Using ����C cross polarization magic angle spinning nuclear magnetic resonance techniques on 5 species of dead trees from the northwest (western hemlock, Douglas fir, Sitka spruce, lodgepole pine and ponderosa pine) I tracked the lignin and cellulose content over a 22 to 36 year period in order to determine the effects of decay fungi, if any, that is attacking certain species of tree. I had samples from the wood of the roots, the bark on the roots and, in some cases, the resin core of the roots. The Department of Forest Science at Oregon State University has studied this problem by using wet chemical analysis, and direct visual observation. Mark Harmon and Hua Chen of the Department of Forest Science believe that white rot occurred most frequently in the lodgepole pine and ponderosa pine and brown rot was more frequent in the Douglas-fir and Sitka spruce. Western hemlock seemed to have both brown and white rots active. The Douglas fir bark sample showed definite decomposition consistent with white rot during the first 10 years. The ponderosa pine sap showed decomposition consistent with white rot in the 10 to 22 year period. Sitka Spruce showed some decomposition consistent with white rot in the bark from 7 to 33 years, and the western hemlock showed some decomposition consistent with white rot in the sap in the first 10 years. The decompositions consistent with brown rot were much easier to see in this study. Virtually all the sap and bark samples showed decomposition consistent with brown rot at some point. The Douglas fir was the only species, other than lodgepole pine, not to show any decomposition consistent with brown rot in the bark of the tree, only decomposition consistent with white rot. The Douglas fir did show a decay consistent with brown rot in the sap for the first ten years. Ponderosa pine showed evidence of decay that brown rot would cause for the first 10 years in the sap and the bark. The Sitka spruce species analysis showed brown rot type decay in the bark for the first 7 years and in the sap for the entire time studied of 33 years. The lodgepole pine was the only species to not show any brown rot type decay in the sap or bark for the entire 22 year period studied. The western hemlock was distinct by not showing any definitive brown rot type decay for the first 10 years, but showed massive decay consistent with brown rot in both sap and bark during the following 26 years studied. I used an 8 Tesla magnet and the MAS frequency was at 5 kHz. The recycle time was 1.5 seconds and the contact time was 1 ms. I generally took about 10,000 acquisitions per sample, which added up to about 4 hours total acquisition time per sample. Presence of these rots shows that certain species are more susceptible than others, and also shows that local environmental conditions can contribute to rot susceptibility. / Graduation date: 2003

No description available.

Comparative studies of nondestructive evaluation methods have shown that nonlinear ultrasonic techniques are more sensitive than conventional linear methods to changes in material microstructure and the associated small-scale damage. Many of the material degradation processes such as carbonation in concrete, corrosion in metals, etc., begin at the surface. In such cases, ultrasonic Rayleigh surface waves are especially appropriate for detection and characterization of damage since their energy is concentrated in the top layer of the test object. For the civil engineering infrastructure, only a limited number of field applicable nonlinear ultrasonic techniques have been introduced. In this paper a nonlinear ultrasonic measurement technique based on the use of Rayleigh waves is developed and used to characterize carbonation in concrete samples. Wedge transducer is used for the generation and an accelerometer for detection of the fundamental and modulated ultrasonic signal components. The measurements are made by varying the input voltage and along the propagation distance. The slope of the normalized modulated amplitudes is taken as the respective nonlinearity parameter. Concrete samples with two different levels of damage are examined, and the difference of the two fundamental frequencies is used to quantify damage state.

The highway bridge infrastructure system within the United States is rapidly deteriorating and a significant percentage of these bridges are approaching the end of their useful service life. Deterioration mechanisms affect the load resisting capacity of critical structural components and render aging highway bridges more vulnerable to earthquakes compared to pristine structures. While past literature has traditionally neglected the simultaneous consideration of seismic and aging threats to highway bridges, a joint fragility assessment framework is needed to evaluate the impact of deterioration mechanisms on bridge vulnerability during earthquakes. This research aims to offer an efficient methodology for accurate estimation of the seismic fragility of aging highway bridges. In addition to aging, which is a predominant threat that affects lifetime seismic reliability, other stressors such as repeated seismic events or simultaneous presence of truck traffic are also incorporated in the seismic fragility analysis. The impact of deterioration mechanisms on bridge component responses are assessed for a range of exposure conditions following the nonlinear dynamic analysis of three-dimensional high-fidelity finite element aging bridge models. Subsequently, time-dependent fragility curves are developed at the bridge component and system level to assess the probability of structural damage given the earthquake intensity. In addition to highlighting the importance of accounting for deterioration mechanisms, these time-evolving fragility curves are used within an improved seismic loss estimation methodology to aid in efficient channeling of monetary resources for structural retrofit or seismic upgrade. Further, statistical learning methods are employed to derive flexible parameterized fragility models conditioned on earthquake hazard intensity, bridge design parameters, and deterioration affected structural parameters to provide significant improvements over traditional fragility models and aid in efficient estimation of aging bridge vulnerabilities. In order to facilitate bridge management decision making, a methodology is presented to demonstrate the applicability of the proposed multi-dimensional fragility models to estimate the in-situ aging bridge reliabilities with field-measurement data across a transportation network. Finally, this research proposes frameworks to offer guidance to risk analysts regarding the importance of accounting for supplementary threats stemming from multiple seismic shocks along the service life of the bridge structures and the presence of truck traffic atop the bridge deck during earthquake events.

No description available.

Concrete bridges in Texas have developed large cracks in bent caps and pretensioned trapezoidal bridge girders. The bridges show premature concrete deterioration due to alkali-silica reaction (ASR) and delayed ettringite formation (DEF). There is concern that deterioration due to ASR/DEF may lead to a loss of structural capacity. However, there are no quantitative guidelines to relate the level of concrete deterioration due to ASR/DEF to structural performance. Using such guidelines, the need for rehabilitation of beams with ASR/DEF cracking can be assessed. The goal of this research was to determine the shear capacity of pretensioned trapezoidal box girder specimens exhibiting varying degrees of ASR and/or DEF cracking and to use the shear testing results to evaluate the severity of the problem that may exist in Texas bridge structures. To achieve this goal, beams that were severely deteriorated due to ASR/DEF over a period of more than ten years were transported to the University of Texas for testing to failure. Both severely deteriorated and uncracked beams were tested in shear. The test results were used to evaluate the shear performance of trapezoidal box beams affected by ASR/DEF. In addition, three different types of forensic analyses were conducted on the beams to understand the nature of the ASR/DEF cracks and severity of the deterioration. After testing, it is found that the shear capacity of the test specimens was not significantly reduced even with heavy ASR/DEF cracking. Assessment using current US design provisions for bridges or buildings (ACI 318-08 and AASHTO LRFD 2008) and the proposed provision from an earlier project (TxDOT Project 5253) yielded conservative estimates of strength. Results from forensic analyses provided a qualitative indication of ASR/DEF damage but did not correlate with the observed levels of ASR/DEF deterioration. / text

Pastaraisiais metais Lietuvoje ženkliai padidėjęs sunkiasvorio transporto eismas sąlygoja ankstyvą daugumos šalies kelių dangų suirtį, nes jau nepakanka esamo jos stiprio. Įvairios asfaltbetonio dangos pažaidos rodo, kad ardoma ne tik danga, bet ir jos konstrukcija – tai didina išlaidas kelių remontui bei priežiūrai, mažėja eismo saugumas bei komfortiškumas. Iki šiol Lietuvoje dar nėra metodikos, kurią taikant būtų galima pakankamai tiksliai įvertinti sunkiasvorio transporto poveikį kelių dangai. Šiame darbe ištirta sunkiasvorio transporto eismo ardomojo poveikio, įvertinant Lietuvos klimato sąlygas, įtaka kelių dangos asfaltbetonio sluoksnių stipriui ir funkcionavimo trukmei. Pateikta metodika sunkiasvorio transporto eismo ir apkrovų ardančio poveikio Lietuvos kelių dangai, priklausomai nuo eismo sezoniškumo, jos stiprio, asfaltbetonio sluoksnių likutinio stiprio bei kelių dangos įtempto-deformuoto būvio kitėjimo, įvertinti. Pasiūlytas kelių dangos asfaltbetonio sluoksnių likutinio stiprio ir funkcionavimo trukmės likutinio resurso modelis. Modelis įvertina apkrovos parametrus bei jos poveikio intensyvumą, automobilių srauto sudėtį, kelių dangos sluoksnių medžiagų bei jai stiprinti naudojamų medžiagų projektines savybes, kelių dangos sluoksnio medžiagos stiprio kitėjimą, atsižvelgiant į jos suirties mastą, kelių dangos darbą, esant įvairioms vietovės klimato sąlygoms, skirtingiems žemės sankasos gruntams ir vietovės hidroterminiams rėžimams, remonto darbų kainą bei ekonominį... [toliau žr. visą tekstą] / The marked increase of heavy weight vehicle traffic in Lithuania in recent years is the reason for early deterioration of majority road pavements of the country due to inadequate strength of road pavements. Various kinds of damages in asphalt concrete pavements indicate that damage is made not only to a pavement but to its construction as well, which increases costs for road repair and maintenance and reduces road safety and comfort. There is no methodology in Lithuania that would allow to evaluate the impact of heavy weight vehicles on a road pavement with adequate preciseness. This study analyses the impact of damaging effect of heavy weight vehicle traffic on the strength and duration of service life of asphalt concrete layers in a road pavement taking account of climate conditions of Lithuania. A methodology to evaluate the damaging effect of heavy weight vehicle traffic and loads on road pavements in Lithuania depending on seasonal peculiarities of traffic, its strength, remaining strength resource of asphalt concrete layers and changes in stressed or deformed state of a road pavement is presented. A model of remaining strength of asphalt concrete layers in a road pavement and remaining resource of service life was proposed. The model evaluates load parameters and intensity of its impact, composition of vehicle flow, design characteristics of materials in layers of a road pavement and materials used when strengthening it, changes in the strength of layer material in a... [to full text]

The dynamics around managing urban infrastructure are changing dramatically. Today???s infrastructure management challenges ??? in the wake of shrinking coffers and stricter stakeholders??? requirements ??? include finding better condition assessment tools and prediction models, and effective and intelligent use of hard-earn data to ensure the sustainability of urban infrastructure systems. Wastewater collection networks ??? an important and critical component of urban infrastructure ??? have been neglected, and as a result, municipalities in North America and other parts of the world have accrued significant liabilities and infrastructure deficits. To reduce cost of ownership, to cope with heighten accountability, and to provide reliable and sustainable service, these systems need to be managed in an effective and intelligent manner. The overall objective of this research is to present a new strategic management framework and related tools to support multi-perspective maintenance, rehabilitation and replacement (M, R&R) planning for wastewater collection networks. The principal objectives of this research include: (1) Developing a comprehensive wastewater collection network asset database consisting of high quality condition assessment data to support the work presented in this thesis, as well as, the future research in this area. (2) Proposing a framework and related system to aggregate heterogeneous data from municipal wastewater collection networks to develop better understanding of their historical and future performance. (3) Developing statistical models to understand the deterioration of wastewater pipelines. (4) To investigate how strategic management principles and theories can be applied to effectively manage wastewater collection networks, and propose a new management framework and related system. (5) Demonstrating the application of strategic management framework and economic principles along with the proposed deterioration model to develop long-term financial sustainability plans for wastewater collection networks. A relational database application, WatBAMS (Waterloo Buried Asset Management System), consisting of high quality data from the City of Niagara Falls wastewater collection system is developed. The wastewater pipelines??? inspections were completed using a relatively new Side Scanner and Evaluation Technology camera that has advantages over the traditional Closed Circuit Television cameras. Appropriate quality assurance and quality control procedures were developed and adopted to capture, store and analyze the condition assessment data. To aggregate heterogeneous data from municipal wastewater collection systems, a data integration framework based on data warehousing approach is proposed. A prototype application, BAMS (Buried Asset Management System), based on XML technologies and specifications shows implementation of the proposed framework. Using wastewater pipelines condition assessment data from the City of Niagara Falls wastewater collection network, the limitations of ordinary and binary logistic regression methodologies for deterioration modeling of wastewater pipelines are demonstrated. Two new empirical models based on ordinal regression modeling technique are proposed. A new multi-perspective ??? that is, operational/technical, social/political, regulatory, and finance ??? strategic management framework based on modified balanced-scorecard model is developed. The proposed framework is based on the findings of the first Canadian National Asset Management workshop held in Hamilton, Ontario in 2007. The application of balanced-scorecard model along with additional management tools, such as strategy maps, dashboard reports and business intelligence applications, is presented using data from the City of Niagara Falls. Using economic principles and example management scenarios, application of Monte Carlo simulation technique along with the proposed deterioration model is presented to forecast financial requirements for long-term M, R&R plans for wastewater collection networks. A myriad of asset management systems and frameworks were found for transportation infrastructure. However, to date few efforts have been concentrated on understanding the performance behaviour of wastewater collection systems, and developing effective and intelligent M, R&R strategies. Incomplete inventories, and scarcity and poor quality of existing datasets on wastewater collection systems were found to be critical and limiting issues in conducting research in this field. It was found that the existing deterioration models either violated model assumptions or assumptions could not be verified due to limited and questionable quality data. The degradation of Reinforced Concrete pipes was found to be affected by age, whereas, for Vitrified Clay pipes, the degradation was not age dependent. The results of financial simulation model show that the City of Niagara Falls can save millions of dollars, in the long-term, by following a pro-active M, R&R strategy. The work presented in this thesis provides an insight into how an effective and intelligent management system can be developed for wastewater collection networks. The proposed framework and related system will lead to the sustainability of wastewater collection networks and assist municipal public works departments to proactively manage their wastewater collection networks.

The catalytic depolymerization/pyrolysis of nylon 6 and 66 were investigated with the prospect of helping to curb the amount of carpet landfilled. Thermogravimetric analysis was used to determine which catalysts (and their nylon/catalyst ratio) were most suited for the depolymerization. By adding bases, the onset of degradation for some bases was 100 aC lower than that of the pure nylons. Potassium hydroxide and sodium hydroxide were found to be the most effective catalysts at a catalyst ratio of 100:1 of nylon 6 and nylon 66 to catalyst, respectively. After determining the most efficient catalyst, kinetic models/parameters from the TGA data were determined. These parameters were used in a reactive extrusion model for depolymerizing nylon 6 in carpet. Data from the model was then used to do cost analysis for the process. It was found that to get a Present Value Ratio greater than 1, the flow rate has to be greater than or equal to 500 lb/hr. At even higher flow rates up to the model¡¦s limit (1500 lb/hr), the Net Present Value shows that this process is economically viable. Extrusion of a 100:1 ratio of pure N6 and KOH was done in a 30 mm counter-rotating non-intermeshing twin screw extruder. The material collected from the vents of the extruder was tested with a gas chromatograph- mass spectrum (GC-MS) in tandem. There was only one significant peak from the GC and the primary molecular weight on the MS was 113, the molecular weight of caprolactam. This shows that the process could be profitable and require little purification if done industrially.

Es desenvolupa una eina de disseny per l'anàlisi de la tolerància al dany en composites. L'eina pot predir el inici i la propagació de fisures interlaminars. També pot ser utilitzada per avaluar i planificar la necessitat de reparar o reemplaçar components durant la seva vida útil. El model desenvolupat pot ser utilitzat tan per simular càrregues estàtiques com de fatiga.El model proposat és un model de dany termodinàmicament consistent que permet simular la delaminació en composites sota càrregues variables. El model es formula dins el context de la Mecànica del Dany, fent ús dels models de zona cohesiva. Es presenta un metodologia per determinar els paràmetres del model constitutiu que permet utilitzar malles d'elements finits més bastes de les que es poden usar típicament. Finalment, el model és també capaç de simular la delaminació produïda per càrregues de fatiga. / A design tool for the analysis of delamination in laminated composites was developed. The design tool is developed using the damage-tolerance concept to predict both delamination initiation and growth. Therefore, the model developed can be used to perform either strength or damage-tolerance verification of new components, and can be used to assess the necessity to repair or replace in-service components. The model developed can be used either to simulate quasi-static or fatigue loading.A thermodinamically consistent damage model is proposed for the simulation of delamination in composite materials under variable-mode loading. The model is formulated in the context of Damage Mechanics by means of the Cohesive Zone Model concept. Moreover, a methodology to determine the parameters of the constitutive model is proposed. The methodology presented allows the use of coarser meshes that is usually admissible. Finally, the model has been enhanced to simulate high cycle fatigue.