A Baía da Guanabara vem sofrendo alterações na sua bacia de drenagem desde o início do século XIX que resultaram em acentuada degradação ambiental. O presente trabalho discute a influência da implantação de um Terminal Aquaviário de Gás Natural Liquefeito (GNL) na Baía, e suas possíveis influências nos processos de sedimentação local e/ou re-disponibilização de sedimentos de fundo, e possíveis contaminantes associados. Os resultados dos modelos matemáticos mostram que as maiores velocidades das plumas termicas que atingem o fundo são em média 0,46 m3/s para as simulações de verão e 0,47 m3/s para as simulações de inverno, sendo que são necessários pelo menos de 0,50 m3/s para uma corrente erodir o fundo, porem velocidades na faixa de 20 a 50 m3/s são suficientes para causar erosão de sedimentos finos inconsolidados. Sendo assim, a influência das plumas térmicas geradas no processo de re-gaseificação do GNL é de pequena magnitude, e suas correntes só conseguem exportar estes sedimentos para distancias inferiores a 1000 m. Em relação a re-disponibilização de contaminantes associados aos sedimentos de fundo se mostrou pouco provável, dado o fato da qualidade dos sedimentos apresentarem, diferente da água, baixa concentração de contaminantes e da baixa competência de erosão, que eles tenham competência para erodir sedimentos consolidados. / Since the beginning of the XIX century, interventions on the Guanabara\'s Bay drainage basin result in severe environmental degradation. This work aimed to analyze the implementation of an Aquaviary Terminal of Liquefied Natural Gas (LNG), and its putative consequences on the local sedimentation processes, and the availability and possible associated contaminants of the bottom sediments. According to the mathematical models developed, the means of the greatest speeds of the thermal plumes that reach the bottom are 0.46m3/s for the summer simulations and 0.47m3/s for the winter. However, for a current to be able to erode the bottom it must be of at least 50m3/s. Currents with speeds ranging from 20 to 50m3/s are sufficient only to cause the erosion of fine and non-consolidated sediment. Therefore, the thermal plumes generated in the process of re-gasification of the LNG are of little magnitude, and will not be able to export these sediments to any distance greater than 1000 meters. The re-availability of the contaminants associated with the bottom sediments is not likely, once these sediments, differently from the water, showed little concentration of contaminants. In addition, with the low erosion capacity of the currents generated, the consolidated sediments are not likely to be eroded.

The results of this study show that novel mesoporous carbons were obtained as inverse replica of SBA-15, HMS and MCM-41 silica templates, with a large pore diameter (2-4 nm), a BET surface area of 1867, 874 and 910 m2g –1 respectively for CA_SBA-15_LPG_105, CA_HMS_LPG_80 and CA_MCM- 41_LPG_80 with bimodal pore size distribution (PSD) in the mesopores range. The results obtained show that mesoporous carbon with graphitic structures can be synthesized via the LPG route.

Current gas sensor technology, although meeting the minimum requirements in many instances, suffers for a number of limitations. Hence, there is currently a considerable volume of research being undertaken at many laboratories of different countries. In the past, all chemical sensors and catalyst were optimized empirically by a trial and error method. Today, however, systematic research and development is becoming increasingly important in order to improve sensors and to find new sensing principles. Obtaining a long term stable gas sensor with improved sensitivity, selectivity, and low cost for mass production passes through fundamental research and material characterization to build new chemically sensitive devices or to improve existing ones. The bottom line in the design and manufacture of modern gas sensors is the transfer from ceramic(of Figaro type) to thin film gas sensors(TFGs). This transfer provides new opportunities for further microminiaturization, power consumption and cost reduction of gas sensors. Therefore, at the present time, thin film gas sensors are the basis for the design of the modern gas sensitive multi-parameter microsensor systems. Applications of these systems include environment, security, home systems, smart buildings, transportation, discrete manufacturing, process industries and so on. Microelectromechanical systems(MEMS) based integrated gas sensors present several advantages for these applications such as ease of array fabrication, small size, and unique thermal manipulation capabilities. MEMS based gas sensors; which are usually produced using a standard CMOS(Complimentary Metal Oxide Semiconductor) process, have the additional advantages of being readily realized by commercial foundries and amenable to the inclusion of on-chip electronics. In order to speed up the design and optimization of such integrated sensors, microheater designs for gas sensor applications have been presented as first part of the present thesis. As heater design is the key part for a gas sensor operation. So 3D simulations have been used to optimize micro-heater geometry. The application of MEMS Design Tool(COVENTORWARE) has been presented to the design and analysis of micro-hotplate (MHP) structures. Coupled Electro-thermal analysis provided an estimation of thermal losses and temperature distribution on the hotplate for realistic geometrical and material parameters pertinent to fabrication technology. Five microheater designs have been proposed in terms of different sizes and shapes in order to optimize the microhotplate structure to be used for gas sensor operation for the specified range of temperature and power consumption. To produce a gas sensor, which is able to detect LPG leak, thin films of tin oxide have been developed. FR sputtering has been used to deposit gas sensitive tin oxide thin filmls under various deposition conditions. Four different values of pressure in the range from high pressure(5 X 10-2 mbar) to lower pressure (2 X 10-3 mbar), three RF power values 50, 75, 100 W and varied oxygen percentage in sputtering atmosphere (0-18%) have been used to optimize the material properties of tin oxide thin films to study the sensitivity towards LPG. All the samples have been analyzed using various macro and microscopic characterization techniques. Extensive studies have been done on the sensor response for the samples deposited under different conditions. Finally the sample film deposited at 5 x 10-3 mbar, with applied power of 75 W in the presence of 8% oxygen, showed maximum sensitivity towards LPG.

The results of this study show that novel mesoporous carbons were obtained as inverse replica of SBA-15, HMS and MCM-41 silica templates, with a large pore diameter (2-4 nm), a BET surface area of 1867, 874 and 910 m2g –1 respectively for CA_SBA-15_LPG_105, CA_HMS_LPG_80 and CA_MCM- 41_LPG_80 with bimodal pore size distribution (PSD) in the mesopores range. The results obtained show that mesoporous carbon with graphitic structures can be synthesized via the LPG route.

To determine whether a weapon system meets the requirements set for insensitivity, the system is getting exposed for special tests. One of these tests shows how the system reacts when it ends up in a fire. This test is called the "Fast Cook-Off (FCO) Test", called FCO-test, and performed with a Sand Bed Burner (SBB). According to primary testing provision, the fuel for this test is used of jet fuel such as Jet A-1. A project at Bofors Test Center (BTC) is in progress to use an alternative fuel of Liquefied Petroleum Gas (LPG). This fuel is very advantageous compared to jet fuel in terms of environmental impact, work environment and testing costs. The aim of this thesis is to improve the existing test equipment considering fire over the entire surface and solve the problems with dropped gas flow and freezing of gas bottles. SBB works in the sense that the new petrol LPG streams into the SBB and expands in the free space below the sand bed before the gas will diffuse through the bed of sand and the fire engulfs the object. LPG is a condensable gas that requires oxygen. LPG exceed from liquid to gas phase and needs a large lateral surface to take up more energy which results in better evaporationto the phase transfer. Reaction products from complete combustion of LPG are only water vapor and carbon dioxide, the same as in your exhaled air. To solve these problems it was needed to change P11 composite bottles to P45 steel bottles to get a longer evaporation and larger lateral surface. Four flow inlets instead were used of one into SBB for a better stream in the free space under the sand bed. Propane regulators used to get a lower and more constant flow to avoid freezing. Compressed airconnected tothe SBB to geta mix between oxygen and LPG. The result shows in higherheat radiation efficiency even though the flow was settled down to 1/3 with the new propane regulators. In test 2 the value was 37 kW/m2 and in test 7 it was around 57 kW/m2. Because of a smaller flow and bigger steel bottles the freezing disappeared. Smaller grain of sand together with four inlets and compressed air gave a more complete combustion.

Carbon dioxide sequestration is one of many mitigation tools available to help reduce carbon dioxide emissions while other disposal/repurposing methods are being investigated. Geologic sequestration is the most stable option for long-term storage of carbon dioxide (CO2), with significant CO2 trapping occurring through mineralization within the first 20-50 years. A fiber optic based monitoring system has been proposed to provide real time concentrations of CO2 at various points throughout the geologic formation. The proposed sensor is sensitive to the refractive index (RI) of substances in direct contact with the sensing component. As RI is a measurement of light propagating through a bulk medium relative to light propagating through a vacuum, the extraction of the effects of any specific component of that medium to the RI remains very difficult. Therefore, a requirement for a selective barrier to be able to prevent confounding substances from being in contact with the sensor and specifically isolate CO2 is necessary. As such a method to evaluate the performance of the selective element of the sensor was investigated. Polybenzimidazole (PBI) and VTEC polyimide (PI) 1388 are high performance polymers with good selectivity for CO2 used in high temperature gas separations. These polymers were spin coated onto a glass substrate and cured to form ultra-thin (>10 μm) membranes for gas separation. At a range of pressures (0.14 –0.41 MPa) and a set temperature of 24.2±0.8 °C, intrinsic permeabilities to CO2 and nitrogen (N2) were investigated as they are the gases of highest prevalence in underground aquifers. Preliminary RI testing for proof of concept has yielded promising results when the sensor is exposed exclusively to CO2 or N2. However, the use of both PBI and VTEC PI in these trials resulted in CO2 selectivities of 0.72 to 0.87 and 0.33 to 0.63 respectively, for corresponding feed pressures of 0.14 to 0.41 MPa. This indicates that both of the polymers are more selective for N2 and should not be used in CO2 sensing applications as confounding gas permeants, specifically N2, will interfere with the sensing element. / Graduate / 0428 / 0495 / 0542 / ben.t.davies@gmail.com

Made available in DSpace on 2009-11-18T19:01:01Z (GMT). No. of bitstreams: 0 Previous issue date: 2004 / A indústria brasileira de gás liquefeito de petróleo, GLP, tem sido alvo freqüente, nos últimos anos, da atenção de órgãos reguladores, mídia e público em geral. Muitas têm sido as especulações a respeito de seu padrão de conduta publicados na imprensa, variando desde práticas predatórias até a formação disciplinada de cartel. A presente pesquisa, baseada em depoimentos de executivos da indústria e no acesso a dados das firmas dessa indústria tomado públicos - dados financeiros e operacionais - explora qual seja, afinal, o padrão de competição desse oligopólio. O estudo parte da Teoria da Estrutura de Capital aplicada para decisões de competição e mercado - preços e quantidades a ofertar para constatar que, dadas suas escolhas de estrutura de capital, as firmas esta indústria específica simplesmente adotam um padrão tradicional de arrefecimento da competição a partir de sua dívida. A dívida, nesta indústria, é utilizada para a criação de barreiras de entrada. Ainda assim, casos de acirramento da competição e de concentração de mercado foram encontrados, indicando que não haja uma disciplina formal de conduta por parte de suas firmas as quais devem, eventualmente, encontrar dificuldades - ou falta de interesse - na convivência em um mercado em fase de transformação. / The Brazilian industry of liquefied petroleum gas, LPG, has been calling, in the late years, the attention of the media, regulatory agencies and the general publico Many speculations have emerged, in the press, over its pattems of behaviour, which have been ranging from predatory practices up to a formal cartel operating under collusion. The present research, based in statements from industry executives as well as in data publicly disclosed by those firms - financiaI and operational ones - explores what their competitive behaviour would be, after alI. The study starts from the Theory of Capital Structure applied to product market competition decisions - output and price decisions - to realize that, given their capital structure choices, the firms within that particular industry simply adopt a classical behaviour of sofier competition. Debt, in this industry, has the role of an entry barrier. Even though, cases of tougher competition have been found, indicating the lack of a formal discipline among its members which ones, eventually, may find it very difficult - or of no interest - to coexist together in a fast changing industrial environment.

Philosophiae Doctor - PhD / The results of this study show that novel mesoporous carbons were obtained as inverse replica of SBA-15, HMS and MCM-41 silica templates, with a large pore diameter (2-4 nm), a BET surface area of 1867, 874 and 910 m2g–1 respectively for CA_SBA-15_LPG_105, CA_HMS_LPG_80 and CA_MCM- 41_LPG_80 with bimodal pore size distribution (PSD) in the mesopores range. The results obtained show that mesoporous carbon with graphitic structures can be synthesized via the LPG route. / South Africa

This study analyses the possibility of introducing liquefied petroleum gas (LPG) as an alternative domestic energy source to charcoal in Zambia to mitigate climate change. The study, conducted in Lusaka, used questionnaires, focus group discussions, interviews and literature study to collect data. The study revealed that the introduction of LPG is possible. However, some challenges need to be addressed in order to actualise the change. Lack of knowledge about LPG; non-availability of LPG in most parts of the country; perceived danger of LPG; high prices of LPG and accessories; changing people‟s mind-sets about charcoal; social inequity and lack of government initiative, were the main challenges identified. Social-Ecology and sustainable livelihoods were used as theoretical frameworks to ground the study and analyse the results. The study recommends that government takes the lead to make the change possible and that further research be done on sustainable livelihoods for charcoal producers and traders. / Development Studies / M. A. (Development Studies)

Wichtigster Bestandteil des Kampfes ums Überleben nach dem Zweiten Weltkrieg war die Nahrungsbeschaffung. Nach der 'offiziellen' Kartoffel-Ernte und der Feld-Freigabe durch den Flurschutz durften endlich die Städter auf die bereits abgeernteten Kartoffelfelder, um noch die letzten lebenswichtigen Kartoffeln aus dem Erdreich zu hacken... Kartoffeln waren zum Teil die einzige Nahrungsquelle, die zum Überleben für die Familien wurde. Auch später war es für Schulkinder selbstverständlich, in den Herbstferien auf den Kartoffelfeldern zu helfen und sich im Leistungslohn ein paar Spargroschen zu verdienen.