Using a theoretical synergy between the Psychological Continuum Model (PCM) and Behavioral Ecological Model (BEM), the current dissertation research provides empirical evidence to support that organized participant sporting events can play a significant role in building a healthier community. First, using a proprietary U.S. community-based panel data from 2008 to 2014, study 1 examines the incremental effects of participant sporting events (PSE) in promoting active living at the population level. Panel regression with an instrumental variable approach and Multigroup Latent Growth Curve Analysis were administered. The key findings included (1) these population-based interventions have the capacity to impact population health at the state level; (2) such an influence significantly varies across the United States contingent upon a state’s economic development and the geographical region to which a state belongs. In study 2, the Multilevel Mediation Analysis was conducted with a spatially clustered cross-sectional data in 2014. The findings revealed that the access to exercise opportunities at the state level represents the underlying mechanism through which various forms of participant sporting events have the ability to elicit positive effects on health with respects to mental health, physical health, and physical activity participation at the county level. The findings suggested that PSEs represent effective public health platform to create healthier communities through integrating physically active leisure into population’s everyday routines. Overall, empirical results also help us better understand the importance of effectively leveraging community sporting events to deliver required health benefits to the general public and create practical guidelines to inform policy formation on resource allocation. / Tourism and Sport

The aerospace industry is increasingly coming to the conclusion that physics-based high-fidelity models need to be used as early as possible in the design of its products. At the preliminary design stage of wing structures, though highly desirable for its high accuracy, a detailed finite element analysis(FEA) is often not feasible due to the prohibitive preparation time for the FE model data and high computation cost caused by large degrees of freedom. In view of this situation, often equivalent beam models are used for the purpose of obtaining global solutions. However, for wings with low aspect ratio, the use of equivalent beam models is questionable, and using an equivalent plate model would be more promising. An efficient method, Equivalent Plate Analysis or simply EPA, using an equivalent plate model, is developed in the present work for studying the static and free-vibration problems of built-up wing structures composed of skins, spars, and ribs. The model includes the transverse shear effects by treating the built-up wing as a plate following the Reissner-Mindlin theory (FSDT). The Ritz method is used with the Legendre polynomials being employed as the trial functions. Formulations are such that there is no limitation on the wing thickness distribution. This method is evaluated, by comparing the results with those obtained using MSC/NASTRAN, for a set of examples including both static and dynamic problems. The Equivalent Plate Analysis (EPA) as explained above is also used as a basis for generating other efficient methods for the early design stage of wing structures, such that they can be incorporated with optimization tools into the process of searching for an optimal design. In the search for an optimal design, it is essential to assess the structural responses quickly at any design space point. For such purpose, the FEA or even the above EPA, which establishes the stiffness and mass matrices by integrating contributions spar by spar, rib by rib, are not efficient enough. One approach is to use the Artificial Neural Network (ANN), or simply called Neural Network (NN) as a means of simulating the structural responses of wings. Upon an investigation of applications of NN in structural engineering, methods of using NN for the present purpose are explored in two directions, i.e. the direct application and the indirect application. The direct method uses FEA or EPA generated results directly as the output. In the indirect method, the wing inner-structure is combined with the skins to form an "equivalent" material. The constitutive matrix, which relates the stress vector to the strain vector, and the density of the equivalent material are obtained by enforcing mass and stiffness matrix equities with regard to the EPA in a least-square sense. Neural networks for these material properties are trained in terms of the design variables of the wing structure. It is shown that this EPA with indirect application of Neural Networks, or simply called an Equivalent Skin Analysis (ESA) of the wing structure, is more efficient than the EPA and still fairly good results can be obtained. Another approach is to use the sensitivity techniques. Sensitivity techniques are frequently used in structural design practices for searching the optimal solutions near a baseline design. In the present work, the modal response of general trapezoidal wing structures is approximated using shape sensitivities up to the second order, and the use of second order sensitivities proved to be yielding much better results than the case where only first order sensitivities are used. Also different approaches of computing the derivatives are investigated. In a design space with a lot of design points, when sensitivities at each design point are obtained, it is shown that the global variation in the design space can be readily given based on these sensitivities. / Ph. D.

Cette thèse est consacrée à l'étude des écoulements de gaz raréfiés à travers divers micro-conduits de type circulaire et rectangulaire dans des conditions isotherme et stationnaire. L'objectif de la thèse est de contribuer à l'étude de l'interaction gaz-surface notamment en déterminant le coefficient d'accommodation de la quantité de mouvement pour différent matériaux de surface (Or, Silice, Acier inoxydable et Sulfinert) associés à différents types de gaz (hélium, azote, argon et dioxyde-de-carbone). Afin d'atteindre cet objectif, on adopte un triple point de vue : expérimental, théorique et numérique. L'aspect expérimental est réalisé par des mesures de débit massique à travers les micro-conduits, en utilisant la méthode dite « à volume constant ». L'aspect théorique original est développé à travers une nouvelle approche basée sur la résolution de l'équation de Stokes. Cette approche a permis d'écrire une expression analytique de débit massique en régime de glissement, qui prenne en compte les effets bidimensionnels dans une section de conduit rectangulaire. Cette approche complètement explicite, est conduite au deuxième ordre. Enfin l'aspect numérique permet de calculer le débit massique, en régimes transitionnel et moléculaire libre, en résolvant numériquement l'équation cinétique BGK linéarisée. La comparaison des mesures de débit massique avec l'équation analytique, en régime de glissement, ou avec les calculs numériques, en régimes transitionnel et moléculaire libre, nous a permis de déduire des coefficients de glissement et les coefficients d'accommodation correspondant à chaque couple gaz-surface dans tous les régimes de raréfaction. / This thesis is devoted to the study of rarefied gas flows through micro-channels of various cross sections (circular and rectangular) under isothermal and stationary conditions. The objective of this thesis is to contribute to the study of gas-surface interaction by determining the tangential momentum accommodation coefficient for different surface materials (gold, silica, stainless steel and Sulfinert) and associated to various gases (helium, nitrogen, argon and carbon-dioxide). To achieve this goal three aspects are considered: experimental, theoretical and numerical. The experimental aspect is considered by measuring the mass flow rate through microchannels using the constant volume technique. The theoretical aspect is considered by the development of a new approach based on the Stokes equations. This approach yields to the analytical expression of the mass flow rate in the slip regime, which takes into account the second order effects. The last aspect, numerical, is considered by the numerical simulations of the mass flow rate in the transitional and free molecular flow regimes by solving the linearized BGK kinetic model. The comparison between the measured mass flow rates and the analytically expressions in the slip regime or with the results of numerical simulations in the transitional and free molecular regimes enabled to deduce the tangential momentum accommodation coefficients corresponding to each pair gas-surface in all flow regimes.

Fauna conservation outside protected areas can make an important complementary contribution to conservation within reserves. This thesis aimed to contribute new information and analytical frameworks to the science of fauna conservation in human-modified landscapes. Two approaches were used: (1) empirical data collection and analysis, and (2) the discussion and development of conceptual landscape models. ¶ Empirical work focused on lizard distribution patterns in two production landscapes in southeastern Australia. Lizards were targeted because ectotherms are frequently neglected by conservation biologists. The “Nanangroe grazing landscape” was used for sheep and cattle grazing. In this landscape, approximately 85% of pre-European woodland cover had been cleared, and understorey vegetation was sparse. Lizards were surveyed at 16 landscape units, which were stratified by aspect, topographic position and amount of tree cover. Each landscape unit contained three sites, and each site contained three plots. Regression modelling showed that different species responded differently to their environment. For example, the four-fingered skink (Carlia tetradactyla) and Boulenger’s skink (Morethia boulengeri) were more likely to occur at woodland sites with northerly aspects, whereas the striped skink (Ctenotus robustus) and olive legless lizard (Delma inornata) were more likely to inhabit sites with a simple microhabitat structure. Statistical analysis further showed that the habitat attributes that lizards were related to varied continuously through space, and over different spatial scales. For example, invertebrate abundance (a proxy for food availability) varied most strongly over tens of metres, whereas the amount of grass cover varied most strongly over hundreds to thousands of metres. Thus, work at Nanangroe revealed spatially complex patterns of lizard occurrence and habitat variables. ¶ The “Tumut plantation landscape” was a spatial mosaic of native eucalypt (Eucalyptus) forest patches embedded within a plantation of the introduced radiata pine (Pinus radiata). In this landscape, thirty sites were surveyed for lizards. Sites were stratified by forest type and patch size, and included eucalypt patches, pine sites, and extensive areas of eucalypt forest adjacent to the plantation. Regression modelling showed that lizard species responded to various habitat attributes, including elevation, the amount of eucalypt forest within 1 km of a site, invertebrate abundance and ground cover. Variables related to habitat fragmentation often were significant predictors of lizard occurrence. However, work at Tumut suggested that important additional insights into lizard distribution patterns could be obtained by considering variables related to food and shelter resources, and climatic conditions. ¶ The Nanangroe and Tumut landscapes were in close proximity, but together spanned an altitudinal gradient of 900 m. An investigation of changes in lizard community composition with altitude showed that (1) only one species was common to Nanangroe and Tumut, (2) different species had different altitudinal preferences, and (3) ecologically similar species replaced one another with increasing altitude. These results highlighted that even in highly modified landscapes, natural gradients (such as climate) can play an important role in shaping animal assemblage composition and species distribution patterns. ¶ Empirical work suggested that, in some landscapes, the frequently used “fragmentation model” is a relatively weak conceptual basis for the study of animal distribution patterns. The fragmentation model implicitly assumes that “habitat patches” can be defined unequivocally across many species, and that patches are located within a relatively inhospitable matrix. Where these assumptions are breached, conservation guidelines arising from the fragmentation model may be too simplified. In spatially complex production landscapes, it may be more appropriate to maintain habitat heterogeneity at multiple spatial scales than to focus solely on the management of large, pre-defined patches. ¶ Given the potential limitations of the fragmentation model, a new, more holistic landscape model was developed. The “continuum model” was derived from continuum theory as developed for plant ecology. The continuum model recognises (1) spatial continua of environmental variables, and (2) species’ individualistic responses to these variables. For animals, key environmental variables may be related to the availability of food, shelter, sufficient space, and suitable climatic conditions. Unlike the fragmentation model, the continuum model is inherently process-based and thus may help to link the perceived gap between patterns and processes in landscape ecology. ¶ Three general conclusions arise from this thesis: 1. Some heterogeneous production landscapes support many native species, and therefore represent important conservation opportunities. 2. In some modified landscapes, the fragmentation model does not capture the complexity of animal distribution patterns. In those landscapes, conservation recommendations derived from the fragmentation model may be overly simplistic. 3. The continuum model may be a useful extension of the fragmentation model. It provides a process-based conceptual basis for empirical work on animal distribution patterns.

It has long been observed that salts affect proteins in a variety of ways, yet comprehensive explanations for different salt effects are still lacking. In the work presented here, the effect of salts on proteins has been investigated through three different effects: the hydrophobic effect; their conformational stability; the hydrogen bonding network of water in a protein’s hydration shell. UV-vis absorbance and fluorescence spectroscopy were used to monitor changes in two model systems, the phenol-acetate contact pair and the model enzyme ribonuclease t1. It was shown that salts affect the hydrophobicity of the contact pair according to their charge density, induced image charges play an important role in the observed salt-induced increase of ribonuclease t1 stability, and that salts affect ribonuclease t1 activity through modulation of the hydrogen bonds of water in the enzyme’s hydration shell. This work contributes a greater understanding of the effect of salts on proteins.

It has long been observed that salts affect proteins in a variety of ways, yet comprehensive explanations for different salt effects are still lacking. In the work presented here, the effect of salts on proteins has been investigated through three different effects: the hydrophobic effect; their conformational stability; the hydrogen bonding network of water in a protein’s hydration shell. UV-vis absorbance and fluorescence spectroscopy were used to monitor changes in two model systems, the phenol-acetate contact pair and the model enzyme ribonuclease t1. It was shown that salts affect the hydrophobicity of the contact pair according to their charge density, induced image charges play an important role in the observed salt-induced increase of ribonuclease t1 stability, and that salts affect ribonuclease t1 activity through modulation of the hydrogen bonds of water in the enzyme’s hydration shell. This work contributes a greater understanding of the effect of salts on proteins.

Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2017-07-12T18:05:35Z No. of bitstreams: 1 2016 - Felipe Augusto da Silva.pdf: 12688361 bytes, checksum: 9f1ec0867eb071ebf8dbb7f89606cf25 (MD5) / Made available in DSpace on 2017-07-12T18:05:35Z (GMT). No. of bitstreams: 1 2016 - Felipe Augusto da Silva.pdf: 12688361 bytes, checksum: 9f1ec0867eb071ebf8dbb7f89606cf25 (MD5) Previous issue date: 2016-09-29 / To understand the behavior of molecules in liquid fase is fundamental for comprihend many chemical and physical process, became reference to severa! areas of scientific and tecnologic knowledge. Methods using polarizable continuum model (PCM) have been proposed and revised to achieve more acurated results and the aplicability of the method. MultiPatch is a analitic and eficient molecular smface tesselation method. This smface is necessary to calcule the eletrostatic component of the interaction energy between solute and solvent Delta G s. The method was tested by comparing the results for the smface area and the energy Delta G s obtained using internai methods of the software GAMESS. / Entender o comportamento de mol?culas em fase l?quida ? fundamental para o compreender diversos processos qu?micos e f?sicos, sendo assim refer?ncia para diversas ?reas do conhecimento cient?fico e tecnol?gico. M?todos usando o modelo de cont?nuo polariz?vel (PCM) tem sido propostos e revisados com o objetivo de melhorar a acur?cia dos resultados e a aplicabilidade desse modelo. MultiPatch ? um m?todo anal?tico e eficiente para se obter uma tessela??o da superf?cie molecular necess?ria para o computo de uma das componentes, de origem eletrost?tica, da energia de intera??o entre soluto e solvente Delta G s:. O m?todo foi testado comparando seus resultados para ?rea da superf?cie e a energia Delta G s com o m?todos internos do software GAMESS.

No description available.

A large amount of low-rise unreinforced masonry structures (URM) can be foundin Groningen, the Netherlands. More and more induced earthquakes with shortduration have been detected in this region due to gas exploitation. Local unreinforcedmasonry (URM) buildings were initially not designed for withstanding seismicactions, so that unexpected damage may occur due to their vulnerability, raising insecurityamong residents. Existing low-rise masonry buildings in Groningen can bedivided into different categories based on their characteristics. Two types of residentialmasonry buildings that fulfil the prerequisites for performing non-linear seismicassessment are chosen to be studied in this thesis project, including the terracedhouse and the detached house.The seismic assessment of structures requires the use of both a discretization methodand a seismic assessment method. The discretization method is used to translate themechanical model into a finite element model used for the numerical analysis. Severalmethods have previously shown to be applicable for seismic assessment, but thiswork investigates the implications of using a continuum model (CM) and an equivalentframe model (EFM) approach to discretization in the general-purpose finiteelement package described in DIANA-FEA-BV (2017). The continuum model approachadopted was in a previous work by Schreppers et al. (2017) validated againstexperimental results and is as such deemed representative of the physical behaviourof the mechanical models investigated. An equivalent frame model approach to beused with DIANA is proposed in the work by Nobel (2017). The continuum modelapproach uses continuum elements with a constitutive model developed for the seismicassessment of masonry structures. This constitutive model captures both shearand flexural failure mechanisms. The equivalent frame model approach uses a combinationof numerically integrated beam elements and nodal interfaces, each witha distinct constitutive model, thus decoupling the description of the flexural andshear behaviour. This approach aims to capture the macro-behaviour at the structurallevel. The applicability of the proposed equivalent frame model approach isevaluated by how well it replicates the validated continuum model approach results.The two discretization methods described are evaluated using two types of seismicassessment methods. The first seismic assessment method used consists of first performinga quasi-static non-linear pushover analysis (NLPO) on the model. Thisresults in the pushover curve, which describes the global behaviour of the modelunder an equivalent lateral load based on the fundamental mode shape of the structure.The pushover curve is then used with the N2-method described in EN1998-1iii(2004) to assess at which peak ground acceleration (PGA) that the model reachesthe near-collapse (NC) limit state. The second seismic assessment method consistsof performing dynamic non-linear time-history analyses (NLTH). This method usesrecorded accelerograms to impose the inertial forces. The PGA for the accelerogramwhere the near-collapse limit state is reached is compared to the PGA fromthe use of the N2-method. The applicability of the pushover analysis in conjunctionwith the N2-method is evaluated by how well it replicates the PGA found from thetime-history analyses and by how well it replicates local failure mechanisms.Therefore, the main objectives of this project can be described by the following twoquestions:i. To what extent can the equivalent frame method be applicable as a properdiscretization method for pushover analyses and time-history analyses oflow-rise unreinforced masonry residential buildings in the Groningen region?ii. To what extent can the non-linear pushover method be adopted toassess the seismic behaviour of low-rise unreinforced masonry residentialbuildings in the Groningen region?The applicability of the equivalent frame model showed to vary. For describing localfailure mechanisms its applicability is poor. Further work on connecting the edgepiers to transverse walls is needed. For seismic assessment using the N2-method theapplicability of the equivalent frame model approach is sensible. The conservativedisplacement capacity counteracts the fact that it is worse at describing local unloading,which produced a larger initial equivalent stiffness of the bi-linear curvesin comparison to the continuum model. For seismic assessment using the timehistorysignals, its applicability is possible. While it could show different behaviourin terms of displacement and damping forces, it still showed a similar PGA at thenear-collapse limit state for the cases at hand.The seismic assessment of the terraced and detached houses by the N2-method issimilar to the seismic prediction by applying time-history analyses. However, thereare still some variations in the initial stiffness, force capacity and displacement capacitybetween these two assessment methods due to the assumptions and limitationsin this study. Overall, considering the pros and cons of the quasi-static pushovermethod, it is deemed applicable during the seismic assessment of the unreinforcedmasonry structures in the Groningen area.

Dissolved organic matter (DOM) is the largest pool of organic carbon in aquatic systems and an important component of the global carbon cycle. Large amounts of DOM are decomposed within lakes, resulting in fluxes of CO2 and CH4 to the atmosphere. Therefore, there is a considerable interest in understanding the controls of DOM decomposition in freshwaters. There is evidence that in lakes intrinsic controls related to DOM composition are of primary importance, yet our knowledge about molecular drivers of DOM degradation is limited. This thesis addresses the link between chemical composition and reactivity of lake DOM by applying an experimental approach, molecular-level DOM characterization, and kinetic modeling of DOM decay. The first study shows that photoinduced transformations and partial removal of colored aromatic components of DOM have profound effects on DOM degradation kinetics, mediated by the shifts in the relative share of rapidly and slowly degrading DOM fractions. Two following studies estimate exponential decay coefficients for each individual molecular formula identified within bulk DOM. A continuous distribution of exponential decay coefficients is found within bulk DOM, which directly corroborates the central and previously empirically untested assumption behind the reactivity continuum model of DOM decay. Further, individual decay rates are evaluated in connection to specific molecular properties. On average, highly unsaturated and phenolic compounds appear to be more persistent than compounds with higher aromatic content (plant polyphenols and polycondensed aromatics), and aliphatic compounds demonstrate the highest decay rates. The reactivity of aromatics additionally increases with increasing nominal oxidation state of carbon. Molecular analysis further indicates that increasing reactivity of DOM after UV exposure is caused by disintegration of supramolecular complexes. Study IV shows that changes in relative proportion of terrestrial versus algal DOM control degradability of DOM through seasons. Under ice, when algal-derived DOM is maximally depleted, DOM degradation potential converges to similarly low levels, regardless of lake type (productive or humic), and bacterial respiration primarily relies on terrestrial carbon. This suggests a general pattern of baseline metabolism across boreal lakes. I conclude that DOM is a dynamic reactivity continuum and a tight link exists between DOM behavior and compositional properties.