des applications biomédicales, dont la forme complexe, la dextérité et la capacité de miniaturisation constituent des avantages majeurs pour la navigation intra corporelle. Parmi cette classe, les robots à tubes concentriques (RTC), qui constituent notre point de départ, sont améliorés grâce à un actionnement embarqué innovant. Nos travaux s’articulent autour de deux thématiques aux frontières de l’état de l’art. D’une part, nous avons proposé une modélisation générique et conduit une analyse cinématique approfondie de robots continus basés sur l’architecture des RTC standards et ceux avec changement de courbure de leurs tubes dans deux variantes : courbures unidirectionnelle et bidirectionnelle. D’autre part, leur commande cartésienne en pose complète est introduite avec une validation expérimentale sur un prototype développé de RTC standard, ainsi que les simulations numériques d’une loi de commande comprenant la gestion de la redondance des RTC à changement de courbure. D’autre part, nous avons effectué la synthèse, la caractérisation et la mise en œuvre de micro-actionneurs souples basés sur les polymères électro-actifs (PEA), intégrés pour la première fois dans un robot continu.Ainsi, l’asservissement visuel d’un prototype de robot télescopique souple est proposé avec des précisions atteignant 0.21 mm sur différentes trajectoires. / Major challenges need to be risen in order to perform navigation in confined spaces with robotic systems in terms of design, modeling, and control, particularly for biomedical applications. Indeed,the complex shape, dexterity, and miniaturization ability of continuum robots can help solving intracorporeal navigation problems. Within this class, we introduce a novel concept in order to augment the concentric tube robots (CTR) with embedded actuation. Our works hinge on two majorcutting-edge thematics. On the one hand, we address modeling and kinematics analysis of standard CTR as well as variable curvature CTR with their two varieties : single and double bending directions.Furthermore, we perform the experimental validation of Cartesian control of a CTR prototype, anda task hierarchy based control law for redundancy resolution of CTR with variable curvatures. Onthe other hand, we develop the synthesis, the characterization, and the integration of soft microactuatorsbased on electro-active polymers (EAP) for the first time in a continuum robot. Thus, thevisual servoing of a telescopic soft robot is performed with precisions down to 0.21 mm following different trajectories.

Les matériaux composites prennent une place de plus en plus importante dans la conception et la fabrication des moyens de transport et notamment dans le domaine naval où ils sont particulièrement privilégiés. En effet, ces matériaux sont utilisés pour leur légèreté, insensibilité à la corrosion et leurs caractéristiques mécaniques. Dans le domaine militaire, où l'optimisation des moyens de communication et de protection électromagnétique est primordiale, le développement de matériaux composites dotés de propriétés de reconfigurabilité sous commande(s) externe(s), présente un atout opérationnel majeur pour les parois structurales exploitant ces matériaux. Afin d'explorer cette voie, DCNS et l'Institut d’Électronique et de Télécommunications de Rennes (IETR, UMR-6164) se sont associés. Les travaux de thèse engagés ont pour objectif d'étudier et de développer des matériaux composites présentant des fonctions de reconfigurabilité applicables aux systèmes navals tels que les radômes, les antennes et exploitables pour répondre aux problématiques de furtivité (SER). Une première étude a permis d'explorer les matériaux à base de carbone, présentant une potentielle agilité de leurs caractéristiques diélectriques sous actuateur électrique. Ces matériaux présentent également un fort pouvoir absorbant électromagnétique, tributaire des propriétés diélectriques, elles-mêmes potentiellement reconfigurables. La seconde étude engagée a étudié l'impact des matériaux ferroélectriques, c'est-à-dire des matériaux reconfigurables sous champ électrique, lorsqu'ils sont intégrés comme charge dans une résine d'imprégnation. Ce nouveau matériau composite présente alors une reconfigurabilité de ses caractéristiques diélectriques, rendant commandable en fréquence sa structure hôte. Une troisième étude, exploitant aussi le matériau ferroélectrique a permis l'obtention d'une reconfigurabilité des caractéristiques de réflectivité de panneaux composites grâce au développement de surfaces sélectives en fréquence reconfigurables. De nouvelles propriétés ont ainsi été mises en évidence en hyperfréquences. Enfin, les matériaux d'âmes et spécifiquement les nids d'abeilles diélectriques ont fait l'étude d'une fonctionnalisation pour des applications DC et hyperfréquences. / Composite materials are used for their lightness, high resistance to corrosion and high mechanical properties over large application areas, such as naval, ground and aerial. Collaboration between DCNS group and the Institute of Electronics and Telecommunications of Rennes (IETR, UMR-6164) has been initiated to develop smart composite materials with tunable properties at microwaves. Three different routes have been investigated during the thesis work. The first one is based on carbon composite material, its electromagnetic absorbing ability and its potential dielectric tunability. For this, we develop composite materials loaded with various carbon particles (carbon nanotube, graphene, black carbon). Next, to elaborate smart composite materials, a ferroelectric material has been used as filler. The dielectric characteristics of such materials can be tuned under external biasing for example. Thus we develop an active composite material under various external actuators for naval application, and especially for new reconfigurable frequency selective surface (RFSS). Finally dielectric honeycomb materials have been specifically elaborated and studied to develop smart properties for DC and microwave applications. During this work, three different prototypes improving composite materials in naval area have been performed: reconfigurable radome, RCS reduction, and antenna isolation.

Cette thèse porte sur une nouvelle approche pour le contrôle d’écoulement aérodynamique. Cette nouvelleapproche est basée sur l’utilisation d’actionneurs plasma. La modélisation numérique peut être une outilpuissante entre les mains des scientifiques et des ingénieurs pour comprendre, optimiser et ainsi ouvrir lavoie à la commercialisation et l’application de cette technologie. Le couplage entre l’électromagnétisme, leplasma et l’écoulement, nécessite des modèles et des techniques numériques avancées. Le travail présentédans cette thèse, a pour principaux objectifs : le développement et la validation de méthodes numériques poursimuler efficacement le fonctionnement de certains des plus importants types d’actionneurs plasma. Nousnous sommes intéressés à trois types d’actionneurs plasma : les décharges micro-ondes, la décharge à barrièrediélectrique (DBD) et le jet synthétique plasma (JSP).En ce qui concerne les décharges microondes, les objectifs sont plus fondamentaux que pour les autrestypes d’actionneurs. Il s’est agit de mieux comprendre la création du plasma, son évolution et de calculerl’efficacité énergétique de dispositifs microondes par la simulation numérique. Un schéma couplé implicite(ADI) - FDTD avec un modèle de plasma fluide simplifié est présenté. Cette formulation conserve la simplicitéet la robustesse des systèmes de FDTD, tout en dépassant la barrière du critère de stabilité CFL. Elle conduità un temps de calcul réduit et la possibilité de réaliser des simulations tridimensionnelles de la formationdu plasma et de l’évolution d’un plasma dans un champ micro-ondes. Afin d’étudier l’énergie absorbée parle plasma et le transfert vers le gaz sous forme de chaleur ainsi que le changement consécutif de la densitédu gaz, un solveur Euler a été couplé avec le modèle EM-plasma en tenant compte des effets de gaz réel.Diverses validations et applications sont ensuite étudiés. Des simulations tridimensionnelles de formationdu plasma sont réalisée qui montrent la formation de structures dans une décharge micro-ondes librementlocalisée. Les effets de chauffage de gaz sur le développement d’un "streamer" et la durée d’un volumepré-ionisé avec des champs sous-critiques sont également calculés.En ce qui concerne les deux autres groupes d’actionneurs, les objectifs de cette thèse se concentrent sur lamodélisation de leur fonctionnement et sur la production d’écoulement qui en résulte. Le Jet Synthétique Plasma a été numériquement étudié par trois modèles couplés. Les résultats obtenus sont prometteurspour l’optimisation du JSP et une meilleure compréhension des mécanismes qui limitent ses performances.L’actionneur DBD a été modélisée en utilisant deux solveurs différents basés sur des modèles physiquessimilaires - celui développé à l’ONERA et l’autre à LAPLACE. Des études paramétriques ont montré queles modèles donnent une estimation assez précise de la force produite par le DBD par rapport à des mesuresexpérimentales. Des applications aérodynamiques de contrôle d’écoulement ont démontré les effets possiblesde ces actionneurs pour la transition laminaire - turbulente et l’amélioration de la portance. Ces travauxouvrent une perspective nouvelle dans la conception et l’optimisation de ces actionneurs. / As aerodynamic flow control still remains one of the top subjects of research in the aerospace scientific world, new ways to perform such a control are being constantly studied. Plasma actuators based on momentum or energy addition in the flow, have been proven capable of positively modifying the flow aerodynamic features. Nevertheless, the development and optimization of such actuators, require further understanding of the basic multi-scale physics involved. In this thesis, we are interested in the numerical modeling of plasma flow control actuators. Three types of plasma actuators are considered: Microwave Plasma Discharges (MPD), the Dielectric Barrier Discharge (DBD) and the Plasma Synthetic Jet (PSJ). Concerning MPDs, a novel implicit approach has been developed which with have enabled three-dimensional simulations in time domain in reduced CPU time. The microwave breakdown and evolution of the plasma due to the electromagnetic waves has been studied numerically, demonstrating the three-dimensional nature of such discharges. Coupling of the EM-plasma model with an Euler based solver accounting for real gas effects, have revealed the plasma modification due to the intense gas heating. For the PSJ actuator, the numerical solver consists of three coupled numerical models and the obtained results of its operation offer important information of its performance and its limits. The DBD actuator has been numerically studied using 2 different solvers (based on the same physical model). Both solvers were capable to give quite accurate estimations of the induced force due to the plasma and various parametric studies have been conducted. These studies offer new perspectives in the understanding and the optimization of plasma actuators for flow control purposes.

Dans le domaine de l'aéronautique, les concepts basés sur l’usage étendu de l'électricité dans les aéronefs plus électriques (MEA) et même tout électriques (AEA) font appel à des actionneurs électromécaniques (EMA) en replacement des actionneurs servo-hydrauliques conventionnels (HSA). Lorsque les EMA sont utilisés pour des applications d'actionnement critique comme les commandes de vol, certains problèmes spécifiques liés à l’équilibre thermique, l'inertie réfléchie, le mouvement parasite dû aux élasticités structurelles, la réponse aux fautes (grippage et rupture) et la synchronisation d’EMA actifs sur charges indépendantes ne peuvent être ignorés. La simulation apporte un support indéniable à la conception pour l’évaluation et la validation des concepts. A cet effet, il est nécessaire de développer des prototypes virtuels des EMA avec une vision système et de façon structurée pour répondre aux besoins des ingénieurs. Malheureusement, les phénomènes physiques qui apparaissent dans les EMA sont multidisciplinaires, couplés et fortement non linéaires. De nombreux logiciels commerciaux de simulation système multi-domaines sont désormais disponibles. Cependant, le processus de modélisation et les besoins des ingénieurs sont rarement pris en compte selon une vision globale, en raison du manque d'approches scientifiques pour la définition d’architectures, la modélisation incrémentale et l’amélioration de l’implémentation numérique des modèles. Dans cette thèse, le prototypage virtuel de l'EMA est adressé en utilisant le formalisme Bond-Graph. De nouvelles approches sont proposées pour permettre la modélisation incrémentale de l'EMA en vue de fournir des modèles pour la synthèse de la commande, l’évaluation de la consommation d'énergie, l'analyse thermique, le calcul des forces de réaction, la simulation de la pollution du réseau d'alimentation électrique, la réponse aux fautes et l'influence de la température. L’intérêt des modèles proposés est illustré sur l’exemple de la synchronisation de position de deux EMA actionnant des charges indépendantes. / In the aerospace field, the concepts based on extended use of electricity in “More Electric Aircraft” (MEA) and even “All Electric Aircraft” (AEA), involve electromechanical actuators (EMAs) to replace conventional hydraulic servo actuators (HSAs). When EMAs are used for safety-critical actuation applications like flight controls, some specific issues related to thermal balance, reflected inertia, parasitic motion due to compliance, response to failure (jamming and free-run) and synchronization of EMAs driving independent loads cannot be ignored. The simulation-aided design process can efficiently support the assessment and validation of the concepts fixing these issues. For that, virtual prototypes of EMAs at system-level have to be developed in a structured way that meets the engineers’ needs. Unfortunately, the physical effects governing the EMAs behavior are multidisciplinary, coupled and highly nonlinear. Although numerous multi-domain and system-level simulation packages are now available in the market of simulation software, the modelling process and the engineers’ needs are rarely addressed as a whole because of lack of scientific approaches for model-based architecting, multi-purpose incremental modelling and model implementation for efficient numerical simulation. In this thesis, the virtual prototyping of EMAs is addressed using the Bond-Graph formalism. New approaches are proposed to enable incremental modelling of EMAs that provides models supporting control design, energy consumption and thermal analysis, calculation of reaction forces, power network pollution simulation, prediction of response to faults and influence of temperature. The case of preliminary design of EMAs position synchronization is used to highlight the interests and advantages of the proposed process and models of EMAs.

In this thesis, a new method is followed to design an active control system which imparts viscoelastic phenomenological damping in an elastic structure. Properties of a hypothetical viscoelastic system are used to design an active feedback controller for an undamped structural system with distributed sensor, actuator and controller. The variational structure is projected on a solution space of a closed-loop system involving a weakly damped structure with distributed sensor and actuator with controller. These controller components assign the phenomenology based on internal strain rate damping parameter of a viscoelastic system to the undamped elastic structure. An elastic cantilever beam with proportional-derivative controller and displacement feedback is considered in all the design formulations. In the first part of the research, a closed-loop control system is designed using two time domain modern control system design methods, pole placement and optimal pole placement, which use viscoelastic damping parameter. Equation of motion of a viscoelastic system is employed to synthesize the desired closed-loop poles. Desired poles are then assigned to an elastic beam with an active controller. Time domain finite element formulation is used without considering actuator-sensor dynamics and the effect of transducer locations. Characteristics of closed-loop system gains are found as a function of desired damping parameter and realization of damping have been analyzed with closed loop system pole positions. The next part consists of a novel frequency domain active control system design to impart desired viscoelastic characteristics, which uses spectral method and the exact dynamic stiffness matrix of the system. In the first case, a sub-optimal local control system for a cantilever beam, with collocated actuator and sensor is designed. In the second case, a closed-loop local controller for an elastic system with non-collocated transducers is designed. Next, a global controller for non-collocated arrangement of sensor-actuator is designed by considering all the degrees-of freedom in the system, which leads to solving an eigenvalue problem. The reason for the failure of the collocated arrangement in global control is also explained. In this novel control system design method transducer dynamics and locations are considered in the formulation. In frequency domain design, the frequency responses of the system show satisfactory performance of the closed-loop elastic system. The closed-loop system is able to reproduce the desired viscoelastic characteristics as targeted in the design. Optimal and sub-optimal system gains are found as functions of transducer locations, transducer properties, excitation frequency and internal strain rate damping parameter of a hypothetical viscoelastic system. Performance of the closed loop system is established by comparing the specific damping capacity of the hypothetical viscoelastic system with that of the closed-loop elastic system. The novel frequency domain method is simple, accurate, efficient and can be extended to complex structures to achieve desired damping. The method can be a better way of designing structures with variable stiffness which has research potential in designing morphing airplanes/spacecrafts. The ultimate goal of this research is that, if this design method is applied to practical applications such as aircraft wings, where vibration is undesirable, one would be able to achieve strength and desired damping characters simultaneously.

No description available.

Problems in the control and identification of structural dynamic systems can lead to multimodal optimization problems, which are difficult to solve using classical gradient based methods. In this work, optimization problems pertaining to the vibration control of smart structures and the exploration of isospectral systems are addressed. Isospectral vibrating systems have identical natural frequencies, and existence of the isospectral systems proves non-uniqueness in system identification. For the smart structure problem, the optimal location(s) of collocated actuator(s)/sensor(s) and the optimal feedback gain matrix are obtained by maximizing the energy dissipated by the feedback control system. For the isospectral system problem, both discrete and continuous systems are considered. An error function is designed to calculate the error between the spectra of two distinct structural dynamic systems. For the discrete system, the Jacobi matrix, derived from the given system, is modified and the problem is posed as an optimization problem where the objective is to minimize the non-negative error function. Isospectral spring-mass systems are obtained. For the continuous system, finite element modeling is used and an error function is designed to calculate the error between the spectra of the uniform beam and the non-uniform beam. Non-uniform cantilever beams which are isospectral to a given uniform cantilever beam are obtained by minimizing the non-negative error function. Numerical studies reveal several isospectral systems, and optimal gain matrices and sensor/actuator locations for the smart structure. New evolutionary algorithms, which do not need genetic operators such as crossover and mutation, are used for the optimization. These algorithms are: Artificial bee colony (ABC) algorithm, Glowworm swarm optimization (GSO) algorithm, Firefly algorithm (FA) and Electromagnetism inspired optimization (EIO) algorithm.

With the discovery of conductivity in doped polyacetylene (PA), a new era in synthetic metals has emerged by breaking the traditionally accepted view that polymers were always insulating. Conducting polymers are essentially characterized by the presence of conjugated bonding on the polymeric back bone, which facilitates the formation of polarons and bipolarons as charge carriers. Among the numerous conducting polymers synthesized to date, polypyrrole (PPy) is by far the most extensively studied because of prodigious number of applications owing to its facile polymerizability, environmental stability, high electrical conductivity, biocompatibility, and redox state dependent physico-chemical properties. Electrochemically prepared PPy is more interesting than the chemically prepared polymer because it adheres to the electrode surface and can be directly used for applications such as supercapacitors, electrochemical sensors, electromechanical actuators and drug delivery systems. In quest for improvement in quality of the device performances in the mentioned applications, micro and nano structured polymeric materials which bring in large surface area are studied. Finding a simple and efficient method of synthesis is very important for producing devices of PPy microstructures. Till date, Hard and soft template methods are the most employed methods for synthesis of these structures. Soft template based electrochemical methods are better than hard template methods to grow clean PPy microstructures on electrode substrates as procedures for removal of hard templates after the growth of microstructures are very complex. As per the literature, there is no unique method available to grow PPy microstructures which can demonstrate several applications. Although gas bubble based soft template methods are exploited to grow conducting polymer microstructures of sizes in few hundreds of micrometers, studies on applications of the same are limited. Hence it is planned to develop procedures to grow microstructures that can be used in several applications. In the current work, PPy microstructures with high coverage densities are synthesized on various electrode substrates by soft template based electrochemical techniques. Hollow, hemispherical and spherical PPy microstructures are developed by a two step method using electro generated hydrogen bubble templates on SS 304 electrodes. In the first step, Hydrogen bubbles are electro generated and stabilized on the electrode in the presence of β- naphthalene sulfonic acid (β-NSA). In the second step, Pyrrole is oxidised over the bubble template to form PPy microstructures. Microstructures (open and closed cups) of average size 15 μm are uniformly spread on the surface with a coverage density of 2.5×105 units /cm2. Globular PPy microstructures are developed by a single step method using concomitantly electro generated oxygen bubble templates on SS 304 electrodes during electropolymerization. Microstructures of average size 4 μm are uniformly spread on the surface with a coverage density of 7×105 units/cm2. Surfactant properties of Zwitterionic 4-(2-hydroxyethyl)-1-piperazine ethane sulfonic acid (HEPES) are exploited for the first time to grow conducting polymer microstructures. Ramekin shaped PPy microstructures are developed using HEPES as the surfactant to stabilize hydrogen bubble templates in a two step electrochemical synthesis method. Microramekins of size 100 µm are uniformly spread on the surface with a coverage density of 3000 units/cm2. Micropipettes and microhorns of PPy are synthesised by a single step electrochemical route using HEPES as a surfactant. Hollow micropipettes of length 7 µm with an opening of 200 nm at the top of the structure are observed. Similarly microhorn/celia structures are observed with length 10-15 µm. Microcelia are uniformly distributed over the surface with each structure having a diameter of 2 µm at the base to 150 nm at the tip. Growth mechanism based on contact angle of the reactant solution droplets on the substrate is proposed. PPy microstructures are characterized by scanning electron microscopy, X-Ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, Raman Spectroscopy and UV-Visible spectroscopy to study morphology, ‘chemical bonding and structure’ , ‘defects and charge carriers’. Applicability of the electrodes with PPy microstructures in supercapacitors is investigated by cyclic voltammetry, chronopotentiometry and electrical impedance spectroscopy. Electrodes developed by all the above methods demonstrated very good supercapacitance properties. Supercapacitor studies revealed very high specific capacitances (580, 915, 728 and 922 F/g,) and specific powers (20, 25, 13.89 and 15.91 kW/kg) for electrodes with PPy microstructures (H2 bubble based two step method, O2 bubble based single step method, HEPES stabilized H2 bubbble method and HEPES based microhorn/celia structures respectively). Supercapacitive behavior of all the electrodes is retained even after an extended charge-discharge cycling in excess of 1500 cycles. Horseradish peroxidase entrapped, bowl shaped PPy microstructures are developed for H2O2 biosensing. Amperometric biosensor has a performance comparable to the sensors reported in the literature with high sensitivity value of 12.8 μA/(cm2.mM) in the range 1.0 mM to 10 mM. Glucose oxidase entrapped PPy amperometric biosensor is developed for Glucose sensing. Sensitivity of 1.29 mA/(cm2.mM) is observed for β-D-Glucose sensing in the 0.1 mM to 5.0 mM range while 58 μA/(cm2.mM) is observed in the 5.0 to 40 mM range. Potentiometric urea sensor with urease entrapped PPy microstructures on SS electrode is developed. It is able to sense urea in the micromolar ranges down to 0.1 μM. It represented an excellent performance with sensitivity of 27 mV/decade. Sensitivity in the micromolar range is 4.9 mV/(μM.cm2). Drug encapsulation and delivery is successfully demonstrated by two actuation means (i) by electrochemical actuation, (ii) by actuation based on pH changes. Concepts are proved by delivering a fluorescent dye into neutral and acidic solutions. Drug delivery is confirmed by UV-Visible spectroscopy and Fluorescence microscopy. Finally, Micro/nanostructures with Tangerine, Hollow globular (Pani Poori), Chip, Flake, Rose, Worm, Horn and Celia shapes are synthesized electrochemically and scanning electron microscopic studies are presented. Controlled growth of microstructures on lithographically patterned gold interdigital electrodes is demonstrated with a future goal of creating addressable microstructures. The studies reported in the thesis provide an insight on various applications of PPy microstructures (supercapacitors, sensors and drug delivery systems) developed by a unique methodology based on electrochemically generated gas bubble templates.