Cette thèse de doctorat s'inscrit dans un projet pour le développement du transport ferroviaire piloté par la société ALSTOM Transport. Il répond aux prévisions de quadruplement des déplacements interurbains et régionaux en France à l'horizon 2020 en respectant les contraintes environnementales très sévères, dont les normes restrictives du niveau de bruit émis par les trains. Une réduction importante du bruit émis par le moteur est donc nécessaire. Notre mission dans ce projet a été de développer un outil capable de prédire le bruit d'origine électromagnétique produit par les moteurs synchrones à aimants permanents, équipés d'un bobinage distribué ou concentré, et alimentés par des tensions MLI. Pour cela, un modèle multi-physique a été développé.Un couplage numérique - analytique a été mis en place pour calculer les forces magnétiques dans l'entrefer. La perméance globale d'entrefer et les inductances synchrones sont ainsi calculées grâce à des simulations éléments finis en statique, et très rapides. Un niveau de précision et de rapidité de résolution inégalé est obtenu pour le calcul des forces magnétiques. L'alimentation MLI, la perméabilité des clavettes, la saillance du rotor et l'asymétrie des dents du stator sont pris en compte. La rapidité de l'outil permet un couplage avec un superviseur d'optimisation. Deux prototypes ont été dimensionnés et fabriqués dans le but de valider le modèle multi-physique / This thesis is part of a project for the development of rail transportation piloted by ALSTOM TRANSPORT. It meets the forecasts of fourfold increase of the interurban and regional travels in France before 2020, by respecting very severe environmental requirements, among which the restrictive standards of noise level emitted by trains. An important reduction of the noise radiated by motors is required. Our mission in this project was to develop a tool capable of predicting the electromagnetic noise produced by permanent magnet synchronous motors equipped with distributed or concentrated windings, and fed by a PWM converter. For that purpose, a multi-physics model was developed.A numerical - analytical coupling was set up to calculate the airgap magnetic pressures. Global airgap permeance and synchronous inductances are thus calculated thanks to statics finite element simulations. An unequalled level of precision and speed of resolution is obtained for the computation of airgap magnetic pressures. The PWM supply, the wedge permeability, the rotor shape and the asymmetry of stator teeth are taken into account. The quickness of the resolution allows coupling our tool with an optimization supervisor. Two prototypes were designed and built in order to validate the multi-physics model

Securing rare earth elements (REE) for a stable supply require sustainable management strategies in Europe due to a missing local primary production and a dependence on China as the main producer of REE. These elements, like neodymium (Nd) and dysprosium (Dy), are contained in permanent magnets (PM) (mostly NdFeB-magnets) in wind turbines. Addressing the question whether PM-material, Nd- and Dy-contents from wind turbines could help to meet future demands of REE in Europe while reducing simultaneously the import dependence, the purpose of the present work was to analyze the urban mining opportunities, recovery - and recycling potentials for REE from end-of-life (EoL) wind turbines. This thesis aimed to identify current and upcoming stocks as well as material flows of the PM and their containing REE in the wind energy sector. Two European countries, Germany and Denmark, were chosen as case studies to be compared based on created future scenarios and the modeling of the theoretical recycling potential of Nd and Dy in both countries. It could have been identified that the German anthropogenic stock contains greater amounts of NdFeB-magnets and REE compared to the Danish stock. Overall it could be concluded that the countries’ demand could partly be met by using secondary Nd and Dy from the EoL-wind turbines. Although future scenarios were used, the results realistically illustrate the German and Danish anthropogenic stock until 2035 by relying on data of already installed turbines up to 2018, which makes an evaluation of capacities and EoL-turbines, which need to be decommissioned by 2035, achievable. The provided information is valuable for further investigations regarding recovery strategies, feasibility analysis, and future decision-making processes. / För att säkra tillgången på jordartsmetaller (REE) i Europa krävs hållbara beslutsstrategier. Detta på grund av avsaknaden av en inhemsk primärproduktion samt ett beroende av Kina som en huvudprodu-cent av REE. Jordartsmetaller som neodymium (Nd) och dysprosium (Dy), finns kvar i permanenta magneter (PM) (mestadels NdFeB-magneter) i vindturbiner. För att ta itu med frågan om huruvida Nd- och Dy-innehållet i PM-material, från vindturbiner skulle kunna bidra till att uppfylla framtida efter-frågan på REE i Europa samtidigt som importberoendet skulle minskas, var syftet med detta arbete att analysera möjligheterna till urban utvininng, återvinning och materialutnyttjande av REE från vindtur-biner i uttjänt tillstånd (EoL).Syftet med denna uppsats var att identifiera nuvarande och kommande tillgångar samt materialflöden av PM och därav följande REE inom vindkraftsektorn. Två europeiska länder, Tyskland och Danmark, valdes ut som fallstudier och jämfördes i framtida scenarier och mo-dellering av Nd -och Dy teoretiska återvinningspotential i båda länderna. Det kunde konstaterats att det tyska antropogena beståndet innehåller större mängder NdFeB-magneter och REE än det danska beståndet. Sammanfattningsvis kan man dra slutsatsen att ländernas efterfrågan delvis kunde tillgodo-ses genom att man använde sekundär Nd och Dy från EoL-vindturbiner. Även om framtida scenarier användes illustreras resultatet på ett realistiskt sätt det det antropogena lagret i Tyskland och Danmark fram till 2035 genom att man förlitar sig på uppgifter om redan installerade turbiner fram till 2018, vilket gör det möjligt att göra en utvärdering av kapaciteten och antal EoL-turbiner, som måste av-vecklas senast 2035. Informationen är värdefull för ytterligare utredningar om återvinningsstrategier, genomförbarhetsanalys och framtida beslutsprocesser.

Dans le domaine du stockage de l'information, la miniaturisation de l'unité magnétique portant l'information est un enjeu capital. Ainsi, la découverte de molécules possédant des propriétés de relaxation lente de leur aimantation, comparables à celles des aimants classiques, constitue une avancée majeure suscitant l'espoir de pouvoir un jour stocker l'information à l'échelle moléculaire.Cette thèse a pour but d'étudier les propriétés magnétiques des chaînes aimants. Ces chaînes sont constituées d'unités magnétiques liées par des interactions magnétiques au sein d'un réseau unidimensionnel. Au delà de leurs potentielles applications, les chaînes aimants sont parfaitement adaptées à l'étude fondamentale des chaînes de spins. Le premier chapitre de ce manuscrit constitue un rappel des propriétés statiques et dynamiques des chaînes aimants connues à ce jour. Le deuxième chapitre décrit les propriétés statiques des parois séparant les différents domaines d'aimantation dans des chaînes de spins de topologies magnétiques variées. Le troisième chapitre de ce manuscrit décrit les propriétés dynamiques des chaînes de spins d'Ising. Bien que seul le modèle de Glauber soit utilisé dans la littérature associée aux chaînes aimants, il existe une infinité de modèles dynamiques d'Ising.Grâce à l'étude détaillée de trois modèles, il est montré dans ce chapitre que l'application d'un champ magnétique permet de révéler différentes dynamiques de relaxation de l'aimantation pour chacun des modèles considérés. Ces résultats permettent enfin de proposer deux protocoles expérimentaux à même de déterminer le modèle dynamique le plus adapté à l'étude des chaînes aimants. / The size reduction of magnetic units able to store information is an important issue for the design of high-density data storage devices. The discovery of molecules that show slow relaxation of their magnetization, similar to classical magnets, is a great breakthrough in terms of molecular scale information storage. The work presented in this thesis is devoted to the study of the magnetic properties of Single Chain Magnets. Single Chain Magnets can be viewed as a one-dimensional assembly of anisotropic magnetic units linked by magnetic interactions. Beyond their potential applications, Single Chain Magnets are interesting prototypes for the fundamental study of spin chains. The first chapter of this manuscript summarizes some known static and dynamic properties of Single Chain Magnets. Chapter II is devoted to the static properties of domain walls, which link the magnetic domains in spin chains, considering various magnetic topologies. Chapter III is dedicated to the dynamic properties of Ising spin chains. In the Single Chain Magnet literature, the Glauber model is used to describe the dynamic properties of such spin chains. However, there exists an infinite number of dynamic Ising models. In this chapter, three dynamic models are studied in detail. We show that the presence of a magnetic field allows us to discern different magnetization relaxation behaviors associated with each dynamic model. These results allow us to establish two experimental protocols in order to determine the most suitable dynamic model to describe the properties of Single Chain Magnets.

We report experimentally results on the low temperature properties of two classes of materials with a special emphasizes near the QCP induced by substitution and magnetic 1.field: (1) the HF systems YbRh2(Si0.95Ge0.05)2, Yb1-yLayRh2Si2 (y = 0.05, 0.1),and YbIr2Si2 with tetragonal structures and CeIn3-xSnx (x = 0.55, 0.6, 0.65, 0.7, 0.8) with cubic structure; (2) the quantum spin systems: Cs2CuCl4 and Cs2CoCl4. In all the HF compounds we have observed NFL behavior in zero magnetic field close to the QCP. The La substituted system does not show an antiferromagnetic (AFM) transition down to the lowest accessible temperature (0.03 K) while in YbRh2(Si1-xGex)2 with x = 0 and x = 0.05 AFM transitions occur at TN =0.07 K and 0.02 K, respectively. For Yb0.9La0.1Rh2Si2 we observe below 0.07 K saturation of DeltaC/T indicating clearly a LFL state for this concentration. For YbIr2Si2, DeltaC/T saturates below 0.5 K. In contrast to the Yb based compounds in the vicinity of the QCP, CeIn3-xSnx shows no evidence of a divergence in Delta C/T, with B or with x. Furthermore, we used specic heat measurements in the mK temperature range and at high fields (up to 12 T) to probe the phase diagrams in the low dimensional quantum antiferromagnets Cs2CuCl4 and Cs2CoCl4. In applied magnetic field, we have presented experimental evidence that in Cs2CuCl4 the field dependence of the critical temperature Tc(B) ~ (Bc-B)^1-Phi close to the critical field Bc = 8.51 T is well described with Phi=1.5. This is in very good agreement with the exponent expected in the mean-field approximation and support the notion of a Bose-Einstein condensation of magnons in Cs2CuCl4.

This work has been devoted to the study of phase transformations involving chemical ordering and magnetic properties evolution in bulk Fe-Pt alloys composed of nanometer-sized grains. A comprehensive study of phase transformations and ordering in Fe-Pt alloys is performed by a combination of in-situ neutron powder diffraction and thermal analysis. The dependence of ordering processes on the alloy composition and initial microstructure (homogeneous A1 phase or multilayer-type) is established. Through the use of mechanical alloying and subsequent heat treatment it has been possible to achieve the formation of chemically highly ordered L10 FePt and, in the case of the Fe-rich and Pt-rich compositions, L12 Fe3Pt and FePt3 phases, respectively. Whereas in Pt-rich alloys the decoupling effect of the FePt3 phase leads to coercivity improvement, in Fe-rich nanocomposites a peculiar nanometer scale multilayer structure gives rise to remanence enhancement due to large effects of exchange interactions between the crystallites of the phases. The structure, magnetic properties and magnetisation reversal processes of these alloys are investigated. Experimentally observed phenomena are understood on the basis of a simple two-particle interaction model. Neutron diffraction has also been used for the investigation of the magnetic structure of ordered and partially ordered nanocrystalline Fe-Pt alloys. It has been shown that the magnetic moment of Fe atoms in L10-type Fe Pt alloys is sensitive to the compositional order. The results are compared to density functional calculations.

No description available.

The continuously increasing demand for clean renewable energy has rekindled interest in multi-terminal high voltage direct current (HVDC) grids. Although such grids have several advantages and a great potential, their materialization has been thwarted due to the absence of HVDC breakers. In comparison with traditional alternating current (AC) breakers, they should operate and interrupt fault currents in a time frame of a few milliseconds. The aim of this thesis is focused on the design of ultra-fast electro-mechanical actuator systems suitable for such HVDC breakers.Initially, holistic multi-physics and hybrid models with different levels of complexity and computation time were developed to simulate the entire switch. These models were validated by laboratory experiments. Following a generalized analysis, in depth investigations involving simulations complemented with experiments were carried out on two of the sub-components of the switch: the ultra-fast actuator and the damper. The actuator efficiency, final speed, peak current, and maximum force were explored for different design data.The results show that models with different levels of complexity should be used to model the entire switch based on the magnitude of the impulsive forces. Deformations in the form of bending or elongation may deteriorate the efficiency of the actuator losing as much as 35%. If that cannot be avoided, then the developed first order hybrid model should be used since it can simulate the behavior of the mechanical switch with a very good accuracy. Otherwise, a model comprising of an electric circuit coupled to an electromagnetic FEM model with a simple mechanics model, is sufficient.It has been shown that using a housing made of magnetic material such as Permedyn, can boost the efficiency of an actuator by as much as 80%. In light of further optimizing the ultra-fast actuator, a robust optimization algorithm was developed and parallelized. In total, 20520 FEM models were computed successfully for a total simulation time of 7 weeks. One output from this optimization was that a capacitance of 2 mF, a charging voltage of 1100 V and 40 turns yields the highest efficiency (15%) if the desired velocity is between 10 m/s and 12 m/s.The performed studies on the passive magnetic damper showed that the Halbach arrangement gives a damping force that is two and a half times larger than oppositely oriented axially magnetized magnets. Furthermore, the 2D optimization model showed that a copper thickness of 1.5 mm and an iron tube that is 2 mm thick is the optimum damper configuration. / <p>QC 20150422</p>

Die vorliegende Promotionsarbeit “Density functional study of the electronic and magnetic properties of selected transition metal complexes” beschäftigt sich mit dem Zusammenhang zwischen strukturellen Merkmalen sowie elektronischen und magnetischen Eigenschaften von Einzelmolekül-Magneten. Im Wesentlichen konnte dabei gezeigt werden, dass die magnetischen Eigenschaften sowohl von strukturellen Merkmalen als auch von den elektronischen Eigenschaften bestimmt werden. Des Weiteren ergab sich, dass verschiedene Kenngrößen der magnetischen Eigenschaften (im speziellen der magnetische Grundzustand S sowie die magnetische Anisotropie D) miteinander korreliert sind. Dies ist im Besonderen für eine mögliche Anwendung von Einzelmolekül-Magneten im Bereich der Datenspeicherung von Bedeutung.

Cette thèse décrit des expériences sur la synthèse de nanotubes de carbone (CNT) mono-paroi, leur intégration dans des dispositifs ultra-propres, ainsi que l'étude de leurs propriétés électroniques par des mesures de transport à très basse température. La première partie de ce travail décrit l'optimisation des paramètres de synthèse par déposition chimique en phase vapeur (CVD) tels que les précurseurs de carbone, les flux de gaz, la température, ou le catalyseur pour la croissance de CNT de très bonne qualité. Parmis tous ces paramètres, la composition du catalyseur joue un rôle decisif pour permettre une croissance sélective en mono-paroi ansi qu'une distribution de faible diamètre. Dans la deuxième partie nous développons la nanofabrication de boites quantiques ultra-propres à base de CNT ainsi que les mesures de transport de ces échantillons à basse température (40 mK). Le spectre de la première couche électronique du nanotube est mesuré par spectroscopie de cotunneling inélastique sous champ magnétique, montrant alors un fort couplage spin-orbite négatif, dans ce système. Nous montrons que la séquence de remplissage d'électrons dans notre cas (ΔSO < 0) est différente de celle que l'on obtiendrait en régime Kondo SU (4) (ΔSO = 0). En effet, un effet Kondo purement orbital est observé pour N =2e à champ magnétique fini. Dans la dernière partie de cette thèse, nous décrivons la mise en œuvre expérimentale d'un évaporateur thermique à aimants à molécule unique (SMM) pour la fabrication future de dispositifs hybrides CNT-SMM ultra-propres. / This thesis describes experiments on the synthesis of single wall carbon nanotubes (SWNTs), fabrication of ultra-clean CNT devices, and study of electronic properties of CNTs with transport measurements. The first part of this work describes the optimization of the synthesis parameters (by chemical vapor deposition - CVD) such as carbon precursor, gas flows, temperature, catalyst for the growth of high quality SWNTs. In all these parameters, the catalyst composition plays a very important role on the high selective growth of SWNTs with a narrow diameter distribution. The second part deals with the nanofabrication of ultra-clean CNT devices and the low temperature (40 mK) transport measurements of these CNT quantum dots. The level spectra of the electrons in the first shell are investigated using inelastic cotunneling spectroscopy in an axial magnetic field, which shows a strong negative spin-orbit coupling of electron. We find that the sequence of electron shell filling in our case (ΔSO < 0) is different from which would be obtained in the pure SU(4) Kondo regime (ΔSO = 0). Indeed, a pure orbital Kondo effect is observed in N=2e at a finite magnetic field. In the last part of this thesis, we describe the experimental implementation of the thermal evaporation of single-molecule magnet (SMM) for the future fabrication of ultra-clean CNT-SMM hybrid devices.

We have modeled some magnetic systems, which consists of a number of sublattices, in the mean field approximation. This is possible in crystalline systems formed by two or more magnetic ions coupled by specific interactions such as the crystal field, exchange, among others. The main idea is to solve the microscopic Hamiltonian that models a given magnetic system in order to obtain their magnetic equation of state: M (H, T). For this, we use the appropriate arrangements to different magnetic (ferro-, ferri- and antiferro- magnetic) scheme sublattices. From the solutions of the Hamiltonian (eigenvalues and eigenvectors), physical quantities of interest were determined. In principle we consider systems with localized magnetism due to 3d and 4f electrons with the participation of non-magnetic ligands including 3d-4f systems with the presence of crystal field. In this dissertation we use the model of two-and three sublattices in order to obtain the equation of state for the following systems: RKKY exchange in RNi2B2C, superexchange in (Y3-zRz)(T1xFe1-x)(T2yFe3-y)O12, LixFe3- xO4 and (NixMn1-x)1.5[Cr(CN)6]. In these formulas, R represents a rare earth ion, T1 and T2 represent non-magnetic ions. Some representative cases are presented to illustrate the different equations of state and behavior of sublattices, metamagnetism, temperature compensation, etc. The extension to other similar systems can be direct or need to incorporate additional phenomenological parameters. / Consideramos neste estudo sistemas magnéticos modeláveis mediante sub- redes na aproximação do campo médio. Isto é possível em sistemas cristalinos formados por dois ou mais íons magnéticos acoplados por interações específicas como as do campo cristalino, troca, entre outros. A ideia central é resolver o hamiltoniano microscópico que modela um determinado sistema magnético de maneira a se obter sua equação de estado magnética: M(H,T). Para isto usamos o esquema de sub- redes adequado a diferentes arranjos magnéticos (ferro-, ferri- e antiferro- magnéticos). Com as soluções do hamiltoniano (autovalores e autovetores), grandezas físicas de interesse foram determinadas. Em princípio, consideramos sistemas com magnetismo localizado devido a elétrons 3d e 4f com participação de ligandos não magnéticos incluindo sistemas 3d-4f com presença de campo cristalino. Neste trabalho de dissertação empregamos o modelo de duas e três sub- redes para obter as equações de estado nos seguintes sistemas: troca tipo RKKY em RNi2B2C, supertroca em (Y3-zRz)(T1xFe1-x)(T2yFe3-y)O12, LixFe3-xO4 e (NixMn1- x)1.5[Cr(CN)6]. Nestas fórmulas, R representa um íon de terra rara, T1 e T2 representam íons não magnéticos. Alguns casos representativos são apresentados para exemplificar as diferentes equações de estado e comportamento das sub- redes, metamagnetismo, temperatura de compensação etc. Em princípio, a extensão para outros sistemas semelhantes, usando os modelos apresentados aqui, pode ser direta ou precisar incorporar parâmetros fenomenológicos adicionais.