Das magnetische Verhalten zahlreicher Materialien lässt sich auf eine indirekte Wechselwirkung lokalisierter magnetischer Momente, vermittelt durch die Elektronen eines Leitungsbandes, zurückführen. Das Kondo-Gitter-Modell hat sich als elegante Möglichkeit bewährt, diesen Prozess quantenmechanisch zu beschreiben. Es reduziert die Physik auf eine intraatomare Wechselwirkung der Spins von lokalisierten und itineranten Elektronen. Die vorliegende Arbeit ist den analytischen Eigenschaften dieses Modells gewidmet. Die besondere Herausforderung des Kondo-Gitter-Modells besteht dabei im Zusammenwirken zweier verschiedener Teilchensorten, beschrieben durch Fermi-Operatoren sowie quantenmechanische Spins. Bisherige Untersuchungen haben sich in der Regel nur auf eine der beiden Teilchensorten konzentriert. Mit der Projektions-Operator-Methode stellen wir eine Möglichkeit vor, beide Teilsysteme in gleicher Qualität zu behandeln. Die Auswertung des Teilsystems der itineranten Elektronen führt auf einen Ausdruck für die Selbstenergie, der lineare und quadratische Effekte in der Wechselwirkung exakt beschreibt. Die resultierenden Zustandsdichten weisen starke Korrelationseffekte auf. Deren Untersuchung dient sowohl der Bestätigung von Ergebnissen weniger systematischer Zugänge als auch dem Aufzeigen neuer Vielteilchen-Phänomene. Die Anwendung der Projektions-Operator-Methode auf das System der lokalisierten Momente führt zu einer Analyse der bereits bekannten RPA (random phase approximation). Zu diesem Zweck werden die Magnonenspektren und die Curie-Temperaturen systematisch untersucht. Dabei treten bisher unbekannte Schwachpunkte der RPA zu Tage, die auch die Kombination mit Theorien für das itinerante Teilsystem verhindern. Verbesserungen und Alternativen zur RPA werden diskutiert. / The magnetic behaviour of various materials is due to an indirect interaction of localized magnetic moments, which is based on itinerant electrons in a conduction band. The Kondo-lattice model is an elegant approach for a quantum-mechanical description of this process. It reduces the relevant physics to an intra-atomic exchange interaction of the localized and the itinerant electrons. The aim of the present work is a detailed investigation of analytic properties of this model. Here, the interplay of two distinct types of particles, described by Fermi operators and quantum-mechanical spin operators respectively, is a major challenge of the considered model. Previous studies have focused on one of these subsystems only. Using the projection-operator method, we suggest an efficient way to describe both subsystems on the same level of approximation. An evaluation of the subsystem of itinerant electrons yields an expression for the self-energy, which describes linear and quadratic interaction effects exactly. The densities of states derived with this theory show strong correlation effects. We were able to assess results obtained with less systematic approaches and to predict new many-particle effects. The application of the projection-operator method to the subsystem of localized magnetic moments results in a detailed analysis of the RPA (random phase approximation). The dependence of magnon spectra and Curie temperatures on model parameters are investigated systematically. Previously unknown drawbacks of the RPA are revealed, which prevent the combination of these results with theories for the itinerant subsystem. Improvements beyond RPA and alternative approximations are discussed.

This thesis develops a critical reading methodology entitled unprincipled formalism. This methodology is tested in close readings of three relatively contemporary Australian literary texts: David Malouf's short story "A Traveller's Tale" (1986) and novella Remembering Babylon (1994), and Peter Carey's short story "The Chance" (1978). Unprincipled formalism is developed in relation to three broad contexts: the fragmented state of the contemporary discipline of literary studies; the complex of international economic and social phenomena which goes under the general rubric of globalisation; and the specific Australian left-liberal literary critical tradition which I have termed, for convenience sake, the Meanjin literary formation. Unprincipled formalism does not draw a distinction between form and content. Unprincipled formalism is a critical methodology that is both avowedly socially concerned and strictly formalist. It is concerned with articulating and analysing the particular social and political interventions made by literary texts (as well as the resultant critical discussion of those texts) through a consideration of the formal techniques by which literary texts situate themselves as acts of communication. Principal among these techniques is the mise en abyme. The thesis provides a detailed analysis of debates around the mise en abyme informed by the work of theorists such as Ross Chambers, Lucien Dallenbach, Frank Lentricchia, Moshe Ron, Jacques Derrida and others. Politically, unprincipled formalism attempts to steer a middling course between neo-liberal triumphalism on the one hand and nostalgic left romanticism on the other. This involves on the one hand a critique of neo-liberalism drawing on the work of Charles Taylor, Stephen Holmes, John Frow and others, and on the other a critique of a nostalgic romantic tendency in "progressive" critical technologies such as postmodern and postcolonial literary studies.

Cette thèse a pour objet les corrections perturbatives de CDQ pour la production de quatre jets dans l'annihilation des électrons et positrons. Les corrections à une boucle pour le sous-processus $e^+ e^- \rightarrow q \bar{q} Q \bar{Q}$ sont calculées avec de nouvelles méthodes qui comprennent la décomposition de couleur, la méthode des spineur d'hélicité, et une décomposition inspirée par la supersymmétrie. Nous avons également profité des contraintes découlants de l'unitarité et des limites colinéaires pour restreindre la forme analytique des amplitudes. Dans une deuxième phase, j'ai écrit un programme numérique qui combine des contributions dues aux corrections radiatives des sous-processus $e^+ e^- \rightarrow q \bar{q} Q \bar{Q}$ et $e^+ e^- \rightarrow q g g \bar{q}$ et dues aux corrections d'émission réelle. Le programme utilise le formalisme des dipoles pour annuler les divergences infra-rouge. L'analyse numérique contient des résultats sur la section efficace totale, le paramètre $D$ et la variable d'élargissement d'un jet.

<p>Einstein's theory of general relativity is a cornerstone in the process of gaining increased understanding about problems of gravitational nature. It can be applied to problems on the huge length scales of cosmology and as far as we know it does not break down before the Planck scale is approached. Irrespective of scale, a perturbative approach is often a very useful way to reduce the Einstein system to manageable complexity and size.</p><p>The projects included in this thesis can be divided into three subcategories. In the first category the keyword is photon-photon scattering. General relativity predicts that scattering can take place on a flat background due to the curvature of space-time caused by the photons themselves. The coupling equations and cross-section are found and a comparison with the corresponding quantum field theoretical results is done to leading order. Moreover, photon-photon scattering due to exchange of virtual electron-positron pairs is considered as an effective field theory in terms of the Heisenberg-Euler Lagrangian resulting in a possible setup for experimental detection of this phenomenon using microwave cavities. The second category of projects is related to cosmology. Here linear perturbations around a flat FRW universe with a cosmological constant are considered and the corresponding temperature variations of the cosmic microwave background radiation are found. Furthermore, cosmological models of Bianchi type V are investigated using a method based on the invariant scheme for classification of metrics by Karlhede. The final category is slowly rotating stars. Here the problem of matching a perfect fluid interior of Petrov type D to an exterior axisymmetric vacuum solution is treated perturbatively up to second order in the rotational parameter.</p>

<p> </p><p>The interaction between light and organometallic chromophores has been investigated theoretically in a strive for fast optical filters. The main emphasis is on two-photon absorption and excited state absorption as illustrated in the Jablonski diagram. We stress the need for relativistic calculations and have developed methods to address this issue. Furthermore, we present how quantum chemical calculations can be combined with Maxwell's equations in order to simulate propagation of laser pulses through a materials doped with chromophores with high two-photon absorption cross sections. Finally, we also discuss how fast agile filters using spin-transition materials can be modeled in order to accomplish theoretical material design.</p> / Report code: LIU-TEK-LIC-2006:55. On the day of the defence date the status on article III was Manuscript, article IV was Accepted and article V was Submitted.

<p>We derive the equation linking the Weyl tensor with its Lanczos potential, called the Weyl-Lanczos equation, in 1+3 covariant formalism for perfect fluid Bianchi type I spacetime and find an explicit expression for a Lanczos potential of the Weyl tensor in these spacetimes. To achieve this, we first need to derive the covariant decomposition of the Lanczos potential in this formalism. We also study an example by Novello and Velloso and derive their Lanczos potential in shear-free, irrotational perfect fluid spacetimes from a particular ansatz in 1+3 covariant formalism. The existence of the Lanczos potential is in some ways analogous to the vector potential in electromagnetic theory. Therefore, we also derive the electromagnetic potential equation in 1+3 covariant formalism for a general spacetime. We give a short description of the necessary tools for these calculations and the cosmological formalism we are using.</p>

<p>Penrose's inequality which relates the total mass of a space-time containing a black hole with the area of the event horizon, is a yet unproven condition that is required for the cosmic censorship hypothesis. It is believed that the inequality could be proved by using properties of the Hawking mass. This thesis gives analytical expressions for the Hawking mass in slowly rotating Kerr and Kerr-Newman space-times. It is also shown that the expressions are monotonically increasing, a result that does not contradict Penrose's inequality.</p>

<p>This paper presents an approach in contemporary, abstract art for a new way of experiencing modernist abstraction. This has not been possible until now, about 40 years after the postmodern turn against modernism in art, and the closely connected formalism. This new approach is represented in this paper by the Swedish contemporary artists Ann Edholm and Jacob Dahlgren. Modernist artists such as Kasimir Malevich and Piet Mondrian receives a new relevance to contemporary abstract art. This opens up for a new, more complex and more dialectical understanding and re-evaluation of modernism and its abstract art.This is shown by a historical and chronological investigation which highlights modernist abstract art, formalism, and the critical and post-modern Neo-geometric ‘abstraction’ of the eighties. This background has been a way of proving how modernist abstraction still can possess a validity for contemporary art today, and even vitalize a continuation for abstract art as a contemporary practice.</p>

Semi-solid thixoforming processes rely on a material microstructure made of globular solid grains more or less connected to each other, thus developing a solid skeleton deforming into a liquid phase. During processing, the material structure changes with the processing history due to the agglomeration of the particles and the breaking of the grains bonds. This particular evolutive microstructure makes semi-solid materials behave as solids at rest and as liquids during shearing, which causes a decrease of the viscosity and of the resistance to deformation while shearing. Thixoforming of aluminum and magnesium alloys is state of the art and a growing number of serial production lines are in operation all over the world. But there are only few applications of semi-solid processing of higher melting point alloys such as steel. This can partly be attributed to the high forming temperature combined with the intense high temperature corrosion that requires new technical solutions. However the semi-solid forming of steels reveals high potential to reduce material as well as energy consumption compared to conventional process technologies, such as casting and forging. Simulation techniques exhibit a great potential to acquire a good understanding of the semi-solid material process. Therefore, this work deals with the development of an appropriate constitutive model for semi-solid thixoforming of steel. The constitutive law should be able to simulate the complex rheology of semi-solid materials, under both steady-state and transient conditions. For example, the peak of viscosity at start of a fast loading should be reproduced. The use of a finite yield stress is appropriate because a vertical billet does not collapse under its own weight unless the liquid fraction is too high. Furthermore, this choice along with a non-rigid solid formalism allows predicting the residual stresses after cooling down to room temperature. Several one-phase material modeling have been proposed and are compared. Thermo-mechanical modeling using a thermo-elasto-viscoplastic constitutive law has been developed. The basic idea is to extend the classical isotropic hardening and viscosity laws to the non solid state by considering two non-dimensional internal parameters. The first internal parameter is the liquid fraction and depends on the temperature only. The second one is a structural parameter that characterizes the degree of structural build up in the microstructure. Those internal parameters can depend on each other. The internal parameters act on the the viscosity law and on the yield surface evolution law. Different formulations of viscosity and hardening laws have been proposed and are compared to each other. In all cases, the semi-solid state is treated as a particular case, and the constitutive modeling remains valid over the whole range of temperature, starting from room temperature to above the liquidus. These models are tested and illustrated by mean of several representative numerical applications.

Einstein's theory of general relativity is a cornerstone in the process of gaining increased understanding about problems of gravitational nature. It can be applied to problems on the huge length scales of cosmology and as far as we know it does not break down before the Planck scale is approached. Irrespective of scale, a perturbative approach is often a very useful way to reduce the Einstein system to manageable complexity and size. The projects included in this thesis can be divided into three subcategories. In the first category the keyword is photon-photon scattering. General relativity predicts that scattering can take place on a flat background due to the curvature of space-time caused by the photons themselves. The coupling equations and cross-section are found and a comparison with the corresponding quantum field theoretical results is done to leading order. Moreover, photon-photon scattering due to exchange of virtual electron-positron pairs is considered as an effective field theory in terms of the Heisenberg-Euler Lagrangian resulting in a possible setup for experimental detection of this phenomenon using microwave cavities. The second category of projects is related to cosmology. Here linear perturbations around a flat FRW universe with a cosmological constant are considered and the corresponding temperature variations of the cosmic microwave background radiation are found. Furthermore, cosmological models of Bianchi type V are investigated using a method based on the invariant scheme for classification of metrics by Karlhede. The final category is slowly rotating stars. Here the problem of matching a perfect fluid interior of Petrov type D to an exterior axisymmetric vacuum solution is treated perturbatively up to second order in the rotational parameter.