High speed and/or high efficiency separations can be realized using small particles (~ 1 µm) in liquid chromatography (LC). However, due to the large pressure drop caused by small particles, conventional LC pumping systems cannot satisfy the pressure requirements needed to drive the mobile phase through the column. Use of ultrahigh pressure, elevated temperature, or both can overcome these pressure limitations and allow the use of very small particles for high speed and/or high efficiency separations. In this dissertation, the use of ultrahigh pressures with and without elevated temperatures in capillary LC is described. Very fast separations of various samples on silica-based stationary phases were achieved using optimized equipment and conditions. Great reduction in separation time, while maintaining high efficiency, is the most significant result of this work. Mechanically, chemically and thermally stable new packing materials were required for this research. Polybutadiene encapsulated nonporous zirconia particles, which are chemically and thermally more stable than silica, were evaluated for fast separations of pharmaceuticals and herbicides at temperatures and pressures as high as 100 °C and 30 kpsi, respectively. Safety is a concern when extremely high pressures are used in LC. Column rupture and system component failure can lead to the creation of high speed liquid jets and capillary projectiles. The use of a plexiglass shroud to cover the initial section of the installed capillary column can eliminate any safety-related concerns about these liquid jets or capillary projectiles. An ultrahigh pressure sample injector, with small dwell volume is critical for sample injection and gradient operation at high pressures. A novel injection assembly, composed of six small needle valves, withstood pressures as high as 30 kpsi. A new capillary connector was designed to hold the capillary by “two-point” holding forces under high pressures. With this new injector and capillary connector, gradient elution was easily achieved for the high resolution separation of a protein tryptic digest.

Active transient voltage compensator (ATVC) has been proposed to improve VR transient response at high slew rate load, which engages in transient periods operating in MHZ to inject high slew rate current in step up load and recovers energy in step down load. Main VR operates in low switching frequency mainly providing DC current. Parallel ATVC has largely reduced conduction and switching losses. Parallel ATVC also reduces the number of VR bulk capacitors. Combined linear and adaptive nonlinear control has been proposed to reduce delay times in the actual controller, which injects one nonlinear signal in transient periods and simplifies the linear controller design. Switching mode current compensator with nonlinear control in secondary side is proposed to eliminate the effect of opotocoupler, which reduces response times and simplifies the linear controller design in isolated DC-DC converters. A novel control method has been carried out in two-stage isolated DC-DC converter to simplify the control scheme and improve the transient response, allowing for high duty cycle operation and large step-down voltage ratio with high efficiency. A balancing winding network composed of small power rating components is used to mitigate the double pole-zero effect in complementary-controlled isolated DC-DC converter, which simplifies the linear control design and improves the transient response without delay time. A parallel post regulator (PPR) is proposed for wide range input isolated DC-DC converter with secondary side control, which provides small part of output power and most of them are handled by unregulated rectifier with high efficiency. PPR is easy to achieve ZVS in primary side both in wide range input and full load range due to 0.5 duty cycle. PPR has reduced conduction loss and reduced voltage rating in the secondary side due to high turn ratio transformer, resulting in up to 8 percent efficiency improvement in the prototype compared to conventional methods.

<p>The photovoltaics (PV) research community is currently pursuing many approaches to reduce the cost of PV and increase the energy conversion efficiency. Single-crystalline silicon (sc-Si) solar cells are able to achieve high efficiency but have a higher cost relative to other technologies. It may be possible to drastically reduce the cost of sc-Si PV by fabricating solar cells which are an order of magnitude thinner than conventional solar cells, i.e. thinner than 30 microns. Aside from new fabrication paradigms, ultra-thin sc-Si solar cells require advanced light-trapping techniques to enhance the absorption of long-wave radiation which is otherwise transmitted through the cell. In this thesis, a novel process flow for the fabrication of ultra-thin sc-Si solar cells in the laboratory was designed and implemented with the aim of testing light-trapping structures in the context of actual ultra-thin sc-Si devices. The process flow uses 10 micron thick sc-Si membranes, 0.95 cm in diameter, fabricated on silicon-on-insulator wafers using double-sided processing. The best fabricated device incorporated a back surface field, a white paint diffuse rear reflector and a silicon nitride antireflection coating. It achieved a fill factor, efficiency, short circuit current and open circuit voltage of 0.67, 9.9%, 27.9 mA cm^-2 and 0.53 V respectively. Simulations suggest the device efficiency can approach 15.4% without light-trapping and 16.5% with a diffuse rear reflector as a light trapping structure. This process flow is intended to be used as a platform on which to test further light-trapping structures with the continuation of this project.</p> / Master of Applied Science (MASc)

The demand for increased renewable energy production has led to increased photovoltaic (PV) installations worldwide. As this demand continues to grow, it is important that the costs of PV installations decrease while the power output capability increases. One of the components in PV installations that has lots of room for improvement is the power conditioning system. The power conditioning system is responsible for converting the power output of PV modules into power useable by the utility grid while insuring the PV array is outputting the maximum available power. Modular power conditioning systems, where each PV module has its own power converter, have been proven to yield higher output power due to their superior maximum power point tracking capabilities. However, this comes with the disadvantages of higher costs and lower power conversion efficiencies due to the increased number of power electronics converters. The primary objective of this dissertation is to develop a high-efficiency, low cost microconverter in an effort to increase the output power capability and decrease the cost of modular power conditioning systems. First, existing isolated dc-dc converter topologies are explored and a new topology is proposed based on the highly-efficient series resonant converter operating near the series resonant frequency. Two different hybrid modes of operation are introduced in order to add wide input-voltage regulation capability to the series resonant converter while achieving high efficiency through low circulating currents, zero-current switching (ZCS) of the output diodes, zero-voltage switching (ZVS) and/or ZCS of the primary side active switches, and direct power transfer from the source to the load for the majority of the switching cycle. Each operating mode is analyzed in detail using state-plane trajectory plots. A systematic design approach that is unique to the newly proposed converter is presented along with a detailed loss analysis and loss model. A 300-W microconverter prototype is designed to experimentally validate the analysis and loss model. The converter featured a 97.7% weighted California Energy Commission (CEC) efficiency with a nominal input voltage of 30 V. This is higher than any other reported CEC efficiency for PV microconverters in literature to date. Each operating mode of the proposed converter can be controlled using simple fixed-frequency pulse-width modulation (PWM) based techniques, which makes implementation of control straightforward. Simplified models of each operating mode are derived as well as control-to-input voltage transfer functions. A smooth transition method is then introduced using a two-carrier PWM modulator, which allows the converter to transition between operating modes quickly and smoothly. The performance of the voltage controllers and transition method were verified experimentally. To ensure the proposed converter is compatible with different types of modular power conditioning system architectures, system-level interaction issues associated with different modular applications are explored. The first issue is soft start, which is necessary when the converter is beginning operation with a large capacitive load. A novel soft start method is introduced that allows the converter to start up safely and quickly, even with a short-circuited output. Maximum power point tracking and double line frequency ripple rejection are also explored, both of which are very important to ensuring the PV module is outputting the maximum amount of available power. Lastly, this work deals with efficiency optimization of the proposed converter. It is possible to use magnetic integration so that the resonant inductor can be incorporated into the isolation transformer by way of the transformer leakage inductance in order to reduce parts count and associated costs. This chapter, however, analyzes the disadvantages to this technique, which are increased proximity effect losses resulting in higher conduction losses. A new prototype is designed and tested that utilizes an external resonant inductor and the CEC efficiency was increased from 97.7% to 98.0% with a marginal 1.8% total cost increase. Additionally, a variable frequency efficiency optimization algorithm is proposed which increases the system efficiency under the high-line and low-line input voltage conditions. This algorithm is used for efficiency optimization only and not control, so the previously presented simple fixed-frequency modeling and control techniques can still be utilized. / Ph. D.

Significant stray magnetic field exists around the coils when charging the electric vehicles (EVs) with inductive power transfer (IPT), owning to the large air gap between the transmitter and receiver. The methods for field attenuation usually introduce extra losses and reduce the efficiency. This study focuses on the synergetic attenuation of stray magnetic field which is optimized simultaneously with the efficiency. The optimization is realized with Pareto front. In this dissertation, three methods are discussed for the field attenuation. The first method is to tune the physical parameters of the winding, such as the inner radii, outer radii, distribution of the turns, and types of the litz wires. The second method is to add metal shields around the IPT coils, in which litz wires are used as shields to reduce the shielding losses. The third method is to control the phases of winding currents, which avoids increasing the size and weight of the IPT coils. To attenuate the stray magnetic field by tuning the physical parameters, the conventional method is to sweep all the physical parameters in finite-element simulation. This takes thousands of simulations to derive the Pareto front, and it's especially time-consuming for three-dimensional simulations. This dissertation demonstrates a faster method to derive the Pareto front. The windings are replaced by the lumped loops. As long as the number of turns for each loop is known, the efficiency and magnetic field are calculated directly from the permeance matrices and current-to-field matrices. The sweep of physical parameters in finite-element simulation is replaced by the sweep of the turns numbers for the lumped loops in calculation. Only tens of simulations are required in the entire procedure, which are used to derive the matrices. An exemplary set of coils was built and tested. The efficiency from the matrix calculation is the same as the experimental measurement. The difference for stray magnetic field is less than 12.5%. Metal shields attenuate the stray magnetic field effectively, but generates significant losses owning to the uneven distribution of shield currents. This dissertation uses litz wires to replace the conventional plate shield or ring shield. Skin effect is eliminated so the shield currents are uniformly distributed and the losses are reduced. The litz shields are categorized to two types: shorted litz shield and driven litz shield. Circuit models are derived to analyze their behaviors. The concept of lumped-loop model is applied to derive the Pareto front of efficiency versus stray magnetic field for the coils with litz shield. In an exemplary IPT system, coils without metal shield and with metal shields are optimized for the same efficiency. Both the simulation and experimental measurement verify that the shorted litz shield has the best performance. The stray magnetic field is attenuated by 65% compared to the coils without shield. This dissertation also introduces the method to attenuate the stray magnetic field by controlling the phases of winding currents. The magnetic field around the coils is decomposed to the component in the axial direction and the component in the radial direction. The axial component decreases with smaller phase difference between windings' currents, while the radial component exhibits the opposite property. Because the axial component is dominant around the IPT coils, decreasing the phase difference is preferred. The dual-side-controlled converter is applied for the circuit realization. Bridges with active switches are used for both the inverter on the transmitter side and the rectifier on the receiver side. The effectiveness of this method was verified both in simulation and experiment. Compared to the conventional series-series IPT with 90° phase difference between winding currents, stray magnetic field was attenuated by up to 30% and 40% when the phase differences of winding currents are 50° and 40°, respectively. Furthermore, an analytical method is investigated to calculate the proximity-effect resistance of the planar coils with ferrite plate. The objective of this method is to work together with the fast optimization which uses the lumped-loop model. The existence of the ferrite plate complicates the calculation of the magnetic field across each turn which is critical to derive the proximity-effect resistance. In this dissertation, the ferrite plate is replaced by the mirrored turns according to the method of image. The magnetic fields are then obtained from Ampere's Law and Biot-Savart Law. Up to 200 kHz, the difference of the proximity-effect resistance is less than 15% between calculation and measurement. / Ph. D. / Inductive power transfer for the battery charging of electric vehicles uses loosely coupled coils to replace the cables and plugs. The power is transferred from transmitter to receiver across tens of centimeters. Significant stray magnetic field exists around the coils owning to the large gap, which should be attenuated for the safety consideration of human beings. Three methods are discussed for the field attenuation. The first method is to tune the physical parameters of the winding, such as the inner radii, outer radii, distribution of the turns, and types of the litz wires. The second method is to add metal shields around the IPT coils, in which litz wires are used as shields to reduce the shielding losses. The third method is to control the phases of winding currents, which avoids the increase of the size and weight of the IPT coils. However, the field attenuation usually comes with reduced efficiency of the system. The work in this dissertation is focused on the synergetic attenuation of stray magnetic field in inductive power transfer for electric vehicles. The optimization is realized with Pareto front. The coils are optimized for low stray magnetic field and high efficiency simultaneously.

Fossil fuel consumption throughout the world is drawing attention to the need for alternative energy sources to provide for the large demand for energy. It is becoming more apparent everyday that fossil fuels are unreliable sources of energy due to the volatile pricing of such commodities as well as the toll that these energy sources take on the environment. Fossil fuels are non-renewable sources of energy that when burned to create energy produce bi-products that are extremely harmful to the global environment. Today, renewable energy sources such as wind and solar energy are playing larger roles as sources of electricity and are providing new jobs as well as research opportunities both in academia and in industry. It is for this reason that wind turbine energy harvesting is the topic of this thesis and how the efficiency of wind turbine power conversion systems can be improved to become a more viable source of energy. Large wind turbines, along with their power conversion electronics, exist today for the sole purpose of serving a large population of consumers with "green" electricity. Unfortunately, systems designed for low power wind turbines do not utilize advanced methods of maximizing energy draw from wind turbines both from hardware and software point of views. This theses is presents a method of efficient energy extraction and conversion from low power wind turbines to charge lead ac id batteries.

This thesis aims to bring an understanding to the silicon carbide (SiC) bipolar junction transistor (BJT). SiC power devices are superior to the silicon IGBT in several ways. They are for instance, able to operate with higher efficiency, at higher frequencies, and at higher junction temperatures. From a system point of view the SiC power device could decrease the cost and complexity of cooling, reduce the size and weight of the system, and enable the system to endure harsher environments. The three main SiC power device designs are discussed with a focus on the BJT. The SiC BJT is compared to the SiC junction field-effect transistor (JFET) and the metal-oxide semiconductor field-effect transistor (MOSFET). The potential of employing SiC power devices in applications, ranging from induction heating to high-voltage direct current (HVDC), is presented. The theory behind the state-of-the-art dual-source (2SRC) base driver that was presented by Rabkowski et al. a few years ago is described. This concept of proportional base drivers is introduced with a focus on the discretized proportional base drivers (DPBD). By implementing the DPBD concept and building a prototype it is shown that the steady-state consumption of the base driver can be reduced considerably.  The aspects of the reverse conduction of the SiC BJT are presented. It is shown to be of importance to consider the reduced voltage drop over the base-emitter junction. Last the impact of SiC unipolar and bipolar devices in series-resonant (SLR) converters is presented. Two full-bridges are designed and constructed, one with SiC MOSFETs utilizing the body diode for reverse conduction during the dead-time, and the second with SiC BJTs with anti-parallel SiC Schottky diodes. It is found that the SiC power devices, with their absence of tail current, are ideal devices to fully utilize the soft-switching properties that the SLR converters offer. The SiC MOSFET benefits from its possibility to utilize reverse conduction with a low voltage drop. It is also found that the size of capacitance of the snubbers can be reduced compare to state-of-the-art silicon technology. High switching frequencies of 200 kHz are possible while still keeping the losses low. A dead-time control strategy for each device is presented. The dual control (DuC) algorithm is tested with the SiC devices and compared to frequency modulation (FM). The analytical investigations presented in this thesis are confirmed by experimental results on several laboratory prototype converters. / <p>QC 20150529</p>

Micro Combined Heat and Power systems or microCHP systems generate heat and electricity for a home. Stirling engines are widely used as prime movers in microCHP applications. Stirling engine is an external combustion engine having an enclosed working fluid (as helium) that is alternately compressed and expanded to operate a piston. The displacer shuttles the working fluid between the hot and cold ends. The piston is coupled to a transmission and to an electrical machine to generate power. Conventional Stirling engines are not controllable to a great degree. The piston and displacer are connected to the same crank and they maintain the same phase difference throughout the cycle. Also the piston and displacer are normally constructed to move in a sinusoidal fashion. The Active Stirling Engine is a new concept introduced in this thesis which has a free displacer. The displacer is driven separately compared to a coupled drive in conventional Stirling engines. The displacer motion can be non-linear with dwell at each ends of the stroke, opening up the possibilities to increase the pressure volume diagram which indicates the work done by the engine. A separately driven displacer also allows introducing phase control and stroke control to improve the controllability of a Stirling engine. This thesis examines the effect of non-linear displacer motion and phase control of the displacer on Stirling engine performance. Simulations are performed in Sage, the leading Stirling engine simulation software, to understand the effect of displacer phase control. A test rig is constructed with the actively controlled displacer connected to a linear machine controlled by a programmable servo. Heat is applied to the test rig though an electric heating coil. The test rig is charged with nitrogen at 20Bar pressure. The power piston is connected to a rotating electrical machine via the transmission. The rotating electrical machine is used to start the engine and to act as the generator. The test rig is instrumented to determine the linear position of the displacer and piston, angular position of the rotating electrical machine shaft, temperatures, pressures and flow. A LabVIEW™ based data acquisition system is set up to capture data from the test rig. Data is collected at various test cases. The simulation result is compared against post processed data. An efficiency improvement of 15% is achieved using this method and is demonstrated experimentally. Applications in micro combined heat and power systems utilising the improved efficiency due to non linear motion and controllability due to phase control are explored in this thesis.

Wide-bandgap (WBG) semiconductor materials such as silicon carbide (SiC) and gallium-nitride (GaN) allow higher voltage ratings, lower on-state voltage drops, higher switching frequencies, and higher maximum temperatures. All these advantages make them an attractive choice when high-power density and high-efficiency converters are targeted. Two different gate-driver designs for SiC power devices are presented. First, a dual-function gate-driver for a power module populated with SiC junction field-effect transistors that finds a trade-off between fast switching speeds and a low oscillative performance has been presented and experimentally verified. Second, a gate-driver for SiC metal-oxide semiconductor field-effect transistors with a short-circuit protection scheme that is able to protect the converter against short-circuit conditions without compromising the switching performance during normal operation is presented and experimentally validated. The benefits and issues of using parallel-connection as the design strategy for high-efficiency and high-power converters have been presented. In order to evaluate parallel connection, a 312 kVA three-phase SiC inverter with an efficiency of 99.3 % has been designed, built, and experimentally verified. If parallel connection is chosen as design direction, an undesired trade-off between reliability and efficiency is introduced. A reliability analysis has been performed, which has shown that the gate-source voltage stress determines the reliability of the entire system. Decreasing the positive gate-source voltage could increase the reliability without significantly affecting the efficiency. If high-temperature applications are considered, relatively little attention has been paid to passive components for harsh environments. This thesis also addresses high-temperature operation. The high-temperature performance of two different designs of inductors have been tested up to 600_C. Finally, a GaN power field-effect transistor was characterized down to cryogenic temperatures. An 85 % reduction of the on-state resistance was measured at −195_C. Finally, an experimental evaluation of a 1 kW singlephase inverter at low temperatures was performed. A 33 % reduction in losses compared to room temperature was achieved at rated power. / <p>QC 20160922</p>

Depuis trois décennies, la tendance du marché répond à la demande actuelle de miniaturisation et d'augmentation de performances des appareils multimédias. Or, toute réduction des dimensions d'un facteur donné impose une diminution des tensions (pour des raisons de fiabilité). Afin d'y répondre, la réduction de taille des circuits intégrés CMOS atteint des échelles d'intégration submicroniques entrainant une baisse importante de la fiabilité des composants et en particulier des transistors. La création de porteurs chauds, ainsi que la dissipation thermique à l'intérieur des circuits submicroniques, sont les deux phénomènes physiques principaux à l'origine de la baisse de fiabilité. La solution technique permettant de garder un bon degré de fiabilité, tout en réduisant la taille des composants, consiste à réduire la tension d'alimentation des circuits. Parallèlement aux contraintes de performances, les normes environnementales demandent une consommation la plus réduite possible. La difficulté consiste alors en la réalisation de circuits associant une alimentation basse puissance (tension et courant) d'où la notion de circuits " Low Power ". Ces circuits sont pour certains déjà utilisés dans le domaine du multimédia, du médical, avec des contraintes d'intégration différentes (possibilité de composants externes, stabilité, etc.). L'augmentation des performances en vitesse des circuits digitaux nécessite par ailleurs l'utilisation de technologies générant des fuites de plus en plus importantes qui sont incompatibles avec une réduction de la consommation dans des modes de veille sans la mise en place de nouvelles techniques / For three decades, the market trend answers the current demand of miniaturization and performance increase of the multimedia devices. Yet, any reduction of the dimensions of a given factor imposes a decrease of the tensions (for reasons of reliability). To answer this question, the downsizing of CMOS integrated circuits reaches submicron scales of integration resulting in a significant decrease in the reliability of components and in particular transistors. The hot carriers creations, as well as heat dissipation within the submicron circuits, are the two main physical phenomena behind the reliability decline. The technical solution to maintain a good degree of reliability, while reducing component size, is to reduce the supply voltage of circuits. In parallel to performance constraints, environmental standards require consumption as small as possible. The challenge is then to build circuits combining low power supply (voltage and current) where the concept of circuits "Low Power". These circuits are used for some already in the field of multimedia, medical, integration with various constraints (possibility of external components, stability, etc..). The speed increase performance of digital circuits also requires the use of technologies that generate leaks increasingly important that are inconsistent with consumption reduction in standby modes without the introduction of new techniques.