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Caracteriza????o filogen??tica e funcional da microbiota do intestino do Cupim Comedor de Serapilheira Syntermes wheeleri (Termitidae: Syntermitinae)Santana, Renata Henrique 31 March 2017 (has links)
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Previous issue date: 2017-03-31 / Termites are well known for their ability to cause agricultural losses and building damage through their ability to digest lignocellulose; however, termites provide important ecosystem services, such as soil bioturbation and nutrient cycling. Microorganisms in the digestive tract of termites are responsible for several of these functions. Syntermes wheeleri (Syntermitinae) is a litter-feeding termite species of the Termitidae family that is abundant in the Brazilian Cerrado. In this work, we characterized the gut microbiota of S. wheeleri, aiming to better understand the ecosystem function of termite-microbe symbiosis and its evolutionary history. First, the gut microbiota composition of worker termites was described by pyrosequencing phylogenetic markers (amplicons), specifically 16S rRNA (archaea and bacteria) and 18S rRNA (fungi). The resulting bacterial taxonomic profile was then compared with the gut microbiota of several other termite species and feeding guilds. To identify the functional groups and activity of the microbiota in the whole gut and the largest proctodeal segments (P1 and P3), the metagenome and metatranscriptome were sequenced by next-generation sequencing (NGS). Amplicon sequences revealed a high abundance of Firmicutes in S. wheeleri, which was not observed in the other termite species. Most archaea belonged to the methanogen orders, and the most abundant fungal classes were Dothideomycetes, Sordariomycetes, and Eurotiomycetes, which have saprophytic species. Ordination analysis of the relative abundance of bacterial taxa showed that the S. wheeleri gut microbiota did not cluster with the microbiota of termites of different clades and feeding guilds. This finding suggests that both variables are important in microbial assembly in termites. The taxonomic profile generated by NGS analysis of the metagenome was similar to the results of amplicon analysis, with higher Firmicutes abundance in P1 and higher Spirochaetes abundance in P3. Additionally, alignment of ribosomal protein S3 identified possible compartment-specific bacterial lineages of Firmicutes, Spirochaetes, Actinobacteria, Bacteroidetes, and Tenericutes. The results of our study revealed a vast metabolic repertoire of termite gut microbes, which supplies nutrients for the host. Differences identified in the P1 and P3 metabolic pathways are likely caused by differences in O2 concentration. As for biomass conversion, the most abundant glycosyl hydrolases (necessary for lignocellulose digestion) detected in the S. wheeleri gut microbiota are a mixture of those that are most abundant in litter-feeding species (fungus growers), as well as wood-, soil-, and dung-feeding species. In addition, putative bacterial laccases (involved in lignin degradation) were detected. Besides the known function of the termite gut microbiota in carbon and nitrogen cycling, we found evidence of its possible involvement in arsenic cycling. This study adds information about microbial establishment in the termite gut, with functional groups selected based on feeding substrate, instead of specific microbial lineages. In addition, our results show that the metagenome can be used to identify molecules with potential industrial applications, such as enzymes useful in biofuel production. / Os cupins s??o conhecidos por causar perdas agr??colas e danos a edifica????es devido a sua capacidade de digerir celulose. No entanto, os cupins tamb??m fornecem importantes servi??os ecossist??micos como a modifica????o do solo e a ciclagem de nutrientes. Os micro-organismos do trato digestivo dos cupins s??o respons??veis por muitas dessas fun????es. Syntermes wheeleri (Syntermitinae) ?? uma esp??cie de cupim da fam??lia Termitidae, comedora de serapilheira e muito abundante no Cerrado. Neste trabalho caracterizamos a microbiota intestinal de Syntermes wheeleri, buscando esclarecer a fun????o ecossist??mica da simbiose entre cupins e micro-organismos e sua hist??ria evolutiva. Inicialmente, a composi????o da microbiota dos oper??rios foi descrita por meio de pirosequenciamento dos marcadores filogen??ticos (amplicons) 16S rRNA (arqueia e bact??ria) e 18S rRNA (fungo). Em seguida, o perfil taxon??mico de bact??rias foi comparado com o apresentado por diferentes esp??cies de cupins e h??bitos alimentares. Finalmente, para identificar os grupos funcionais presentes e ativos da microbiota no intestino inteiro e em seus compartimentos mais volumosos (primeiro - P1 e terceiro - P3 proctodeo) o metagenoma e metatranscriptoma foram submetidos a sequenciamento de alto rendimento (NGS). As sequ??ncias de amplicons revelaram alta abund??ncia de Firmicutes, n??o observada em outras esp??cies de cupins. A maioria das arqueias pertence ??s ordens de metanog??nicas e as classes de fungos mais abundantes foram Dothideomycetes, Sordariomycetes, e Eurotiomycetes, que possuem membros saprof??ticos. Uma an??lise de ordena????o da abund??ncia relativa dos t??xons de bact??ria mostrou que a microbiota de S. wheeleri n??o agrupou com nenhum clado de cupins da fam??lia Termitidae nem com outras guildas alimentares. Esse resultado indica que ambas as vari??veis afetam a composi????o da microbiota. An??lises do metagenoma apontaram perfil taxon??mico semelhante ao obtido pelas an??lises das sequ??ncias de DNA dos marcadores filogen??ticos, com abund??ncia de Firmicutes maior em P1 e de Spirochaetes maior em P3. Adicionalmente, o alinhamento das prote??nas ribossomais S3, mostrou poss??veis linhagens de bact??rias compartimento-espec??ficas de Firmicutes, Spirochaetes, Actinobacteria, Bacteroidetes e Tenericutes. Os resultados deste estudo revelaram vasto repert??rio metab??lico da microbiota, que fornece nutrientes ao hospedeiro. As diferen??as identificadas nas vias metab??licas de P1 e P3 s??o provavelmente causadas por diferen??as na concentra????o de O2. Em rela????o ?? convers??o de biomassa, as fam??lias de glicosil hidrolases (necess??rias para digest??o da lignocelulose) mais abundantes detectadas na microbiota de S. wheeleri s??o uma mistura daquelas mais abundantes na microbiota de cupins comedores de madeira, de esterco e de cultivadores de fungos. Tamb??m foram detectadas lacases putativas (envolvidas na degrada????o de lignina) de origem bacteriana. Al??m da conhecida fun????o da microbiota de cupins no ciclo do carbono e do nitrog??nio, encontramos evid??ncias de sua poss??vel participa????o no ciclo do ars??nio. Este estudo adiciona informa????o sobre o estabelecimento da microbiota no intestino de cupins, com sele????o de grupos funcionais baseados no alimento, ao inv??s de linhagens microbianas espec??ficas. Adicionalmente, os dados aqui gerados podem ser explorados na produ????o de biocombust??veis e em outros processos biotecnol??gicos.
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Padr?o de crescimento, par?metros de desempenho e diverg?ncia gen?tica de gen?tipos de frangos tipo caipira / Growth pattern, performance parameters and genetic divergence of genotypes in Alternative strain of Broiler ChickensVeloso, Rog?rio de Carvalho 16 July 2012 (has links)
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Previous issue date: 2012 / Funda??o de Amparo ? Pesquisa do estado de Minas Gerais (FAPEMIG) / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico (CNPq) / Objetivou-se com este trabalho comparar o padr?o de crescimento, avaliar o desempenho, as caracter?sticas de carca?a e, verificar a diverg?ncia gen?tica por meio de t?cnicas de an?lise multivariada de diferentes gen?tipos de aves tipo caipira. Foram utilizados 840 pintos de um dia, machos, distribu?dos em delineamento inteiramente casualizado, dos seguintes gen?tipos: Caboclo, Carij?, Colorpak, Gigante Negro, Pesad?o Vermelho, Pesco?o Pelado e Tricolor. Para a determina??o das curvas de crescimento do peso corporal das aves, os dados coletados foram avaliados a partir dos modelos n?o-lineares: Brody, Gompertz, Log?stico, Richards e von Bertalanffy. Foi empregado o ?proc nlin? do SAS, utilizando o m?todo interativo de Gauss-Newton. Os crit?rios utilizados para escolha do modelo de melhor ajuste da curva de crescimento foram o coeficiente de determina??o, o desvio padr?o assint?tico, o desvio m?dio absoluto dos res?duos e o ?ndice assint?tico. O estudo do crescimento relativo dos cortes foi realizado mediante o modelo da equa??o alom?trica de Huxley. As caracter?sticas de desempenho (convers?o alimentar, ganho em peso m?dio di?rio, consumo de ra??o m?dio di?rio) foram avaliadas em quatro per?odos: 1 a 28, 1 a 56, 1 a 70 e 1 a 84 dias de idade. As caracter?sticas de carca?a (peso e rendimento de carca?a, peito e pernas) foram obtidas a partir do abate de 2 aves por boxe, aos 85 dias de idade. O peso corporal foi medido ao nascimento, 14, 28, 42, 56, 70 e 84 dias de idade. As an?lises estat?sticas foram realizadas utilizando-se o ?proc glm? do SAS. O desempenho dos gen?tipos tamb?m foi avaliado por meio da an?lise de vari?ncia multivariada e da fun??o discriminante linear de Fisher, usando os testes do maior autovalor de Roy e da uni?o-interse??o de Roy para as compara??es m?ltiplas. O estudo da diverg?ncia gen?tica foi feito por meio da an?lise por vari?veis can?nicas e pelo m?todo de otimiza??o de Tocher. Apenas as equa??es propostas por Gompertz, von Bertalanffy e Log?stico atingiram a converg?ncia, sendo que o modelo de von Bertalanffy o mais adequado para descrever o crescimento das aves. Todos os gen?tipos apresentaram crescimento alom?trico tardio, indicando que o crescimento do peito ? lento em rela??o ? carca?a. Verificou-se que em todos os per?odos, as aves do gen?tipo Colorpak apresentaram maior peso corporal, consumo de ra??o m?dio di?rio, ganho em peso m?dio di?rio e convers?o alimentar. Entretanto, os gen?tipos Caboclo e Gigante Negro apresentaram os piores desempenhos. Quanto ao rendimento de cortes pode ser observado que o gen?tipo Tricolor diferiu estatisticamente somente do Colorpak o para o rendimento de pernas. Para o rendimento de peito o Carij? e o Pesad?o Vermelho diferiu estatisticamente dos gen?tipos Caboclo e Gigante Negro, n?o diferindo dos demais. As duas primeiras vari?veis can?nicas explicaram 97,41% da varia??o entre os gen?tipos. A escolha do gen?tipo para cria??o deve ser feita de acordo com o interesse de mercado, pois h? diferen?as no desempenho e no rendimento de carca?a e dos cortes. A diverg?ncia gen?tica entre os gen?tipos avaliados permitiu a forma??o de quatro grupos com os seguintes gen?tipos: grupo 1 - Colorpak, grupo 2 - Pesad?o Vermelho e Pesco?o Pelado, grupo 3 - Carij? e Tricolor e grupo 4 - Caboclo e Gigante Negro. / Disserta??o (Mestrado) ? Programa de P?s-Gradua??o em Zootecnia, Universidade Federal dos Vales do Jequitinhonha e Mucuri, 2012 / ABSTRACT
The objective of this work was to compare the growth pattern, evaluate performance, carcass characteristics, and verify the genetic diversity by means of multivariate analysis of different genotypes in alternative lines of broiler chickens. We used 840 day old chicks, males distributed in a completely randomized design, the following genotypes: Caboclo, Carij?, Colorpak, Gigante Negro, Pesad?o Vermelho, Pesco?o Pelado and Tricolor. To determine the growth curves of the body weight of birds, collected data were evaluated from the nonlinear models: Brody, Gompertz, Logistic, Richards and von Bertalanffy. Was used "proc nlin" of SAS, using the iterative method of Gauss-Newton. The criteria used to choose the best model of the growth curve were the coefficient of determination, the asymptotic standard deviation, the mean absolute deviation of the waste and the asymptotic index. The study of the relative growth of the sections was performed using the model of Huxley's allometric equation. The performance characteristics (feed conversion, average daily weight gain, average daily feed intake) were evaluated in four periods: 1-28, 1-56, 1-70 and 1-84 days old. The carcass traits (weight and carcass yield, breast and leg) were obtained from the slaughter of two birds per pen, at 84 days old. Body weight was measured at birth, 14, 28, 42, 56, 70 and 84 days of age. Statistical analyzes were performed using the "proc glm" SAS. The performance of genotypes was also evaluated by multivariate analysis of variance and Fisher's linear discriminant function, using the tests of the largest eigenvalue of Roy and the Roy union-intersection for multiple comparisons. The study of genetic diversity was done by canonical variate analysis and the method of Tocher. Only the equations proposed by Gompertz, von Bertalanffy and Logistic reached convergence, and the von Bertalanffy model more appropriate to describe the growth of the birds. All genotypes showed late allometric growth, indicating that breast growth is slow relative to the housing. It was found that in all periods, the birds Colorpak genotype had higher body weight, average daily feed intake, average daily weight gain and feed conversion. However, the genotypes Caboclo and Gigante Negro had the worst performances. The yield of the cuts can be seen that the genotype Tricolor significantly different only from Colorpak to yield the legs. For breast meat yield Carij? and the Pesad?o Vermelho significant different genotypes Caboclo and Gigante Negro, not differing from the others. The first two canonical variables accounted for 97.41% of the variation among genotypes. The choice of the genotype for breeding should be done according to market interest, because there are differences in performance and carcass yield and cuts. The genetic divergence between the genotypes allowed the formation of four groups with the following genotypes: group 1 - Colorpak, group 2 - Pesad?o Vermelho and Pesco?o Pelado, group 3 - Carij? and Tricolor and group 4 - Caboclo and Gigante Negro.
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Les Cisterciens face à leur environnement spatial et humain : exemple des abbayes claravalliennes possessionnées dans le Bas-Maine (début XIIe - fin XVe siècle) / The relationship between Cistercian monks and their spatial and human environment : the example of Claravallian abbeys in the Lower Maine (12th - 15th century)Ladurée, Jean-René 15 November 2014 (has links)
La présente étude a pour but d’exposer les spécificités du monachisme cistercien du Bas-Maine entre le XIIe et le XVe siècle au travers des exemples d’abbayes claravalliennes installées ou possessionnées dans cet espace de frange Il s’agit des abbayes de Clermont, Fontaine-Daniel, Rouez et Savigny. Les trois premières sont localisées dans le Maine et sont fondées par des barons entre la mi-XIIe et le début du XIIIe siècle. Un sort particulier est réservé à la dernière, Savigny, de par sa fondation précoce et son intégration à l’ordre cistercien en 1147, face aux autres abbayes créées par efflorescence. Le caractère conflictuel de la région (terrain d’oppositions régulières entre Angevins, Normands et Bretons), l’importance de l’érémitisme, y expliquent le retard de l’installation des moines cisterciens. Les critères de fondation d’une abbaye cistercienne sont passés en revue, tout comme l’ambiguïté de l’acte fondateur. La question des dépendances cisterciennes, au premier chef desquelles on relève le système des granges est évoqué tout comme les rapports de ces abbayes avec leur environnement humain (moines, convers, population, etc...) Enfin, l’auteur revient également sur l’empreinte laissée par les Cisterciens dans des domaines comme la mise en valeur de l’espace, le commerce ou l’usure. Chacun de ces éléments étant envisagé dans le cadre des principes des premiers Cisterciens et du rapport fonctionnel à la règle. / The present study’s aim is to present the specificities of Cistercian monasteries in the Lower Maine area between the 12th and 15ththe area i.e. the Abbey of Clermont, Fontaine-Daniel, Rouez et Savigny. The first three are located within the Maine province and were founded by barons between the mid-12ththat it was established earlier and became part of the Cistercian order in 1147, as opposed to the other abbeys which were formed through efflorescence. The relatively late establishment of Cistercian Monks in the lower Maine is due to the fact that the area was the setting of frequent confrontations between Angevins, Normand and Bretons as well as to large number of hermits during this time period. In this paper I will examine the criteria necessary for the establishment of Cistercian Abbeys as well as the ambiguity of the founding act. I will also deal with Cistercian properties, above all the farm system, as well as the relationship between the abbeys and their human environment (monks, lay brothers, the population etc). Lastly, the author will explore the traces left by the Cistercians in areas such as the usage and development of the land, commerce and usary. Each of these elements is examined within the framework of the principals of the first Cistercians and the functional relationship to the rule. century through examples of Claravallian abbeys located or owning property in
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Histoire d'une répression : les judéo-convers dans le royaume de Valence aux premiers temps de l'Inquisition (1461-1530) / The history of a repression : the Judeo-Christian converts in the Kingdom of Valencia in the early days of the Spanish Inquisition (1461-1530)Banères, Patricia 24 November 2012 (has links)
L’étude de l’Inquisition dans le district de Valence reposait essentiellement sur l’analyse menée par l’historien Ricardo García Cárcel en 1976. Nous avons voulu par l’étude exhaustive de différents documents : abécédaires inquisitoriaux, procès, mais aussi documents comptables, documents notariés, établir une nouvelle liste des condamnés entre 1478, date de l’implantation du Saint-Office à Valence et 1530, période où le filon judéo-convers se tarit, laissant place à des nouvelles stratégies et à la persécution de nouveaux groupes dissidents. À Valence, les années 1520-1530 marquent le déclin de la région au profit d’une Castille conquérante, dominatrice en Espagne et dans le monde. Le nouveau registre que nous avons établi, riche de 3 094 condamnés en grande majorité judéo-convers (93,39 %), nous a servi de fondement pour dresser les contours de ce que fut la répression dans cette région et comprendre le rôle d’une Inquisition qui, entre urgences financières du monarque et uniformisation religieuse et culturelle, bouleversa l’équilibre d’une communauté judéo-converse, de plus en plus intégrée à la société vieille-chrétienne à laquelle elle appartenait depuis sa conversion. À travers l’analyse des comptes du receveur des biens confisqués, limitée aux familles judéo-converses de trois des villes principales du royaume, Gandía, Xàtiva et Segorbe, nous avons voulu déterminer le niveau social de cette communauté et savoir quel fut l’impact de cette répression dans une région qui perdait ses prérogatives et son pouvoir au profit de la nouvelle monarchie des Habsbourg. / The study of the Spanish Inquisition in Valencia has up until now depended primarily on the 1976 analysis by historian Ricardo García Cárcel. Through exhaustive investigation of different documents in archives in Madrid and Valencia – lists of convicted persons, trials, but also accounting and notarial records –, our aim was to establish a new list of Inquisition victims between 1478, when the Holy Office was established in Valencia, and 1530, when the massive persecution of converts from Judaism began to be replaced by other strategies and repression of other dissident groups. The period of the 1520s and 1530s saw the decline of the Kingdom of Valencia in favour of the dominant Castille, then in the process of becoming a world power. The new list that we have drawn up includes the names of 3,094 victims, most of whom (93.39%) were conversos. It forms the basis for describing the characteristics of this repression and understanding the part played by the Inquisition which, between the growing financial needs of the king and the drive to standardise religion and culture, disrupted a community which, since its conversion, had become increasingly integrated into the ancient Christian society. Analysis of receivers’ ledgers of confiscated goods from converso families from three of the major cities of the kingdom— Gandia, Xativa and Segorbe—, offers insight into the socio-economic level of this community, as well as the impact of this repression in a region which was losing its prerogatives and its power to the new Habsburg monarchy.
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M?dulo de elasticidade e grau de convers?o de mon?meros de sistemas adesivos autocondicionantes e primer e adesivo combinadosCorr?a, Bianca Moro 19 January 2017 (has links)
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Previous issue date: 2017-01-19 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPES / Objectives: The aims of this study were to evaluate the elastic modulus and the monomer conversion of self- etching adhesives (Single Bond Universal and Clearfil SE Bond) and two- steps etch-and-rinse adhesives (primer + adhesive in the same bottle, Adper Single Bond 2 and Gluma 2Bond). The null hypothesis was that two-step adhesive systems will have higher degree of monomer conversion and a higher elastic modulus than the self-etching ones. Materials and methods: On dentin disks obtained from 10 extracted third molars were applied self- etching and etch-and-rinse adhesive systems according to manufacturer's instructions and light cured by a LED light. Right after, the specimens were submitted to elastic modulus by atomic force with 50g load for 10s. The degree of conversion of the adhesives was calculated by Fourier Transform Infrared Spectroscopy (FTIR). Results: The Single Bond 2 adhesive system presented the highest monomer conversion result (88%) followed by Universal Single Bond (79%), Gluma 2Bond (71%) and Clearfil SE Bond (69%). The results for elastic modulus (MPa) were (means followed by the same letter did not present statistical difference for Tukey (p?0,05)): Single Bond 2, 2319 (A); Single Bond Universal, 2051 (AB); Gluma, 2038 (AB); Clearfil SE Bond, 1788 (B). Conclusion: lt is not possible to infer that, as a rule, conventional adhesives systems with combined primer and adhesives will have a better performance in terms of the degree of monomer conversion as well as modulus of elasticity when compared to self-etching agents. / Objetivos: Este trabalho teve por objetivos avaliar o m?dulo de elasticidade e a taxa de convers?o de mon?meros de sistemas adesivos autocondicionantes (Single Bond Universal e Clearlil SE Bond) e convencionas de dois passos (primer+adesivo no mesmo frasco, Adper Single Bond 2 e Gluma 2Bond). A hip?tese inicial foi que os sistemas adesivos de dois passos ter?o maior grau de convers?o de mon?meros e maior m?dulo de elasticidade que os autocondicionantes. Materiais e m?todos: sobre discos de dentina obtidos a partir de 10 molares extra?dos foram aplicados os sistemas adesivos de condicionamento ?cido total e os autocondicionantes de acordo com a recomenda??o dos fabricantes de cada material e fotoativados com luz LED. Ap?s, os corpos de prova foram submetidos ? medi??o de m?dulo de elasticidade por for?a at?mica com carga de 50g pelo tempo de 10s. O grau de convers?o dos adesivos foi calculado usando espectroscopia por infravermelho (FTIR). Resultados: O sistema adesivo Single Bond 2 apresentou o maior resultado de convers?o de mon?meros (88%) seguido do Single Bond Universal (79%), Gluma (71%) e Cleartil SE Bond (69%). Os resultados para o m?dulo de elasticidade (MPa) foram (m?dias seguidas de mesma letra n?o apresentam diferen?a estat?stica para Tukey (p?0,05)): Single Bond 2, 2319(A); Single Bond Universal, 2051(AB); Gluma, 2038(AB); Clearfil SE Bond, 1788(B). Conclus?o: N?o ? poss?vel inferir que via de regra pelo fato de serem os sistemas adesivos convencionais com primer e adesivos combinados ter?o um melhor desempenho quanto ao grau de convers?o de mon?meros bem como m?dulo de elasticidade quando comparados aos autocondicionantes.
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Estudo da conversão descendente de frequência com íons de Tb3+/Yb3+ , Eu3+ e Er3+ para aplicações fotovoltaicasLIMA, Bismarck Costa 13 April 2015 (has links)
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Previous issue date: 2015-04-13 / CAPES, CNPq, FACEPE / C elulas solares apresentam-se como uma alternativa vi avel para a gera c~ao de energia limpa e renov avel pela sua capacidade de convers~ao da energia solar em el etrica atrav es do efeito fotovoltaico. Entretanto, um dos fatores limitantes na utiliza c~ao deste tipo de energia tem sido a incompatibilidade espectral, a qual implica que apenas uma determinada parte do espectro solar seja efetivamente utilizado no processo de convers~ao fotovoltaica. Entre os diversos materiais fot^onicos, pesquisas em materiais dopados com ons de Terras Raras capazes de realizar a convers~ao de f otons de infravermelho para vis vel-UV ou vice-versa tem sido realizadas. Em aplica c~oes fotovoltaicas, este efeito pode melhorar a coleta da radia c~ao solar. Para a realiza c~ao desta tarefa dois mecanismos s~ao utilizados: Convers~ao Ascendente de Frequ^encia e Convers~ao Descendente de Frequ^encia. Este trabalho teve como objetivo estudar
as propriedades espectrosc opicas e o mecanismo de Convers~ao Descendente de Frequ^encia em vidros dopados com os ons de Terras Raras Tb3+/Yb3+, Eu3+ e Er3+, e veri car suas poss veis aplica c~oes no melhoramento da e ci^encia de c elulas solares. A mesma matriz hospedeira foi utilizada. O estudo das propriedades espectrosc opicas foi realizado atrav es de medidas de absor c~ao, luminesc^encia e evolu c~ao temporal da luminesc^encia. Observamos o processo de convers~ao descendente de frequ^encia com emiss~ao no infravermelho, regi~ao que as c elulas solares de sil cio cristalino possuem maior e ci^encia, com excita c~ao em 355nm, que promoveu uma maior e ci^encia, e 482nm. Em seguida, para as matrizes dopadas com ons de Tb3+/Yb3+, foi determinado o mecanismo gerador do processo de convers~ao descendente de frequ^encia e a e ci^encia de transfer^encia de energia. Foi obtida uma e ci^encia de transfer^ encia de energia m axima de 112,7%. Para as matrizes dopadas com Eu3+ e Er3+ foram realizadas medidas de luminesc^encia com excita c~ao via laser de 482nm. Como aplica c~ao, foram realizadas medidas el etricas, para c elulas convencionais de Si e GaP, usando como fonte de radia c~ao um simulador solar com ltro AM 1.5. Os resultados foram avaliadas na presen ca e aus^encia dos vidros dopados com ons de Terras Raras na superf cie da c elula solar. Foi observado um aumento na e ci^encia de convers~ao fotovoltaica das c elulas de sil cio cobertas pelos vidros dopadas com 1%Tb3+ e 1%Eu3+ em rela c~ao a matriz sem dopagem. / Solar cells are shown as a viable alternative for generation renewable and clean energy due their ability of converter solar power in electric power by the photovoltaic e ect. However, one of the limitant facts to use photovoltaic devices to make electricity is spectral mismatch, that implies only a speci c range of solar spectrum is e ectively used in the process of photovoltaic conversion. Between the several photonics devices, research in Rare Earth ions doped materials able to do the conversion of infrared photons in visible-UV photons or the opposite have been performed. In photovoltaic applications, this e ect can enhance the harvesting of solar light. To realize this task two mechanism are used: Frequency up-conversion and frequency down-conversion. This work had the goal of study the spectroscopic properties and the Frequency Down-conversion mechanism in Tb3+/Yb3+, Eu3+ and Er3+ Rare Earth doped glasses, and check their possible applications to enhance solar cell e ciency. The same host matrix are used. The spectroscopic study was realized by luminescence, absorption, and temporal evolution luminescence measurements. We observe the frequency down-conversion and infrared emission, zone that crystaline silicon solar cell have the best e ciency, with 355nm excitation, that promote the best e ciency, and 482nm excitation. Then, for host matrix doped with Tb3+/Yb3+ ions, was determined the generation mechanism of frequency
down-conversion and energy transfer e ciency. The major energy transfer e ciency was
112,7%. For host matriz doped with Eu3+ and Er3+ ions, was realized luminescence measurements with 482nm excitaion. Was realized electric measurements as applications in Si and GaP cells, solar simulator with AM 1.5 lter was used as radiation source. The results were evaluated with and without Rare Earth ions doped glasses on the surface of solar cell. We observed the enhancement of photovoltaic conversion when the silicon solar cell are covered with by glasses doped with 1%Tb3+ and 1%Eu3+ with respect to matrix covered.
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A Cruz e o Imp?rio: a expans?o portuguesa e a cristianiza??o das bailadeiras e vi?vas em Goa (1567-1606)ANJOS, Camila Domingos 25 April 2016 (has links)
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Previous issue date: 2016-04-25 / CAPES / The present dissertation seeks to analyse the initiatives of coercion to convert the hindu widows and bailadeiras (dancing girls) in Goa, between 1597 to 1606. We will research the pretentions of royal and ecclesiastical agents to convert and integrate the bailadeiras to a Christian project of colonization, from the decrees issued in the five provincial councils of Goa (made in the chronological cut above), of the legislation contained in the ?Book of the Father of the Christians?, from the royal determinations and from the viceroys of the State of India. We will investigate how the interdependence of the political and religious power favored the issuance of decrees that aimed at homogenizing the local societies, precisely the bailadeiras and the hindu widows from a Christian discipline. / A presente disserta??o busca analisar as iniciativas de coer??o ? convers?o de vi?vas hindus e bailadeiras em Goa, entre 1567 a 1606. Pesquisaremos as pretens?es dos agentes r?gios e eclesi?sticos em converter e integrar as bailadeiras a um projeto crist?o de coloniza??o, a partir dos decretos emitidos nos cinco conc?lios provinciais de Goa (realizados no recorte cronol?gico supracitado), da legisla??o contida no ?Livro do Pai dos Crist?os?, das determina??es r?gias e dos vice-reis do Estado da ?ndia. Investigaremos assim, como a interdepend?ncia do poder pol?tico e religioso favoreceu a emiss?o de decretos que visavam homogeneizar as sociedades locais, precisamente bailadeiras e as vi?vas hindus, a partir de uma disciplina crist?.
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Fun??es executivas e mem?rias em idosos com e sem comprometimento cognitivo leve : perfis de fun??es executivas e follow up neurocognitivoHolz, Maila Rossato 02 March 2018 (has links)
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Previous issue date: 2018-03-02 / Both health aging and mild cognitive impairment are associated with the existence of
neurocognitive profiles and sociodemographic and clinical factors that may be considered as a risk for conversion to a major neurocognitive disorder. However, it is known that within this continuum between normal and pathological aging there are heterogeneous characteristics that are still little explored that need to be better understood to identify factors of cognitive reserve and demential risk. Thus, the present dissertation is composed of two studies, the first with the objective of verifying if there are subgroups of executive processing in the elderly with MCI and controls; secondarily, to examine whether the latent executive profiles are differentiated by sociodemographic, clinical and mnemonic variables. In this study 120 elderly adults (50 controls and 70 MCI patients) participated in a complete neuropsychological evaluation battery. A latent profile analysis was performed to verify possible subgroups of executive functions (EF), followed by a multivariate ANOVA controlling years of formal education and frequency of reading and writing habits (FRWH). Three executive profiles were found (1) Profile 1 with processing speed, executive attention and
visuospatial initiation impairment (23.33% of the sample); (2) Profile 2 with intermediate performance in EF (45.84% of the sample); and (3) Profile 3 with superior performance in working memory, planning and verbal organization (30.83% of the sample). Comparative analysis showed differences in education, economy class, FRWH, global cognition, symptoms of depression, immediate episodic memory, recent memory, visual memory, recognition of new information learned and prospective memory. In all variables, Profile 1 had worse performance and Profile 3 had the best performance. The second study aimed at evaluating cognitive processing evolution (mnemonic, executive, linguistic, praxis and attentional), socio-demographic and clinical characteristics of elderly individuals with MCI and elderly controls, as well as verifying whether the elderly will convert the clinical condition and if there were risk factors for this conversion. In study 2, 65 elderly adults (41 MCI patients and 24 controls) participated in two complete neuropsychological assessments (time 1 and time 2). ANOVA analyzes of repeated measures were performed, controlling years of formal education and FRWH. There were differences in the evaluation one year later in the
working memory, visual episodic memory, and visual and spatial cognitive flexibility
variables. Eighteen participants (27.69%) converted to the clinical condition. The 11
functionality explained 12.5% of clinical conversion. The results of these two studies
suggest that there is heterogeneity in the neurocognitive and executive profile within
healthy aging and MCI that need to be monitored longitudinally to identify the
continuum of these impairments. Variables such as processing speed, working memory
and inhibitory control are essential executive measures for monitoring beyond episodic
memory evaluation. Future studies should investigate transversally and longitudinally
MCI severity, using factorial analyzes and composite scores of cognitive components,
more specifically from executive components. These measures may be quantitative and
qualitative measures of better measurement of cognitive impairment extent in elderly
patients, allowing more accurate and earlier diagnoses towards the implementation of
specific neurocognitive stimulation programs. / O envelhecimento seja ele saud?vel ou com Comprometimento Cognitivo Leve (CCL) tende a estar relacionado ? exist?ncia de perfis neurocognitivos e fatores sociodemogr?ficos e cl?nicos que podem ser considerados de risco para convers?o para um transtorno neurocognitivo maior. Contudo, sabe-se que dentro desse cont?nuo entre o envelhecimento normal e patol?gico existem caracter?sticas heterog?neas ainda pouco
exploradas que necessitam ser mais bem compreendidas para identifica??o de fatores de reserva cognitiva e de risco demencial. Assim, a presente disserta??o ? composta por dois estudos, sendo o primeiro com o objetivo de verificar se h? subgrupos de processamento executivo em idosos com CCL e controles; secundariamente, examinar se os perfis executivos latentes se diferenciam por vari?veis sociodemogr?ficas, cl?nicas e mnem?nicas. Nesse estudo participaram 120 adultos idosos (50 controles e 70 com CCL) que realizaram uma bateria de avalia??o neuropsicol?gica completa. Foi conduzida uma an?lise de perfis latentes para verificar poss?veis subgrupos de fun??es executivas, seguida de uma ANOVA multivariada controlando escolaridade e frequ?ncia de h?bitos de leitura e de escrita (FHLE). Foram encontrados tr?s perfis
executivos (1) Perfil 1 com preju?zos de velocidade de processamento, aten??o executiva e inicia??o visuoespacial (23,33% da amostra); (2) Perfil 2 com desempenho intermedi?rio em FE (45,84% da amostra); e (3) Perfil 3 com desempenho superior em mem?ria de trabalho, planejamento e organiza??o verbal (30,83% da amostra). A an?lise comparativa mostrou diferen?as quanto ? escolaridade, classe econ?mica, FHLE, cogni??o global, sintomas de depress?o, mem?ria epis?dica imediata e recente, mem?ria visual, reconhecimento de novas informa??es aprendidas e mem?ria prospectiva, sendo que em todas as vari?veis o Perfil 1 teve pior desempenho e o Perfil 3 teve o melhor desempenho. J? o segundo estudo, teve como objetivo avaliar a evolu??o do processamento cognitivo (mnem?nico, executivo, lingu?stico, pr?xico e
atencional), sociodemogr?fico e cl?nico de idosos com CCL e idosos controles verificando, ainda, se os idosos iriam converter o quadro cl?nico e se existiriam fatores de risco para essa convers?o. No estudo 2 participaram 65 adultos idosos (41 CCL e 24 controles) no qual passaram por duas avalia??es neuropsicol?gicas completas (tempo 1 e tempo 2). Foram realizadas an?lises de ANOVA de medidas repetidas, controlando escolaridade e FHLE. Houve diferen?as na avalia??o um ano depois nas vari?veis de mem?ria de trabalho, mem?ria epis?dica visual, e flexibilidade cognitiva visuoespacial. 9 Dezoito participantes da amostra (27,69%) converteram o quadro cl?nico. A funcionalidade explicou 12,5% da convers?o do quadro cl?nico. Os resultados dos dois estudos sugerem que h? uma heterogeneidade no perfil neurocognitivo e executivo dentro do envelhecimento saud?vel e com CCL que precisam ser acompanhadas longitudinalmente para identificar o cont?nuo desses preju?zos. Percebe-se que vari?veis como velocidade de processamento, mem?ria de trabalho e controle inibit?rio s?o medidas executivas essenciais para acompanhamento al?m da mem?ria epis?dica. Futuros estudos que investiguem de forma transversal e longitudinal a severidade do CCL a partir de an?lises fatoriais e de escores compostos dos componentes cognitivos, mais especificamente de componentes executivos, podem ser medidas quantitativas e qualitativas de melhor mensura??o da dimens?o do preju?zo cognitivo em idosos, permitindo diagn?sticos mais acurados e mais precoces rumo ? implementa??o de programas de estimula??o neurocognitiva espec?fica.
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Histoire d'une répression : les judéo-convers dans le royaume de Valence aux premiers temps de l'Inquisition (1461-1530)Banères, Patricia 24 November 2012 (has links) (PDF)
L'étude de l'Inquisition dans le district de Valence reposait essentiellement sur l'analyse menée par l'historien Ricardo García Cárcel en 1976. Nous avons voulu par l'étude exhaustive de différents documents : abécédaires inquisitoriaux, procès, mais aussi documents comptables, documents notariés, établir une nouvelle liste des condamnés entre 1478, date de l'implantation du Saint-Office à Valence et 1530, période où le filon judéo-convers se tarit, laissant place à des nouvelles stratégies et à la persécution de nouveaux groupes dissidents. À Valence, les années 1520-1530 marquent le déclin de la région au profit d'une Castille conquérante, dominatrice en Espagne et dans le monde. Le nouveau registre que nous avons établi, riche de 3 094 condamnés en grande majorité judéo-convers (93,39 %), nous a servi de fondement pour dresser les contours de ce que fut la répression dans cette région et comprendre le rôle d'une Inquisition qui, entre urgences financières du monarque et uniformisation religieuse et culturelle, bouleversa l'équilibre d'une communauté judéo-converse, de plus en plus intégrée à la société vieille-chrétienne à laquelle elle appartenait depuis sa conversion. À travers l'analyse des comptes du receveur des biens confisqués, limitée aux familles judéo-converses de trois des villes principales du royaume, Gandía, Xàtiva et Segorbe, nous avons voulu déterminer le niveau social de cette communauté et savoir quel fut l'impact de cette répression dans une région qui perdait ses prérogatives et son pouvoir au profit de la nouvelle monarchie des Habsbourg.
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S?ntese, caracteriza??o de ?xido de alum?nio a partir de esferas h?bridase aplica??o na convers?o do glicerol: influ?ncia do grau de substitui??o e polimeriza??o da carboximetilceluloseSilva, Monickarla Teixeira Pegado da 23 February 2016 (has links)
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Previous issue date: 2016-02-23 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / Suportes catal?ticos ? base de ?xido de alum?nio foram sintetizados pelo m?todo e esferas h?bridas utilizando carboximetilcelulose (CMC) como precursor org?nico (template) e nitrato de alum?nio como precursor inorg?nico. As caracteriza??es foram realizadas por an?lises de termogravimetria (TG), difra??o de raios-X (DRX), espectroscopia no infravermelho por transformada de fourier (FTIR), microscopia eletr?nica de varredura (MEV) e fisissor??o N2. Os materiais sintetizados foram testados na rea??o de convers?o do glicerol em fase g?s. Os estudos da s?ntese indicaram que as caracter?sticas do biopol?mero (grau de substitui??o e de polimeriza??o) influenciam diretamente no valor m?ximo da rela??o entre o precursor org?nico e inorg?nico para a forma??o das esferas h?bridas. As propriedades f?sico-qu?micas do material final (cristalinidade, porosidade, ?rea espec?fica e morfologia) mostraram uma depend?ncia direta com as propriedades do biopol?mero (grau de substitui??o e de polimeriza??o), indicando a versatilidade desta rota s?ntese. Os espectros de FTIR confirmaram a forma??o de um material h?brido quando se compara o espectro da CMC pura com os s?lidos obtidos ap?s a secagem. Os resultados de DRX mostraram um perfil de material amorfo para algumas amostras. Para alguns s?lidos foi poss?vel identificar a forma??o de uma fase cristalina relacionada com a alumina hidratada, ?xido de alum?nio e ?xido de cobre. As imagens obtidas por MEV indicaram a forma??o de um material com morfologia semelhante a uma esponja ap?s a calcina??o, caracter?stico de um s?lido altamente poroso. O perfil de adsor??o/dessor??o de N2 confirma a forma??o de materiais contendo micro-mesoporos com uma ?rea espec?fica entre 50-162 m2.g-1 para os suportes e 112-303 m2.g-1 para os catalisadores com cobre, indicando um aumento ?rea ap?s a adi??o do Cu por impregna??o devido a redissolu??o e recristaliza??o da fase alumina. Testes catal?ticos indicaram que os ?xidos s?o ativos e seletivos para a convers?o do glicerol (92-15%) a bioprodutos de alto maior valor agregado, confirmando a viabilidade do m?todo de s?ntese. / Catalytic supports based on aluminum oxide were synthesized by the method of hybrid
spheres using carboxymethylcellulose (CMC) as organic precursor (template) and
aluminum nitrate as inorganic precursor. The characterizations were performed by
thermal chemical analysis (TGA), X-Ray diffraction (XRD), fourier transform infrared
(FTIR) spectroscopy, scanning electron microscopy (SEM) and N2 physisorption. The
study of synthesis indicated that the characteristics of the biopolymer (degree of
substitution and polymerization) directly influence on the maximum value of the ratio
between the organic and inorganic precursor for the formation of hybrid spheres. The
physicochemical properties of the final material (crystallinity, porosity, surface area
and morphology) showed a direct dependence on the biopolymer properties (degree of
substitution and polymerization), indicating the versatility of this synthesis route. The
FTIR spectra confirm the formation of a hybrid material when comparing the pure
CMC spectrum with the obtained solids after drying. The XRD results show a profile
of amorphous and crystalline material for the different samples. For some solids were
possible to identify the formation of a crystalline phase related to the hydrated
alumina, aluminium oxide and copper oxide. The images obtained by SEM analysis
showed the formation of a material with sponge-like morphology after calcination,
characteristic of highly porous solid. The N2 adsorption/desorption isotherm profile
confirms the formation of micro-mesoporous materials with a specific surface area
between 50-162 m2.g-1 for the supports and 112-303 m2.g-1 for the copper-based
catalysts, indicating an increase in the area after the addition of Cu by impregnation
due to redissolution and recrystallization of alumina phase. Catalytic tests were tested
in the glycerol conversion reaction (92-15%) to added value products in order to
confirm their real viability.
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