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Architectural Nanomembranes as Cathode Materials for Li-O2 BatteriesLu, Xueyi 17 August 2017 (has links)
Li-O2 batteries have attracted world-wide research interest as an appealing candidate for future energy supplies because they possess the highest energy density of any battery technology. However, such system still face some challenges for the practical application. One of the key issues is exploring highly efficient cathode materials for Li-O2 batteries.
Here, a rolled-up technology associated with other physical or chemical methods are applied to prepare architectural nanomembranes for the cathode materials in Li-O2 batteries. The strain-release technology has recently proven to be an efficient approach on the micro/nanoscale to fabricate composite nanomembranes with controlled thickness, versatile chemical composition and stacking sequence.
This dissertation first focuses on the synthesis of trilayered Pd/MnOx/Pd nanomembranes. The incorporation of active Pd layers on both sides of the poor conductive MnOx layer commonly used in energy storage systems greatly enhances the conductivity and catalytic activity. Encouraged by this design, Pd nanoparticles functionalized MnOx-GeOy nanomembranes are also fabricated, which not only improve the conductivity but also facilitate the transport of Li+ and oxygen-containing species, thus greatly enhancing the performance of Li-O2 batteries. Similarly, Au and Pd arrays decorated MnOx nanomembranes act as bifunctional catalysts for both oxygen reduction reaction and oxygen evolution reaction in Li-O2 batteries. Moreover, by introducing hierarchical pores on the nanomembranes, the performance of Li-O2 batteries is further promoted by porous Pd/NiO nanomembranes. The macropores created by standard photolithography facilitate the rolling process and the nanopores in the nanomembranes induced by a novel template-free method supply fast channels for the reactants diffusion. In addition, a facile thermal treatment method is developed to fabricate Ag/NiO-Fe2O3/Ag hybrid nanomembranes as carbon-free cathode materials in Li-O2 batteries. A competing scheme between the intrinsic strain built in the oxide nanomembranes and an external driving force provided by the metal nanoparticles is introduced to tune the morphology of the 3D tubular architectures which greatly improve the performance by providing continuous tunnels for O2 and electrolyte diffusion and mitigating the side reactions produced by carbonaceous materials.
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Transformation of epitaxial NiMnGa/InGaAs nanomembranes grown on GaAs substrates into freestanding microtubesMüller, Christian, Neckel, I., Monecke, M., Dzhagan, V., Salvan, Georgeta, Schulze, S., Baunack, S., Gemming, T., Oswald, S., Engemaier, Vivienne, Mosca, D. H. 09 September 2016 (has links)
We report the fabrication of Ni2.7Mn0.9Ga0.4/InGaAs bilayers on GaAs (001)/InGaAs substrates by molecular beam epitaxy. To form freestanding microtubes the bilayers have been released from the substrate by strain engineering. Microtubes with up to three windings have been successfully realized by tailoring the size and strain of the bilayer. The structure and magnetic properties of both, the initial films and the rolled-up microtubes, are investigated by electron microscopy, X-ray techniques and magnetization measurements. A tetragonal lattice with c/a = 2.03 (film) and c/a = 2.01 (tube) is identified for the Ni2.7Mn0.9Ga0.4 alloy. Furthermore, a significant influence of the cylindrical geometry and strain relaxation induced by roll-up on the magnetic properties of the tube is found. / Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
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Stretchable Magnetoelectronics / Dehnbare MagnetoelektronikMelzer, Michael 22 December 2015 (has links) (PDF)
In this work, stretchable magnetic sensorics is successfully established by combining metallic thin films revealing a giant magnetoresistance effect with elastomeric materials. Stretchability of the magnetic nanomembranes is achieved by specific morphologic features (e.g. wrinkles), which accommodate the applied tensile deformation while maintaining the electrical and magnetic integrity of the sensor device. The entire development, from the demonstration of the world-wide first elastically stretchable magnetic sensor to the realization of a technology platform for robust, ready-to-use elastic magnetoelectronics with fully strain invariant properties, is described. The prepared soft giant magnetoresistive devices exhibit the same sensing performance as on conventional rigid supports, but can be stretched uniaxially or biaxially reaching strains of up to 270% and endure over 1,000 stretching cycles without fatigue. The comprehensive magnetoelectrical characterization upon tensile deformation is correlated with in-depth structural investigations of the sensor morphology transitions during stretching.
With their unique mechanical properties, the elastic magnetoresistive sensor elements readily conform to ubiquitous objects of arbitrary shapes including the human skin. This feature leads electronic skin systems beyond imitating the characteristics of its natural archetype and extends their cognition to static and dynamic magnetic fields that by no means can be perceived by human beings naturally. Various application fields of stretchable magnetoelectronics are proposed and realized throughout this work. The developed sensor platform can equip soft electronic systems with navigation, orientation, motion tracking and touchless control capabilities. A variety of novel technologies, like smart textiles, soft robotics and actuators, active medical implants and soft consumer electronics will benefit from these new magnetic functionalities.
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Strain engineered nanomembranes as anodes for lithium ion batteriesDeng, Junwen 30 January 2015 (has links) (PDF)
Lithium ion batteries (LIBs) have attracted considerable interest due to their wide range of applications, such as portable electronics, electric vehicles (EVs) and aerospace applications. Particularly, the emergence of a variety of nanostructured materials has driven the development of LIBs towards the next generation, which is featured with high specific energy and large power density.
Herein, rolled-up nanotechnology is introduced for the design of strain-released materials as anodes of LIBs. Upon this approach, self-rolled nanostructures can be elegantly combined with different functional materials and form a tubular shape by relaxing the intrinsic strain, thus allowing for enhanced tolerance towards stress cracking. In addition, the hollow tube center efficiently facilitates electrolyte mass flow and accommodates volume variation during cycling. In this context, such structures are promising candidates for electrode materials of LIBs to potentially address their intrinsic issues.
This work focuses on the development of superior structures of Si and SnO2 for LIBs based on the rolled-up nanotech. Specifically, Si is the most promising substitute for graphite anodes due to its abundance and high theoretical gravimetric capacity. Combined with the C material, a Si/C self-wound nanomembrane structure is firstly realized. Benefiting from a strain-released tubular shape, the bilayer self-rolled structures exhibit an enhanced electrochemical behavior over commercial Si microparticles. Remarkably, this behavior is further improved by introducing a double-sided carbon coating to form a C/Si/C self-rolled structure. With SnO2 as active material, an intriguing sandwich-stacked structure is studied. Furthermore, this novel structure, with a minimized strain energy due to strain release, exposes more active sites for the electrochemical reactions, and also provides additional channels for fast ion diffusion and electron transport. The electrochemical characterization and morphology evolution reveal the excellent cycling performance and stability of such structures.
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Nanomembranes Based on Nickel Oxide and Germanium as Anode Materials for Lithium-Ion BatteriesSun, Xiaolei 08 September 2017 (has links)
Rechargeable lithium-ion batteries are now attracting great attention for applications in portable electronic devices and electrical vehicles, because of their high energy density, long cycle and great convenience. For new generations of rechargeable lithium-ion batteries, they applied not only to consumer electronics but also especially to clean energy storage and hybrid electric vehicles. Therefore, further breakthroughs in electrode materials that open up a new important avenue are essential. Graphite, the most commonly used commercial anode material, has a limited reversible lithium intercalation capacity (372 mAh g-1). In this regard, tremendous efforts have been made towards even further improving high capacity, excellent rate capability, and cycling stability by developing advanced anode materials.
This work focuses on the lithium storage properties of nickel oxide (NiO) and germanium (Ge) nanomembranes anodes mainly fabricated by electron-beam evaporation. Specifically, NiO is selected for conversion-type material because of high theoretical specific capacity of 718 mAh g-1 and easily obtained material. The resultant curved NiO nanomembranes anodes exhibit ultrafast power rate of 50 C (1 C = 718 mA g-1) and good capacity retention (721 mAh g-1, 1400 cycles). Remarkably, multifunctional Ni/NiO hybrid nanomembranes were further fabricated and investigated. Benefiting from the advantages of the intrinsic architecture and the electrochemical catalysis of metallic nickel, the hybrid Ni/NiO anodes could be tested at an ultrahigh rate of ~115 C. With Ge as active alloying-type material (1624 mAh g-1), the effect of the incorporated oxygen to the lithium storage properties of amorphous Ge nanomembranes is well studied. The oxygen-enabled Ge (GeOx) nanomembranes exhibit improved electrochemical properties of highly reversible capacity (1200 mAh g-1), and robust cycling performance.
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Stretchable MagnetoelectronicsMelzer, Michael 19 November 2015 (has links)
In this work, stretchable magnetic sensorics is successfully established by combining metallic thin films revealing a giant magnetoresistance effect with elastomeric materials. Stretchability of the magnetic nanomembranes is achieved by specific morphologic features (e.g. wrinkles), which accommodate the applied tensile deformation while maintaining the electrical and magnetic integrity of the sensor device. The entire development, from the demonstration of the world-wide first elastically stretchable magnetic sensor to the realization of a technology platform for robust, ready-to-use elastic magnetoelectronics with fully strain invariant properties, is described. The prepared soft giant magnetoresistive devices exhibit the same sensing performance as on conventional rigid supports, but can be stretched uniaxially or biaxially reaching strains of up to 270% and endure over 1,000 stretching cycles without fatigue. The comprehensive magnetoelectrical characterization upon tensile deformation is correlated with in-depth structural investigations of the sensor morphology transitions during stretching.
With their unique mechanical properties, the elastic magnetoresistive sensor elements readily conform to ubiquitous objects of arbitrary shapes including the human skin. This feature leads electronic skin systems beyond imitating the characteristics of its natural archetype and extends their cognition to static and dynamic magnetic fields that by no means can be perceived by human beings naturally. Various application fields of stretchable magnetoelectronics are proposed and realized throughout this work. The developed sensor platform can equip soft electronic systems with navigation, orientation, motion tracking and touchless control capabilities. A variety of novel technologies, like smart textiles, soft robotics and actuators, active medical implants and soft consumer electronics will benefit from these new magnetic functionalities.:Outline
List of abbreviations 7
1. INTRODUCTION
1.1 Motivation and scope of this work 8
1.1.1 A brief review on stretchable electronics 8
1.1.2 Stretchable magnetic sensorics 10
1.2 Technological approach 11
1.3 State-of-the-art 12
2. THEORETICAL BACKGROUND
2.1 Magnetic coupling phenomena in layered structures 14
2.1.1 Magnetic interlayer exchange coupling 14
2.1.2 Exchange bias 15
2.1.3 Orange peel coupling 16
2.2 Giant magnetoresistance 17
2.2.1 Electronic transport through ferromagnets 17
2.2.2 The GMR effect 19
2.2.3 GMR multilayers 20
2.2.4 Spin valves 21
2.3 Theory of elasticity 22
2.3.1 Elastomeric materials 22
2.3.2 Stress and strain 23
2.3.3 Rubber elasticity 25
2.3.4 The Poisson effect 26
2.3.5 Viscoelasticity 27
2.3.6 Bending strain in a stiff film on a flexible support 27
2.4 Approaches to stretchable electronic systems 28
2.4.1 Microcrack formation 28
2.4.2 Meanders and compliant patterns 29
2.4.3 Surface wrinkling 30
2.4.4 Rigid islands 32
3. METHODS & MATERIALS
3.1 Sample fabrication 34
3.1.1 Polydimethylsiloxane (PDMS) 34
3.1.2 PDMS film preparation 35
3.1.3 Lithographic structuring on the PDMS surface. 36
3.1.4 Magnetic thin film deposition 38
3.1.5 GMR layer stacks 40
3.1.6 Mechanically induced pre-strain 43
3.1.7 Methods and materials for the direct transfer of GMR sensors 45
3.1.8 Materials used for imperceptible GMR sensors 47
3.2 Characterization 48
3.2.1 GMR characterization setup with in situ stretching capability 48
3.2.2 Sample mounting 50
3.2.3 Electrical contacting of stretchable sensor devices 51
3.2.4 Customized demonstrator electronics 52
3.2.5 Microscopic investigation techniques 53
4. RESULTS & DISCUSSION
4.1 GMR multilayer structures on PDMS 54
4.1.1 Pre-characterization 54
4.1.2 Thermally induced wrinkling 55
4.1.3 Self-healing effect 57
4.1.4 Demonstrator: Magnetic detection on a curved surface 60
4.1.5 Sensitivity enhancement 61
4.1.6 GMR sensors in circumferential geometry 64
4.1.7 Stretchability test 67
4.2 Stretchable spin valves 69
4.2.1 Random wrinkles and periodic fracture 70
4.2.2 GMR characterization 73
4.2.3 Stretching of spin valves 74
4.2.4 Microcrack formation mechanism 76
4.3 Direct transfer printing of GMR sensorics 81
4.3.1 The direct transfer printing process 82
4.3.2 Direct transfer of GMR microsensor arrays 84
4.3.3 Direct transfer of compliant meander shaped GMR sensors 86
4.4 Imperceptible magnetoelectronics 89
4.4.1 GMR multilayers on ultra-thin PET membranes 89
4.4.2 Imperceptible GMR sensor skin 92
4.4.3 Demonstrator: Fingertip magnetic proximity sensor 93
4.4.4 Ultra-stretchable GMR sensors 94
4.4.5 Biaxial stretchability 99
4.4.6 Demonstrator: Dynamic detection of diaphragm inflation 101
5. CONCLUSIONS & OUTLOOK
5.1 Achievements 102
5.2 Outlook 104
5.2.1 Further development steps 104
5.2.2 Prospective applications. 105
5.3 Technological impact: flexible Bi Hall sensorics 106
5.3.1 Application potential 106
5.3.2 Thin and flexible Hall probes 107
5.3.3 Continuative works and improvements 108
5.4 Activities on technology transfer and public relations 108
Appendix
References 110
Selbständigkeitserklärung 119
Acknowledgements 120
Curriculum Vitae 121
Scientific publications, contributions, patents, grants & prizes 122
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Nanomembrane-based hybrid semiconductor-superconductor heterostructuresThurmer, Dominic J. 20 July 2011 (has links)
The combination of modern self-assembly techniques with well-established top-down processing methods pioneered in the electronics industry is paving the way for increasingly sophisticated devices in the future[1]. Nanomembranes, made from a variety of materials, can provide the necessary framework for a diverse range of device structures incorporating wrinkling, buckling, folding, and rolling of thin films[2, 3]. Over the past decade, an elegant symbiosis of bottom-up and top-down methods has been developed, allowing the fabrica- tion of hybrid layer systems via the controlled release and rearrangement of inherently strained layers [4]. Self-assembled rolled-up structures[4, 5] have become increasingly at- tractive in a number of fields including micro/nano uidics[6], optics[7](including metama- terial optical fibers[8]), Lab on a Chip applications[9], and micro- and nanoelectronics[10]. The use of such structures for microelectronic applications has been driven by the versatility in contacting geometries and the abundance of material combinations that these devices offer. By allowing devices to expand in the third dimension, certain obstacles that inhibit 2D structuring can be overcome in elegant ways. Similarly, recent progress in nanostructured superconducting electronic structures has been receiving increased attention[11]. The advancement of such devices has been mo- tivated by their use in quantum computation[12], high sensitivity radiation sensors[13], precision voltage standards[14] and superconducting spintronics[15] to name a few. Combining semiconductor with superconductor materials to create new hybrid geometries is advantageous because it adds the functionalities of the semiconductor, including high charge carrier mobilities, gating possibilities, and refined processing technologies.
The main focus of the work presented in this thesis is the development of new methods for controlling strain behavior and its applications toward novel semiconduc- tor/superconductor heterostructures based on nanomembranes. More specifically, the goal is to integrate inherently strained semiconductor layer structures with superconducting materials to create innovative electronic devices by the controlled releasing and rearrangement of thin films. By rolling up pre-patterned semiconductor/superconductor layers, device geometries have been realized that are not feasible using any other technique. In this way, superconducting hybrid junctions, or Josephson junctions, have been created and their basic properties investigated.
The Josephson effect, and junctions displaying this quantum coherent behavior, have found many essential uses in diverse areas of science and technology. Many research groups around the world are involved in finding new materials and fabrication methods to tune the properties and structure of such Josephson devices further[11]. The inclusion of semi- conductors, for example, allows for a greater control of the charge carrier density within the junction area, thus allowing for "transistor-like" behavior in these superconducting devices.
By rolling up the superconductor contacts using a strained semiconductor as scaffolding, the fabrication of hybrid nano-junctions is simplified drastically, removing the need for complicated processing steps such as electron-beam or nano-imprint lithography. Furthermore, the technique allows many nanometer-sized devices to be created in parallel on a single chip which has the advantage that it can be scaled up to full-wafer processing.
First, post-growth processing techniques of epitaxial layers are developed in order to extend the control of hybrid device fabrication. Here, three unique concepts for controlling the rolling behavior of strained semiconductor nanomembranes are presented. First an optical method for inhibiting the rolling of the strained layers is described. Next, a selective etching method for destroying the inherent strain within the semiconductor layer is introduced. Finally, a method by which the strain gradient across a trilayer stack is altered in situ during rolling is presented. Next, the fabrication of a hybrid nanomembrane-based superconducting device is presented. Various experimental details of the fabrication process are analyzed, and the electronic properties of the completed device are investigated. The devices created here highlight the fabrication process in which nanometer-sized structures are created using self-assembly techniques and standard microelectronics fabrication methods, presenting a new method to circumvent more complicated processing techniques.
References
[1] G. M. Whitesides and B. Grzybowski. Self-assembly at all scales. Science 295, 2418{2421 (2002).
[2] Y. G. Sun, W. M. Choi, H. Q. Jiang, Y. G. Y. Huang and J. A. Rogers. Controlled buckling of semiconductor
nanoribbons for stretchable electronics. Nature Nanotechnology 1, 201{207 (2006).
[3] O. G. Schmidt and K. Eberl. Nanotechnology - Thin solid films roll up into nanotubes. Nature 410, 168 (2001).
[4] O. G. Schmidt, C. Deneke, Y. Nakamura, R. Zapf-Gottwick, C. Mller and N. Y. Jin-Phillipp. Nanotechnology
{ Bottom-up meets top-down. Advanced Solid State Physics 42, 231 (2002).
[5] V. Ya. Prinz, V. A. Seleznev, A. K. Gutakovsky, A. V. Chehovskiy, V. V. Preobrazhenskii, M. A. Putyato
and T. A. Gavrilova. Free-standing and overgrown InGaAs/GaAs nanotubes, nanohelices and their arrays. Physica
E 6, 828 (2000).
[6] D. J. Thurmer, C. Deneke, Y. F. Mei and O. G. Schmidt. Process integration of microtubes for
uidic applications.
Applied Physics Letters 89, 223507 (2006).
[7] R. Songmuang, A. Rastelli, S. Mendach and O. G. Schmidt. SiOx/Si radial superlattices and microtube optical
ring resonators. Applied Physics Letters 90, 091905 (2007).
[8] E. J. Smith, Z. W. Liu, Y. F. Mei and O. G. Schmidt. Combined surface plasmon and classical waveguiding through
metamaterial fiber design. Nano Letters 10, 1{5 (2010).
[9] G. S. Huang, Y. F. Mei, D. J. Thurmer, E. Coric and O. G. Schmidt. Rolled-up transparent microtubes as
two-dimensionally confined culture scaffolds of individual yeast cells. Lab on a Chip 9, 263{268 (2009).
[10] C. C. B. Bufon, J. D. C. Gonzalez, D. J. Thurmer, D. Grimm, M. Bauer and O. G. Schmidt. Self-assembled
ultra-compact energy storage elements based on hybrid nanomembranes. Nano Letters 10, 2506{2510 (2010).
[11] G. Katsaros, P. Spathis, M. Stoffel, F. Fournel, M. Mongillo, V. Bouchiat, F. Lefloch, A. Rastelli,
O. G. Schmidt and S. De Franceschi. Hybrid superconductor-semiconductor devices made from self-assembled
SiGe nanocrystals on silicon. Nature Nanotechnology 5, 458{464 (2010).
[12] Y. J. Doh, J. A. van Dam, A. L. Roest, E. P. A. M. Bakkers, L. P. Kouwenhoven and S. De Franceschi.
Tunable supercurrent through semiconductor nanowires. Science 309, 272{275 (2005).
[13] F. Giazotto, T. T. Heikkila, G. P. Pepe, P. Helisto, A. Luukanen and J. P. Pekola. Ultrasensitive proximity
Josephson sensor with kinetic inductance readout. Applied Physics Letters 92, 162507 (2008).
[14] S. P. Benz. Superconductor-normal-superconductor junctions for programmable voltage standards. Applied Physics
Letters 67, 2714{2716 (1995).
[15] Y. C. Tao and J. G. Hu. Superconducting spintronics: Spin-polarized transport in superconducting junctions with
ferromagnetic semiconducting contact. Journal of Applied Physics 107, 041101 (2010).
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Strain engineered nanomembranes as anodes for lithium ion batteriesDeng, Junwen 08 January 2015 (has links)
Lithium ion batteries (LIBs) have attracted considerable interest due to their wide range of applications, such as portable electronics, electric vehicles (EVs) and aerospace applications. Particularly, the emergence of a variety of nanostructured materials has driven the development of LIBs towards the next generation, which is featured with high specific energy and large power density.
Herein, rolled-up nanotechnology is introduced for the design of strain-released materials as anodes of LIBs. Upon this approach, self-rolled nanostructures can be elegantly combined with different functional materials and form a tubular shape by relaxing the intrinsic strain, thus allowing for enhanced tolerance towards stress cracking. In addition, the hollow tube center efficiently facilitates electrolyte mass flow and accommodates volume variation during cycling. In this context, such structures are promising candidates for electrode materials of LIBs to potentially address their intrinsic issues.
This work focuses on the development of superior structures of Si and SnO2 for LIBs based on the rolled-up nanotech. Specifically, Si is the most promising substitute for graphite anodes due to its abundance and high theoretical gravimetric capacity. Combined with the C material, a Si/C self-wound nanomembrane structure is firstly realized. Benefiting from a strain-released tubular shape, the bilayer self-rolled structures exhibit an enhanced electrochemical behavior over commercial Si microparticles. Remarkably, this behavior is further improved by introducing a double-sided carbon coating to form a C/Si/C self-rolled structure. With SnO2 as active material, an intriguing sandwich-stacked structure is studied. Furthermore, this novel structure, with a minimized strain energy due to strain release, exposes more active sites for the electrochemical reactions, and also provides additional channels for fast ion diffusion and electron transport. The electrochemical characterization and morphology evolution reveal the excellent cycling performance and stability of such structures.
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High Quality Rolled-Up Microstructures Enabled by Silicon Dry Release TechnologiesSaggau, Christian Niclaas 24 August 2022 (has links)
Micro-technology relies on a highly parallel fabrication of 2D electronic and/or microelectromechanical devices, where in most cases silicon wafers are used as substrates. In contrast 3D fabrication shows unique advantages, such as footprint reduction or the possibility to obtain additional functionalities. For example, in the case of a sensor, knowledge of the acceleration in all possible directions, the surrounding electric or magnetic field among other quantities can help to determine the exact position of an object in 3D space. To do that it is crucial to retrieve all components of a vector field, which requires at least one out of plane component. In other fields like integrated optics three dimensional structures can enhance the coupling efficiency with free space interactions. As such 3D micro-structures will be crucial for upcoming products and devices. A highly parallel fabrication is required to enable mass-adaption, self-assembly is an emerging technology that could deliver this purpose. Examples of 3D structures created by self-assembly include polyhedrons like cubes, pyramids or micro tubular structures such as tubes or
spirals. Following a self assembly scheme, 3D devices would be created through the fabrication of standard 2D structures that are reshaped through a self-assembly step into a 3D object.
In this thesis a novel dry release protocol was developed to roll-up strained nanomembranes from a silicon sacrificial layer employing dry fluorine chemistry. This way a wet release is totally circumvented thus preventing damage of the created structures due to turbulent flow or capillary forces. Additionally the developed process enabled the use of standard CMOS deposition and processing tools, leading to a high increase in yield and quality, with yields exceeding 99% for microtubes. Building on the developed technology various devices where fabricated, for example rolled-up micro capacitors at a wafer scale with an increased yield and a low spread of electrical characteristics. For the E12 industrial standard more than 90% of devices behaved within the required performance characteristics. Furthermore the yield and Q-factor of roll-up whispering gallery mode resonators was strongly improved, making it possible to self assemble 3D coupled photonic molecules, which showed a mode splitting exceeding the FSR, as well as hybrid
supermodes at points of energy degeneracy.:Contents
Bibliographic Record i
List of Abbreviations vii
List of Chemical Substances ix
1 Introduction 1
1.1 Microelectromechanical Systems 1
1.2 Strain Engineering 2
1.3 Rolled - Up Nanotechnology 3
1.4 Objective and Structure of the Thesis 5
2 Materials and Methods 9
2.1 Fabrication Techniques 9
2.1.1 Substrates 9
2.1.2 Plasma Enhanced Chemical Vapor Deposition 9
2.1.3 Dry Etching12
2.1.4 Deep Reactive Ion Etching 18
2.1.5 Atomic Layer Deposition 19
2.1.6 Lithography 20
2.2 Characterization Techniques 22
2.2.1 Strain Measurement 22
2.2.2 Ellipsometry 23
3 Dry Roll-Up of Strained Nanomembranes 25
3.1 Rolled - Up Nanotechnology 25
3.2 Fabrication 26
3.2.1 Release 29
3.3 Conclusions 33
4 Rolled-UpMicro Capacitors 35
4.1 Micro Capacitors 35
4.2 Fabrication 38
4.3 Characterization 39
4.4 Conclusion 41
5 Optical Micro-Cavities 43
5.1 Optical Micro Cavities 43
5.2 Theorectical Background 45
5.2.1 Quality - factor 49
5.2.2 FDTD 52
6 Optical Microtube Resonators 55
6.1 Optical Whispering Gallery Mode Microtube Resonators 55
6.2 Fabrication 57
6.3 Active Characterization 60
6.4 Conclusions 64
7 Photonic Molecules 65
7.1 Coupled Photonic Systems 65
7.2 Fabrication 68
7.3 Device Characterization 71
7.4 Multimode Waveguides 84
7.5 Conclusions 85
8 Conclusions and Outlook 87
8.1 Conclusions 87
8.2 Outlook 88
Bibliography 91
List of Figures 109
List of Tables 117
A Equipment 119
Cover Pages 121
Selbstständigkeitserklärung 123
Acknowledgements 125
List of Publications 127
List of Presentations 129
Curriculum Vitae 131
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