Today, emission legislations for engine exhaust particles are mass based. The engines of today are low-emitting with respect to particle mass, with the emissions approaching the detection limit of the current measurement method. This calls for new and improved measurement methods. Both from the point of view of the engine developers and regarding human health effects, particle number seem to be the particle property of greatest interest to legislate upon. Recently, a proposal for a new particle number based measurement methodology has been put forward by the United Nations Economic Commission for Europe (UN ECE). The gas and particle mixture (the aerosol) of engine exhaust is not a stable system. The size and the number of the particles change over time as the temperature and pressure change. Particle number measurements call for dilution which changes the gas-phase concentrations of the condensing gases. The dilution process alters the conditions in the aerosol and thereby influences the measurements. Within the current project it was desired to better understand the outcome of particle number measurements and the complexities of particle sampling, dilution and conditioning prior to measurements. Two experimental set-ups have been developed within the project. The first system includes a rotating disc diluter followed by a volatility Tandem Differential Mobility Analyser (v-TDMA). The second set-up, called the EMIR-system, includes ejector diluters in series followed by a stand-alone Condensation Particle Counter (CPC). After the development of these experimental set-ups, the v-TDMA has been used to study the volatility and the size distributed number concentration of exhaust particles. The EMIR-system was used for total number concentration measurements including only the solid fraction of the aerosol. The experimental work has given practical experience that can be used to estimate the benefits and disadvantages of upcoming measuring methodology. For the engine developers, in order to produce engines that meet future legislation limits, it is essential to know how the measurement procedure influences the aerosol. In summary, the experimental studies have shown that the number of nucleation mode particles is strongly affected by varied dilution. No upper threshold value of the dilution has been found where the dilution effect diminishes. The volatility studies have shown that it is mainly the nucleation mode particles that are affected by heat. The v-TDMA instrument have shown to be a sensitive analytical tool which, if desired to use for further engine exhaust particle characterization, needs some development work. Experimental work with the EMIR-system, which in principle is similar to the instruments proposed for a future standard, shows that these types of measurement systems are sensitive to small changes in the detector cut-off. The major outcome of the project lies in the new detailed knowledge about particle number measurements from engines. / QC 20100628

<p>In recent decades much effort has gone into reducing particle emissions in the exhaust gases of heavy-duty diesel engines. Engine development has now reached the stage where it is worth to put heavy focus on the contribution of lubricating oil to particulate emissions in order to further reduce these emissions.</p><p> </p><p>A literature study demonstrates that the cylinder system is usually the largest source of oil-related particles. Oil consumption in the cylinder can be divided into <em>throw-off</em> effects when inertia forces act on the piston, piston rings and oil; <em>evaporation</em> from hot surfaces; <em>reverse blow-by</em> when gas pressure drives the oil consumption; and <em>top land scraping </em>when oil is scraped off the cylinder liner.</p><p> </p><p>The pressure between the compression rings strongly affects the stability and position of the upper compression ring as well as the oil consumption caused by the reverse blow-by. A method to measure the inter-ring pressure was developed and evaluated. The measurements showed that cycle-to-cycle variations were small, but that the inter-ring pressure varied over time. Calculations with AVL Excite Piston and Rings confirmed that ring gap positions can have a major influence on the inter-ring pressure.</p><p> </p><p>The measured particle size and number distributions at motoring conditions show interesting and unexpected results. The high number of particles with a diameter of around 100 nm was greatly reduced when the temperature in the diluter was increased. The mean number particle diameter decreased until 10 nm and then became stable independent of further temperature increase. Other authors have found that the small particles (nucleation mode) are reduced and the larger particles (accumulation mode) are more or less unaffected when exhaust gases are heated up and diluted.  </p><p> </p>

In recent decades much effort has gone into reducing particle emissions in the exhaust gases of heavy-duty diesel engines. Engine development has now reached the stage where it is worth to put heavy focus on the contribution of lubricating oil to particulate emissions in order to further reduce these emissions. A literature study demonstrates that the cylinder system is usually the largest source of oil-related particles. Oil consumption in the cylinder can be divided into throw-off effects when inertia forces act on the piston, piston rings and oil; evaporation from hot surfaces; reverse blow-by when gas pressure drives the oil consumption; and top land scraping when oil is scraped off the cylinder liner. The pressure between the compression rings strongly affects the stability and position of the upper compression ring as well as the oil consumption caused by the reverse blow-by. A method to measure the inter-ring pressure was developed and evaluated. The measurements showed that cycle-to-cycle variations were small, but that the inter-ring pressure varied over time. Calculations with AVL Excite Piston and Rings confirmed that ring gap positions can have a major influence on the inter-ring pressure. The measured particle size and number distributions at motoring conditions show interesting and unexpected results. The high number of particles with a diameter of around 100 nm was greatly reduced when the temperature in the diluter was increased. The mean number particle diameter decreased until 10 nm and then became stable independent of further temperature increase. Other authors have found that the small particles (nucleation mode) are reduced and the larger particles (accumulation mode) are more or less unaffected when exhaust gases are heated up and diluted. / QC 20101112

There is a consensus worldwide that the share of renewable energy sources should be increased to mitigate climate change. The strive to increase the renewable energy fraction can partly be met by an increased utilization of different biomass feedstocks. Many of the "new" feedstocks puts stress on certain challenges such as air pollution emissions and operation stability of the combustion process. The overall objective was to investigate, evaluate, and explain the effects of fuel design and combustion control - fuel engineering - as primary measures for control of slag formation, deposit formation, and fine particle emissions during biomass combustion in small and medium scale fixed-bed appliances. The work in this thesis can be outlined as having two main focus areas, one more applied regarding fuel engineering measures and one more fundamental regarding the time-resolved release of ash forming elements, with particular focus on potassium. The overall conclusion related to the abatement of particle emissions and slag formation, is that the release of fine particle and deposit forming matter can be controlled simultaneously as the slag formation during fixed-bed biomass combustion. The methodology is in this perspective denoted “fuel engineering” and is based on a combined approach including both fuel design and process control measures. The studies on time-resolved potassium release showed that a Macro-TG reactor with single pellet experiments was a valuable tool for studying ash transformation along the fuel conversion. The combination of dedicated release determinations based on accurate mass balance considerations and ICP analysis, with phase composition characterization by XRD, is important for the understanding of potassium release in general and time-resolved data in particular. For wood, the results presented in this work supports the potassium release mechanism from "char-K" but questions the previously suggested release mechanism from decomposition of K-carbonates. For straw, the present data support the idea that the major part of the potassium release is attributed to volatilization of KCl. To further explore the detailed mechanisms, the novel approach developed and applied in this work should be complemented with other experimental and analytical techniques. The research in this thesis has explored some of the challenges related to the combined phenomena of fuel conversion and ash transformation during thermochemical conversion of biomass, and has contributed with novel methods and approaches that have gained new knowledge to be used for the development of more effective bioenergy systems.

The control of particle emissions from an oil refinery is often difficult, due to changing operational conditions and the limited range of available treatment options. Excessive particle emissions have often been attributed start up problems with Fluidized Catalytic Cracker Units (FCCU) and little information is available regarding the exact composition and nature of these excessive emissions. Due to the complex nature of a FCCU, it has in the past been difficult to identify and control emissions, without the use of expensive end of pipe technologies. An Australian Oil Refinery, concerned with their catalyst emissions, sponsored this study of FCCU particle emissions. Due to the industrial nature of the project, a holistic approach to the management of emissions was taken, instead of a detailed investigation of a single issue. By looking at the broader range of issues, practical and useful outcomes can be achieved for the refinery. Initially, detailed emissions samplings were conducted to investigate the degree of particle emissions under start up conditions. Stack emissions were collected during a standard start up, and analysed to determine the particle size distribution and metal concentration of the emitted material. Three distinct stages of emissions were discovered, initially a high concentration of larger particles, followed by a peak in the very fine particles and finally a reduction of particle emissions to a more steady or normal operational state. The variation in particle emissions was caused by operational conditions, hardware design and catalyst characteristics. Fluctuations in the gas velocity through the system altered the ability of the cyclones to collect catalyst material. Also, the low bed level allowed air bypass to occur more readily, contributing to the increased emissions levels seen during the initial stage of the start up. Reduced fluidity characteristics of the circulating catalyst also affected the diplegs operations, altering the collection efficiency of the cyclone. During the loading of catalyst into the system, abraded material was quickly lost due to its particle size, contributing to fine particle emissions levels. More importantly, thermal fracturing of catalyst particles occurred when the cold catalyst was fed into the hot regenerator. Catalyst particles split causing the generation of large amounts of fine particle material, which is easily lost from the system. This loading of catalyst directly linked to the period of high concentration of fine particles in the emissions stream. It was found that metals, and in particular iron, calcium and silicon form a thick layer on the outside of the catalyst, with large irregular shaped metal ridges, forming along the surface of the particle. These ridges reduce the fluidity of the catalyst, leading to potential disruptions in the regenerator. In addition to this, the metal rich ridges are preferentially removed via attrition, causing metal rich material to be emitted into the atmosphere. To overcome these high particle emissions rates from the FCCU the refinery should only use calcinated catalyst to reduce the influence of thermal process and particle fracture and generation. Although the calcinated catalyst can fracture when added to the system, it is far less than that obtained with uncalicinated catalyst. To further reduce the risk of particle fracture due to thermal stresses the refinery should consider reducing the temperature gradients between the hot and cold catalyst. Due to the economics involved with the regenerator, possible pre-warming of catalyst before addition into system is the preferred option. This pre-heating of catalyst should also incorporate a controlled attrition stage to help remove the build up of metals on the surface of the particles whilst allowing this material to be collected before it can be released into the atmosphere. The remove of the metal crust will also improve the fluidity of the system and reduce the chance of catalyst blockages occurring. Finally, modelling of the system has shown that control of key parameters such as particle size and gas velocity are essential to the management of air emissions. The refinery should look at adjusting start up procedures to remove fluctuations in these key parameters. Also the refinery should be careful in using correlation found in the literature to predicted operational conditions in the system as these correlations are misleading when used under industrial situations.

Intresset för biobränsleproducerad energi har ökat i takt med att kunderna blivit mer miljömedvetna. På grund av detta har efterfrågan på briketter ökat samtidigt som träindustrin har haft det svårt i en sviktande konjunktur. Därför har ett examensarbete utförts i samarbete med E.ON Värme Sverige AB där undersökningar på bränslebyte i pannor avsedda för torra bränslen till fuktigare, stamvedflis har utfört. För denna undersökning har begränsningar införts på övre och undre effekt i form av uppehållstid och slutförbränningstemperatur. Intervallen är enbart beräknade på stamvedflis med 30 och 40 % fukthalt. Undersökning visar att det går bra att elda stamvedsflis i briketteldade pannor utan att emissionerna ökar så pass mycket att villkoren för anläggningarna överskrids om lasten hålls inom vissa intervall. Det möjliga effektintervallet ökar med minskad fukthalt på bränslet. Undersökningen har visat att det är bränslets kvalitet som är den mest begränsande faktorn. / The interest in bioenergy has increased with increased environmental awareness. The increasing demand on biofuels and the decreasing availability of the rawmaterials for making refined biofuels such as wood briquettes and wood pellets have caused the prices of these biofuels to increase. This report is performed in collaboration with E.ON Värme Sverige AB and its purpose is to investigate the possibilities for a change of fuels in existing boilers designed for refined biofuels, from wood briquettes to wood chips. To be able to calculate a power interval where it would be possible to use wood chips with moisture contents of 30 and 40% by weight respectively, we had to make some assumptions regarding maximum flue gas flow, minimum retention time and the lowest temperature regarding complete combustion of CO. Our calculations show that it is possible to use woodchips with a moisture content of 30 % w/w without any significant problems in all our boilers. When the moisture content is increased to 40 % w/w the interval for possible power output becomes more narrow. The amount of dust that is being emitted from the boilers does not exceed the limits regulated by environmental law, unless the thermal load of the boiler is too high. The single most important factor for a successful change of fuel from wood briquettes to woodchips is that the fuel quality is good.

<p>Intresset för biobränsleproducerad energi har ökat i takt med att kunderna blivit mer miljömedvetna. På grund av detta har efterfrågan på briketter ökat samtidigt som träindustrin har haft det svårt i en sviktande konjunktur. Därför har ett examensarbete utförts i samarbete med E.ON Värme Sverige AB där undersökningar på bränslebyte i pannor avsedda för torra bränslen till fuktigare, stamvedflis har utfört.<strong></strong></p><p>För denna undersökning har begränsningar införts på övre och undre effekt i form av uppehållstid och slutförbränningstemperatur. Intervallen är enbart beräknade på stamvedflis med 30 och 40 % fukthalt.</p><p>Undersökning visar att det går bra att elda stamvedsflis i briketteldade pannor utan att emissionerna ökar så pass mycket att villkoren för anläggningarna överskrids om lasten hålls inom vissa intervall. Det möjliga effektintervallet ökar med minskad fukthalt på bränslet.</p><p>Undersökningen har visat att det är bränslets kvalitet som är den mest begränsande faktorn.</p> / <p>The interest in bioenergy has increased with increased environmental awareness. The increasing demand on biofuels and the decreasing availability of the rawmaterials for making refined biofuels such as wood briquettes and wood pellets have caused the prices of these biofuels to increase. This report is performed in collaboration with E.ON Värme Sverige AB and its purpose is to investigate the possibilities for a change of fuels in existing boilers designed for refined biofuels, from wood briquettes to wood chips.</p><p>To be able to calculate a power interval where it would be possible to use wood chips with moisture contents of 30 and 40% by weight respectively, we had to make some assumptions regarding maximum flue gas flow, minimum retention time and the lowest temperature regarding complete combustion of CO.</p><p>Our calculations show that it is possible to use woodchips with a moisture content of 30 % w/w without any significant problems in all our boilers. When the moisture content is increased to 40 % w/w the interval for possible power output becomes more narrow. The amount of dust that is being emitted from the boilers does not exceed the limits regulated by environmental law, unless the thermal load of the boiler is too high.</p><p>The single most important factor for a successful change of fuel from wood briquettes to woodchips is that the fuel quality is good.<strong></strong></p>

Denna kandidatuppsats är en studie av miljöprestandan hos   en lastbilskran satt i relation till användning av en mobilkran.   Miljöprestandan hos lastbilskranen studeras och jämförs med mobilkranens   givet ett visst nyttjandescenario. Miljöprestandan mäts i miljöparametrarna:   klimatpåverkan, energiförbrukning, energieffektivitet samt partikelutsläpp.   Realistiska och mätbara nyttjandescenarier har utarbetats utifrån studiebesök   och intervjuer med Vemservice, Jämtlands Mobilkranar och Curt Sillström   Åkeri. Kandidatuppsatsen är skriven som en del i den miljöstudie som ingår i   utvecklingsprojektet Forskning och utveckling av lastbilars   centralram för minskad miljöpåverkan vid tung transport. Projektet   drivs av Vemservice (Vemdalsservice AB) och syftar till att utveckla   centralramen på en lastbilskran genom att öka dess lyftkapacitet. Projektets   mål är att ersätta mobilkranar med lastbilskranar i en högre utsträckning än   vad som görs idag. I projektet deltar även teknikkonsultföretaget DRIV   Innovation, materialoptimeringstjänsten SSAB Shape samt Mittuniversitetet. En lastbilskran är en lastbil med en kran påmonterad på   flaket, med plats på flaket för att transportera gods. Lyftförmågan hos en   lastbilskran beror både av kranens styrka och själva lastbilens vrid- och böjhållfasthet.   I denna studie har en lastbilskran från Curt Sillströms Åkeri studerats.   Lastbilskranens främsta användningsområden är vid nybyggnationer av   bostäder, flytt av containrar och bodar på arbetsplatser samt vid flytt av   tunga föremål in och ut ur byggnader. Mobilkran kallas det   arbetsfordon som har en lyftkran med svängarm monterad på fordonet, den används inte för transport av gods.   Mobilkranen i denna studie tillhör Jämtlands Mobilkranar och används främst i   lyftarbeten såsom byggande av bostäder och arbeten vid vattenkraftverk. Resultatet   av den studerade miljöprestandan baseras på tre specifika nyttjandescenarior.   Nyttjandescenarierna innefattade att transportera och lyfta en given mängd   gods en given sträcka och tid. Lastbilskranen har högre miljöprestanda än   mobilkranen vid jämförelse i de tre scenarierna, dvs. lägre utsläpp och   mindre energiförbrukning. Den minsta skillnaden i miljöprestanda uppstår när   enbart lyftarbete utförs, då lastbilskranens fulla funktion inte nyttjas då   den ej transporterar något gods. Det troligtvis mest typiska   nyttjandescenariot är att gods både ska transporteras och lyftas. I detta   fall har lastbilskranen flera fördelar tack vare att dess fulla funktion   utnyttjas. / This bachelor thesis is a study of the environmental performance of a loader crane in relationship to the usage of a mobile crane. The environmental performance of the loader crane is studied and compared to the mobile cranes performance given a set of specific user scenarios. The environmental performance is measured using the following environmental parameters:climate impact, energy consumption, energy efficiency and particle emissions. Realistic and measurable user scenarios were prepared using information from visits and interviews with Vemservice, Jämtlands Mobilkranar and Curt Sillström Åkeri. The thesis is written as a part of the environmental study that is included in the developmental project “Forskning och utveckling av lastbilars centralram för minskad miljöpåverkan vid tung transport”. The project is managed by Vemservice (Vemdalsservice AB) and the purpose of the project is to develop the frame on a loader crane by increasing the capacity for lifting. The goal of the project is to replace mobile cranes with loader cranes to a higher degree than what is currently the case. The projects participants are also made up by the technology consulting DRIV Innovation, SSAB Shape and also Mid Sweden University. A loader crane is a truck with a crane mounted on its flatbed and also room on the flatbed for the transport of goods. The lifting capabilities of a loader crane is dependent on the strength of the crane and the rigidity of the frame of the truck itself. In this thesis, a loader crane from Curt Sillström Åkeri AB is studied. The main usage of the loader crane in this study is in construction, the moving of work site sheds and in the moving of heavy objects in and out of houses. A mobile crane is a work vehicle with a crane and swing arm mounted on the back of the vehicle. The mobile crane in this study belongs to Jämtlands Mobilkranar and is primary used for heavy lifting in construction and work at a hydro power plant. As opposed to the loader crane, the mobile crane is not used for the transport of goods. The resulting environmental performance was based on three specific user scenarios. The user scenarios consisted of lifting and transporting a given amount of goods for a specified distance and time. When a comparison is made between the loader crane and mobile crane for total emissions and energy consumption in each user scenario, the loader crane has a larger environmental performance. The smallest difference in environmental performance arises when lifting is the only work being done, due to the fact that the full capacity of the loader crane is not utilized since it is not used to transport goods. Likely the most typical user scenario consists of goods being both transported and lifted. In this case the loader crane has a number of advantages because its full capacity is being utilized. / <p>2018-02-01</p>

<p>Additive manufacturing (AM) can be an advantageous substitute to various traditional manufacturing techniques. Due to the ability to rapidly create products, AM has been traditionally used to prototype more efficiently. As the industry has progressed, however, use cases have gone beyond prototyping into production of complex parts with unique geometries. Amongst the most popular of AM processes is fused deposition modeling (FDM). FDM fabricates products through an extrusion technique where plastic filament is heated to the glass transition temperature and extruded layer by layer onto a build platform to construct the desired part. The purpose of this research is to elaborate on the potential of this technology, while considering environmental impact as it becomes more widespread throughout industry, research, and academia.</p> <p>Although AM consumes resources more conservatively than traditional methodologies, it is not free from having environmental impacts. Several studies have shown that additive manufacturing can affect human and environmental health by emitting particles of a dynamic size range into the surrounding environment during a print. To begin this study, chapters investigate emission profiles and characterization of emissions from FDM 3D printers with the intention of developing a better understanding of the impact from such devices. Background work is done to confirm the occurrence of particle emission from FDM using acrylonitrile butadiene styrene (ABS) plastic filament. An aluminum bodied 3D printer is enclosed in a chamber and placed in a Class 1 cleanroom where measurements are conducted using high temporal resolution electrical low-pressure impactor (ELPI), scanning mobility particle sizer (SMPS), and optical particle sizer (OPS), which combined measure particles of a size range 6-500nm. Tests were done using the NIST standard test part and a honeycomb infill cube. Results from this study show that particle emissions are closely related to filament residence time in the extruder while less related to extruding speed. An initial spike of particle concentration is observed immediately after printing, which is likely a result of the long time required to heat the extruder and bed to the desired temperature. Upon conclusion of this study, it is theorized that particles may be formed through vapor condensation and coagulation after being released into the surrounding environment.</p> <p>With confirmation of FDM ultrafine particle emission at notable concentrations, an effort was consequently placed on diagnosing the primary cause of emission and energy consumption based on developed hypotheses. Experimental data suggests that particle emission is mainly the result of condensing and agglomerating semi-volatile organic compounds. The initial emission spike occurs when there is dripping of semi-liquid filament from the heated nozzle and/or residue left in the nozzle between prints; this supports the previously stated hypothesis regarding residence time. However, the study shows that while printing speed and material flow influence particle emission rate, the effects from these factors are relatively insignificant. Power profile analysis indicates that print bed heating and component temperature maintaining are the leading contributors to energy consumption for FDM printers, making time the primary variable driving energy input.</p> <p>To better understand the severity of FDM emissions, further investigation is necessary to diligence the makeup of the process output flows. By collecting exhaust discharge from a Makerbot Replicator 2x printing ABS filament and diffusing it through a type 1 water solution, we are able to investigate the chemical makeup of these compounds. Additional exploration is done by performing a filament wash to investigate emissions that may already be present before extrusion. Using solid phase micro-extraction, contaminants are studied using gas chromatography mass spectrometry (GCMS) thermal desorption. Characterization of the collected emission offers more comprehensive knowledge of the environmental and human health impacts of this AM process.</p> <p>Classification of the environmental performance of various manufacturing technologies can be achieved by analyzing their input and output material, as well as energy flows. The unit process life cycle inventory (UPLCI) is a proficient approach to developing reusable models capable of calculating these flows. The UPLCI models can be connected to estimate the total material and energy consumption of, and emissions from, product manufacturing based on a process plan. The final chapter focuses on using the knowledge gained from this work in developing UPLCI model methodology for FDM, and applying it further to the second most widely used AM process: stereolithography (SLA). The model created for the FDM study considers material input/output flows from ABS plastic filament. Energy input/output flows come from the running printer, step motors, heated build plate, and heated extruder. SLA also fabricates parts layer by layer, but by the use of a photosensitive liquid resin which solidifies when cured under the exposure of ultraviolet light. Model material input/output flows are sourced from the photosensitive liquid resin, while energy input/output flows are generated from (i) the projector used as the ultraviolet light source and (ii) the step motors. As shown in this work, energy flow is mostly time dependent; material flows, on the other hand, rely more on the nature of the fabrication process. While a focus on FDM is asserted throughout this study, the developed UPLCI models show how conclusions drawn from this work can be applied to different forms of AM processes in future work.</p>