The change in climate as a consequence of anthropogenic activities is a subject ofmajor concerns. In order to reduce the amount of greenhouse gas emissions inthe atmosphere, the utilization of renewable, fossil-free power generationapplications becomes inevitable. Geothermal and solar energy play a major rolein covering the increased demand for renewable energy sources of today’s andfuture’s society. A special focus hereby lies on the Concentrating Solar Powertechnologies and different geothermal concepts. The costs for producingelectricity through Concentrating Solar Power and therefore Parabolic Trough Collectorsas well as geothermal conversion technologies are still comparatively high. Inorder to minimize these expenses and maximize the cycle’s efficiency, thepossible synergies of a hybridization of these two technologies becomeapparent. This thesis therefore investigates the thermodynamic and economicbenefits and drawbacks of this combination from a global perspective. For that,a Parabolic Trough Collector system is combined with the geothermal conversionconcepts of Direct Steam, Single and Double Flash, Organic Rankine as well asKalina Cycles. The solar integrations under investigation are Superheat,Preheat and Superheat & Reheat of the geothermal fluid. The thermodynamicanalysis focuses on the thermal and utilization efficiencies, as well as therequired Parabolic Trough Collector area. The results indicate that in the caseof the Superheat and Superheat & Reheat setup, the thermal efficiency canbe improved for all geothermal concepts in comparison to their correspondinggeothermal stand-alone case. The Preheat cases, with the major contributionfrom solar energy, are not able to improve the cycle’s thermal efficiencyrelative to the reference setup. From an exergy perspective the findings varysignificantly depending on the applied boundary conditions. Still, almost allcases were able to improve the cycle’s performance compared to the referencecase. For the economic evaluation, the capital investment costs and thelevelized costs of electricity are studied. The capital costs increasesignificantly when adding solar energy to the geothermal cycle. The levelizedelectricity costs could not be lowered for any hybridization case compared tothe reference only-geothermal configurations. The prices vary between20.04 €/MWh and 373.42 €/MWh. When conducting a sensitivity analysison the solar system price and the annual mean irradiance, the Kalina Superheatand Superheat & Reheat, as well as the Organic Rankine Preheathybridizations become cost competitive relative to the reference cases.Concluding, it is important to remark, that even if the hybridization of the ParabolicTrough and the different geothermal concepts makes sense from a thermodynamicperspective, the decisive levelized costs of electricity could not be improved.It is, however, possible that these costs can be further reduced under speciallocal conditions, making the addition of Parabolic Trough solar heat tospecific geothermal concepts favorable.

A significant portion of the reinforced concrete railway bridges in Sweden are reaching their designed lifespan and are scheduled to be demolished and replaced in the upcoming years. To limit the econom-icand environmental impact related to the replacement of existing railway infrastructure, a comprehen-siveevaluation of their capacity is required with the aim of extending its lifespan. In fact, experimental evidence has shown that some of these bridges may have a higher capacity than previously determined due to the conservative assumptions used during their design. The proper stress distribution pattern at the ballast-concrete interface is among the factors that need to be studied, as research on the topic has shown that some of the available guidelines to calculate it can produce conservative results. In this paper, available analytical models for computing the internal forces in concrete bridges due to train axle loads are compared to a numerical model calibrated using the experimental results obtained from the test of ballasted reinforced concrete trough bridge, a typical structural type found in Sweden, and existing research. As a first step, a literature review of existing numerical modeling strategies for ballast-edconcrete railway structures (e.g., finite element models, discrete element models, and their combina-tion)is conducted. Then, the most appropriate numerical modelling strategy is identified and used to develop the numerical model of the bridge, including the ballast. Finally, results of contact pressure and vertical stresses in the numerical model are compared to those obtained analytically.

Reducing carbon emissions in our societies requires a massive shift towards renewables. In Sweden, biomass is the dominant source for the district heat production, but growing demand for biomass in other sectors may cause pressure on it. In this context, this thesis explores the possibility to supply heat with solar parabolic thermal collectors to a district heating system in Kosta, a locality in Lessebo municipality, Kronoberg county. The simulations and calculations are based on the locally available hourly data of weather conditions, supply and return temperatures of district heat and heat demand profiles. The energy production as well as the profitability of the installation is evaluated through the calculation of carbon abatement costs, considering that heat supplied from solar collectors spares biomass which can be made available for decarbonating the power sector. Results have shown that a solar installation that cover most of the heat demand during the months of summer, thus 10% of the annual heat demand, can be profitable. This study also investigates different scenarios with increased costs for the biomass resource to simulate the growing pressure around this resource and concludes that with growing costs of the biomass resource, solar application will become more attractive, allowing to make larger solar district heating plants profitable.

Made available in DSpace on 2016-04-28T14:16:41Z (GMT). No. of bitstreams: 1 Renata Mourao Crecchi.pdf: 12889816 bytes, checksum: 1c44d7bd5410bdc474064fee2a6f44a6 (MD5) Previous issue date: 2009-06-17 / Secretaria da Educação do Estado de São Paulo / The present work focuses on illustrations of the pneumatic trough used by Lavoisier. Verify its role as an icon of modern chemistry. For this purpose we have analysed images of this apparatus presented in chemistry textbooks printed during the first half of XX century, regarding its relations to the text and also to ideas concerning the origins of modern chemistry. The selected primary sources include the Traité Elementaire de Chimie de Lavoisier and some Brasilian chemistry textbooks that were available in the first half of the XX century, such as: Noções de Chimica Inorganica (1875) by João Martins Teixeira; Traité Élémentaire de Chimie (1910) de Troost & Ed Pechard; Lições de Chimica (1915) and Chimica Geral Chimica Organica Analyse Chimica (1915) by J. Basin; Elementos de Chimica Inorganica (1918 and 1921) by Tibúrcio do Amaral; Pontos de Chimica (1937) by Almeida Cousin / No presente trabalho focalizamos a ilustração da cuba pneumática usada por Lavoisier. Verificamos seu papel como um ícone da química moderna. Para isso analisamos imagens desse aparato presente em livros didáticos de química, da primeira metade do século XX, suas relações com o texto e com idéias sobre as origens da química moderna. Usamos como fonte primária o Traité Elementaire de Chimie de Lavoisier e os livros didáticos de química que circulavam no Brasil, na primeira metade do século XX, entre eles: Noções de Chimica Inorganica (1875) de João Martins Teixeira; Traité Élémentaire de Chimie (1910) de Troost & Ed Pechard; Lições de Chimica (1915) e Chimica Geral Chimica Organica Analyse Chimica (1915) de J. Basin; Elementos de Chimica Inorganica (1918 e 1921) de Tibúrcio do Amaral; Pontos de Chimica (1937) de Almeida Cousin

A new depth-based method of seismic imaging is used to provide insights into the 3D structural geometry of faults, and to facilitate a detailed structural interpretation of the Penola Trough, Otway Basin, South Australia. The structural interpretation is used to assess fault kinematics through geological time and to evaluate across-fault juxtaposition, shale gouge and fault reactivation potential for three selected traps (Zema, Pyrus and Ladbroke Grove) thus providing a full and systematic assessment of fault seal risk for the area. Paper 1 demonstrates how a depth-conversion method was applied to two-way time seismic data in order to redisplay the seismic in a form more closely representative of true depth, here termed ‘pseudo-depth’. Some apparently listric faults in two-way time are demonstrated to be planar and easily distinguishable from genuine listric faults on pseudo-depth sections. The insights into fault geometry provided by pseudo-depth sections have had a significant impact on the new structural interpretation of the area. Paper 2 presents the new 3D structural interpretation of the area. The geometry of faulting is complex and reflects variable stress regimes throughout structural development and the strong influence of pre-existing basement fabrics. Some basement-rooted faults show evidence of continual reactivation throughout their structural history up to very recent times. Structural analysis of all the live and breached traps of the area demonstrate that traps associated with a basement rooted bounding fault host breached or partially breached accumulations, whereas non-basement rooted faults are associated with live hydrocarbon columns. Papers 3 and 4 demonstrate that for all the traps analysed (Zema, Pyrus and Ladbroke Grove), initial in-place seal integrity was good. The initial seal integrity was provided by a combination of both favourable across fault juxtaposition (Ladbroke Grove) and/or sufficiently well developed shale gouge over potential leaky sand on sand juxtaposition windows to retain significant hydrocarbon columns (Zema, Pyrus). The palaeocolumns observed at Zema and Pyrus indicate that there has been subsequent post-charge breach of seal integrity of these traps while Ladbroke Grove retains a live hydrocarbon column. Evidence of open, permeable fracture networks within the Zema Fault Zone suggest that it is likely to have recently reactivated, thus breaching the original hydrocarbon column. Analysis of the in-situ stress tensor and fault geometry demonstrates that most of the bounding faults to the selected traps are at or near optimal orientations for reactivation in the in-situ stress tensor. The main exception being the Ladbroke Grove Fault which has a NW-SE trending segment (associated with a relatively high risk of fault reactivation and possible leakage at the surface) and an E-W trending segment (associated with a relatively low risk of fault reactivation and a present day live column). The free water level of the Ladbroke Grove accumulation coincides with this change in fault orientation. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1339545 / Thesis (Ph.D.) - University of Adelaide, Australian School of Petroleum, 2008

Cette thèse s'intéresse à la coordination des sous-systèmes d'un nouveau genre de centrale de production d'énergie : un cycle combiné hybride (HCC - Hybrid Combined Cycle). Cette centrale HCC n'existe pas encore mais combine un cycle combiné gaz (CCG), un moyen de production solaire thermodynamique (miroirs cylindro-paraboliques) et un moyen de stockage thermique (stockage indirect de chaleur sensible utilisant deux réservoirs de sels fondus). Comment coordonner ces trois sous-systèmes de manière optimale lors des variations de demande de puissance ou des prix du gaz ?Dans un premier temps, chacun des trois sous-systèmes est étudié de manière indépendante afin d'obtenir, d'une part, un modèle physique permettant de caractériser le comportement dynamique du sous-système considéré et, d'autre part, un contrôle local qui agit en fonction des objectifs de fonctionnement prédéfinis. Un modèle du système complet interconnecté de l'HCC est ensuite obtenu en couplant les modèles des trois sous-systèmes. Enfin, une coordination des différents sous-systèmes est mise en place pour adapter le fonctionnement de chacun, en fonction des objectifs globaux de la centrale HCC complète, en optimisant les consignes de chaque sous-système. Dans ce travail, une coordination de type linéaire quadratique et une coordination de type optimale prédictive sont étudiées. Les résultats obtenus sont bien prometteurs : ils montrent, tout d'abord, que lors d'un appel de puissance, la commande coordonnée permet au système HCC de répondre plus rapidement, en utilisant plus efficacement la partie solaire. De plus, lorsque la demande subit beaucoup de variations, la partie solaire et la partie stockage absorbent toutes ces variations et la Turbine à Combustion (TAC) du CCG est beaucoup moins sollicitée. Lorsqu'il n'y a plus d'irradiation solaire, la partie stockage prend la relève pour continuer à produire de la vapeur solaire, jusqu'à ce que les stocks se vident. Finalement, le stockage permet d'ajuster la production de la TAC en fonction des prix du gaz. / This work concerns the subsystems coordination of a new type of power plant: a Hybrid Combined Cycle (HCC). This HCC plant is not yet build but consists of a Combined Cycle Power Plant (CCPP), a concentrated solar plant (parabolic trough) and a thermal storage system (a molten-salts two-tank indirect sensible thermal storage). How to coordinate these three subsystems optimally during variations in power demand or in gas price?First, each subsystem is studied independently in order to get on one hand a physical model that reproduces the dynamical behavior of the considered subsystem, and on the other hand, a local control that achieves an operation according to pre-specified objectives. Then, a model of the HCC system is obtained by coupling the models of the three defined subsystems.Eventually, a coordination of the subsystems is set up in order to adapt the behavior of each subsystem according to the global objectives for the full HCC system, by optimizing subsystem setpoints. In this study, a linear quadratic coordination and a model predictive coordination are designed. The obtained results are promising: they first show that during a power demand, the coordination allows the global system to quickly respond, using extensively the solar production. Besides, when the power demand undergoes many fluctuations, the solar and storage parts absorb these variations and the gas turbine of the CCPP is much less stressed. In addition, when there is no more solar radiation, the storage part continues producing solar steam, until storage tanks are empty. At last, the storage part allows to adjust the gas turbine production according to the gas prices.

Comme les autres technologies liées aux énergies renouvelables, le solaire à concentration souffre des problèmes liés à l’intermittence de la ressource. La technologie thermocline est une solution prometteuse qui réduirait le coût du stockage thermique dans les centrales solaires de ce type. Cependant, aucune étude n’a jusqu’ici porté sur l’impact de la variation de la température en sortie du réservoir de stockage de type thermocline sur les autres composants de la centrale. Ce travail de thèse a pour but d’améliorer les connaissances sur ce sujet, grâce à l’utilisation d’une mini boucle solaire cylindro parabolique intégrant un stockage thermocline.En premier lieu, la compatibilité entre le fluide de transfert de la centrale (huile synthétique) et les potentiels matériaux de garnissage de la cuve de stockage (Cofalit, briques de cendres volantes, alumine) est vérifiée. Puis les performances de chacun des composants de la centrale (cuve de stockage, collecteurs solaires, générateur de vapeur) sont analysées expérimentalement et numériquement. Enfin, le comportement du système global est étudié, avec un accent porté sur l’impact de la variation de la température de sortie de la cuve thermocline sur les autres composants.Il a été montré qu’avec un dimensionnement et une stratégie de contrôle appropriés, la technologie thermocline diminue très peu les performances de la centrale solaire par rapport à la technologie conventionnelle à deux cuves (maximum 3 4 % de diminution de la production électrique). / Like other renewable energy technologies, concentrated solar power (CSP) suffers from resource intermittence. Thermocline technology is a promising solution to decrease cost of thermal energy storage in CSP plants. Thermocline behavior has thoroughly been studied in the past years and its behavior is considered well known. However no study treated of thermocline tanks integrated in CSP plants. Thus, the impact of the varying outlet temperature of the thermocline storage has not been assessed yet. This work aims to fill this lack of knowledge by studying a mini parabolic trough power plant integrating a thermocline tank as storage.First, the compatibility between the heat transfer fluid of the plant (synthetic oil) and various potential filler materials (Cofalit, coal fly ash bricks, alumina) of the storage tank is verified. Then, some performance studies are performed on the three main components of the power plant (energy storage tank, solar collectors, steam generator). Finally, the behavior of the whole system is assessed, with a focus on the impact of the varying fluid temperature at the outlet of the thermocline tank on the other components.It has been shown that, with a proper sizing and an appropriate control strategy, thermocline technology induces very low decrease of the solar power plant performance in comparison to the conventional two tank technology (maximum 3-4% of electrical power production difference).

In concentrated solar power (CSP) stations, large arrays of mirrors which are capable of changing its orientation are used to reflect the incident solar energy to a stationary receiver kept at a distance. Such mirrors are often called as heliostats. The receiver contains a heat absorbing medium like molten salt. By absorbing the thermal energy reflected from thousands of heliostats, the temperature would reach around 6000C and the heat can be used in thermal power plants to generate steam and thus run a turbine to produce electricity. One of the biggest advantages of CSP over conventional energy harvesting from Sun is that it can generate electricity during night for long hours of time from the thermal energy stored during daytime. This eliminates the usage of batteries or any other energy storing methods. The conversion efficiency is also high in CSP due to the high temperature achieved. With prior knowledge of the station coordinates, viz., the latitude and longitude, the day of the year and time, the direction or the path of sun can be fully determined. Typically, the sun's motion is tracked by the azimuth-elevation (Az-El) or the target-aligned configuration heliostats. In both these approaches, the mirror needs to be moved about two axes independently using two actuators in series with the mirror effectively mounted at a single point at the centre. This arrangement causes the mirror to deform in presence of gusty winds in a solar field which results in loss of pointing accuracy. Typically a beam error of less than 2-3 mrad is desirable in a large solar field and this value also includes other sources of loss of pointing accuracy like gravity and wind loading. In order to prevent this, a rigid support frame is required for each of the heliostats. In this work, two three degree-of-freedom parallel manipulators, viz., the 3-UPU wrist and 3-RPS, have been proposed to track the sun in central receiver systems. The main reasons for choosing a parallel manipulator as heliostat are its desirable characteristics like large load carrying capacity, high accuracy in positioning the mirror and easy to obtain the inverse kinematics and convenient for real time control. The proposed parallel manipulators support the load of the mirror, structure and wind loading at three points resulting in less deflection and thus a much larger mirror can be moved with the required tracking accuracy and without increasing the weight of the support structure. The algorithm for sun tracking is developed, extensive simulation study with respect to actuations required, variation of joint angles, spillage loss and leg intersection has been carried out. Using FEA, it is shown that for same sized mirror, wind loading of 22 m/s and maximum deflection requirement (2 mrad), the weight of the support structure is between 15% and 60% less with the parallel manipulators when compared to azimuth-elevation or the target-aligned configurations. A comprehensive study on stroke minimization of prismatic joints is carried out. It is found that a stroke of 700 mm is required for a 2 m x 2 m heliostat at Bangalore when the farthest heliostat is at a distance of 300 m from the tower. Although, there is an extra motor required to track the sun, the 3-RPS manipulator is better than the conventional methods if the mirror area per actuator criteria is taken into consideration. Prototypes of the Az-El and 3-RPS heliostats were made with a mirror size of 1 m x 1 m. A PID controller implemented using MATLAB-Simulink and a low cost, custom made motor driver circuit is used to control the motion of the 3-RPS heliostat. The algorithm developed is tested on the prototype by tracking a point marked on the wall of the lab space and is found to have a tracking error of only 7.1 mrad. Finally, the actual sun tracking is carried out on the roof of a building reflecting the sun-light to a wall situated 6.72 m above and a distance of 15.87 m from the heliostats. The images are captured at various instances of time from 11:30 a.m. to 3:30 p.m. on October 15th and November 10th, 2016, tracking errors are quantified and it is demonstrated that the proposed 3-RPS parallel manipulator can indeed work as a heliostat in concentrated solar power plants.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / It was evaluated the performance of beef heifers on grazing receiving different levels of supplement: 0,0; 0,3; 0,6 and 0,9% of live weight (LW), in black oats (Avena strigosa Schreb.) plus Italian ryegrass (Lolium multiflorum Lam.) pasture and exclusively in natural pasture engaged by Annoni grass (Eragrostis planna Nees) after the end of the cycle of these forages. On cultivated pasture it was evaluated the botanic composition and the diurnal ingestive behavior of beef heifers. The supplement utilized was a commercial ration (14% CP; 18,8% NDF; 78,2% TDN) daily supplied at 2 pm. The studied variables were the average daily gain (ADG), body condition (BC), stocking rate (SR), weight gain per area (WGA), total forage on offer (TFO), height, live weight:height relation at 12 and 18 month of age and efficiency of transformation of forage in animal product. On the diurnal ingestive behavior were determined: grazing time, rumination, idle, trough permanence, biting rate and bite weight, in four dates. In cultivated pasture the ADG did not differ between animals that received different levels of supplement and it was bigger to supplemented animals. At 12 month of age the BC, SR, WGA, TFO and height of the animals did not differ between the supplement levels. On supplemented animals it was necessary 8.8 kg of DM of grass to produce 1 kg of live weight. The supply of supplement for heifers in grazing of oats and ryegrass interfere in a positive way on life weight, body condition and life weight: height relation of these animals at 18 months of age. The supplement levels affected partially the diurnal ingestive behavior of animals, reducing grazing time, increasing idle time, interfering on trough permanence time, biting rate and bite weight (P<0.05). The rumination time was not affected by supplement levels (P>0.05). The botanic and structural composition of pasture is influenced by supplement levels utilized and it is related with the cycle of forages production (P>0.05). / Foi avaliado o desempenho de bezerras de corte em pastejo recebendo diferentes níveis de suplemento: 0,0; 0,3; 0,6 e 0,9% do peso vivo (PV), em pastagem de aveia (Avena strigosa Schreb.) mais azevém (Lolium multiflorum Lam.) e exclusivamente em campo nativo ocupado por capim Annoni (Eragrostis plana Nees), após o final do ciclo destas forrageiras. Na pastagem cultivada foi avaliada a composição botânica e o comportamento ingestivo diurno de bezerras de corte. O suplemento utilizado foi uma ração comercial (14% PB; 18,8% FDN; 78,2% NDT), fornecida diariamente às 14:00 h. As variáveis estudadas foram ganho médio diário (GMD), condição corporal (CC), carga animal (CA), produção animal por hectare (GPA), oferta de forragem total (OFT), altura, relação peso vivo:altura aos 12 e 18 meses de idade, e eficiência de transformação de Kg de forragem em produto animal. No comportamento ingestivo diurno foram determinados: tempo de pastejo, ruminação, ócio, permanência no cocho, taxa de bocada e peso de bocado, em quatro datas. Em pastagem cultivada o GMD não diferiu entre animais que receberam diferentes níveis de suplemento e foi maior para animais suplementados. Aos 12 meses de idade a CC, CA, GPA, OFT e altura dos animais não diferiram entre níveis de suplemento. Nos animais suplementados foram necessários 8,8 kg de MS do pasto para produzir 1 kg de peso vivo. O fornecimento de suplemento para novilhas em pastejo em aveia e azevém interfere de forma positiva no peso vivo, CC e relação peso vivo:altura destes animais aos 18 meses de idade. Níveis de suplemento afetaram parcialmente o comportamento ingestivo diurno dos animais, reduzindo o tempo de pastejo, aumentando o tempo de ócio, interferindo no tempo de permanência no cocho, na taxa de bocada e peso do bocado (P<0,05). Tempo de ruminação não foi afetado pelos níveis de suplemento (P>0,05). A composição botânica e estrutural da pastagem é influenciada pelos níveis de suplemento utilizados e está relacionada com o ciclo de produção das forrageiras.

Thesis deals with issues of recognition and capture of permanent and temporary changes in the value of assets and liabilities in financial accounting from the perspective of International Financial Reporting Standards (IFRS), US generally accepted accounting principles (US GAAP) and the Czech accounting law. Top of the thesis discusses the bases for accounting for changes in the value of assets in the accounts - attention is paid to the fundamental accounting assumptions and principles, cost basis, latent reserves and deferred tax. A separate section compares the issue of depreciation of fixed assets in terms of IFRS, US GAAP and the Czech accounting law. The main part discusses the rules for identifying and capturing the transitional changes in the value of assets and liabilities in their subsequent valuation rules under IFRS, US GAAP and Czech accounting regulations. There is also the issue of exchange rate differences.