The optical efficiency of a commercially available sputter deposited spectrally selective solar absorber was improved. The main purposes were to decrease the thermal emittance, increase the solar absorbtance of the absorber and to protect the substrate from degradation due to environmental influence. The adhesion properties between the corrosion-protecting barrier and the substrate were also studied. This project was focused on process improvements that are realistic to implement in industrial production. The thermal emittance of the absorber was decreased from 0.12 to 0.06 by changing the material of the corrosion-protecting layer from nickel-chromium to copper-nickel. Copper-nickel was less sensitive to variations in the sputter parameters than nickel-chromium. A novel method that could simplify the search for alternative corrosion resistant materials with a low thermal emittance has been purposed. Since resistivity data usually exist or can easily be measured and infrared measurements require more sophisticated measurements, the Hagen-Rubens relation was investigated for copper-nickel and nickel-chromium alloys. The dc-resistivity was found to be related to the infrared emittance or the integrated thermal emittance for alloys in their solid soluble fcc phase. The solar absorbtance was increased when a graded index absorbing coating was tailored for a crossover of the reflectance from low to high reflectance at about 2.5 µm. The solar absorber graded index coating was optimized for nickel metal content in nickel oxide and a solar absorptance of 0.89-0.91 was achieved. The solar absorptance was further increased to 0.97 when an antireflection coating was added on top of the absorbing layer. Finally, extrapolation algorithms were developed to assure correct determination of the thermal emittance for coatings on glass since modern spectrometers that do not cover the complete wavelength interval required to calculate the thermal emittance of surfaces at room temperatures accurately. The error arising from the extrapolation algorithms were smaller than the noise from the optical measurements. Similar strategies can be used for other surfaces.

Ceramics constitute an important group of low-density armour materials. Their high intrinsic strength makes it possible to design ceramic armour systems capable of defeating projectiles directly on the ceramic surface. This capability, named interface defeat, signifies that the projectile material is forced to flow radially outwards on the surface of the ceramic without penetrating significantly. This thesis presents impact experiments between long-rod projectiles and ceramic targets. The projectile/target interaction was studied using flash X-ray technique. Transition velocities (the impact velocity at which interface defeat can no longer be maintained and penetration starts) were estimated for different combinations of metallic projectiles and ceramic targets and compared to critical velocities estimated on a theoretical basis. Replica scaling experiments were also performed in order to investigate the possible influence of scale. All ceramic materials tested showed a distinct transition from interface defeat to penetration. Experiments with different silicon carbides showed that the transition velocity correlated better with the fracture toughness than with the hardness of the ceramic materials. For conical projectiles, penetration occurred along a conical surface crack and at a lower transition velocity than that observed for cylindrical projectiles. Experiments with unconfined alumina targets in different scales showed only a slight increase in dimensionless final penetration with length scale. A unique transition velocity seems to exist for each combination of projectile, target material and target configuration. This velocity was found to depend on both the strength (hardness) and the brittleness (fracture toughness) of the ceramic. The lower transition velocity of conical projectiles compared with cylindrical ones is mainly due to the radially expanding load and the penetration of projectile material into surface cracks. The results of the experiments in different scales indicate that replica scaling is valid for penetration in ceramics.

Microengineering has developed a broad range of production techniques to reduce size, increase throughput, and reduce cost of electrical and mechanical devices. The miniaturisation has also entailed entirely new opportunities. In this work, a piezoresistive silicon sensor measuring mechanical deformation has been designed and fabricated with the help of microengineering. Due to the large variety of used processes, this device can serve as a survey of techniques in this field. Four basic process categories are recognised: additive, subtractive, modifying, and joining methods. The last category, joining methods, has previously been the least investigated, especially when it comes to compatibility with the other categories. The adaptability of wet chemical etching to established silicon wafer bonding technique has been investigated. Further, phenomena related to oxygen plasma pre-treatment for direct bonding has been investigated by blister bond adhesion tests, X-ray photoelectron spectroscopy, and atomic force microscopy. Wafer bonding has been adapted to monocrystalline quartz. For wet chemical pre-treatment, characteristics specific for quartz raise obstacles. Problems with limited allowable annealing temperature, low permeability of water released in the bond at annealing, and electrostatic bonding of particles to the quartz surface, have been studied and overcome. The influence of internal bond interfaces on resonators has been investigated. Chemical polishing of quartz by ammonium bifluoride has been experimentally investigated at high temperatures and concentrations. Chemometrical methods were used to search for optimum conditions giving the lowest surface roughness. These extreme conditions showed no extra advantages. Adhesion quantification methods for wafer bonding have been comprehensively reviewed, and augmentations have been suggested. The improved techniques’ usefulness for three areas of use has been forecasted: general understanding, bonding scheme optimisation, and quality control. It was shown that the quality of measurements of all commonly used methods could be dramatically improved by small means.

In recent years portable electronic devices, such as mobile phones and personal digital assistants, have increased the demand for high performance displays with low power consumption. An interesting candidate with the potential of fulfilling these demands is the reflective single-polarizer surface controlled bistable twisted nematic liquid crystal display. The main focus of this work involves the optical properties of displays based on these bistable structures. In the investigations, the display is considered as an integrated optical system, containing not only the liquid crystal cell, but also components such as polarizers and retardation films. The specific aim of the thesis was to derive new optical modes of the reflective single-polarizer bistable twisted nematic device using the Jones matrix method to study the interaction between the polarization of light and the optically anisotropic media. The electro-optical properties of the derived modes have been studied and evaluated both theoretically and experimentally. The modes possess excellent brightness and high contrast ratio. By introducing a quarter-wave retardation film into the optical configuration, the contrast ratio can be significantly increased by preventing spectral leakage of light in the dark state. To experimentally realize the derived optical modes, special layers for the alignment of the liquid crystal molecules on the cell substrate surface have been proved needed. Therefore, also the photo-alignment technology of nematic liquid crystals on novel alignment materials has been studied with the aim to control liquid crystal cell parameters such as pretilt angle and anchoring energy, both critical for the bistable switching. The results of this thesis will increase the understanding of the optical properties of the reflective single-polarizer bistable twisted nematic liquid crystal display and will be valuable when considering this type of device for practical applications.

Complex moduli and Poisson’s ratio have been estimated using extensional and torsional wave experiments. The data were used for assessment of linearity and isotropy of two polymers, polymethyl methacrylate (PMMA) and polypropylene (PP). The responses of both materials were found to be close to linear and isotropic. A statistical analysis of different estimation approaches for complex modulus and Poisson’s ratio was conducted. It was shown that a joint estimation of complex modulus and Poisson’s ratio improves the estimated results. Considerable improvement was achieved in the frequency range 5-15 kHz for Poisson’s ratio. A non-equilibrium split Hopkinson pressure bar (SHPB) procedure for identification of complex modulus has been developed. Two simplified procedures were also established. Both overestimated the magnitude of the complex modulus. The complex modulus of PP was identified using PMMA and aluminium bars, and the estimated complex modulus was in good agreement with published results. The procedure was found to be accurate regardless of the specimen size or the specimen-to-bar impedance ratio. The procedure was also used to analyze the mechanical response of four compacted pharmaceutical tablet materials. A Debye-like relaxation was observed for all tested materials. Utilizing SHPB effectively requires knowledge about the impact process that is normally used for excitation. Therefore the impact between a cylindrical striker and a long cylindrical bar of viscoelastic material was studied theoretically and experimentally. Strains measured at three locations along a PMMA bar impacted by strikers of the same material agreed well with the theoretical results. A method for identification of complex shear modulus from measured shear strains on a disc subjected to a transient torque at its centre has been established. The two-dimensional wave solutions used are exact in the sense of three-dimensional theory. The results from experimental tests with different load amplitudes and durations agree well with each other.

Thermonuclear fusion is a promising energy source for the future. If an economically efficient thermonuclear reactor would be built it has to be a cheap, safe, and highly productive electric power plant, or, a heating plant. The emphasis of this thesis is on the single cell mirror trap with a marginally stable minimum B vacuum magnetic field, the straight field line mirror field, which provides MHD stability of the system, absence of the radial drift even to the first order in plasma β , and a reduced magnetic flux tube ellipticity. Strong density depletion at the mirrors is proposed as a mean to build up a strong potential barrier for the electrons and thereby increase the electron temperature. Conditions to obtain an energy gain factor Q>10 are briefly analyzed. Current coils which could generate the derived magnetic field are proposed. A sloshing ion distribution function is constructed for the three dimensional ‘straight line mirror field’. The gyro centre Clebsch coordinates are found to be a new pair of motional invariants for this magnetic field. The gyro centre Clebsch coordinate invariants can be used to obtain complete solutions of the Vlasov equation, including the diamagnetic drift. These solutions show that the equilibria satisfy the locally omniginuity criterion to the first order in β . Contributions of the plasma diamagnetism to the magnetic flux tube ellipticity are studied for the straight field line mirror vacuum magnetic field and a sloshing ion distribution. Computations employing ray tracing have shown that there is a modest increase in the ellipticity, but the effect is small if β <0.2 . Adiabatic charged particle motion in general field geometry has been studied. A set of four independent stationary invariants, the energy, the magnetic moment, the radial drift invariant, and the bounce average parallel velocity is proposed to describe adiabatic equilibria.

<p>Solar electricity is a promising energy technology for the future, and by using reflectors for concentrating solar radiation onto photovoltaic cells, the cost per produced kWh can be significantly reduced. The optical efficiency of a concentrating system determines the fraction of the incident energy that is transferred to the cells and depends on the optical properties of the system components. In this thesis, low-concentrating photovoltaic and photovoltaic-thermal systems with two-dimensional parabolic reflectors were studied and optimised, and a new biaxial model for the incidence angle dependence of the optical efficiency was proposed.</p><p>Concentration of light generally results in high cell temperatures, and the uneven irradiance distribution on cells with parabolic reflectors leads to high local currents and temperatures, which reduce fill-factor and voltage. Cooling the cells by means of water increases the voltage and makes it possible to utilize the thermal energy. The performance of a 4X concentrating photovoltaic-thermal system was evaluated. If operated at 50°C, this system would produce 250 kWh_electrical and 800 kWh_thermal per m² cell area and year. Optical performance can be increased by 20% by using better reflectors and anti-reflectance glazing.</p><p>Low-concentrating photovoltaic systems for façade-integration were studied and optimised for maximum annual electricity production. The optimisation was based on measured short-circuit currents versus solar altitude. Measurements were performed outdoors and in a solar simulator. It was found that the use of 3X parabolic reflectors increases the annual electricity production by more than 40%. High solar reflectance is crucial to system performance but by using a low-angle scattering reflector, the fill-factor and power are increased due to a more even irradiance on the modules.</p><p>Long-term system performance depends on the durability of the components. The optical properties and degradation of reflector materials were assessed using spectrophotometry, angular resolved scatterometry, Fresnel modelling, optical microscopy, and surface profilometry before and after ageing. The degradation of reflectors was found to be strongly dependent on material composition and environmental conditions. Back surface mirrors, all-metal reflectors, and polymer-metal laminates degraded in different ways, and therefore accelerated ageing must be tailored for testing of different types of reflector materials. However, new types of reflector laminates showed a potential for increasing the cost-effectiveness of low-concentrating solar energy systems.</p>

This thesis presents experimental and modelling research on atmospheric pressure hollow cathodes and hollow electrodes. Experiments with the hybrid hollow electrode activated discharge (H-HEAD), which is a combination of a hollow cathode and a microwave plasma source, is presented. The experiments show that this source is able to produce long plasma columns in air and nitrogen at atmospheric pressure and at very low gas flow rates. Measurements of the vibrational temperature of the nitrogen molecules are also presented in this thesis. The vibrational temperature is an indication of the electron temperature in the plasma, an important characteristic of the plasma. Modelling work on the hollow cathode at atmospheric pressure with fluid equations is also presented. It is shown that the inclusion of fast and secondary electrons, characteristic of the hollow cathode plasmas, increases the sheath width. The sheath width was found to be of the order of 100 μm. By modelling the plasma as highly collisional by using the drift-diffusion approximation, it was shown that the increase in sheath thickness was larger at lower pressures than at higher pressures. Still, the sheath width can be of the order of 100 μm. A pulsed atmospheric plasma in a hollow electrode geometry was also modelled by the drift-diffusion fluid equations, with the addition of the energy equation for electrons. Rate and transport coefficients for the electrons were calculated from the solution to the Boltzmann equation as functions of mean electron energy. The dynamics of the plasma at pulse rise time showed large electron density and mean energy peaks at the cathode ends, but also that these quantities were enhanced at the centre of the discharge, between the cathode plates.

A parallel finite element code with adaptive meshing was developed and used to study three dimensional, time-dependent fluid flows caused by thermocapillary convection as well as temperature and dopant distribution in fusion welding and floating zone crystal growth. A comprehensive numerical model of the three dimensional time-dependent fluid flows in a weld pool had been developed. This model considered most of the physical mechanisms involved in gas tungsten arc welding. The model helped obtaining the actual chaotic time-dependent melt flow. It was found that the fluid flow in the weld pool was highly complex and influenced the weld pool’s depth and width. The physicochemical model had also been studied and applied numerically in order to simulate the surfactant adsorption onto the surface effect to the surface tension of the metal liquid in a weld pool. Another model, a three dimensional time-dependent, with adaptive mesh refinement and coarsening was applied for simulating the effect of weak flow on the radial segregation in floating zone crystal growth. The phase change equation was also included in this model in order to simulate the real interface shape of floating zone. In the new parallel code, a scheme that keeps the level of node and face instead of the complete history of refinements was utilized to facilitate derefinement. The information was now local and the exchange of information between each and every processor during the derefinement process was minimized. This scheme helped to improve the efficiency of the parallel adaptive solver. / QC 20100527

Flexible printed circuit boards (flex PCBs) are used in a wide range of electronic devices today due to their light weight, bendability, extensive wiring possibilities, and low-cost manufacturing techniques. The general trend in the flex PCB industry is further miniaturization alongside increasing functionality per device and reduced costs. To meet these demands, a new generation of low cost manufacturing technologies is being developed to enable structures with smaller lateral dimensions and higher packing densities. Wet etching is today the most cost-efficient method for producing a large number of through-foil structures in flex PCBs. However, conventional wet etch techniques do not allow for through-foil structures with aspect ratios over 1 – a fact that either necessitates thin and mechanically weak foils or puts severe limitations on the packing density. The fabrication techniques presented in this thesis allow for through-foil structures with higher aspect ratios and packing densities using wet etching. To achieve high aspect ratios with wet etching, the flex PCB foils are pre-treated with irradiation by swift heavy ions. Each ion that passes through the foil leaves a track of damaged material which can be subsequently etched to form highly vertical pores. By using conventional flex PCB process techniques on the porous foils, high aspect ratio metallized through-foil structures are demonstrated. The resulting structures consist of multiple sub-micrometer sized wires. These structures are superior to their conventional counterparts when it comes to their higher aspect ratios, higher possible packing densities and low metallic cross-section. Furthermore, metallized through-foil structures with larger areas and more complicated geometries are possible without losing the mechanical stability of the foil. This in turn enables applications that are not possible using conventional techniques and structures. In this thesis, two such applications are demonstrated: flex PCB vertical thermopile sensors and substrate integrated waveguides for use in millimeter wave applications. / wisenet