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Étude et exploitation de bolomètres de nouvelle génération à électrodes concentriques pour la recherche de matière noire froide non-baryonique dans l’expérience Edelweiss II / Study of new germanium bolometers with interleaved concentric electrodes fot non-baryonic cold dark matter direct detection in the Edelweiss-II experimentDomange, Jocelyn 30 September 2011 (has links)
EDELWEISS est une expérience de détection directe de matière noire froide non-baryonique sous forme de particules massives et faiblement interagissantes (connues sous l'acronyme de WIMPs), qui constituent actuellement les candidats les plus populaires pour rendre compte de la masse manquante de l'Univers. Dans ce but, EDELWEISS utilise des bolomètres de germanium opérés à température cryogénique (20 mK environ) dans le Laboratoire Souterrain de Modane (LSM) à la frontière franco-italienne. En particulier, depuis 2008, un nouveau type de détecteur est en fonctionnement, équipé d'électrodes concentriques pour optimiser le rejet des évènements de surface (détecteurs à grilles coplanaires). Cette thèse se décompose en plusieurs axes de recherche. Tout d'abord, nous avons réalisé des mesures concernant la collecte des charges dans les cristaux. Les lois de vitesse des porteurs (électrons et trous) ont été déterminées dans le germanium à 20 mK dans la direction <100>, et une étude complète de la répartition des charges a été menée, avec une évaluation de l'anisotropie du transport et de la diffusion transverse des porteurs. Ces résultats permettent d'avoir une meilleure compréhension du fonctionnement interne des détecteurs d'Edelweiss. Ensuite, des études portant sur l'amélioration des performances ont été effectuées. Nous avons en particulier permis d'optimiser la procédure de régénération des cristaux et améliorer le rejet passif des évènements de surface (β). Le volume utile de détection des détecteurs a été évalué en utilisant les raies de deux radio-isotopes activés cosmiquement, le 68Ge et le 65Zn. Enfin, une étude exhaustive portant sur l'étude des spectres à basse énergie a été menée, ce qui permet de mettre au point une méthode d'analyse systématique pour la recherche de WIMPs de basse masse dans EDELWEISS. / EDELWEISS is a direct non-baryonic cold dark matter detection experiment in the form of weakly interacting massive particles (also known as WIMPs), which currently constitute the most popular candidates to account for the missing mass in the Universe. To this purpose, EDELWEISS uses germanium bolometers at cryogenic temperature (20 mK approximately) in the Underground Laboratory of Modane (LSM) at the French-Italian border. Since 2008, a new type of detector is operated, equipped with concentric electrodes to optimize the rejection of surface events (coplanar-grid detectors). This thesis work is divided into several research orientations. First, we carried out measurements concerning charge collection in the crystals. The velocity laws of the carriers (electrons and holes) have been determined in germanium at 20 mK in the <100> orientation, and a complete study of charge sharing has been done, including an evaluation of the transport anisotropy and of the straggling of the carriers. These results lead to a better understanding of the inner properties of the EDELWEISS detectors. Then, studies relating to the improvement of the performances were carried out. In particular, we have optimized the space-charge cancellation procedure in the crystals and improved the passive rejection of surface events (β). The fiducial volume of the detectors has been evaluated using two X-ray lines from cosmically activated radionuclides: 68Ge and 65Zn. Lastly, an exhaustive study of the low energy spectra has been carried out, which makes it possible to develop a systematic analysis method for the search of low-mass WIMPs in EDELWEISS.
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Modélisation de solides à nanocristaux de silicium / Modelling of silicon nanocrystal solidsLepage, Hadrien 22 October 2012 (has links)
Les propriétés physico-chimiques d'un nanocristal semi-conducteur sphérique, intermédiaires entre la molécule et le solide, dépendent de sa taille. Empilés ou dispersés, ces nanocristaux sont les briques architecturales de nouveaux matériaux fonctionnels aux propriétés ajustables, en particulier pour l’optoélectronique. Cette thèse s'inscrit dans le développement de ces nouveaux matériaux et présente avant tout une méthodologie pour la simulation du transport électronique dans un solide à nanocristaux en régime de faible couplage électronique appliquée à des nanocristaux de silicium dans une matrice de SiO2 pour les applications photovoltaïques. La cinétique du déplacement des porteurs est liée au taux de transfert tunnel (hopping) entre nanocristaux. Ces taux sont calculés dans le cadre de la théorie de Marcus et prennent en compte l'interaction électron-phonon dont l'effet du champ de polarisation dans la matrice ainsi que les interactions électrostatiques à courte et longue portée. Le calcul des états électroniques (électrons et trous) en théorie k.p associé à l'utilisation de la formule de Bardeen donne au code la capacité, par rapport à la littérature, de fournir des résultats (mobilité ou courant) en valeur absolue. Les résultats de mobilité ainsi obtenus pour des empilements cubiques idéaux viennent contredire les résultats de la littérature et incitent à considérer d'autres matériaux notamment en ce qui concerne la matrice pour obtenir de meilleurs performances. En outre, les résultats de simulation de dispositifs montrent l'impact considérable des électrodes sur les caractéristiques courant-tension. Aussi, un nouvel algorithme Monte-Carlo Cinétique accéléré a été adapté afin de pouvoir reproduire le désordre inhérent à la méthode de fabrication tout en maintenant un temps de simulation raisonnable. Ainsi l'impact du désordre en taille se révèle faible à température ambiante tandis que les chemins de percolation occultent la contribution des autres chemins de conduction. Des résultats de caractérisation comparés aux simulations tendent par ailleurs à indiquer que ces chemins peuvent concentrer les porteurs et exhiber un phénomène de blocage de coulomb. Enfin, la section efficace d'absorption est calculée théoriquement et permet d'obtenir le taux de génération sous illumination qui se révèle proche du silicium massif. Et une méthode en microscopie à sonde de Kelvin est décrite pour caractériser la durée de vie des porteurs c'est-à-dire le taux de recombinaison, les résultats ainsi obtenus étant cohérents avec d'autres techniques expérimentales. / The physicochemical properties of a spherical semiconductor nanocrystal, intermediate between the molecule and the solid depend on its size. Stacked or dispersed, these nanocrystals are building blocks of new functional materials with tunable properties, particularly appealing for optoelectronics. This thesis takes part in the development of these new materials. It mainly presents a methodology for the simulation of electronic transport in nanocrystal solids within the weak electronic coupling regime. It is applied to a material made of silicon nanocrystals embedded in silicon oxide and considered for photovoltaïc applications. The displacement kinetics of charge carriers is related to the tunneling transfer rate (hopping) between nanocrystals. These rates are calculated within the framework of Marcus theory and take into account the electron-phonon interactions, the effect of the bias field and the electron-electron interactions at short and long range. The calculation of electronic states (electrons and holes) in k.p theory associated with the use of Bardeen's formula provides, compared to previous works, results (mobility or current) in absolute terms. The mobility thus computed is far lower than the results of the literature and encourage to consider other materials. Furthermore, the device simulations show the significant impact of the electrodes on the current-voltage characteristics. Also, a new accelerated kinetic Monte-Carlo algorithm has been adapted in order to reproduce the disorder inherent in the manufacturing process while maintaining a reasonable simulation time. Thus the impact of the size disorder is poor at room temperature while the percolation paths shunt the contribution of other conduction paths. Characterization results compared to simulations tend to show that these paths concentrate carriers and exhibit Coulomb blockade phenomenon. Finally, the absorption cross section is calculated theoretically to obtain the generation rate under illumination. It is similar to the bulk silicon one. And a method employing a Kelvin probe microscope is described to characterize the carrier lifetime, namely the recombination rate. The results thus obtained are consistent with other experimental technics.
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Modern Computational Physical Chemistry : An Introduction to Biomolecular Radiation Damage and Phototoxicity / Modern fysikalisk-kemisk beräkningsmetodik : En introduktion till biomolekylära strålningsskador och fototoxicitetLlano, Jorge January 2004 (has links)
<p>The realm of molecular physical chemistry ranges from the structure of matter and the fundamental atomic and molecular interactions to the macroscopic properties and processes arising from the average microscopic behaviour.</p><p>Herein, the conventional electrodic problem is recast into the simpler molecular problem of finding the electrochemical, real chemical, and chemical potentials of the species involved in redox half-reactions. This molecular approach is followed to define the three types of absolute chemical potentials of species in solution and to estimate their standard values. This is achieved by applying the scaling laws of statistical mechanics to the collective behaviour of atoms and molecules, whose motion, interactions, and properties are described by first principles quantum chemistry. For atomic and molecular species, calculation of these quantities is within the computational implementations of wave function, density functional, and self-consistent reaction field theories. Since electrons and nuclei are the elementary particles in the realm of chemistry, an internally consistent set of absolute standard values within chemical accuracy is supplied for all three chemical potentials of electrons and protons in aqueous solution. As a result, problems in referencing chemical data are circumvented, and a uniform thermochemical treatment of electron, proton, and proton-coupled electron transfer reactions in solution is enabled.</p><p>The formalism is applied to the primary and secondary radiation damage to DNA bases, e.g., absorption of UV light to yield electronically excited states, formation of radical ions, and transformation of nucleobases into mutagenic lesions as OH radical adducts and 8-oxoguanine. Based on serine phosphate as a model compound, some insight into the direct DNA strand break mechanism is given.</p><p>Psoralens, also called furocoumarins, are a family of sensitizers exhibiting cytostatic and photodynamic actions, and hence, they are used in photochemotherapy. Molecular design of more efficient photosensitizers can contribute to enhance the photophysical and photochemical properties of psoralens and to reduce the phototoxic reactions. The mechanisms of photosensitization of furocoumarins connected to their dark toxicity are examined quantum chemically.</p>
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Modern Computational Physical Chemistry : An Introduction to Biomolecular Radiation Damage and Phototoxicity / Modern fysikalisk-kemisk beräkningsmetodik : En introduktion till biomolekylära strålningsskador och fototoxicitetLlano, Jorge January 2004 (has links)
The realm of molecular physical chemistry ranges from the structure of matter and the fundamental atomic and molecular interactions to the macroscopic properties and processes arising from the average microscopic behaviour. Herein, the conventional electrodic problem is recast into the simpler molecular problem of finding the electrochemical, real chemical, and chemical potentials of the species involved in redox half-reactions. This molecular approach is followed to define the three types of absolute chemical potentials of species in solution and to estimate their standard values. This is achieved by applying the scaling laws of statistical mechanics to the collective behaviour of atoms and molecules, whose motion, interactions, and properties are described by first principles quantum chemistry. For atomic and molecular species, calculation of these quantities is within the computational implementations of wave function, density functional, and self-consistent reaction field theories. Since electrons and nuclei are the elementary particles in the realm of chemistry, an internally consistent set of absolute standard values within chemical accuracy is supplied for all three chemical potentials of electrons and protons in aqueous solution. As a result, problems in referencing chemical data are circumvented, and a uniform thermochemical treatment of electron, proton, and proton-coupled electron transfer reactions in solution is enabled. The formalism is applied to the primary and secondary radiation damage to DNA bases, e.g., absorption of UV light to yield electronically excited states, formation of radical ions, and transformation of nucleobases into mutagenic lesions as OH radical adducts and 8-oxoguanine. Based on serine phosphate as a model compound, some insight into the direct DNA strand break mechanism is given. Psoralens, also called furocoumarins, are a family of sensitizers exhibiting cytostatic and photodynamic actions, and hence, they are used in photochemotherapy. Molecular design of more efficient photosensitizers can contribute to enhance the photophysical and photochemical properties of psoralens and to reduce the phototoxic reactions. The mechanisms of photosensitization of furocoumarins connected to their dark toxicity are examined quantum chemically.
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From cuprates to manganites: spin and orbital liquidsKilian, Rolf 05 July 1999 (has links) (PDF)
Both cuprates and manganites belong to the transition metal oxides. The physics of these compounds is characterized by a dualism of local electron interaction and itinerant charge motion. In the present work, several key issues of metallic cuprates and manganites are addressed on a theoretical level, while close connection to recent experimental work is kept. The work is based on the notion of spin and orbital liquids, representing elegant tools to handle the strongly correlated nature of the metallic state in an efficient and transparent manner. A concise introduction to the physics of cuprates and manganites as well as to the methods employed is presented at the beginning of the work. In a subsequent part, we show that the peculiar magnetic response of metallic cuprates upon impurity doping can be successfully explained within a spin-liquid picture. The remainder of the work is devoted to the metallic state of manganites. Elaborating on the notion of an orbital liquid, the interplay of electron correlations, orbital degeneracy, and double exchange is studied. Thereby, the unconventionally large incoherent optical spectrum of metallic manganites and the pronounced softening of the magnon spectrum observed in experiment can be explained. Finally, a theory of the metal-insulator transition of manganites is presented which is based upon the newly introduced notion of orbital polarons. In general, we believe the close agreement of our results with experiment to strongly support the validity of our approach, giving new insight into the spectacular and sometimes as-tonishing physics of transition metal oxides.
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Elektronischer Transport in defektbehafteten quasi-eindimensionalen Systemen am Beispiel von KohlenstoffnanoröhrchenTeichert, Fabian 15 April 2014 (has links) (PDF)
Die vorliegende Arbeit beschäftigt sich mit den Transporteigenschaften defektbehafteter Kohlenstoffnanoröhrchen (CNTs). Als Beispiel werden dabei einfache und doppelte Fehlstellen betrachtet. Der Fokus liegt auf der Berechnung des Transmissionsspektrums und der Leitfähigkeit mit einem schnellen, linear skalierenden rekursiven Greenfunktions-Formalismus, mit dem große Systeme quantenmechanisch behandelt werden können. Als Grundlage wird ein dichtefunktionalbasiertes Tight-Binding-Modell verwendet. Der Einfluss der Defektdichte und des CNT-Durchmessers wird im Rahmen einer statistischen Analyse untersucht. Es wird gezeigt, dass im Grenzfall kleiner Transmission die Leitfähigkeit exponentiell mit der Defektanzahl skaliert. Das System befindet sich im Regime starker Lokalisierung, wobei die Lokalisierungslänge von der Defektdichte und dem CNT-Durchmesser abhängt.
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Dvourozměrný elektronový plyn v kvantových jamách CdTE: studie ve vysokých magnetických polích / High mobility two-dimensional electron gas in CdTe quantum wells:High magnetic field studiesKunc, Jan January 2011 (has links)
KurHigh mobility two-dimensional electron gas in CdTe quantum wells: High magnetic field studies Experimental studies of two-dimensional electron gases confined in CdTe and CdMnTe quantum wells are presented. The data analysis is supported by numerical calcula- tions of the band structure of confined states, using the local density and envelope func- tion approximations. Four by four, k.p calculations have been performed to justify the parabolic approximation of valence bands. Samples were characterized by Raman scatter- ing spectroscopy and far infrared cyclotron resonance absorption measurements. Low-field magneto-transport shows the dominant contribution of the semi-classical Drude conduc- tivity and three orders of magnitude weaker contributions of weak localization, electron- electron interaction and Shubnikov-de Haas oscillations. The contribution of electron- electron interactions is explained within a semi-classical model of circling electrons. The shape of Landau levels, broadening, transport and quantum lifetimes and dominant long- range scattering mechanism have been determined. High-field magneto-transport displays fractional quantum Hall states at Landau levels N = 0 and N = 1. The ground states 5/3 and 4/3 have been determined to be fully spin polarized, in agreement with the approach of composite...
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Propriétés de transport électronique des isolants topologiques / Electronic transport properties of topological insulatorsAdroguer, Pierre 15 February 2013 (has links)
Les travaux présentés dans cette thèse ont pour objectif d’apporter à la physique mésoscopique un éclairage concernant la compréhension des propriétés de transport électroniques d’une classe de matériaux récemment découverts : les isolants topologiques.La première partie de ce manuscrit est une introduction aux isolants topologiques, mettant en partie l’accent sur leurs spécificités par rapport aux isolants "triviaux" : des états de bords hélicaux (dans le cas de l’effet Hall quantique de spin en 2 dimensions) ou de surface relativistes (pour les isolants topologiques tridimensionnels) robustes vis-à-vis du désordre.La deuxième partie propose une sonde de l’hélicité des états de bords de l’effet Hall quantique de spin en étudiant les propriétés remarquables de l’injection de paires de Cooper dans cette phase topologique.La troisième partie étudie la diffusion des états de surface des isolants topologiques tridimensionnels dans le régime cohérent de phase. L’étude de la diffusion, de la correction quantique à la conductance (antilocalisation faible) et de l’amplitude des fluctuations universelles de conductance de fermions de Dirac sans masse est présentée. Cette étude est aussi menée dans la cas d’états de surface dont la surface de Fermi présente la déformation hexagonale observée expérimentalement. / The works presented in this thesis intend to contribute to condensed matter physics in the understanding of the electronic properties of a recently discovered class of materials : the topological insulators.The first part of this memoir is an introduction to topological insulators, focusing on their specifities compared to "trivial" insulators : helical edge states (in the two dimensional quantum spin Hall effect) or relativistic surface states (for three dimensional topological insulators) both robust agiant disorder.The second part proposes a new way to probe the unique properties of the helical edge states of quantum spin Hall effect via the injection of Cooper pair from a superconductor.The third part deals with the diffusion of the three dimensional topological insulator surface states, in the phase coherent regime. The diffusion, the quantum correction to conductivity, and the amplitude of the universal conductance fluctuations are studied. This study is also led in the experimentally relevant case where the Fermi surface presents a hexagonal deformation.
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Etude théorique de la transition de spin dans la molécule Fe(phen)2(NCS)2 adsorbée sur des surfaces métalliques / Theoretical study of the spin crossover in a single Fe(phen)2(NCS)2 molecule adsorbed onto metallic substratesGueddida, Saber 24 September 2014 (has links)
L’objectif principal de cette thèse est d’utiliser le calcul ab initio fondé sur la théorie de la densité fonctionnelle (DFT) pour calculer et comprendre la transition HS-BS de la molécule FePhen adsorbée sur un substrat métallique. Il s’agit d’abord de décrire les interactions entre FePhen et un substrat métallique ferromagnétique, comme le Co, ou un substrat paramagnétique comme l’or ou le cuivre. Nous avons calculé la barrière de potentiel nécessaire pour basculer la molécule de l’état BS à l’état HS en utilisant la méthode ’Nudged Elastic Band’ (NEB) et développé une méthode basée sur les principes de la méthode NEB, pour déterminer la trajectoire d’énergie minimale (TEM) de la molécule adsorbée sur un substrat métallique. Nous avons calculé le couplage ferromagnétique entre la molécule et le cobalt en fonction du nombre de couches intermédiaires de cuivre. Nous avons étudié en particulier (1) le rôle joué par les interactions van der Waals, (2) la modélisation de la microscopie à effet tunnel (STM) et (3) les propriétés de transport. Nous avons calculé les images STM en utilisant l’approximation de Tersoff et Hamann, qui montrent un bon accord avec les résultats expérimentaux. Nous vons étudié les propriétés de transport de la molécule FePhen adsorbée sur une surface métallique, en utilisant le code Smeagol basé sur la méthode des fonctions de Green hors-équilibre, et le formalisme de Landauer. / The main objective of this PhD thesis is to use ab initio methods based on DFT to calculate and understand the mechanism of spin crossover phenomena in FePhen molecule adsorbed on a metallic substrate. We studied the structural, electronic and magnetic properties of the free and adsorbed FePhen molecule on a ferromagnetic metal substrate, such as cobalt, or a paramagnetic substrate such as gold or copper. We calculated the energy barrier required for the molecule to switch from low-spin to high-spin states using the ’Nudged Elastic Band’ (NEB) method. We also computed the ferromagnetic coupling between two magnetic layers, the magnetic FePhen molecule and the cobalt substrate according to the number of non-magnetic intermediate layer of copper. The focus is mainly on (1) the role played by van der Waals interactions, (2) the modeling of scanning tunneling microscopy (STM) and (3) the transport properties. We calculated the STM images using the Tersoff-Hamann approximation, which showed a good agreement with recent experimental STM images. We studied the transport properties of the adsorbed molecule FePhen on a metallic surface, using the Smeagol code which is based on the non-equilibrium Green’s function and Landauer formalism.
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From cuprates to manganites: spin and orbital liquidsKilian, Rolf 26 July 1999 (has links)
Both cuprates and manganites belong to the transition metal oxides. The physics of these compounds is characterized by a dualism of local electron interaction and itinerant charge motion. In the present work, several key issues of metallic cuprates and manganites are addressed on a theoretical level, while close connection to recent experimental work is kept. The work is based on the notion of spin and orbital liquids, representing elegant tools to handle the strongly correlated nature of the metallic state in an efficient and transparent manner. A concise introduction to the physics of cuprates and manganites as well as to the methods employed is presented at the beginning of the work. In a subsequent part, we show that the peculiar magnetic response of metallic cuprates upon impurity doping can be successfully explained within a spin-liquid picture. The remainder of the work is devoted to the metallic state of manganites. Elaborating on the notion of an orbital liquid, the interplay of electron correlations, orbital degeneracy, and double exchange is studied. Thereby, the unconventionally large incoherent optical spectrum of metallic manganites and the pronounced softening of the magnon spectrum observed in experiment can be explained. Finally, a theory of the metal-insulator transition of manganites is presented which is based upon the newly introduced notion of orbital polarons. In general, we believe the close agreement of our results with experiment to strongly support the validity of our approach, giving new insight into the spectacular and sometimes as-tonishing physics of transition metal oxides.
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