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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
101

Control of Pore Structure in Plasma-Polymerized SiOCH Films for Gas Separation / Contrôle de la porosité dans les films SiOCH de polymère-plasma pour la séparation gazeuse

Lo, Chia-Hao 19 July 2010 (has links)
La synthèse d'une membrane composite formée d'une couche fine de surface de structure très réticulée et permsélective aux gaz déposée sur un substrat poreux a été étudiée comme solution pour accroître la perméabilité aux gaz tout en conservant une sélectivité importante. Une couche mince de polymère-plasma SiOCH a été retenue comme membrane de séparation gazeuse car elle possède une structure dont l'ultramicroporisté peut être contrôlée en ajustant les paramètres du procédé plasma comme la puissance, le flux de monomère et la pression de travail. Néanmoins, dans la membrane SiOCH, la taille moyenne des pores et leur distribution sont difficiles à appréhender par des techniques de caractérisation classiques, notamment proche de la surface car elle est très fine. Ce mémoire de thèse concerne le contrôle de la structure poreuse dans une couche mince de polymère-plasma SiOCH déposée sur un substrat polymère en utilisant un précurseur organosilicié. La spectroscopie d'annihilation de positron couplée à un faisceau de positron lent a été utilisée pour identifier la microstructure de couches minces SiOCH avec la profondeur. Ceci a nécessité tout d'abord l'acquisition d'une bonne connaissance de la caractérisation de l'annihilation de positron de matériaux polymères et céramiques. Des couches minces de SiOCH conformes ou superhydrophobes (SHP) ont été obtenues à deux fréquences différentes, respectivement à 13,56 MHz ou 40 kHz. Pour une couche conforme, le type de substrat, la structure chimique du précurseur et la puissance RF sont les paramètres majeurs qui influencent la structure des pores. Quand les films de SiOCH sont composées de deux couches (couche uniforme de surface et couche de transition) déposées sur un substrat poreux, l'analyse PAS met en évidence une couche de transition large et l'ensemble possède une perméabilité aux gaz élevée grâce à la porosité de surface du support. Lors de la préparation des couches minces SHP, quand la pression totale dépasse 0,6 mbar, la nucléation en phase gaz apparaît ce qui augmente la rugosité de la surface. Ceci induit des angles de contact à l'eau supérieurs à 160° et une hystérésis d'angles de contact avancée-reculée de seulement 2°. La préservation des chaînes carbonées et la microstructure sont les facteurs déterminant pour accroître l'hydrophobicité des couches minces de SiOCH. / In gas separation, the fabrication of composite membranes consisting of a permselective thin top layer with high cross-linking structures and a porous substrate has been regarded as a solution for improving gas permeability and simultaneously retaining high selectivity. A plasma-polymerized SiOCH film has been known as an appropriate gas separation membrane because it possesses a dense structure, the crosslinking degree of which could be controlled by adjusting plasma parameters such as plasma power, monomer flow rate, and system pressure. However, the pore size and distribution in SiOCH films, especially in the region of depth profile, are difficult to measure by conventional techniques because of they are very thin.This thesis is concerned with the control of pore structure in a plasma-polymerized SiOCH film on a polymeric substrate by using an organosilicon source. The positron annihilation spectroscopy (PAS) coupled to the slow positron beam technique was used to identify the microstructure of SiOCH films as a function of depth. This step required to have a good understanding of the positron annihilation characteristics of different materials such as organic, inorganic, and hybrid materials. Depending on plasma frequency adjustments, SiOCH films with a flat and a superhydrophobic (SHP) surface were fabricated at 13.56 MHz and 40 kHz, respectively. For a flat SiOCH film, substrate type, chemical structure of precursor, and RF power were the major variables that influenced the pore structure. When SiOCH films composed of two layers (bulk and transitions layers) were deposited on porous substrates, they displayed a long transition layer based on the PAS analysis and possessed a high gas permeability due to the surface porosity of the substrate. When the precursor used possessed a cyclic ring structure, an opportunity of a break-up of the cyclic ring would increase with increasing RF power and then induce formation of new big pores. For the preparation of SHP films, when the total pressure was higher than 0.6 mbar, the gas nucleation reaction was enhanced to induce roughness on SiOCH films, and it would show a high WCA of over 160o and a low WCAH of only 2 degrees. Both the hydrocarbon preservation and microstructure were the main factors in improving the surface superhydrophobicity of SiOCH films.
102

Detection of Early Stages of Degradation on PPTA Fibers Through the Use of Positron Annihilation Lifetime Spectroscopy

Nelyan Lopez-Perez (7038068) 14 August 2019 (has links)
<p>High-performance fibers used for ballistic protection are characterized by having outstanding mechanical properties such high modulus and strength. These mechanical properties are granted by the fiber’s chemical and physical structure as well as their high degree of orientation. Twaron fibers are one of the most commonly used fibers on soft body armors such as bulletproof vests. They are made from poly (p-phenylene terephthalamide) (PPTA), a rigid-rod and highly crystalline polymer. Although these fibers are crystalline and have great mechanical properties, their performance can decrease when they are exposed to different degradation factors. Free volume is the unoccupied space between the polymer molecules. It is responsible for characteristics such as diffusion and viscosity. Hence, the free volume changes as the polymer degrades. This thesis focuses on the effects of sonication, pH changes, and sweat on the free volume of PPTA fibers. </p><p><br></p> <p>A non-destructive technique known as positron annihilation lifetime spectroscopy (PALS) was used to measure the free volume in PPTA. Changes in the free volume of fibers degraded under different conditions were compared to their mechanical performance. Degradation in DI water, pH 4 and pH 10 aqueous solutions was conducted for 10 weeks at 80<sup>o</sup>C. Sweat degradation of PPTA fibers was also conducted for 10 weeks at 25<sup>o</sup>C, 50<sup>o</sup>C, and 100<sup>o</sup>C. Fibers degraded in pH4 and sweat solutions had greater loss of mechanical performance and changes in the free volume. PALS was able to detect changes in the nanostructure of PPTA fibers at early stages of degradation. This data was supported by mechanical tests and is complementary to other characterization techniques such as small angle X-ray scattering (SAXS). Results of this research are a steppingstone for future studies on lifetime predictions of bulletproof vests and the development of the next generation of soft body armors. </p>
103

Novel computational methods for image analysis and quantification using position sensitive radiation detectors

Sanchez Crespo, Alejandro January 2005 (has links)
<p>The major advantage of position sensitive radiation detector systems lies in their ability to non invasively map the regional distribution of the emitted radiation in real-time. Three of such detector systems were studied in this thesis, gamma-cameras, positron cameras and CMOS image sensors. A number of physical factors associated to these detectors degrade the qualitative and quantitative properties of the obtained images. These blurring factors could be divided into two groups. The first group consists of the general degrading factors inherent to the physical interaction processes of radiation with matter, such as scatter and attenuation processes which are common to all three detectors The second group consists of specific factors inherent to the particular radiation detection properties of the used detector which have to be separately studied for each detector system. Therefore, the aim of this thesis was devoted to the development of computational methods to enable quantitative molecular imaging in PET, SPET and in vivo patient dosimetry with CMOS image sensors.</p><p>The first task was to develop a novel quantitative dual isotope method for simultaneous assessments of regional lung ventilation and perfusion using a SPET technique. This method included correction routines for photon scattering, non uniform attenuation at two different photon energies (140 and 392 keV) and organ outline. This quantitative method was validated both with phantom experiments and physiological studies on healthy subjects.</p><p>The second task was to develop and clinically apply a quantitative method for tumour to background activity uptake measurements using planar mammo-scintigraphy, with partial volume compensation.</p><p>The third stage was to produce several computational models to assess the spatial resolution limitations in PET from the positron range, the annihilation photon non-collineairy and the photon depth of interaction.</p><p>Finally, a quantitative image processing method for a CMOS image sensor for applications in ion beam therapy dosimetry was developed.</p><p>From the obtained phantom and physiological results it was concluded that the methodologies developed for the simultaneous measurement of the lung ventilation and perfusion and for the quantification of the tumour malignancy grade in breast carcinoma were both accurate. Further, the obtained models for the influence that the positron range in various human tissues, and the photon emission non-collinearity and depth of interaction have on PET image spatial resolution, could be used both to optimise future PET camera designs and spatial resolution recovery algorithms. Finally, it was shown that the proton fluence rate in a proton therapy beam could be monitored and visualised by using a simple and inexpensive CMOS image sensor.</p>
104

Novel computational methods for image analysis and quantification using position sensitive radiation detectors

Sanchez Crespo, Alejandro January 2005 (has links)
The major advantage of position sensitive radiation detector systems lies in their ability to non invasively map the regional distribution of the emitted radiation in real-time. Three of such detector systems were studied in this thesis, gamma-cameras, positron cameras and CMOS image sensors. A number of physical factors associated to these detectors degrade the qualitative and quantitative properties of the obtained images. These blurring factors could be divided into two groups. The first group consists of the general degrading factors inherent to the physical interaction processes of radiation with matter, such as scatter and attenuation processes which are common to all three detectors The second group consists of specific factors inherent to the particular radiation detection properties of the used detector which have to be separately studied for each detector system. Therefore, the aim of this thesis was devoted to the development of computational methods to enable quantitative molecular imaging in PET, SPET and in vivo patient dosimetry with CMOS image sensors. The first task was to develop a novel quantitative dual isotope method for simultaneous assessments of regional lung ventilation and perfusion using a SPET technique. This method included correction routines for photon scattering, non uniform attenuation at two different photon energies (140 and 392 keV) and organ outline. This quantitative method was validated both with phantom experiments and physiological studies on healthy subjects. The second task was to develop and clinically apply a quantitative method for tumour to background activity uptake measurements using planar mammo-scintigraphy, with partial volume compensation. The third stage was to produce several computational models to assess the spatial resolution limitations in PET from the positron range, the annihilation photon non-collineairy and the photon depth of interaction. Finally, a quantitative image processing method for a CMOS image sensor for applications in ion beam therapy dosimetry was developed. From the obtained phantom and physiological results it was concluded that the methodologies developed for the simultaneous measurement of the lung ventilation and perfusion and for the quantification of the tumour malignancy grade in breast carcinoma were both accurate. Further, the obtained models for the influence that the positron range in various human tissues, and the photon emission non-collinearity and depth of interaction have on PET image spatial resolution, could be used both to optimise future PET camera designs and spatial resolution recovery algorithms. Finally, it was shown that the proton fluence rate in a proton therapy beam could be monitored and visualised by using a simple and inexpensive CMOS image sensor.
105

Μελέτη ακτίνας ποζιτρονίου σε τομογραφία εκπομπής ποζιτρονίου (ΡΕΤ) με χρήση υπολογιστικού πακέτου GATE

Μουζακίτης, Παναγιώτης 11 November 2009 (has links)
Σκοπός της παρούσης διπλωματικής εργασίας είναι η μελέτη της ακτίνας εξαΰλωσης του ποζιτρονίου στην Τομογραφία Εκπομπής Ποζιτρονίου (PET) ύστερα από διάσπαση βήτα ενός ραδιενεργού πυρήνα. Η μελέτη γίνεται σε περιβάλλον GATE, ενός πακέτου που χρησιμοποιείται για προσομοίωση απεικονιστικών τεχνικών. Προσομοιώνονται διάφοροι πυρήνες και σε διαφορετικά περιβάλλοντα με σκοπό την ανάλυση και τη σύγκριση των αποτελεσμάτων. / Main objective of the present diplomatic thesis is the positron annihilation distance study in Positron Emission Tomography, after radioactive nucleus’ beta decay. The study is using GATE, which is an application used in imaging techniques. Under GATE we simulate a variety of nuclei in different ambient materials in order to analyze and compare the results.
106

Comportement thermique des défauts lacunaires induits par l’hélium et les gaz de fission dans le dioxyde d’uranium / Helium behavior and damage induced by fission products in the uranium dioxide

Belhabib, Tayeb 18 December 2012 (has links)
Dans les nouvelles centrales nucléaires dites 4ème génération, comme d’ailleurs les anciennes, le dioxyde d’uranium devra opérer dans des milieux hostiles de températures et d’irradiation avec la présence des produits de fission (PF) et des particules alpha (α). Le fonctionnement dans ces conditions extrêmes induira des déplacements d’atomes et dégradera les propriétés thermiques et mécaniques du combustible UO2. La compréhension du comportement des défauts lacunaires, des PF et de l’hélium est cruciale pour prévoir le comportement du dioxyde d’uranium au sein de ces futures installations nucléaires. La première partie de cette thèse est consacrée à l’étude des défauts lacunaires induits par l’implantation de krypton et d’iode (quelques MeV) dans l’UO2 polycristallin et leurs stades de recuits. L’analyse par spectroscopie d’annihilation de positons (PAS) a permis de mettre en évidence la création de défauts de Schottky VU-2VO dans le cas des implantations iode et la formation de clusters lacunaires contenant du gaz pour les implantations krypton. L’évolution en température de ces défauts générés dépend des paramètres d’implantation (nature des ions, énergie, fluence). Cette étude a montré les rôles importants que peuvent jouer les défauts lacunaires et la présence des gaz de fission dans l’évolution du matériau UO2. Ensuite, nous nous sommes intéressés à l’étude et à la caractérisation, par PAS et les techniques d’analyse par faisceau d’ions (NRA/C et RBS/C), du comportement de l’hélium dans l’UO2. Les mesures de NRA/C et RBS/C révèlent une localisation d’une grande fraction d’hélium dans les sites interstitiels octaédriques de la matrice UO2. La localisation de l’hélium reste stable dans ces sites pour T< 600°C, évoluent légèrement entre 600 et 700°C et devient aléatoire à 800°C. Les mesures PAS mettent en évidence trois stades d’évolution des défauts lacunaires : la recombinaison par migration des interstitiels d’oxygène, l’agglomération des défauts entre 600 et 800°C et leur dissociation et élimination lorsque la température augmente. Ces résultats suggèrent que le transport d'hélium est assisté par les défauts lacunaires. / In the new fourth generation nuclear plants, as in the old ones, uranium dioxide must operate in hostile environments of temperature and irradiation with the presence of fission products (FP) and alpha particles (α). Operation in these extreme conditions will induce atoms displacements and degrade the thermal and mechanical properties of UO2 fuel. Understanding the behavior of induced vacancy defects, FP and helium is crucial to predict the uranium dioxide behavior in the future nuclear reactors. The first part of this thesis is dedicated to the study of vacancy defects induced by krypton and iodine implantation (a few MeV) in the UO2 polycrystalline and of their evolution under annealing. Analysis by positron annihilation spectroscopy (PAS) has highlighted the creation of Schottky defects VU-2VO in the case of iodine implantations and formation of vacancy clusters containing the gas for krypton implantation. The temperature evolution of these defects depends on the implantation parameters (nature of the ion energy, fluence). This study showed the important roles that can play vacancy defects and the presence of fission gases in the evolution of UO2 material. Then we were interested in the study of the helium behavior in UO2 its location and migration, agglomeration and interaction with vacancy defects by using PAS and ion beam analysis (NRA/C and RBS/C). The NRA/C and RBS/C characterizations showed a localization of a large helium fraction in the octahedral interstitial sites of the UO2 matrix. The helium location in these sites remains stable for T <600°C, changing slightly between 600 and 700°C and becomes random at 800°C. Positron annihilation spectroscopy reveals three stages of vacancy defects evolution : The recombination with oxygen interstitial migration, defects agglomeration between 600 and 800°C and their dissociation and elimination when the temperature increases. These results suggest that the He transport is assisted by the vacancy defects.
107

Identification of equilibrium and irradiation-induced defects in nuclear ceramics : electronic structure calculations of defect properties and positron annihilation characteristics / Calcul de structure électronique des propriétés des défauts et caractéristiques d' annihilation de positions dans les céramiques nucléaires : identification des défauts d'équilibre et créés par l'irradiation

Wiktor, Julia 02 October 2015 (has links)
Durant l'irradiation en réacteur la fission des atomes d'actinides entraine la création de grandes quantités de défauts, qui affecte les propriétés physiques et chimiques des matériaux dans le réacteur, en particulier les matériaux combustibles ou de structure. Une des méthodes non destructives pouvant être utilisées pour caractériser les défauts induits par irradiation, vides ou contenant les produits de fission, est la spectroscopie d'annihilation de positons (SAP). Cette technique expérimentale consiste à détecter le rayonnement généré lors de l'annihilation du paire électron-positon dans un échantillon et en déduire les propriétés de la matière étudiée. Les positons peuvent être piégés dans les défauts de type lacunaire dans les solides, et en mesurant leur temps de vie et les distribution de moment du rayonnement d'annihilation, on peut obtenir des informations sur les volumes libres et les environnements chimiques des défauts. Dans ce travail, des calculs de structure électronique des caractéristiques d'annihilation de positons ont été effectués en utilisant la théorie de la fonctionnelle de la densité à deux composants (TCDFT). Pour calculer les distributions de moment rayonnement d'annihilation, nous avons implémenté les méthodes nécessaires dans le code de calcul libre ABINIT. Les résultats théoriques ont été utilités pour contribuer à l'identification des défauts d'irradiation dans deux céramiques nucléaires, le carbure de silicium (SiC) et le dioxyde d'uranium (UO2). / During in-pile irradiation the fission of actinide nuclei causes the creation of large amounts of defects, which affect the physical and chemical properties of materials inside the reactor, in particular the fuel and structural materials. Positron annihilation spectroscopy (PAS) can be used to characterize irradiation induced defects, empty or containing fission products. This non-destructive experimental technique involves detecting the radiation generated during electron-positron annihilation in a sample and deducing the properties of the material studied. As positrons get trapped in open volume defects in solids, by measuring their lifetime and momentum distributions of the annihilation radiation, one can obtain information on the open and the chemical environments of the defects. In this work electronic structure calculations of positron annihilation characteristics were performed using two-component density functional theory (TCDFT). To calculate the momentum distributions of the annihilation radiation, we implemented the necessary methods in the open-source ABINIT program. The theoretical results have been used to contribute to the identification of the vacancy defects in two nuclear ceramics, silicon carbide (SiC) and uranium dioxide (UO2).
108

Study of defects and doping in β-Ga2O3

Islam, Md Minhazul 01 September 2021 (has links)
No description available.
109

Studium mikrostruktury ultrajemnozrnných kovových materiálů metodou pozitronové anihilace / Studium mikrostruktury ultrajemnozrnných kovových materiálů metodou pozitronové anihilace

Barnovská, Zuzana January 2011 (has links)
In the presented thesis we study the changes in distribution of the size of vacancy clusters in metals processed by severe plastic deformation, so called ul- tra fine grained materials. We use a modern non-destructive method of positron annihilation spectroscopy, which is one of the few methods that allow us to inves- tigate point defects like vacancies with sizes of a few ˚A. The obtained spectra of positrons annihilating in the samples enable us to determine changes of vacancy cluster sizes depending on temperature or severity of the deformation applied on the samples. 1
110

Studium defektů v tenkých kovových vrstvách / Studium defektů v tenkých kovových vrstvách

Hruška, Petr January 2014 (has links)
In the present work Mg films prepared by RF magnetron sputtering were studied. Variable energy positron annihilation spectroscopy (VEPAS) was employed for investigation of defects in the Mg films. VEPAS characterization was combined with scanning electron microscopy and X-ray diffraction in order to determine grain size, phase composition and texture. The effect of different deposition rate and deposition temperature, annealing, various substrates and film thickness on the structure and amount of defects present in the Mg films was examined. Defect studies by VEPAS showed that positrons in studied Mg films are trapped at misfit dislocations and at vacancy-like defects in grain boundaries and their density can be reduced by the deposition at elevated temperature. 1

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