Ce travail démontre l'utilité des propriétés photothermiques dans le proche Infrarouge (NIR) des complexes de nickel-bis(dithiolène) neutres pour des applications en science des matériaux et biotechnologies. Des complexes Ni-bis(dithiolène) neutres hydrophiles et hydrophobes ont été élaborés et leur effet photothermique, sous irradiation laser NIR, a été quantifié pour la première fois. Grâce à cette propriété remarquable et à leur grande stabilité sous irradiation, il a été mis en évidence, que ces complexes pouvaient trouver des applications pour la thérapie photothermique, la libération contrôlée de médicament mais également pour le développement de nanomatériaux photosensibles à un stimulus externe. En effet, cet effet photothermique, sous irradiation laser NIR, permet de détruire des cellules cancéreuses, d'augmenter la perméabilité de nanoparticules polymériques ou de liposomes contenant des principes actifs et de désagréger des métallogels à base de complexes Ni-bis(dithiolène). Enfin, nous avons montré que les complexes [Ni(R2-timdt)2]0 ayant une haute efficacité photothermique sont de nouveaux candidats très prometteurs pour ce type d'applications. / The photothermal properties in the near Infrared (NIR) of neutral nickel-bis(dithiolene) complexes were used in materials science and for the first time in biotechnology. Hydrophilic and hydrophobic neutral Ni-bis(dithiolene) complexes were developped and for the first time, their photothermal effect under NIR laser irradiation was quantified. Thanks to this remarkable property and their high stability under irradiaton, it has been demonstrated that these complexes could find applications to photothermal therapy, controlled drug delivery but also in the developpement of stimuli responsive nanomaterials. Indeed, this photothermal effect, under NIR laser irradiation, allow to destroy malignant cells, increase the permeability of polymeric nanoparticles or liposomes containing active ingredients and disintegrate métallogels based on Ni-bis(dithiolene) cores. Finally, we showed that the [Ni(R2-timdt)2]0 complexes having higher phothothermal activity are very promising new candidates for these applications.

<p>Ba&scaron;tenska jagoda (Fragaria x ananassa Duch.), poznata po svom delikatnom mirisu, ukusu i bogastvu u vitaminima i mineralima, gaji se u svim regionima sveta. Jagode, kao voće sa visokom proizvodnom i upotrebnom vredno&scaron;ću, zahtevaju visoka ulaganja rada i metrijala po jedinici povr&scaron;ine. Imajući ovo u vidu, jagoda zahteva posebnu pažnju u svim etapama proizvodnje (gajenja) tj. od zasnivanja jagodnjaka do berbe i prodaje. Cilj ovog istraživanja je, utvrđivanje investicione vrednosti zasnivanja i ostvarenih ekonomskih efekata koji se postižu u proizvodnji jagode karatkog i neutralnog dana u uslovima jugo-zapadnog Ontarija u Kanadi. Najveća proizvodnja u svetu se ostvaruje u severnoj hemisferi (90,5%). Vodeće zemlje po proizvodnji jagode su: SAD, &Scaron;panija, Japan i Republika Koreja. Ove četiri zemlje čine 47,2% od ukupne svetske proizvodnje. Najveće povećanje kapaciteta jagode postignuto je u južnoj hemisferi. Za prikupljanje podataka o tehnologiji gajenja i investicionoj vrednosti ulaganja u proizvodnji jagode, kori&scaron;ćena je metoda anketiranja. U anketi je učestvovalo 19. proizvođača jagoda kratkog i 9. neutralnog dana u toku 2011. i 2012. godine. Upitnikom su prikupljeni podaci o tehnologije gajenja jagode po radnim operacijama, upotrebi materijala, ma&scaron;ina i radne snageTakođe, evidentirane su i strane usluge, ostvareni prosečni prinosi, prodajni kanali i procenat uče&scaron;ća u ukupnoj prodaji i postignuta prosečna cena.</p><p>Na osnovu prikupljenih podataka izračunati su tro&scaron;kovi zasnivanja jagodnjaka, redovne nege i brbe u prvoj i drugoj godini i ostvareni profit za obe grupe jagode. Jagode kratkog dana se isključivo gaje u redovima na otvorenom, a jagode neutralnog dana na bankovima obloženim belom polietilenskom folijom i instaliranim kap-po-kap sistemom za navodnjavanje. Najveći procenat (70%) jagode kratkog dana se prodaje direktno kupcima na gazdinstvu ili lokalnim pijacama, a 55% jagode neutralnog dana se prodaje kanalima veleprodaje. U proseku, proizvođači jagode kratkog dana su postigli profit $CAD 22.300/ha (29,10% od ukupnog prihoda), a proizvođači jagode neutralnog dana $CAD 37.962/ha (29,50% od ukupnog prihoda). Znači, proizvodnja obe grupe jagoda je veoma profitabilna, i postoji realna osnova za dalje povećanje profita.</p> / <p>The cultivated strawberries (Fragaria x ananassa Duch.), known for its delicate fragrance, flavour, and rich vitamin and mineral content, can be grown in most arable regions of the globe. Strawberry production, like many high-value crops, is resource and labour-intensive. Therefore, attention to detail is required at all stages of strawberry production, from establishment to harvest and marketing. The objective of this study was to determn the cost of strawberry establishment and achived economic effects of short-day and day-neutral strawberry production in south-western Ontario, Canada. The most of the production is located in the northern hemisphere (90.5%). The leading strawberry producing nations are USA, Spain, Japan and Republic of Korea. These four countries counted for 47.2% of all world&rsquo;s strawberry production. The largest increase in strawberry production capacity was recorded in the southern hemisphere. For data collection on procedure for growing a crop of strawberries and investment in strawberry production a survey technique was used. In survey participated 19 short-day and 9 day-neutral strawberry growers and was conducted in 2011 and 2012. The survey recorded strawberry production procedures, materials, equipment and labour use. Also, growers reported external<br />Mr Dragan M. Galić - Doktorska disertacija<br />vii<br />services used, achieved yields, marketing channels of sale, percent of each channel and achieved average sale prices. Based on collected information the cost of establishment, regular care, harvest in first and second year and total income were calculated for both groups of strawberries. Short-day strawberries are grown on matted-rows, while day-neutral on raised beds on white plastic with trickle irrigation installed. Most (70%) of the short-day crop was sold via direct sale (&ldquo;U-pick&rdquo;, ready-picked and farmers&rsquo; market), while 55% of day-neutral strawberries were sold in wholesale. On average, growers of short-day strawberries generated a profit of 22,300 $CAD/ha (29.10% of total income), and growers of day-neutral strawberries 37,962 $CAD/ha (29.50% of total income). Based on this study, both groups of strawberries in Ontario are highly profitable and with great potential for frofit increase.</p>

This dissertation investigates CsI(Tl) pulse shape discrimination (PSD) as a novel experimental technique to improve challenging areas of particle identification at high energy $e^+ e^-$ colliders using CsI(Tl) calorimeters. In this work CsI(Tl) PSD is implemented and studied at the Belle II experiment operating at the SuperKEKB $e^+ e^-$ collider, representing the first application of CsI(Tl) PSD at a $B$ factory experiment. Results are presented from Belle II as well as a testbeam completed at the TRIUMF proton and neutron irradiation facility. From the analysis of the testbeam data, energy deposits from highly ionizing particles are shown to produce a CsI(Tl) scintillation component with decay time of $630\pm10$ ns, referred to as the hadron scintillation component, and not present in energy deposits from electromagnetic showers or minimum ionizing particles. By measuring the fraction of hadron scintillation emission relative to the total scintillation emission, a new method for CsI(Tl) pulse shape characterization is developed and implemented at the Belle II experiment's electromagnetic calorimeter, constructed from 8736 CsI(Tl) crystals. A theoretical model is formulated to allow for simulations of the particle dependent CsI(Tl) scintillation response. This model is incorporated into GEANT4 simulations of the testbeam apparatus and the Belle II detector, allowing for accurate simulations of the observed particle dependent scintillation response of CsI(Tl). With $e^\pm$, $\mu^\pm$, $\pi^\pm$, $K^\pm$ and $p/\bar{p}$ control samples selected from Belle II collision data the performance of this new simulation technique is evaluated. In addition the performance of hadronic interaction modelling by GEANT4 particle interactions in matter simulation libraries is studied and using PSD potential sources of data vs. simulation disagreement are identified. A PSD-based multivariate classifier trained for $K_L^0$ vs. photon identification is also presented. With $K_L^0$ and photon control samples selected from Belle II collision data, pulse shape discrimination is shown to allow for high efficiency $K_L^0$ identification with low photon backgrounds as well as improved $\pi^0$ identification compared to shower-shape based methods. / Graduate

Cette thèse porte sur l’étude de la production de surface des ions négatifs (IN) pour des applications dans la fusion thermonucléaire. Ce travail a été réalisé à l'aide d'une source plasma PHISIS. Les IN formés en surface de l'échantillon sont collectés et analysés avec un spectromètre de masse (SM). La fonction de la distribution en énergie des ions négatifs FDEIN est mesurée. Dans cette thèse, une technique de polarisation DC pulsée est introduite pour permettre l'étude de la production d'IN en surface sur des échantillons isolants comme le diamant. Un modèle qui calcule le taux de changement de la variation de la tension sur une surface isolante polarisée en mode pulsé est développé. De façon surprenante, la production d’IN en surface sur un diamant dopé au bore ou non dopé est beaucoup plus élevée en mode pulsé qu'en mode continu. Il est traité également la production d’IN en surface dans les conditions de faible tension de polarisation. Le meilleur rendement d’IN mesuré à faible polarisation est obtenu avec du diamant dopé au bore (BDD) et il est 2 fois plus élevé que celui mesuré sur HOPG (high oriented pyrolitic graphite). L'analyse de la production d’IN en surface à différents polarisations pour différents matériaux a été effectuée afin de corréler l'évolution du rendement d’IN aux changements d'état de surface. Une étude approfondie de la production en surface d'IN a été réalisée sur la surface de Nanoporous 12 CaO. 7Al2O3 electride surface. L'influence des conditions expérimentalles sur le rendement en IN a été étudiée. Dans cette contribution, nous montrons que ce matériau pourrait potentiellement être utilisé dans les sources d'ions négatifs sans césium / This thesis deals with negative ions (NI) surface production for applications in thermonuclear fusion. This work was conducted using a plasma source PHISIS. NI formed on a negatively biased sample surfaceare collected and analyzed with energy mass spectrometer (MS). Negative ion distribution function NIEDF is measured. A SIMION calculation was done to have a complete idea about MS transmission effect on the NIEDF. In the course of this thesis, a DC pulsed bias technique is introduced to enable the study of negative ion surface production on insulating samples as non-doped diamond layers. A model that calculate the rate of change of bias on insulator surface biased in pulsed mode is developed. Surprisingly, negative-ion surface production on boron-doped or non-doped diamond is much higher in pulsed mode than in continuous mode. This thesis deals also with negative ion surface production in low bias condition. The best NI yield measured at low bias is obtained with Boron doped diamond (BDD) ant it is 2 times higher than the one measured on HOPG (highly oriented pyrolytic graphite) surface. Analysis of NI surface production at different surface bias for different material were performed in order to correlate the NI yield evolution to the surface state changes.An extensive study of NI surface production was performed on Nanoporous 12CaO.7Al2O3 electride surface. The influence of surface temperature, bias and plasma exposure time on negative-ion yield was investigated. In this contribution, we show that the electride material has potentials to be used as a production surface in negative ion sources devoted to nuclear fusion application

Spatially explicit ecological models rely on spatially exhaustive data layers that have scales appropriate to the ecological processes of interest. Such data layers are often categorical raster maps derived from high-resolution, remotely sensed data that must be scaled to a lower spatial resolution to make them compatible with the scale of ecological analysis. Statistical functions commonly used to aggregate categorical data are majority-, nearest-neighbor- and random-rule. For heterogeneous landscapes and large scaling factors, however, use of these functions results in two critical issues: (1) ignoring large portions of information present in the high-resolution grid cells leads to high and uncontrolled loss of information in the scaled dataset; and (2) maintaining classes from the high-resolution dataset at the lower spatial resolution assumes validity of the classification scheme at the low-resolution scale, failing to represent recurring mixes of heterogeneous classes present in the low-resolution grid cells. The proposed new scaling algorithm resolves these issues, aggregating categorical data while simultaneously controlling for information loss by generating a non-hierarchical, representative, classification system valid at the aggregated scale. Implementing scaling parameters, that control class-label precision effectively reduced information loss of scaled landscapes as class-label precision increased. In a neutral-landscape simulation study, the algorithm consistently preserved information at a significantly higher level than the other commonly used algorithms. When applied to maps of real landscapes, the same increase in information retention was observed, and the scaled classes were detectable from lower-resolution, remotely sensed, multi-spectral reflectance data with high accuracy. The framework developed in this research facilitates scaling-parameter selection to address trade-offs among information retention, label fidelity, and spectral detectability of scaled classes. When generating high spatial resolution land-cover maps, quantifying effects of sampling intensity, feature-space dimensionality and classifier method on overall accuracy, confidence estimates, and classifier efficiency allowed optimization of the mapping method. Increase in sampling intensity boosted accuracies in a reasonably predictable fashion. However, adding a second image acquired when ground conditions and vegetation phenology differed from those of the first image had a much greater impact, increasing classification accuracy even at low sampling intensities, to levels not reached with a single season image.

Orientador: João Francisco Galera Monico / Resumo: A tecnologia Global Navigation Satellite Systems (GNSS) tem sido amplamente utilizada em posicionamento, desde as aplicações cotidianas (acurácia métrica), até aplicações que requerem alta acurácia (poucos cm ou dm). Quando se pretende obter alta acurácia, diferentes técnicas devem ser aplicadas a fim de minimizar os efeitos que o sinal sofre desde sua transmissão, no satélite, até sua recepção. O sinal GNSS ao se propagar na atmosfera neutra (da superfície até 50 km), é afetado por gases hidrostáticos e vapor d’água. A variação desses constituintes atmosféricos causa uma refração no sinal que gera um atraso. Esse atraso pode ocasionar erros na medida de no mínimo 2,5 m (zenital) e superior a 25 m (inclinado). A determinação do atraso na direção inclinada (satélite-receptor) de acordo com o ângulo de elevação é realizada pelas funções de mapeamento. Uma das técnicas para o cálculo do atraso é o traçado de raio (ray tracing). Essa técnica permite mapear o caminho real que o sinal percorreu e modelar a interferência da atmosfera neutra sobre esse sinal. Diferentes abordagens podem ser usadas para obter informações que descrevem os constituintes da atmosfera neutra. Dentre as possibilidades pode-se citar o uso de medidas de radiossondas, modelos de previsão do tempo e clima (PNT), medidas GNSS, assim como modelos teóricos. Modelos de PNT regionais do Centro de Previsão de Tempo e Estudos Climáticos (CPTEC) do Instituto Nacional de Pesquisas Espaciais (INPE) apresentam-se como um... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: Global Navigation Satellite Systems (GNSS) technology has been widely used in positioning, from day-to-day applications (metric accuracy) to applications that require high accuracy (few cm or dm). For high accuracy, different techniques may be applied to minimize the effects that the signal suffers from its transmission on the satellite to its reception. GNSS signal when propagating in the neutral atmosphere (from surface up to 50km) is influenced by hydrostatic gases and water vapor. The variation of these atmospheric constituents causes a refraction in the signal that generates a delay. This delay may cause errors of at least 2.5 m (zenith) and greater than 25 m (slant). The determination of the delay in the slanted direction (satellite-receiver) according to the elevation angle is performed by the mapping functions. One of the techniques for calculating the delay is raytracing. This technique allows us to map the actual path that the signal has traveled and to model the interference of the neutral atmosphere on it. Different approaches can be used to obtain information describing the neutral atmosphere constituents - temperature, pressure and humidity. The possibilities include the use of radiosonde measurements, weather and climate models (NWP), GNSS measurements, as well as theoretical models. Regional NWP models from the Center Weather Forecasting and Climate Studies (CPTEC) of the National Institute for Space Research (INPE) are a good alternative to provide atmospheri... (Complete abstract click electronic access below) / Doutor

This dissertation begins with a discussion of the rediscovery and rehabilitation of masks as tools of performance and pedagogy in Western theatre over the past century, considering the work of various theorists, directors, teachers and performers in whose work the mask occupies a significant position. Discussion then focuses on the development of the neutral mask as an object and as a paradigm of pedagogy for the actor over the past eighty years and undertakes a comparative investigation of the concept of neutrality as a performant state. The discussion takes in the teaching of Jacques Copeau, Etienne Decroux and Jacques Lecoq, and extends to the theories of Eugenio Barba, considering the possible parallels between Barba's 'pre-expressive' state and the state of neutrality which the mask assists to develop in the actor. The dissertation further proposes that the term 'performative liminality' is an appropriate term to adopt for this performant state, and makes this proposal with reference to the theories of anthropologist Victor Turner regarding the liminal state. The practice-as-research component of the project sought to investigate and document the various uses of the neutral mask and its application to the creative processes of the actor, and aimed to provide qualitative analysis and evaluation of the neutral mask when used in a developmental workshop environment. The dissertation contains a full account of the practice component of the project and details the processes used to investigate the neutral mask, offering analysis drawn from the inside experiences of the actors and the outside observations of the researcher. Within that analysis is a consideration of the neutral mask as a tool for developing the scenic presence of the actor. / Masters Thesis

本研究依據Hu(1998)的理論模型來探討證券市場的存在對所得分配的影響，並且以跨國橫斷面迴歸方式進行實證分析，利用Deininger and Squire(1996)所整理的吉尼係數資料，探討五十二國1986-1990年間的平均股市發展、資本市場完全程度與所得分配之間的關係；此外，我們也對Kuzents的倒U型假設進行驗證，以分析不同經濟發展程度與所得分配之間的關係；最後，本研究進一步探討先進工業化與開發中子樣本群中，股票市場對所得分配的影響是否不同。 模型推導的結論為股市的存在並不會使所得分配惡化，產生惡化效果的原因是因為資本市場的不完全性，使窮人受限於借貸限制與賣空限制，無法取得公平的投資機會；而投資人對股市看法的分歧也是造成所得分配惡化的原因。實證分析的結果與理論模型之結論一致，也就是股市的發展並不會惡化所得分配，甚至有益於所得分配，而資本市場限制愈大的國家其所得分配愈為惡化；Kuzents的倒U型假設也獲得了支持。股市的發展程度與資本市場的完全性對開發中國家的所得分配有顯著的影響，然而這種效果在先進工業化國家中並不明顯；而教育對先進國家之所得分配有顯著影響力，對開發中國家則無。本研究的結果隱含著政府除了消除貧窮與實行所得重分配政策外，更應致力於健全資本市場，將市場的不完全性降到最低，讓市場上的資訊充分流通，使每個投資人都能得到公平的投資機會，如此便可改善所得分配。

現實社會中，由於人並非如傳統學派所聲稱完全理性制定決策，自1980年以來即產生諸多傳統學派無法說明的現象，因此行為財務學派興起。本篇導入行為財務學的模型，探討當經理人具過度自信與過度樂觀特質時，經理人的特性會如何影響公司價值。研究假設當經理人為風險中立者，可達到公司價值極大化first-best value。若經理人為風險趨避，產生的效用成本將使其無法達成此目標，但此時經理人若具過度自信，則可抵消風險趨避帶來的公司價值減損，而達成股東所希望達到的公司價值極大。除此之外，根據Heaton(2003)模型所聲稱，過度樂觀的經理人無法達成公司價值極大，而本篇修改其模型，得出當公司經理人具過度樂觀特性，是有可能符合股東利益，而達到公司價值極大化的目標。 / In real world, people don’t make decisions depend on rationality. Therefore, there exists many facts that traditional researchers can’t explain since 1980’s and that’s why behavioral finance school arises. In this paper, we use behavioral finance models to discuss when managers are overconfident or optimistic, how their personality will affect the value of company. We find that when a manager is risk-neutral, he can maximize the firm value that we called “first-best value.” However, when a manager is risk-averse, the utility cost will be the huge obstacle to attain the goal. However, if the manager is overconfident, this characteristic will counterbalance the drawback that risk-averse will decrease company value. In addition, according to Heaton’s (2003) model, an optimistic manager can’t maximize firm value. This paper modifies Heaton’s model and finds that when managers are optimistic, it is likely that a manager can meet shareholder’s needs and maximize the firm value.

Quanto EIA是一種具有選擇權特性且能連結至外幣投資的保險年金商品.以往針對權益連動年金所做的文獻中,均未考慮Quanto的特性.本文利用風險中立評價法求算出六種具有Quanto特性的鎖高型權益連動年金商品的評價公式,並進一步利用數值分析來探討各個契約及市場參數對契約價值的影響. / Quanto Ratchet EIAs link to foreign investments and provide options-like properties. The literature covers the pricing of the EIAs that are not quantos. This paper intends to fill the hole. To derive the pricing formulas, we added an exchange rate model as well as a foreign risk-free rate model to the pricing framework of Black and Scholes. Our formulas cover quanto ratchet EIA products for both compound and simple versions that may have a return cap and employ two types of geometric return averaging. We further provide numerical analyses on how contract features and market parameters affect the contract value.