Le monde biologique est rempli de mystères. La compréhension de nombreux processus biologiques extrêmement complexes est grandement améliorée par la combinaison d’approches empruntées à différentes disciplines telles que la chimie et plus récemment la physique. La physique utilise des outils expérimentaux tels que les pinces optiques et les microscopies optique et électronique pour explorer les mécanismes à l’échelle microscopique se déroulant dans la cellule. La connaissance de la nature des interactions entre biomolécules et la possibilité de traduire ces interactions en équations ont permis à la physique de construire des modèles simples mais contenant les ingrédients suffisants à la description d’un mécanisme spécifique. La simulation numérique de tels modèles permet d’améliorer notre compréhension de la relation entre les mécanismes pertinents à l’échelle moléculaire et les observations expérimentales de phénomènes biologiques. / The biological world is full of mysteries. The understanding of many extremely complex biological processes is greatly improved by the combination of approaches borrowed from different disciplines such as chemistry and more recently physics. Physics uses experimental tools such as optical tweezers and optical and electron microscopes to explore the microscopic mechanisms taking place in the cell. Knowledge of the nature of the interactions between biomolecules and the possibility of translating these interactions into equations allowed physics to construct models that are simple, but contain the ingredients sufficient to describe a specific mechanism. The numerical simulation of such models improves our understanding of the relationship between relevant molecular-scale mechanisms and experimental observations of biological phenomena. The structural organization of biomolecular complexes is a process that involves various scales of length and time.

<p>In recent years portable electronic devices, such as mobile phones and personal digital assistants, have increased the demand for high performance displays with low power consumption. An interesting candidate with the potential of fulfilling these demands is the reflective single-polarizer surface controlled bistable twisted nematic liquid crystal display. The main focus of this work involves the optical properties of displays based on these bistable structures. In the investigations, the display is considered as an integrated optical system, containing not only the liquid crystal cell, but also components such as polarizers and retardation films. The specific aim of the thesis was to derive new optical modes of the reflective single-polarizer bistable twisted nematic device using the Jones matrix method to study the interaction between the polarization of light and the optically anisotropic media. The electro-optical properties of the derived modes have been studied and evaluated both theoretically and experimentally. The modes possess excellent brightness and high contrast ratio. By introducing a quarter-wave retardation film into the optical configuration, the contrast ratio can be significantly increased by preventing spectral leakage of light in the dark state. To experimentally realize the derived optical modes, special layers for the alignment of the liquid crystal molecules on the cell substrate surface have been proved needed. Therefore, also the photo-alignment technology of nematic liquid crystals on novel alignment materials has been studied with the aim to control liquid crystal cell parameters such as pretilt angle and anchoring energy, both critical for the bistable switching. The results of this thesis will increase the understanding of the optical properties of the reflective single-polarizer bistable twisted nematic liquid crystal display and will be valuable when considering this type of device for practical applications.</p>

In recent years portable electronic devices, such as mobile phones and personal digital assistants, have increased the demand for high performance displays with low power consumption. An interesting candidate with the potential of fulfilling these demands is the reflective single-polarizer surface controlled bistable twisted nematic liquid crystal display. The main focus of this work involves the optical properties of displays based on these bistable structures. In the investigations, the display is considered as an integrated optical system, containing not only the liquid crystal cell, but also components such as polarizers and retardation films. The specific aim of the thesis was to derive new optical modes of the reflective single-polarizer bistable twisted nematic device using the Jones matrix method to study the interaction between the polarization of light and the optically anisotropic media. The electro-optical properties of the derived modes have been studied and evaluated both theoretically and experimentally. The modes possess excellent brightness and high contrast ratio. By introducing a quarter-wave retardation film into the optical configuration, the contrast ratio can be significantly increased by preventing spectral leakage of light in the dark state. To experimentally realize the derived optical modes, special layers for the alignment of the liquid crystal molecules on the cell substrate surface have been proved needed. Therefore, also the photo-alignment technology of nematic liquid crystals on novel alignment materials has been studied with the aim to control liquid crystal cell parameters such as pretilt angle and anchoring energy, both critical for the bistable switching. The results of this thesis will increase the understanding of the optical properties of the reflective single-polarizer bistable twisted nematic liquid crystal display and will be valuable when considering this type of device for practical applications.

This dissertation is focused on theoretical and experimental studies of optical properties of materials and multilayer structures composing liquid crystal displays (LCDs) and electrochromic (EC) devices. By applying spectroscopic ellipsometry, we have determined the optical constants of thin films of electrochromic tungsten oxide (WOx) and nickel oxide (NiOy), the films’ thickness and roughness. These films, which were obtained at spattering conditions possess high transmittance that is important for achieving good visibility and high contrast in an EC device. Another application of the general spectroscopic ellipsometry relates to the study of a photo-alignment layer of a mixture of azo-dyes SD-1 and SDA-2. We have found the optical constants of this mixture before and after illuminating it by polarized UV light. The results obtained confirm the diffusion model to explain the formation of the photo-induced order in azo-dye films. We have developed new techniques for fast characterization of twisted nematic LC cells in transmissive and reflective modes. Our techniques are based on the characteristics functions that we have introduced for determination of parameters of non-uniform birefringent media. These characteristic functions are found by simple procedures and can be utilised for simultaneous determination of retardation, its wavelength dispersion, and twist angle, as well as for solving associated optimization problems. Cholesteric LCD that possesses some unique properties, such as bistability and good selective scattering, however, has a disadvantage – relatively high driving voltage (tens of volts). The way we propose to reduce the driving voltage consists of applying a stack of thin (~1µm) LC layers. We have studied the ability of a layer of a surface stabilized ferroelectric liquid crystal coupled with several retardation plates for birefringent color generation. We have demonstrated that in order to accomplish good color characteristics and high brightness of the display, one or two retardation plates are sufficient.

The investigation of liquid crystal polymer (LCP) technology to function as a low-cost next-generation organic platform for designs up to millimeter-wave frequencies has been performed. Prior to this research, the electrical performance of LCP had been characterized only with the implementation of standard transmission lines and resonators. In this research, a wide variety of passive functions have been developed on LCP technology and characterized for the first time. Specifically, we present the development of patch antenna arrays for remote sensing applications, the performance of compact low-pass and band-pass filters up to millimeter-wave frequencies, and the integration of passive elements for X-band and V-band transceiver systems. First, dual-frequency/dual-polarization antenna arrays have been developed on multilayer LCP technology and have been integrated with micro-electro-mechanical-system (MEMS) switches to achieve real-time polarization reconfigurability. These arrays are conformal, efficient and have all the features desirable for applications that require space deployment. Second, a wide variety of filters with different physical and functional characteristics have been implemented on both single and multilayer LCP technology. These filters can be classified based on the filter type (low-pass/band-pass), the resonators used (single-mode/dual-mode), the response characteristics (symmetric/asymmetric), and the structure of the filter (modular/non-modular). Last, examples of integrated modules for use in transceiver systems are presented. This part of the research involves the development of duplexers, radiating elements, as well as their integration. The duplexers themselves are realized by integrating a set of band-pass filters and matching networks. The characterization of the individual components, and of the integrated system are included. This research has resulted in a thorough understanding of LCP's electrical performance and its multilayer lamination capabilities pertaining to its functioning as a material platform for integrated microwave systems. Novel passive prototypes that can take advantage of such multilayer capabilities have been developed.

Abstract With the critical development trend of industry of the world, TFT-LCD industry, following the footstep of semi-conductive industry, has become an important leading industry of Taiwan to the economic policy of the Government. The ¡§Two Trillion Double Star¡¨plan pro- -moted by Industrial Development Bureau fo Taiwan intends to push up the production values of the two industries, semi-conductive and flat panel photonic displayer, to exceed NT$ 1 trillion respectively in 2006. This plan also promotes digital contents and biotechnical industry to be two star industries with high potentials of development. Therefore, TFT- LCD industry is undoubtedly the core industry of the next wave of econo- mic growth in Taiwan. According to the distinguishing characteristics of capital and technology density, short-lived productive cycle, and variable productive technique in TFT-LCD industry, cash flow out of investment activities became the key point to promote the competitiveness with the continuously overcharge in the next generation panel field.In addition, the investors would find that the TFT-LCD panel factories have no ability to support the cash flow out which invested in equipment if they do not ask for finance. In this paper, we attempt to investigate the relationship between variation of cash flow in operation, investment, and finance activities and potential risk of operation in enterprise by financial statement in TFT-LCD industry. In addition, this dissertation commence with ROE and development from Du-Pont Formula. Our research decomposes ROE to fundamental elements in enterprise step by step, such as the construction of cost and expense and the risk of business. Furthermore, we afford a referable approach to estimate performance of companies by Du-Pont Formula. Key Words¡G Thin Film Transistor (TFT), Liquid Crystal Display (LCD),Cash Flow, Risk, Risk Management, Du Pont Equation, Du Pont Ratio.

LCD panel industry is one of the most promising industries in the world. Taiwanese LCD panel makers have performed quite well in the past few years. On the controversy, the BLU has been viewed as a low entry barrier industry with many suppliers and its profit margin seems to have been squeezed due mainly to its position between big giant LCD panel makers and limited key materials suppliers. However, BLU is one of Taiwan's few competitive industries in the global market because of its high self-sufficient rate and leading technologies over their Korean and Japanese competitors. Sometimes, Taiwan¡¦s BLU industry is even performing better than other component industries within the LCD industry supply chain. It's worth examining the competitive advantages for Taiwan BLU industry by analyzing "Company R", one of the leaders in Taiwan BLU industry. We start our research by highlighting the key characteristics of the LCD industry and the dynamics of the BLU supply chain. After analyzing the marketing, technology, and management requirements for the BLU industry, we have concluded the key success factors of the BLU industry. Then with a brief introduction of ¡§Company R¡¨, we have identified the company's competitive advantages and potential long-term strategies by analyzing the company¡¦s unique positioning and resources, and comparing those with the above-mentioned key success factors of the BLU industry. According to our study, demand for BLU should continue to grow with increasing demand for LCD TVs, in longer term. The major issue for LCD panel industry will be "demand and supply" relationship, while for BLU industry is the "volume" and its "competitive advantages" for each company. The technology development for BLU will continue. BLU is not just a so-called ¡§assembling business¡¨, and its industry entry barrier is much higher than before. Besides, the cluster effect and vertical integration are inevitable for LCD panel makers. To be successful in BLU industry, a company not only needs to focus on these key success factors, but also needs to keep developing and improving its core competencies relative to its competitors.

A tunable snapshot imaging spectrometer has been demonstrated. A liquid crystal spatial light modulator (LC SLM) has been integrated into a computed tomographic imaging spectrometer (CTIS) to achieve tunability. The LC SLM allows for rapid, programmable, and non-mechanical alteration of its phase profile by the application of appropriate voltages to its transparent electrodes.The goal of this dissertation is twofold: (1) to integrate a liquid crystal spatial light modulator into a CTIS instrument and characterize its performance as a tunable CTIS disperser, and (2) to implement tunability by analyzing different CTIS configurations.The theoretical model of CTIS operation, calibration, reconstruction, and disperser design are covered in detail. The cross talk of the LC SLM forces the use of a feedback design algorithm rather than designing the desired phase profile a priori in the computer. The modifications to the current polychromatic linear inversion technique for use with the LC SLM in feedback are presented. The result of the modifications is the successful integration of a reprogrammable (i.e. tunable) disperser for the CTIS instrument.The implementation of tunability is explored by analyzing the spectral resolution of a reconstructed point source for different disperser configurations. A method for experimentally determining the CTIS spectral resolution is presented.

The present work introduces a new method that is used to explore the connection between molecular order and molecular dynamics in liquid crystals. In liquid crystals, the building blocks show a liquid like disorder in at least one dimension of space with an otherwise crystalline like positional or orientational long range order. A new microscope is introduced that combines polarization measurements with the ability to track single fluorescent probe molecules in a thin sample of ordered liquid crystal. A new method for the analysis of orientation dependent diffusion is also introduced. It can be used to spatially resolve the anisotropic diffusion of the probe molecules. With this setup, molecular structure and molecular dynamics can be directly compared on a μm scale. Three different kinds of liquid crystal samples are analyzed with the new experimental method. First, twisted nematic liquid crystal cells are used to verify a proposed model for the connection between molecular structure and the dynamics in twisted nematic cells. Second, the liquid crystal structure and probe mobility are analyzed in homogeneous samples in a temperature regulated environment. The third experiment focuses on the combination of both of these scenarios. Different domains in a heterogeneous section of a sample are analyzed with different methodical approaches at various temperatures. The results display the close connection between molecular order and molecular dynamics in the samples. It is also found that the probe molecules introduce local distortions in the director field of the host material. Despite this realization, only the absolute value of the probes mobility seems to be effected. The anisotropy of the translational diffusion of the probe molecules resembles the results found in the literature on the self-diffusion of the liquid crystal molecules. The anisotropy also follows the same temperature dependence as the order of the host molecules. Using these results and the new method of analyzing single molecule tracking data, it is shown that the structure of a heterogeneous sample can be spatially resolved, only by means of single probe molecule tracking.

[pt] O presente estudo investiga a estrutura e a potencial aplicação de nanopartículas formadas por copolímeros que possuem um bloco neutro e outro bloco aniônico combinados a um surfactante catiônico. Em água, os blocos aniônicos se complexam eletrostaticamente às micelas de surfactante, interconectando-as e formando um núcleo concentrado, que pode até apresentar estrutura líquido-cristalina. Os blocos neutros são hidrofílicos e por isso formam uma casca que estabiliza as nanopartículas em água. Devido à formação do núcleo concentrado de micelas, espera-se que estas nanopartículas sejam capazes de incorporar uma maior quantidade de moléculas hidrofóbicas em comparação a micelas de surfactante puro na mesma concentração. Os resultados indicam que quanto mais longo é o bloco aniônico, mais alta é a incorporação das moléculas hidrofóbicas. Por outro lado, o bloco neutro tem um papel importante para aumentar a estabilidade das nanopartículas em meio aquoso. A incorporação de moléculas hidrofóbicas no núcleo das nanopartículas causa alterações na organização das micelas, levando à formação de diferentes estruturas líquido-cristalinas ou a alterações nas distâncias de correlação. Com base nas propriedades das nanopartículas, foi proposta uma formulação aquosa capaz de incorporar uma quantidade significativa de um filtro solar orgânico. Com os resultados obtidos para esta formulação, foi possível demonstrar sua eficácia em evitar a degradação de cabelos por irradiação ultravioleta, o que torna este sistema um candidato de alto potencial para aplicação na indústria de cosméticos. / [en] The present study investigates the structure and potential application of core-shell nanoparticles formed by block copolymers (consisted of an anionic and a neutral blocks) and a cationic surfactant. In water, the anionic blocks electrostatically complex to the surfactant micelles, interconnecting them and forming a concentrated nucleus, which may form even liquid-crystalline structures. Because the neutral blocks are hydrophilic, they form a shell which stabilizes the nanoparticles in water. The concentrated nuclei of micelles are expected to uptake a higher amount of hydrophobic molecules than the regular micelles of pure surfactant in the same concentration. The longer is the anionic block forming the nucleus, the higher is the uptake of hydrophobic substances. On the other hand, the neutral block plays a key role to increase nanoparticle stability in aqueous medium. The uptake of hydrophobic molecules increased the ordering of the micelles in the nucleus, leading either to the formation of different liquid-crystalline structures or to variations in the correlation distances. Taking these results in to account, we proposed an aqueous formulation with a considerable uptake capacity of an organic sunscreen. The results obtained for this formulation demonstrate its efficacy to avoid hair degradation by ultraviolet radiation exposition, which make this system a potential candidate for applications in the cosmetic industry.