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付記する学位プログラム名: 京都大学卓越大学院プログラム「先端光・電子デバイス創成学」 / 京都大学 / 新制・課程博士 / 博士(工学) / 甲第24621号 / 工博第5127号 / 新制||工||1980(附属図書館) / 京都大学大学院工学研究科電子工学専攻 / (主査)教授 竹内 繁樹, 教授 川上 養一, 教授 木本 恒暢 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

We investigate the influence of the pump and collection mode parameters on the collection efficiency of Type I down converted photons into single mode fibers. For best single and coincidence counting rates, we find that the mode sizes should be close to the same size and that the mode waists should be located near the down-conversion crystal. Larger collection waists give higher collection efficiencies, but lower singles counts.

Direct-Down Conversion (DDC) principle based transceiver architectures are of interest to meet the diverse needs of present and future wireless systems. DDC transceivers have a simple structure with fewer analog components and offer low-cost, flexible and multi-standard solutions. However, DDC transceivers have certain circuit impairments affecting their performance in wide-band, high data rate and multi-user systems. IQ imbalance is one of the problems of DDC transceivers that limits their image rejection capabilities. Compensation techniques for frequency independent IQI arising due to gain and phase mismatches of the mixers in the I/Q paths of the transceiver have been widely discussed in the literature. However for wideband multi-channel transceivers, it is becoming increasingly important to address frequency dependent IQI arising due to mismatches in the analog I/Q lowpass filters. A hardware-efficient and standard independent digital estimation and compensation technique for frequency dependent IQI is introduced which is also capable of tracking time-varying IQI changes. The technique is blind and adaptive in nature, based on the second order statistical properties of complex random signals such as properness/circularity. A detailed performance analysis of the introduced technique is executed through computer simulations for various real-time operating scenarios. A novel technique for finding the optimal number of taps required for the adaptive IQI compensation filter is proposed and the performance of this technique is validated. In addition, a metric for the measure of properness is developed and used for error power and step size analysis. / Master of Science

Le projet s’inscrit dans le développement de sources lasers RGB miniaturisées pour l’affichage et la vidéoprojection, la conversion de fréquence dans les cellules solaires.Les verres fluorés ZLAG (ZrF4-LaF3-AlF3-GaF3) codopés terres rares ont été considérés. Ce verre possède une faible énergie de phonon, une forte solubilité des terres rares et peut être fabriqué en couche mince par la technique PVD. Il est de plus le précurseur de vitrocéramiques transparentes. On a observé dans les verres massifs et les guides d’onde des émissions bleue, orange et rouge avec un codopage Pr3+-Yb3+, bleue et rouge avec un co-dopage Tm3+-Yb3+. L’émission RGB dans les verres tri-dopés Tm3+-Er3+-Yb3+ semble prometteuse. Par ailleurs, la vitro-céramisation a permis d’augmenter de plus de 30% les sections efficaces d’absorption des ions Pr3+ et Yb3+.Une efficacité de transfert de 92% a été obtenue dans les verres co-dopés 0,5Pr3+-10Yb3+ pour le processus de conversion d’un photon bleu en deux photons IR. / The project joins in the development of miniaturized laser sources RGB for display and videoprojection, frequency conversion in solar cells.Fluoride glasses ZLAG ( ZrF4-LaF3-AlF3-GaF3) co-doped with rare earths were studied. This glass has a low phonon energy, a strong solubility of the rare earth ions and can be fabricated as thin films by PVD. It is also the precursor of transparent glass-ceramics. Similar emissions in both co-doped bulk and waveguides have been observed ; blue, orange, red emission for Pr3+-Yb3+ and blue, red emission for Tm3+-Yb3+. The RGB emission in bulk Tm3+-Er3+-Yb3+ tri-doped glass seems promising. Furthermore, the absorption cross section of Pr3+ and Yb3+ ions has been increased by 30% with the ceraming process.An energy transfer efficiency (ETE) of 92% has been obtained for co-doped glass with 0,5Pr3+-10Yb3+ for the conversion process of a blue photon into two infrared one.

Le but de cette thèse est de sonder la flexibilité de NCp7 et de Δ(-)PBS, deux bio-molécules impliquées dans le second saut de brin de la transcription inverse du VIH. Deux stratégies expérimentales ont été mises en place. Un nouveau montage de spectroscopie ultra-rapide de fluorescence par down-conversion a été construit. Les dynamiques de quenching de la 2-aminopurine (2Ap), insérée en position 6, 8 et 10 de la boucle Δ(-)PBS ont pu être entièrement résolues à une résolution sub-ps. Pour chaque position, 4 temps de vie ont été révélés. Des mesures d'anisotropie confirment que les deux composantes < 5 ps sont liées à un empilement de la 2Ap avec les Guanines avoisinantes. Cet empilement est site-spécifique, prouvé par l'augmentation significative de leurs amplitudes lorsque la 2Ap est située près de la tige (position 10). La faible proportion de conformations reliées à un quenching collisionnel est significative de la faible exposition des 2Ap au solvant et de l'encombrement général de la boucle. La seconde approche avait pour but d'étudier l'effet du repliement du squelette protéique de [35-50] NCp7 autour de son atome de zinc par CID et par LID. Les spectres CID de la protéine nue sont expliqués par le modèle du proton mobile et une description détaillée d'un schéma de fragmentation spécifique autour du Tryptophane (Trp) a été soulignée, attribué une Lysine voisine. Un seul fragment issu de l'excitation à 266 nm a été identifié, son apparition entre en compétition avec les fragments CID du Trp. L'effet général du repliement autour du Zinc se traduit par une augmentation du taux de fragmentation autour du Trp et par une perte de spécificité pour le reste du spectre.Les flexibilités de Δ(-)PBS et NCp7 ont été respectivement évaluées par spectroscopie ultra-rapide de type down-conversion et par spectrométrie en phase gazeuse. La première méthode nécessite l'utilisation d'une sonde fluorescente non invasive, la 2-aminopurine (2Ap), placée en position 6, 8 et 10 de la boucle Δ(-)PBS. Notre résolution temporelle permet de résoudre entièrement les dynamiques locales de quenching et d'anisotropie de la 2Ap. Les composantes liées au quenching statique et quenching collisionnel ont été discriminées et révèlent les degrés d'empilement / encombrement locaux de la boucle. L'effet du repliement de [35-50] NCp7 autour de son atome de zinc a été étudié par CID et par LID à 266 nm. La protéine nue présente un interessant shéma de fragmentation autour du Tryptophane (Trp), exalté par la complexation avec le zinc, au prix une perte de spécificité pour le reste du spectre. Un seul fragment LID a été identifié, un mécanisme de sa formation est proposé. / This thesis aims to probe the flexibility of NCp7 and Δ(-)PBS, two biomolecules involved in the second strand transfer of the HIV's reverse transcription. We brought to the front two original experimental methods. A new ultrafast fluorescence down-conversion setup has been built, suitable for biological chromophore investigations. The quenching dynamics of 2-aminopurine (2Ap), site-mutated at the positions 6, 8 and 10 of Δ(-)PBS loop, were completely resolved under a ps scale. For each location, 4 decay times, were highlighted. Further anisotropy measurements confirmed that the two < 5 ps components correspond to stacking interactions of 2Ap with neighbouring Guanines. The site-specific aspect of the stacking were supported by a significant increase of their relative amplitudes when 2Ap were cloesly located to the stem (position 10). The minor portion of conformations involved with ps to ns collisional quenching suggests a low exposure of 2Ap towards the solvent as well as a general restriction of the loop. The second method planned to investigate the effet of the zinc-folding on [35-50] NCp7's peptidic backbone, thanks to CID and LID. The CID-generated spectra of the bare peptide were explained by the mobile proton model, and an exhaustive tryptophan (Trp) fragmentation pattern was described, mainly due to a neighbouring Lysin effects. Only one LID-fragment has been identified upon 266 nm excitation, probably created through a pathway competing with the generation of Trp fragments by CID. The main aspects related to zinc-folding are a general enhancement of the fragmentation ratios related to Trp and a loss of specificity for the remaining mass spectra parts.Δ(-)PBS et NCp7 has been respectively investigated by ultrafast down-conversion spectroscopy and gas-phase spectrometry. The first method implies the use of a non invasive fluorescent probe, named 2 aminopurine (2Ap), site mutated in position 6, 8 et 10 of the Δ(-)PBS loop. Our time resolution allows to fully depict the local quenching dynamics and anisotropy decays. The component related to static and collisional has been solved, thus describing different stacking degrees as well as local restrictions. The effect of [35-50] NCp7 folding around its zinc atom has been studied by CID and 266 nm LID. The bare protein displays an interesting fragmentation pathway around its Tryptophan (Trp), enhanced with zinc complexation, at the cost of a loss of specificity for the remaining mass spectra parts. Only one LID fragment has been identified, its occurence has been interpreted.

ITC/USA 2006 Conference Proceedings / The Forty-Second Annual International Telemetering Conference and Technical Exhibition / October 23-26, 2006 / Town and Country Resort & Convention Center, San Diego, California / This paper presents a practical implementation of a hardware design for transmission of data over aircraft power lines. The intent of such hardware is to significantly reduce the wiring in the aircraft instrumentation system. The potential usages of this technology include pulse code modulation (PCM), Ethernet and other forms data communications. Details of the fieldprogrammable gate array (FPGA) and printed circuit board (PCB) designs of the digital and analog front end will be discussed. The power line is not designed for data transmission. It contains considerable noise, multipath effects, and time varying impedance. Spectral analysis data of an aircraft is presented to indicate the difficulty of the problem at hand. A robust modulation is required to overcome the harsh environment and to provide reliable transmission. Orthogonal frequency division multiplexing (OFDM) has been used in power line communication industry with a great deal of success. OFDM has been deemed the most appropriate technology for high-speed data transmission on aircraft power lines. Additionally, forward error correction (FEC) techniques are discussed.

Material and structure engineering are increasingly employed in active optical media,in this context defined as media capable of providing laser or/and optical parametric gain. For laser materials, the main aim of the engineering is to tailor the absorption and emission cross sections in order to optimise the laser performance. At the same time, the engineering also results in a collateral modification of the material’s nonlinear response. In the first part of this work, the nonlinear index of refraction is characterised for two crystallographic forms of laser-ion doped and undoped double-tungstate crystals. These laser crystals have broad gain bandwidths, in particular when doped with Yb3+. As shown in this work, the crystals also have large Kerr nonlinearities, where the values vary significantly for different chemical compositions of the crystals. The combination of a broad gain bandwidthand a high Kerr nonlinearity makes the laser-ion doped double tungstates excellent candidates to employ for the generation of ultrashort laser pulses by Kerr-lens modelocking. The second part of the work relates to the applications of engineered second-order nonlinear media, which here in particular are periodically-poled KTiOPO4 crystals. Periodic structure engineering of second-order nonlinear crystals on a submicrometre scale opens up for the realisation of novel nonlinear devices. By the use of quasi-phase matching in these structures, it is possible to efficiently downconvert a pump wave into two counterpropagating parametric waves, which leads to a device called a mirrorless optical parametric oscillator. The nonlinear response in these engineered submicrometre structures is such that the parametric wave that propagates in the opposite direction of the pump automatically has a narrow bandwidth, whereas the parametric wave that propagates with the pump essentially is a frequency-shifted replica of the pump wave. The unusual spectral properties andthe tunabilities of mirrorless optical parametric oscillators are investigated. / QC 20120330

Entanglement is a key resource in many quantum information schemes and in the last years the research on multi-qubit entanglement has drawn lots of attention. In this thesis the experimental generation and characterisation of multi-qubit entanglement is presented. Specifically we have prepared entangled states of up to six qubits. The qubits were implemented in the polarisation degree of freedom of single photons. We emphasise that one type of states that we produce are rotationally invariant states, remaining unchanged under simultaneous identical unitary transformations of all their individual constituents. Such states can be applied to e.g. decoherence-free encoding, quantum communication without sharing a common reference frame, quantum telecloning, secret sharing and remote state preparation schemes. They also have properties which are interesting in studies of foundations of quantum mechanics. In the experimental implementation we use a single source of entangled photon pairs, based on parametric down-conversion, and extract the first, second and third order events. Our experimental setup is completely free from interferometric overlaps, making it robust and contributing to a high fidelity of the generated states. To our knowledge, the achieved fidelity is the highest that has been observed for six-qubit entangled states and our measurement results are in very good agreement with predictions of quantum theory. We have also performed another novel test of the foundations of quantum mechanics. It is based on an inequality that is fulfilled by any non-contextual hidden variable theory, but can be violated by quantum mechanics. This test is similar to Bell inequality tests, which rule out local hidden variable theories as possible completions of quantum mechanics. Here, however, we show that non-contextual hidden variable theories cannot explain certain experimental results, which are consistent with quantum mechanics. Hence, neither of these theories can be used to make quantum mechanics complete.

The rapidly developing interdisciplinary field of quantum information, which merges quantum and information science, studies non-classical aspects of quantum systems. These studies are motivated by the promise that the non-classicality can be used to solve tasks more efficiently than classical methods would allow. In many quantum informational studies, non-classical behaviour is attributed to the notion of entanglement. In this thesis we use photons to experimentally investigate fundamental questions such as: What happens to the entanglement in a system when it is affected by noise? In our study of noisy entanglement we pursue the challenging task of creating bound entanglement. Bound entangled states are created through an irreversible process that requires entanglement. Once in the bound regime, entanglement cannot be distilled out through local operations assisted by classical communication. We show that it is possible to experimentally produce four-photon bound entangled states and that a violation of a Bell inequality can be achieved. Moreover, we demonstrate an entanglement-unlocking protocol by relaxing the condition of local operations. We also explore the non-classical nature of quantum mechanics in several single-photon experiments. In these experiments, we show the violation of various inequalities that were derived under the assumption of non-contextuality. Using qutrits we construct and demonstrate the simplest possible test that offers a discrepancy between classical and quantum theory. Furthermore, we perform an experiment in the spirit of the Kochen-Specker theorem to illustrate the state-independence of this theorem. Here, we investigate whether or not measurement outcomes exhibit fully contextual correlations. That is, no part of the correlations can be attributed to the non-contextual theory. Our results show that only a small part of the experimental generated correlations are amenable to a non-contextual interpretation. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 5: Submitted. Paper 6: Submitted.</p>