231 |
Émissions polluantes des NOx : mécanisme de formation et de réduction / NOx polluting emissions : formation and reduction mechanismNguyen, Thi Huyen Trang 05 July 2013 (has links)
Les émissions des NOₓ par l'industrie métallurgique proviennent principalement de la combustion du charbon au cours du procédé d'agglomération. Parmi les méthodes de réduction des NOₓ de ce procédé, l'ajout des additifs dans le mélange de matières premières du procédé d'agglomération a été choisi grâce à ses avantages. Ces techniques sont relativement simples à mettre en oeuvre, et ne nécessitent qu'un faible coût d'investissement. Cette thèse est une partie du projet européen INTERREG IVA CleanTech et du projet industriel d'ArcelorMittal de Dunkerque, qui portent sur les études de réductions de NOₓ par méthode d'ajout des additifs. L'objectif de cette thèse consiste à étudier le mécanisme de réduction des NOₓ par ces additifs afin d'optimiser le procédé et de choisir des nouveaux additifs. De plus, les propriétés des produits d'agglomérés sont également étudiées pour déterminer l'influence des additifs sur les qualités de produit final. Une première étude expérimentale a été consacrée à l'étude de la décomposition thermique des additifs utilisés afin de comprendre le mécanisme de diminution des NOₓ. Nous avons pu déterminer des composés-réducteurs de NOₓ et des quantités formées au cours de la pyrolyse des additifs. Cela nous permet de confirmer les produits influençant sur la réduction des NOₓ. Dans une deuxième partie, les produits d'agglomérés obtenus lors des essais dans la cuve pilote, ont été mesurés par différentes méthodes (diffraction X au laboratoire, diffraction X à haute énergie et haute résolution sur synchrotron, spectroscopie Mössbauer). Nous avons d'abord déterminé les compositions des phases cristallines contenus dans les agglomérés. Nous avons ensuite comparé les différences entre les agglomérés références (sans additifs) et les agglomérés obtenus avec différents additifs afin de déterminer les phases responsables pour la résistance mécanique. / NOₓ emission in the steel industry mainly come from the combustion of coal in the agglomeration process. Among the methods of NOₓ reduction for this process, the addition of additives to the mixture of raw materials agglomeration process is chosen due to its advantages. This technique is comparatively simple to implement, and requires only a low-cost investment. This thesis is part of European project INTERREG IVA CleanTech and industrial project ArcelorMittal Dunkerque in order to study NOₓ reductions by additives. The objectives of this thesis is to have a better comprehension in the mechanism of NOₓ reduction by additives to optimize the process with more effective additives. With that purpose, the properties of agglomerated products are also studied to determine the additives' influences on the quality of the final product. In the first part, an experimental study was devoted to sutdy the thermal decomposition of the additives to understand the mechanism of NOₓ reduction. The compounds formed during the pyrolysis of additives are identified and quantified. This allows us to confirm the products' influence on the reduction of NOₓ. In the second part, agglomerated products obtained in the pilot test are measured by different methods (X-ray diffraction laboratory, high-energy and high-resolution X-ray diffraction, Mössbauer spectroscopy). To determine the compositions of crystalline phases contained in the agglomerates. We then compared the differences between the reference agglomerate (without additives) and agglomerate obtained with different additives in order to determine the phases related to the mechanical resistance.
|
232 |
Modélisation de sous-maille de la combustion turbulente : développement d'outils pour la prédiction de la pollution dans une chambre aéronautique / Turbulent combustion subgrid scale modeling : towards predictive tools for pollutant emissions in aeronautical chambers.Godel, Guillaume 01 February 2010 (has links)
Cette thèse est consacrée à l’amélioration des capacités de prédiction des émissions polluantes (CO, NOx . . . ) des foyers de combustion de turboréacteurs. L’étude, exclusivement numérique, repose sur des simulations aux grandes échelles (ou LES pour Large-Eddy Simulation) basées sur des méthodes de tabulation de la chimie détaillée. L’approche PCM-FPI (pour Presumed Conditional Moments - Flame Prolongation of ILDM) a été étendue à la chimie des oxydes d’azote via la modification de la variable d’avancement. Différentes validations sur des configurations laminaires simples puis des flammes de laboratoire (Cabra, Sandia) sont présentées. Les résultats en terme de structure de flamme et de champs d’espèces chimiques sont confrontés aux mesures expérimentales. Le rôle du formaldéhyde comme marqueur de la zone réactionnelle est illustré à l’aide de calculs de flammes laminaires puis confirmé par un calcul 3D LES. Une analyse des spécificités de l’implantation de ce type de modèle sur des machines à architecture massivement parallèle est ensuite menée. Diverses modifications de la structure de la table et des méthodes d’interpolation sont réalisées, servant de base à une étude de sensibilité de maillage appliquée à la flamme Sandia D. Les difficultés relatives à la prédiction du NO dans les flammes turbulentes sont exposées : divers modèles de sous-maille sont alors employés et comparés. / This thesis is focused on the prediction capabilities of pollution (CO, NOx especially) for numerical tools applied to aeronautical combustion chambers. The modeling work is based on Large-Eddy Simulation methods coupled with a tabulated detailed chemistry approach. The PCM-FPI model, which stands for Presumed Conditional Moments - Flame Prolongation of ILDM, has been revised to take into account nitrogen chemistry through a modification of the progress variable. Several benchmarks and test-cases (laminar and turbulent flames) are gathered in this study : Cabra and Sandia flames have been computed and satisfactory comparisons with measurements are obtained. The role of CH2O as a marker of heat release is investigated, first in the frame of laminar premixed flames and then validated through LES runs. The challenges of the implementation of tabulated chemistry methods on massively parallel machines are discussed. Modifications are proposed regarding both the table structure and the interpolation methods leading to a mesh sensitivity review applied to the Sandia D flame. Difficulties arising when dealing with NOx chemistry in turbulent flows are presented : new Sub-Grid Scale models are introduced and investigated.
|
233 |
High temperature corrosion in a biomass-fired power boiler : Reducing furnace wall corrosion in a waste wood-fired power plant with advanced steam dataAlipour, Yousef January 2013 (has links)
The use of waste (or recycled) wood as a fuel in heat and power stations is becoming more widespread in Sweden (and Europe), because it is CO2 neutral with a lower cost than forest fuel. However, it is a heterogeneous fuel with a high amount of chlorine, alkali and heavy metals which causes more corrosion than fossil fuels or forest fuel. A part of the boiler which is subjected to a high corrosion risk is the furnace wall (or waterwall) which is formed of tubes welded together. Waterwalls are made of ferritic low-alloyed steels, due to their low price, low stress corrosion cracking risk, high heat transfer properties and low thermal expansion. However, ferritic low alloy steels corrode quickly when burning waste wood in a low NOx environment (i.e. an environment with low oxygen levels to limit the formation of NOx). Apart from pure oxidation two important forms of corrosion mechanisms are thought to occur in waste environments: chlorine corrosion and alkali corrosion. Although there is a great interest from plant owners to reduce the costs associated with furnace wall corrosion very little has been reported on wall corrosion in biomass boilers. Also corrosion mechanisms on furnace walls are usually investigated in laboratories, where interpretation of the results is easier. In power plants the interpretation is more complicated. Difficulties in the study of corrosion mechanisms are caused by several factors such as deposit composition, flue gas flow, boiler design, combustion characteristics and flue gas composition. Therefore, the corrosion varies from plant to plant and the laboratory experiments should be complemented with field tests. The present project may thus contribute to fill the power plant corrosion research gap. In this work, different kinds of samples (wall deposits, test panel tubes and corrosion probes) from Vattenfall’s Heat and Power plant in Nyköping were analysed. Coated and uncoated samples with different alloys and different times of exposure were studied by scanning electron microscopy (SEM), energy dispersive x-ray analysis (EDX), X-ray diffraction (XRD) and light optical microscopy (LOM). The corrosive environment was also simulated by Thermo-Calc software. The results showed that a nickel alloy coating can dramatically reduce the corrosion rate. The corrosion rate of the low alloy steel tubes, steel 16Mo3, was linear and the oxide scale non-protective, but the corrosion rate of the nickel-based alloy was probably parabolic and the oxide much more protective. The nickel alloy and stainless steels showed good corrosion protection behavior in the boiler. This indicates that stainless steels could be a good (and less expensive) alternative to nickel-based alloys for protecting furnace walls. The nickel alloy coated tubes (and probe samples) were attacked by a potassium-lead combination leading to the formation of non-protective potassium lead chromate. The low alloy steel tubes corroded by chloride attack. Stainless steels were attacked by a combination of chlorides and potassium-lead. The Thermo-Calc modelling showed chlorine gas exists at extremely low levels (less than 0.1 ppm) at the tube surface; instead the hydrated form is thermodynamically favoured, i.e. gaseous hydrogen chloride. Consequently chlorine can attack low alloy steels by gaseous hydrogen chloride rather than chlorine gas as previously proposed. This is a smaller molecule than chlorine which could easily diffuse through a defect oxide of the type formed on the steel. / <p>QC 20130423</p>
|
234 |
Aerothermal and Kinetic Modelling of a Gas Turbine Dry Low Emission Combustion System / Aerotermisk och kinetisk modellering av en gasturbins "dry low emission" - förbränningssystemHåkansson, David January 2021 (has links)
Growing environmental concerns are causing a large transformation within the energy industry. Within the gas turbine industry, there is a large drive to develop improved modern dry-low emission combustion systems. The aim is to enable gas turbines to run on green fuels like hydrogen, while still keeping emission as NOx down. To design these systems, a thorough understanding of the aerothermal and kinetic processes within the combustion system of a gas turbine is essential. The goal of the thesis was to develop a one-dimensional general network model of the combustion system of Siemens Energy SGT-700, which accurately could predict pressure losses, mass flows, key temperatures, and emissions. Three models were evaluated and a code that emulated some aspects of the control system was developed. The models and the code were evaluated and compared to each other and to test data from earlier test campaigns performed on SGT-700 and SGT-600. Simulations were also carried out with hydrogen as the fuel. In the end, a model of the SGT-700 combustion chamber was developed and delivered to Siemens Energy. The model had been verified against test data and predictions made by other Siemens Energy thermodynamic calculation software, for a range of load conditions. The preforms of the model, when hydrogen was introduced into the fuel mixture, were also tested and compared to test data / En växande medvetenhet kring klimatfrågan, har medfört stora förändringar i energibranschen. I och med detta behöver även gasturbinindustrin förbättra de nuvarande dry-low emissions systemen och göra det möjligt för gasturbiner att förbränna gröna bränslen som väte. Samtidigt måste också utsläppen av NOx hållas nere. För att kunna utforma dessa system behövs en fullständig förståelse för de aerotermiska och kinetiska processerna i en gasturbins förbränningskammare. Målet med detta examensarbete var att utveckla en endimensionell generell nätverksmodell för förbränningssystemet i Siemens Energys SGT-700. Modellen skulle noggrant kunna förutsäga tryckförluster, massflöden, viktiga temperaturer samt utsläpp. Tre modeller utvärderades och en kod som emulerade vissa aspekter av styrsystemet utvecklades också. Modellerna och koden utvärderades och jämfördes mot varandra och även mot testdata från tidigare testserier som utfördes på SGT-700 och SGT-600. Simuleringar utfördes också med väte som bränsle. Slutligen levererades en modell av SGT-700 förbränningskammaren till Siemens Energy. Modellen har verifierats för en rad olika lastfall, mot testdata och data som genererats av andra termodynamisk beräkningsprogram som utvecklats av Siemens Energy. Hur modellen uppförde sig när väte var introducerat in i olika lastfall jämfördes också mot testdata
|
235 |
Water blow out phenomena inside a heavy truck silencer / Vatten blåser ut fenomen i en tung ljuddämpareSuram Venkata Subramaniyam, Rohit January 2020 (has links)
NOx sensors have become salient components in the development of efficient exhaust after treatment system for heavy duty vehicles in the past few years. When the accumulated water inside the silencer splashes on to the NOx sensor, it can cause permanent cracks in the sensor. To protect the sensor from this mode of failure, a dew point strategy is developed at Scania. This is important to predict when it is safe to switch on the NOx sensor without causing any harm to it. But the strategy currently includes only the phase transfer phenomena and neglects the effect of the water blow out phenomena inside the silencer. To investigate the effect of water blow out, an experimental test method is designed and the experiments are conducted at different locations in the silencer. The results from the experiments shows that the effect of water blow out is certainly an important factor to develop a better dew point strategy model. For a selected location, the quantity of water remaining after blow out and the time taken for the blow out phase are collected as data from the experiments. A mathematical model for the water blow out phenomena is developed in MATLAB. The model estimates the maximum amount of water which could be present in all the subvolumes of the silencer considering the effect of water blow out. The model is verified with the experimental data for a Scania CAS1 silencer. Calibration guidelines for the developed blow out model are also documented in this report. / NOx sensorer har blivit viktiga komponenter i utvecklingen av ett effektivt avgassystem för tunga fordon under de senaste åren. När det ackumulerade vattnet i ljuddämparen stänker på NOx-sensorn kan det orsaka permanenta sprickor i sensorn. För att skydda sensorn från detta misslyckande utvecklas en daggpunktsstrategi på Scania. Detta är viktigt att förutsäga när det är säkert att slå på NOx-sensorn utan att skada den. Men strategin innehåller för närvarande endast fasöverföringsfenomenen och försummar effekten av att vatten blåser ut fenomen inuti ljuddämparen. För att undersöka effekten av utblåsning av vatten utformas en experimentell testmetod och experimenten utförs på olika platser i ljuddämparen. Resultaten från experimenten visar att effekten av vattenblåsning verkligen är en viktig faktor för att utveckla en bättre daggpunktsstrategimodell. För en vald plats samlas mängden vatten kvar efter utblåsning och den tid det tar för utblåsningsfasen som data från experimenten. En matematisk modell för fenomen för vattenblåsning utvecklas i MATLAB. Modellen uppskattar den maximala mängden vatten som kan finnas i ljuddämparens undervolymer med tanke på effekten av vatten som blåser ut. Modellen verifieras med experimentdata för en Scania CAS1 ljuddämpare. Kalibreringsriktlinjer för den utvecklade utblåsningsmodellen dokumenteras också i denna rapport.
|
236 |
Diesel low temperature combustion : an experimental studySarangi, Asish January 2012 (has links)
Diesel engine emissions of oxides of nitrogen and particulate matter can be reduced simultaneously through the use of high levels of exhaust gas recirculation (EGR) to achieve low temperature combustion (LTC). Although the potential benefits of diesel LTC are clear, the main challenges to its practical implementation are the requirement of EGR levels that can exceed 60%, high fuel consumption, and high unburned hydrocarbon and carbon monoxide emissions. These limit the application of LTC to medium loads. In order to implement the LTC strategy in a passenger vehicle engine, a transition to conventional diesel operation is required to satisfy the expected high load demands on the engine. The investigation presented in this thesis was therefore aimed at improving the viability of the high-EGR LTC strategy for steady-state and transient operation. An experimental investigation was carried out on a single cylinder high-speed direct injection diesel engine. This thesis presents research on engine in-cylinder performance and engine-out gaseous and particulate emissions at operating conditions (i.e. EGR rate, intake pressure, fuel quantity, injection pressure) likely to be encountered by an engine during transient and steady-state operation. At selected operating points, further investigation in terms of in-cylinder spray and combustion visualization, flame temperature and soot concentration measurements provided deeper insight into the combustion and emissions phenomena. Increased intake pressure at single injection high-EGR LTC operation was investigated as a strategy to reduce the emissions of partial combustion by-products and to improve fuel economy. The higher intake pressure, although effective in reducing partial combustion by-products emissions and improving fuel economy, increased the EGR requirement to achieve LTC. A split fuel injection strategy with advanced injection timing on the other hand was effective in reducing the EGR requirement for LTC from 62% with single injection to 52% with split injections at 120 kPa (absolute) intake pressure. Unburned hydrocarbon emissions and fuel economy were particularly sensitive to intake oxygen mass fraction, and injection and dwell timings with the split injection strategy. In-cylinder soot formation and oxidation mechanisms with the split injection strategy were found to be significantly different from the single injection high-EGR LTC case. Transient simulation of an engine during combustion mode transition identified engine operating parameters on a cycle-by-cycle basis. Steady-state investigation of these test conditions provided significant insight into the combustion conditions and their effect on emissions and performance. The results from this thesis demonstrated the importance of optimizing both the air handling system performance and the fuel injection system during engine transients. The increased emissions and impaired performance due to slow response of the EGR and turbocharger systems during transitions to and from LTC modes can in part be mitigated through split injections optimized for the specific transient point. This provides a clear direction for engine developers to pursue in optimizing engine calibration when running with LTC-conventional diesel dual-mode strategies.
|
237 |
Optimization of a Dry Low NOx Micromix Combustor for an Industrial Gas Turbine Using Hydrogen-Rich Syngas FuelKeinz, Jan 11 September 2018 (has links) (PDF)
Environmentally friendly and efficiently produced energy from sustainable and renewable resources is of great importance. Carbon dioxide (CO2) and nitric oxides (NOx) are the main emissions of air-breathing gas turbines in power plants. Gas turbines of the power generation industry are normally fueled with liquid fuels, natural gas or syngas in changing qualities. Syngas can be produced by gasification processes in IGCC power plants and consist of varying percentages of the main fractions hydrogen (H2) and carbon monoxide (CO). CO2 emissions can be reduced by a decrease of the CO-share and an increase of the hydrogen-share in the syngas fuel, and by using pre-combustion carbon capture and sequestration (CCS) technology. For low NOx, current gas turbine combustion chamber technologies require diluents, a rather low H2 content and modifications of the combustor hardware. A feasible solution for low NOx hydrogen and syngas combustion in gas turbines is the Micromix principle developed at Aachen University of Applied Sciences. The goal of this doctoral thesis is the research on a Micromix combustor with increased power densities fueled with hydrogen-rich syngas with about 90% by volume hydrogen, and going up to 100% hydrogen in the fuel. Test burner experiments are used to characterize the combustion and emission properties of a multitude of key drivers. Based on this optimization with a variety of scaled model test burners, a prototype dual-fuel hydrogen/syngas Micromix combustor is designed and integrated into the annular combustion chamber of an industrial gas turbine. In the gas turbine, the performance characteristics of the prototype-combustor are investigated under real operational conditions with hydrogen-rich syngas and pure hydrogen. / Doctorat en Sciences de l'ingénieur et technologie / info:eu-repo/semantics/nonPublished
|
238 |
Uncertainty Quantification for Scale-Bridging Modeling of Multiphase Reactive FlowsIavarone, Salvatore 24 April 2019 (has links) (PDF)
The use of Computational Fluid Dynamics (CFD) tools is crucial for the development of novel and cost-effective combustion technologies and the minimization of environmental concerns at industrial scale. CFD simulations facilitate scaling-up procedures that otherwise would be complicated by strong interactions between reaction kinetics, turbulence and heat transfer. CFD calculations can be applied directly at the industrial scale of interest, thus avoiding scaling-up from lab-scale experiments. However, this advantage can only be obtained if CFD tools are quantitatively predictive and trusted as so. Despite the improvements in the computational capability, the implementation of detailed physical and chemical models in CFD simulations can still be prohibitive for real combustors, which require large computational grids and therefore significant computational efforts. Advanced simulation approaches like Large Eddy Simulation (LES) and Direct Numerical Simulation (DNS) guarantee higher fidelity in computational modeling of combustion at, unfortunately, increased computational cost. However, with adequate, reduced, and cost-effective modeling of physical phenomena, such as chemical kinetics and turbulence-chemistry interactions, and state of the art computing, LES will be the tool of choice to describe combustion processes at industrial scale accurately. Therefore, the development of reduced physics and chemistry models with quantified model-form uncertainty is needed to overcome the challenges of performing LES of industrial systems. Reduced-order models must reproduce the main features of the corresponding detailed models. They feature predictivity and capability of bridging scales when validated against a broad range of experiments and targeted by Validation and Uncertainty Quantification (V/UQ) procedures. In this work, V/UQ approaches are applied for reduced-order modeling of pulverized coal devolatilization and subsequent char oxidation, and furthermore for modeling NOx emissions in combustion systems.For coal devolatilization, a benchmark of the Single First-Order Reaction (SFOR) model was performed concerning the accuracy of the prediction of volatile yield. Different SFOR models were implemented and validated against experimental data coming from tests performed in an entrained flow reactor at oxy-conditions, to shed light on their drawbacks and benefits. SFOR models were chosen because of their simplicity: they can be easily included in CFD codes and are very appealing in the perspective of LES of pulverized coal combustion burners. The calibration of kinetic parameters was required to allow the investigated SFOR model to be predictive and reliable for different heating rates, hold temperatures and coal types. A comparison of several calibration approaches was performed to determine if one-step models can be adaptive and able to bridge scales, without losing accuracy, and to select the calibration method to employ for wider ranges of coal rank and operating conditions. The analysis pointed out that the main drawback of the SFOR models is the assumption of a constant ultimate volatile yield, equal to the value from the coal proximate analysis. To overcome this drawback, a yield model, i.e. a simple functional form that relates the ultimate volatile yield to the particle temperature, was proposed. The model depends on two parameters that have a certain degree of uncertainty. The performances of the yield model were assessed using a collaboration of experiments and simulations of a pilot-scale entrained flow reactor. A consistency analysis, based on the Bound-to-Bound Data Collaboration (B2B-DC) approach, and a Bayesian method, based on Gaussian Process Regression (GPR), were employed for the investigation of experiments and simulations. In Bound-to- Bound Data Collaboration the model output, evaluated at specified values of the model parameters, is compared with the experimental data: if the prediction of the model falls within the experimental uncertainty, the corresponding parameter values would be included in the so-called feasible set. The existence of a non-empty feasible set signifies consistency between the experiments and the simulations, i.e. model-data agreement. Consistency was indeed found when a relative error of 19% for all the experimental data was applied. Hence, a feasible set of the two SFOR model parameters was provided. A posterior state of knowledge, indicating potential model forms that could be explored in yield modeling, was obtained by Gaussian Process Regression. The model form evaluated through the consistency analysis is included within the posterior derived from GPR, indicating that it can satisfactorily match the experimental data and provide reliable estimation in almost every range of temperatures. CFD simulations were carried out using the proposed yield model with first-order kinetics, as in the SFOR model. Results showed promising agreement between predicted and experimental conversion for all the investigated cases.Regarding char combustion modeling, the consistency analysis has been applied to validate a reduced-order model and quantify the uncertainty in the prediction of char conversion. The model capability to address heterogeneous reaction between char carbon and O2, CO2 and H2O reagents, mass transport of species in the particle boundary layer, pore diffusion, and internal surface area changes was assessed by comparison with a large number of experiments performed in air and oxy-coal conditions. Different model forms had been considered, with an increasing degree of complexity, until consistency between model outputs and experimental results was reached. Rather than performing forward propagation of the model-form uncertainty on the predictions, the reduction of the parameter uncertainty of a selected model form was pursued and eventually achieved. The resulting 11-dimensional feasible set of model parameters allows the model to predict the experimental data within almost ±10% uncertainty. Due to the high dimensionality of the problem, the employed surrogate models resulted in considerable fitting errors, which led to a spoiled UQ inverse problem. Different strategies were taken to reduce the discrepancy between the surrogate outputs and the corresponding predictions of the simulation model, in the frameworks of constrained optimization and Bayesian inference. Both strategies succeeded in reducing the fitting errors and also resulted in a least-squares estimate for the simulation model. The variety of experimental gas environments ensured the validity of the consistent reduced model for both conventional and oxy-conditions, overcoming the differences in mass transport and kinetics observed in several experimental campaigns.The V/UQ-aided modeling of coal devolatilization and char combustion was done in the framework of the Predictive Science Academic Alliance Program II (PSAAP-II) funded by the US Department of Energy. One of the final goals of PSAAP-II is to develop high-fidelity simulation tools that ensure 5% uncertainty in the incident heat flux predictions inside a 1.2GW Ultra-Super-Critical (USC) coal-fired boiler. The 5% target refers to the expected predictivity of the full-scale simulation without considering the uncertainty in the scenario parameters. The data-driven approaches used in this Thesis helped to improve the predictivity of the investigated models and made them suitable for LES of the 1.2GW USC coal-fired boiler. Moreover, they are suitable for scale-bridging modeling of similar multi-phase processes involved in the conversion of solid renewable sources, such as biomass.In the final part of the Thesis, the sensitivity to finite-rate chemistry combustion models and kinetic mechanisms on the prediction of NO emissions was assessed. Moreover, the forward propagation of the uncertainty in the kinetics of the NNH route (included in the NOx chemistry) on the predictions of NO was investigated to reveal the current state of the art of kinetic modeling of NOx formation. The analysis was carried out on a case where NOx formation comes from various formation routes, both conventional (thermal and prompt) and unconventional ones. To this end, a lab-scale combustion system working in Moderate and Intense Low-oxygen Dilution (MILD) conditions was selected. The results showed considerable sensitivity of the NO emissions to the uncertain kinetic parameters of the rate-limiting reactions of the NNH pathway when a detailed kinetic mechanism is used. The analysis also pointed out that the use of one-step global rate schemes for the NO formation pathways, necessary when a skeletal kinetic mechanism is employed, lacks the required chemical accuracy and dims the importance of the NNH pathway in this combustion regime. An engineering modification of the finite-rate combustion model was proposed to account for the different chemical time scales of the fuel-oxidizer reactions and NOx formation pathways. It showed an equivalent impact on the emissions of NO than the uncertainty in the kinetics of the NNH route. At the cost of introducing a small mass imbalance (of the order of ppm), the adjustment led to improved predictions of NO. The investigation established a possibility for the engineering modeling of NO formation in MILD combustion with a finite-rate chemistry combustion model that can incorporate a detailed mechanism at affordable computational costs. / Doctorat en Sciences de l'ingénieur et technologie / info:eu-repo/semantics/nonPublished
|
239 |
Os meios digitais na arquitetura do grupo NoxVelloso, Ivan Mac-Dowell January 2009 (has links)
Atualmente, vários pesquisadores da arquitetura, investiga as possibilidades de absorção da tecnologia digital na arquitetura. Dentre as diversas posturas, destaca a do grupo de arquitetos holandeses Nox cujo método de concepção que utiliza técnicas digitais e analógicas, assim como acolhe o conhecimento de outras disciplinas e enfatizam a topologia como um dos eixos norteador, a obra do grupo indica as questões para o debate. Dialogando com outros autores, este tema reflete sobre as modificações pelas quais passa a arquitetura. / Nowadays, different groups of architects search for the possibilities of digital Technology contribution to architecture. Among the various stances, this paper particularly highlights the Dutch architects group called Nox, which develops a design method that uses both digital and analogical techniques, as well as incorporates knowledge from other disciplines. The Dutch group’s work serves as a guideline, as it indicates the subjects to be examined. Also based on the studies of other authors, the present research analyses the modifications contemporary architecture is going through, such as matters related to form, design method and conceiving of space, time and reality.
|
240 |
Optimization of N2O decomposition RhOx/ceria catalysts and design of a high N2-selective deNOx system for diesel vehiclesRico Pérez, Verónica 12 July 2013 (has links)
No description available.
|
Page generated in 0.025 seconds