Vibration energy harvesters, or energy scavengers, recover mechanical energy from their surrounding environment and convert it into useable electricity as sustainable self-sufficient power sources to drive micro-to milli-Watt scale power electronics in small, autonomous, wireless devices and sensors. Using semiconducting, organic piezoelectric nanomaterials are attractive in low-cost, high resistance to fatigue, and environmentally friendly applications. Significantly, the deposition processes of sputtering ZnO (zinc oxide) thin films with high c-axis preferred orientation and electrospun PVDF (polyvinylidene fluoride) nanofibers with high piezoelectric £]-phase crystallisation are controlled at room temperature. Thus they don¡¦t have the necessity of post-annealed and electrical repoling process to obtain an excellent piezoelectricity, and are suitable for all flexible substrates such as PET (polyethylene terephthalate) and PI (polyimide). These works are divided into two parts. Part 1: Flexible piezoelectric harvesters based on ZnO thin films for self-powering and broad bandwidth applications. A new design of Al (aluminum)/PET-based flexible energy harvester was proposed. It consists of flexible Al/PET conductive substrate, piezoelectric ZnO thin film, selectively deposited UV (ultraviolet)-curable resin lump structures and Cu (copper) foil electrode. The design and simulation of a piezoelectric cantilever plate was described by using commercial software ANSYS FEA (finite element analysis) to determine the optimum thickness of PET substrate, internal stress distribution, operation frequency and electric potential. With the optimum thickness predicted by developed accurate analytical formula analysis, the one-way mechanical strain that is efficient to enhance the induced electric potential can be controlled within the piezoelectric ZnO layer. In addition, the relationship among the model solution of piezoelectric cantilever plate equation, vibration induced electric potential and electric power was realized. ZnO thin film of high (002) c-axis preferred orientation with an excellent piezoelectricity was deposited on the Al/PET by RF (radio-frequency) magnetron sputtering in room temperature. Al was sputtered on the PET substrate as the bottom electrode because of its low sheet resistance, superior adhesion with PET, and lattice constants matching with ZnO thin film. The selectively deposited UV-curable resin lump structures as proof mass were directly constructed on flexible piezoelectric plate using electrospinning with a stereolithography technique. One individual harvester achieves a maximum OCV (open-circuit voltage) up to 4V with power density of 1.247 £gW/cm2. This self-powered storage system can drive the warning signal of the LED (light emitting diode) module in both resonant and non-resonant conditions. We also succeeded in accomplishing a broad bandwidth harvesting system with operating frequency range within 100 Hz to 400 Hz to enhance powering efficiency. This system comprises four units of individual ZnO piezoelectric harvester in the form of a cantilever structure connected in parallel, and rectifying circuit with storage module. In addition, a modified design of a flexible piezoelectric energy-harvesting system with a serial bimorph of ZnO piezoelectric thin film was presented to enhance significantly higher power generation. This high-output system was examined at 15 Hz. The maximum DC (direct current) voltage output voltage with loading was 3.18 V, and the maximum DC power remained at 2.89 £gW/cm2. Furthermore, in order to examine the deformation between interfaces and the adhesion mechanism of multi-layer flexible electronics composites (e.g., ITO (indium tin oxide)/PET, Al/PET, ZnO/ITO/PET, and ZnO/Al/PET), nanoscratching and nano-indention testing (nanoindenter XP system) were conducted to analyze the adhesion before and after the vibration test. The plastic deformation between the ductile Al film and PET substrate is observed using SEM (scanning electron microscopy). Delamination between the ZnO and Al/PET substrate was not observed. This indicates that Al film provides excellent adhesion between the ZnO thin film and PET substrate. Part 2: Pre-strained piezoelectric PVDF nanofiber array fabricated by near-field electrospining on cylindrical process for flexible energy conversion. In various methodologies of energy harvesting from ambient sources, one-dimensional nanoharvesters have been gaining more attention recently. However, these nanofibers fabricated by micro-forming technologies may not easily control their structural diameter and length. This study originally presented the HCNFES (hollow cylindrical near-field electrospining) process to fabricate permanent piezoelectricity of PVDF piezoelectric nanofibers. Under high in-situ electric poling and strong mechanical stretching effect during HCNFES process, large PVDF nanofiber array with high piezoelectric £]-phase crystallisation was demonstrated. These pre-strained piezoelectric PVDF nanofibers fabricated by HCNFES with high process flexibility at low cost, availability in ultra-long lengths, various thicknesses and shapes can be applied at power scavenge, sensing and actuation. Firstly, PVDF nanofibers lay on a PET substrate, silver paste was applied at both ends of fibers to fix their two ends tightly on a Cu foil electrode pair. The entire structure was packaged inside a thin flexible polymer to maintain its physical stability. Repeatedly stretching and releasing the nanoharvester (NH 1) with a strain of 0.05% at 5 Hz vibration created a maximum peak voltage and current of -50 mV and -10 nA in forward connection, respectively. Secondly, a total of 44 parallel nanofibers have been fabricated and transferred onto an IDT (interdigital) electrode with 64 electrode pairs as a nanohavester (NH 2) to amplify current outputs under repeated mechanical vibration and impact tests. Under a repeated maximum strain of 0.14% at 6 Hz vibration, a peak current of 39 nA and peak voltage of 20.2 mV have been measured. Impact testing at 15 Hz, peak current of 130 nA has been collected with a voltage of 24.4 mV. Finally, the single PVDF fiber as nanoharvester (NH 3) with a strain of 0.05-0.1% at 5 Hz vibration created a maximum peak voltage and current of -45 mV and -3.9 nA, respectively. The maximum power remained at 18.45 pW/cm2 with a load resistor of 6.8 M£[. Based on the mechanism of converes piezoelectric effect, ANSYS software with coupled field analysis was used to realize piezoelectric actuation behavior of the PVDF fibers. From the observation of actuation property, a fixed-fixed single nanofiber was tested under different DC voltage supply. Comparing the polarized fiber with non-polarized fibers, the measurement of the center displacements as a function of electric field was conducted and characterized.

Tie-down systems are used to fasten drilling rigs to the deck of offshore structures during harsh environmental conditions such as hurricanes. During Hurricane Ivan (2004) and Katrina (2005), a number of offshore structures were moved and several tie-down systems were damaged. In the present study, the reaction force and connection capacity of tie-down systems for a TLP and SPAR are investigated. The environmental conditions are taken from the API Bulletin 2INT-MET which has been updated after several major storms during 2004-2005. The hydrodynamic coefficients of the TLP and SPAR are obtained using a 3D diffraction/radiation panel method. The motions of the TLP and SPAR are then simulated in the time domain by using the hull-mooring-riser coupled dynamic analysis tool CHARM3D. Based on the simulated motion and acceleration time series, the inertial and gravity loads on derrick and skid base footing are calculated. In addition to the inertial-gravity loads, wind forces exerted on the derrick are also calculated. All the external forces and resultant hull motions are simulated for 100-year, 200-year and 1000-year storms to observe the derrick structural integrity with increasing environmental intensity. Various environmental headings are also considered to find the maximum reaction forces. In the present method, the phase differences between gravity-inertia forces and wind forces are taken into consideration to obtain more realistic loads on derrick and skid base footings. This research shows that the maximum and minimum load values are appreciably higher for the SPAR. In addition, the direction of external forces is also important to determine maximum reaction forces on footings. The capacities of the clamps in slip, bolt tension, and bolt shear can be also analyzed using the resultant data to provide guidance on appropriate design values.

A basic understanding of the hydrodynamic response behavior of the two-body system is important for a wide variety of offshore operations. This is a complex problem and model tests can provide data that in turn can be used to retrieve key information concerning the response characteristics of such systems. The current study demonstrates that the analysis of these data using a combination of statistical tools and system identification techniques can efficiently recover the main hydrodynamic parameters useful in design. The computation of the statistical parameters, spectral densities and coherence functions provides an overview of the general response behavior of the system. The statistical analysis also guides the selection of the nonlinear terms that will be used in the reverse multi-input / single-output (R-MI/SO) system identification method in this study. With appropriate linear and nonlinear terms included in the equation of motion, the R-MISO technique is able to estimate the main hydrodynamic parameters that characterize the offshore system. In the past, the R-MISO method was primarily applied to single body systems, while in the current study a ship moored to a fixed barge was investigated. The formulation included frequency-dependant hydrodynamic parameters which were evaluated from the experimental measurements. Several issues specific to this extension were addressed including the computation load, the interpretation of the results and the validation of the model. Only the most important cross-coupling terms were chosen to be kept based on the estimation of their energy. It is shown that both the heading and the loading condition can influence system motion behavior and that the impact of the wave in the gap between the two vessels is important. The coherence was computed to verify goodness-of-fit of the model, the results were overall satisfying.

The subject of this thesis is an extension of a two-dimensional, axisymmetric, Timoshenko-beam finite-element rotordynamic code to include a three-dimensional non-axisymmetric solid-element casing model. Axisymmetric beams are sufficient to model rotors. Spring and damper forces provide the interface between the rotor and its casing and capture the dynamics of the full model. However, axisymmetric beams limit the modeling of real-case machine structures, where the casing is not axisymmetric. Axisymmetric and non-axisymmetric 3D finite element casing structures are modeled. These structures are then reduced using a technique called substructuring. Modal equations are developed for axisymmetric and non-axisymmetric casing models. In a 3D non-axisymmetric model, structural dynamics modes can be modeled by lateral modes in two orthogonal planes. Modal information of the complex 3D casing structures are generated, and then incorporated into the 2D code after a series of pre-processing steps. A reduction method called Component Mode Synthesis (CMS) is used to reduce the large dimensionality involved in calculation of rotordynamic coefficients. The results from the casing structures are merged with the rotor model to create a combined rotor-casing model. The analysis of the combined structure shows that there is a difference in the natural frequencies and unbalance response between the model that uses symmetrical casing and the one that uses non-axisymmetric casing. XLTRC2 is used as an example of a two-dimensional axisymmetric beam-element code. ANSYS is used as a code to build three-dimensional non-axisymmetric solid-element casing models. The work done in this thesis opens the scope to incorporate complex non-axisymmetric casing models with XLTRC2.

The instrumentation amplifier (IA) is one of the crucial blocks in an electrocardiogram recording system. It is the first block in the analog front-end chain that processes the ECG signal from the human body and thus it defines some of the most important specifications of the ECG system like the noise and common mode rejection ratio (CMRR). The extremely low ECG signal bandwidth also makes it difficult to achieve a fully integrated system. In this thesis, a fully integrated IA topology is presented that achieves low noise levels and low power dissipation. The chopper stabilized technique is implemented together with an AC coupled amplifier to reduce the effect of flicker noise while eliminating the effect of the differential electrode offset (DEO). An ultra low power operational transconductance amplifier (OTA) is the only active power consuming block in the IA and so an overall low power consumption is achieved. A new implementation of a large resistor using the T-network is presented which makes it easy to achieve a fully integrated solution. The proposed IA operates on a 2V supply and consumes a total current of 1.4µA while achieving an integrated noise of 1.2µVrms within the bandwidth. The proposed IA will relax the power and noise requirements of the analog-to-digital converter (ADC) that immediately follows it in the signal chain and thus reduce the cost and increase the lifetime of the recording device. The proposed IA has been implemented in the ONSEMI 0.5µm CMOS technology.

Determination of Ca and P in foods and B, Si, P and S in steels by dynamic reaction cell inductively coupled plasma mass spectrometry

Ga,Ge,As,Se and Sb in coal fly ash S and Pb in gasoline

Cylindrical dielectric waveguides such as the optical fiber and photonic crystal fiber are very important passive devices in optical communication systems. There are many kinds of commercial software and methods of simulation at present. In this thesis, we proposed the following four methods to analyze arbitrarily profiled cylindrical dielectric waveguides: The first two methods are modified from published work while the last two methods are entirely developed by ourselves. 1. Cylindrical ABCD matrix method: We take the four continuous electromagnetic field components as main variables and derive the exact four-by-four matrix (with Bessel functions) to relate the four field vector within each homogeneous layer. The electromagnetic field components of the inner and outer layer can propagate toward one of the selected interface of our choice by using the method of ABCD matrix. We can then solve for the £]-value of the waveguide mode with this nonlinear inhomogeneous matrix equation. 2. Runge-Kutta method: Runge-Kutta method is mostly used to solve the initial value problems of the differential equations. In this thesis, we introduce the Runge-Kutta method to solve the first-order four-by-four nonlinear differential equation of the electromagnetic field components and find the £]-value of the cylindrical dielectric waveguides in a similar way depicted in method one. 3. Coupled Ez and Hz method: It uses the axial electromagnetic filed components to solve cylindrical dielectric waveguides. The formulation is similar to cylindrical ABCD matrix method, but it requires less variables then cylindrical ABCD matrix method. The numerical solution obtained from this method is most stable, but it is more complicated to derive harder to write the program. 4. Simple basis expansion method: The simple trigonometric functions (sine or cosine) are chosen as the bases of the horizontal coupled magnetic field equation derived from the second-order differential equation of the transverse magnetic field components. We do not select the horizontal coupling electric field because the normal component of the electric field is discontinuous on the interface. But the normal and tangential components of the magnetic field are continuous across the interfaces. The modal solution problem is converted to a linear matrix eigenvalue-eigenvector equation which is solved by the standard linear algebra routines. We will compare these four numerical methods with one another. The characteristics and advantage as well as the disadvantage of each method will be studied and compared in detail.

Because of IC technology evolution and the increase of market demand, the communication industry grows vigorously in recent years. The voltage-controlled oscillator plays a key role in the RF transceiver and provides oscillation signals needed for upconversin and downconvertion. Usually, we separate the signals into I/Q channels for modulation and demodulation in upconversin and downconvertion. Because the quality of the local oscillator influences the performance of communication system, designing a voltage-controlled oscillator that can provide two identical signals in accurate quadrature is necessary. In this thesis, a new quadrature voltage-controlled oscillator is presented. We use two identical relaxation oscillators with adjustable Schmitt triggers to construct the cross-coupled architecture. This oscillator has accurate ( <1¢X) and stable quadrature outputs which are independent of operating frequency and process variations. This oscillator circuit is fabricated in TSMC 0.35£gm CMOS Mixed-Signal process provided by National Chip Implementation Center (CIC). Our design is verified by simulation and measurement results.

The communication system using Wavelength-division multiplexing (WDM) allows for better utilization of the spectral bandwidth. Photonic crystals (PhCs) exhibit photonic bandgap (PBG) due to the periodic variation of the dielectric constant and photons with a range of frequencies within the PBG cannot travel through the crystal. By introducing defects into PhCs, it is possible to control the light propagation along certain paths. In this thesis, the characteristics of coupled cavity waveguides (CCWs) and drop filter are discussed. Then we propose a multi-channel WDM system based on CCWs. It can be applied in FTTH to filter the wavelengths of 1310, 1490 and 1550 nm in different CCWs and also can make the bandwidth of output wavelength become narrow to filter more wavelengths. In addition, by modulating the size of the resonator on the PhCs, it can drop the particular wavelength into the waveguide. Finally, we proposed a multi-channel drop filter with FHWM 0.8 nm. This device design is leading the way to achieve CWDM specification with 100% drop efficiency, high quality factor and almost no crosstalk. The operations of such an ultra-compact demultiplexer and drop filter based on PhCs are suitable to be used in WDM optical communication systems.