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Here we investigate sedimentological responses to past climate change in shallow to deep marine depositional environments. Our primary study spans from the Late Pliocene to the Pleistocene (3.3 to 0.7 Ma), and features results from two International Ocean Discovery Program (IODP) Sites U1525 and U1524. Each of these sites is discussed in separate chapters here (Chapters 1 and 2). This interval experienced the change from the warming of the Late Pliocene, known as the Mid-Piacenzian Warming Period, to the Pleistocene cooling. This shift significantly impacted the expansion of the West Antarctic Ice Sheet, sea ice/polynya formation, and, notably, the genesis of Antarctic Bottom Water (AABW), a crucial component of the global thermohaline circulation. In Chapter 1, we propose that turbidite currents, arising from the formation of dense shelf water (DSW) in the Ross Sea (a precursor to AABW), leave a distinct record in the levees of Hillary Canyon. This canyon acts as a conduit, channeling DSW into the deep ocean and contributing to AABW production. By analyzing turbidite beds based on their frequency, thickness, and grain size, we gain insights into the historical occurrence and magnitude of these currents. Furthermore, we explore the influence of factors such as shelf availability and sea ice/polynya formation within the broader climate context of AABW formation. Chapter 2 shifts its focus to the sedimentological variability from shelf-to-slope along Hillary Canyon. This chapter examines the turbidite record associated with AABW formation within the shared timeframe (2.1 to 0.7 million years ago) between IODP Sites U1524 and U1525, and the impact of along slope currents and other processes in the sedimentary deposition and transport. The second study interval (Chapter 3), focuses on the regional sedimentological response proximal to a hydrothermal vent complex associated with the Paleocene-Eocene Thermal Maximum (PETM; ca. 56 Ma), a global warming event during which thousands of Gt C was released into the ocean-atmosphere on Kyr timescales. IODP Site U1568, strategically located near the hydrothermal vent complex and part of a broader drilling transect in the Modgunn Arch, North Atlantic, is the main study subject. This site's proximity to the vent complex offers a distinctive environment for refining our understanding of stratigraphy and sedimentology within the PETM. We achieve this through a comprehensive analysis of grain size and composition, coupled with a comparison to XRF data. Our findings show that the timing between the onset of the PETM and the response of the sedimentary system to the warming, reflected in the grain size coarsening after the start of the PETM, is not synchronous. Notably, the transition from a marine to a more terrestrial composition predates this shift in grain size, aligning with the PETM onset instead. / Doctor of Philosophy / Deep-marine core records are invaluable sources of sedimentological information that provide insights into the ocean's response to past climates. These cores, extracted from the deep-ocean floor, contain layers of sediment that accumulate over time because of the different processes that occur in the ocean. Analyzing these sediments, by looking at their physical characteristics like how frequently are they deposited, the thickness of the layers, their grain size, and their composition helps to reconstruct past environmental conditions and understand how the oceans have responded to climatic changes. This dissertation focuses on studying the record of two main processes. The first one is the sedimentary record left behind by the formation of Antarctic Bottom Water (AABW), one of the coldest (-1°C), deepest (> 2000 meters below sea level), and densest water masses in the ocean. AABW is a key component of the global ocean circulation system, often referred to as the "global conveyor belt" or the thermohaline circulation. This circulation pattern plays a crucial role in redistributing heat, salt, and nutrients around the world's oceans. AABW is formed near Antarctica through a process that begins with the cooling and sinking of surface waters near the continent. As these waters sink, they become denser and eventually form AABW, filling the deep ocean basins around Antarctica. The dense water flows from the surface to the bottom of the ocean forming turbidity currents. These turbidity currents, dense plumes of water and sediments, flow down submarine conduits, such as Hillary Canyon in the Ross Sea, Antarctica, leaving a sedimentary record in the levees or flanks, called turbidites. The turbidite sequences in sediment cores can reveal information about the frequency and magnitude of these currents, providing insights into the sediment transport processes in deep-marine settings, and for this work, the history of the AABW formation over the last 3.3 Ma. This study will help to understand what are the main controls for AABW formation across different climates in the past, and how we project this into the future climate scenarios. In the second part of the study (Chapter 3), we look at the sedimentary record of a warming event that happened around 56 million years ago. This event, known as the Paleocene-Eocene Thermal Maximum (PETM), involved a significant amount of carbon being released into the air and oceans over thousands of years (150,000 to 200,000). Our focus is IODP Site U1568, located near a submarine hydrothermal vent, and part of a larger drilling transect in the North Atlantic's Modgunn Arch. The vent's unique location provides a crucial perspective for understanding how the system responded to the warming during the Paleocene-Eocene Thermal Maximum (PETM). This warming event was triggered by the release of carbon into the atmosphere, with the vent serving as one of the conduits for this release. To understand this, we studied the grain size and content of the sediment, and compared that with XRF data. Changes in grain size serve as indicators of shifts in the energy of the environment – coarser grains signify a more energetic system. Warmer weather, for instance, can increase precipitation, leading to more erosion and sediment influx into the basin. This influx also brings in more materials from the land, as evidenced by the presence of microfossils and plant fragments. Our discoveries indicate that the sedimentary system responded gradually to the PETM, as reflected in the coarsening of grain size after the PETM's onset. Notably, the transition from a marine to a more terrestrial composition occurred before the change in grain size, aligning more closely with the initiation of the PETM itself.

During the Late Pliocene, between 3.3 Ma and 2.6 Ma, tectonic events changed ocean basin interactions against a background of shifting orbital forcing mechanisms and a global cooling trend. A climate system that had been locked in a stable, warm state gradually transformed into one typified by the high-amplitude glacial–interglacial fluctuations characteristic of the later Quaternary. The onset of Northern Hemisphere glaciations in the Late Pliocene marks an important step in this transition, due to the role of feedback mechanisms including ice albedo. A crucial factor in this Northern Hemisphere ice sheet expansion is the North Atlantic surface ocean circulation. To evaluate how they are linked, a ca. 200-kyr time slab spanning 2782-2520 ka (Late Pliocene–Early Pleistocene) was analyzed at millennial scale resolution from eastern North Atlantic Deep Sea Drilling Project (DSDP) Site 610 and Integrated Ocean Drilling Program (IODP) Site U1313. The causes of the Plio-Pleistocene climatic turnover are compared to that of the well-documented Marine Isotope Stage (MIS) M2 occurring in the Late Pliocene (3.3 Ma). MIS M2, a severe glacial event seen as a precursor to later Quaternary-style glaciations, was investigated from western North Atlantic DSDP Site 603. Utilizing a same-sample methodology, two paleoceanographic proxies were used: (1) dinocyst assemblages, and (2) foraminiferal geochemistry (δ18O and Mg/Ca). Dinocysts are proven tracers of sea-surface temperature (SST), salinity, nutrient supply, and sea ice cover, and are analyzed here to characterize the overlying water masses at the studied sites. Strong dinocyst assemblage fluctuations attest to variations in the influence of the North Atlantic Current (NAC). Using Mg/Ca ratios for the planktonic foraminifer Globigerina bulloides to determine absolute SSTs allows salinity changes to be reconstructed when combined with stable oxygen isotopes. This study shows a persistent Gulf Stream–NAC in the western North Atlantic during MIS M2, favoring a southern shift of the NAC over a shutdown of the thermohaline circulation. At the newly established Plio-Pleistocene boundary, a profound turnover in dinoflagellate cyst assemblages reveals a shift in ocean mode during MIS 104 (2.6 Ma). Three distinct dinocyst ecozones demonstrate this fundamental reorganization of the North Atlantic circulation.

La formation géologique Mursi est datée à plus de 4 millions d’années, ce qui correspond à la période de l’émergence présumée des australopithèques, premiers hominines présentant une bipédie incontestable. La collection faunique Mursi (N=201) est comparée à celle du membre A de la Formation Shungura (N=300) sur une base taphonomique. La taphonomie est la science dédiée aux modes de formation des fossiles ainsi qu’aux traces laissées par ceux-ci. L’objectif principal de ce mémoire est de vérifier quelles sont les différences et ressemblances entre ces deux assemblages fossiles et d’en tirer des interprétations paléoenvironnementales. Pour chacun des agents taphonomiques (météorisation, piétinement, etc.), les fossiles sont gradés en fonction de stades prédéfinis tirés des écrits scientifiques. Finalement, malgré quelques différences (action des carnivores, intempérisation) on constate que les assemblages sont assez semblables et que, comme prédit par les reconstructions paléoenvironnementales préexistantes, leur lien à l’eau est assez bien démontré (groupes de Voorhies, abrasion). / The Mursi Formation has an age estimated at more than 4 million years, which corresponds to the emergence of the australopithecines, the first indisputably bipedal hominins. The Mursi faunal collection (N=201) is compared taphonomically to that of the Member A of the Shungura Formation (N=300). Taphonomy is the study of the processes that intervene between the death of an animal and its discovery as a fossil. This thesis aims to describe the main differences and similarities of these two collections and to make paleoenvironmental inferences. For each taphonomical agent (weathering, trampling, etc.), fossils are graded using stages established by other researchers. In spite of a few significant differences (carnivore action, weathering), it seems that the two collections are taphonomically similar and their link with water, as predicted by paleoenvironmental reconstructions, is supported (Voorhies groups, abrasion).

Clays and clay mineral distribution studies are important for understanding the geological history of the Gulf of Mexico Basin, but few studies document any subsurface clay mineral distribution in the Gulf of Mexico. Shale samples from nine wells (30 samples) in the South Timbalier protraction were selected near known paleontological markers identifying the Miocene, Pliocene, and Pleistocene boundaries. Bulk mineralogy of each sample, determined by XRD, is primarily mixed-layer smectite and illite with a minor amount of kaolinite. The mixed-layer mineralogies are end-member smectite, mixed-layer smectite, mixed-layer illite, and end-member illite. These clay mineral fractions do not correlate with age. The illite mixed layer percentage correlates with depth, but the correlation decreases when depth is converted to temperature. However, the illite mixed layer fraction does not exhibit a strong correlation in this multiwell study when compared to a single well study in Ship Shoal using identical methods (Totten et al., 2002).

Les plantes et les insectes forment l’un des principaux niveaux trophiques des écosystèmes au cours des 325 derniers millions d’années. Aujourd’hui, l’augmentation rapide et continuelle de la température principalement causée par l’activité humaine depuis les derniers siècles, perturbe la balance des écosystèmes sur Terre. En conséquence, comprendre le rôle des interactions entre les plantes et les insectes, à travers le temps mais aussi les réseaux trophiques, est essentiel. Le registre fossile est une opportunité exceptionnelle d’examiner les réponses aux interactions plante-insecte lors de longues variations climatiques et à travers des traces de réaction de la plante sachant que la Terre a déjà été soumise à de nombreux changements climatiques. Durant les derniers 3 millions d’années, des oscillations entre de longues périodes froides et de courtes périodes chaudes ont eu lieu. Les écosystèmes Européens ont particulièrement été impactés par ces oscillations. Le Langerstätte de Willershausen (Allemagne) a été particulièrement étudié. C’est un gisement contenant plus de 8000 feuilles fossiles. Ces feuilles relatent d’une paléoforêt ayant existé il y a 3- 2,6 Ma dans un climat plus chaud qu’aujourd’hui (ca.+5°C). Dans ces conditions climatiques, de nombreuses espèces d’écosystèmes Méditerranéens étaient présentes, telles que l’Érable de Montpellier ou l’Olivier. En comparaison, d’autres paléoforêts ont été prise en compte : Berga (du même âge et proche de Willershausen) et Bernasso (plus jeune que Willershausen (2,16 — 1,96 Ma) localisée dans le sud de la France près de la Méditerranée. Ces forêts sont comparables notamment du fait des nombreux taxons communs qu’elles partagent. En outre, certaines de ces espèces sont aujourd’hui endémiques de la région du Caucase, telles que le Parrotie de Perse ou encore l’orme du Caucase. Le but de cette étude a été de déterminer en quoi les différences climatiques peuvent être impliquées dans les changements des interactions plante-insecte au sein des paléoforêts Européennes de la fin du Pliocène - début du Pléistocène. Les résultats obtenus ont permis de mettre en évidence les impacts de la saisonnalité des températures et précipitations facteurs impactants les interactions plante-insecte des paléoforêts Européennes. Il est apparu que les écosystèmes sujets à d’intenses saisonnalités hydriques ont pu engendrer une plus grande spécialisation des interactions plante-insecte déduite d’un fort taux d’interactions spécialistes observées. En parallèle, les températures les plus froides durant l’année semble être un facteur important dans la faible diversité de dégâts, probablement dû à un faible métabolisme de la majorité des insectes. L’absence de corrélation convergente entre la richesse des plantes et la richesse des interactions pourrait suggérer que l’influence des facteurs climatiques surpasse l’impact potentiel des interactions biotiques locales. Pour l’ensemble de ces paramètres qui ont pu avoir un impact sur les interactions plante-insecte, nos connaissances actuelles sont encore insuffisantes. Il serait intéressant de focaliser davantage d’études sur les forêts modernes avec les méthodes appliquées dans le fossile. C’est dans cette intention qu’une partie de cette étude a étudié une espèce de plante (Parrotia persica) actuellement endémique de la forêt Hyrcanienne (Iran). Cette forêt est supposée être une forêt analogue des paléoforêts Européennes étudiées dans cette thèse. Pour le moment, les observations qui ont été faites en Iran semblent corroborer notre interprétation. Au final, les études sur les interactions plante-insecte des forêts anciennes et actuelles, combinés avec les études de changements climatiques, pourraient nous permettre de mieux caractériser les relations entre les insectes et les plantes au sein d’une forêt. / Insects are the most diverse animals on Earth, and neatly associated with plants they represent two of the major groups of organisms both in species diversity and biomass quantity. The majority of their interactions involves insect feeding and insect parasitism mostly on leaves. Plant and insect compose one of the main trophic levels in ecosystems over the 325 million years. Today, the continuous and fast rising of temperature mostly due to human activities since the last century is disturbing the balance of ecosystems on Earth. Consequently, to understand the role of plant and insect interactions, through time but also trophic networks, becomes crucial. The fossil record is an exceptional opportunity to survey responses of plant-insect interaction to climate variations over long time interval through traces of plants reactions caused by interaction with insects, as Earth has already experienced many climate changes. For the last 3 million years, oscillations between long cold periods and short warm periods have occurred. Europe ecosystems has been particularly impacted. The Lagerstätte of Willershausen (Germany) was specifically study. It is an exceptional fossil outcrop that contains ca. 8000 collected fossil leaves. These leaves testify a paleoforest developed there around 3—2.6 Ma ago in a climate warmer than today (ca. +5°C). Under these conditions, many plant species typical of the Mediterranean ecosystems were settled there, such as Montpellier maple or Olive tree. For comparison, other paleoforests were studied: Berga (similar in age and geographically close to Willershausen) and Bernasso (younger than Willershausen (2.16—1.96 Ma) and located in southern France close to Mediterranean. These forests were compared as many common plant taxa were similar between each other. Furthermore, some species today endemic to the Caucasian region, such as Persian ironwood or Caucasian elm, were also present in these outcrops. The aim of this study is to determine how far the climate differences could be involved in the changes of plant-insect interactions in European paleoforests of the late Pliocene – early Pleistocene. Results highlighted the impacts of both hydric and temperature seasonality, hitherto underestimated in the fossil record, on the patterns of plant-insect interaction in the European paleoforests. It appeared that ecosystems subject to intense hydric seasonality could led to higher specialization of plant-insect interaction inferred by higher rate of observed damages due to ‘specialists insects’. In parallel, the coolest temperature during the year seems to be a major factor in the low diversity of damage in paleoforest, presumably due to lower insect metabolism. Absence of convergent correlations between plant richness and damage richness could suggested that influence of climatic factors override impact of these local biotic factors. In order to understand the whole parameters that could have an impact on plant-insect interactions, our current knowledges are still insufficient. It would be wise to make more investigations on modern forests with the methods as applied in fossil record community structure studies. These investigations could help to understand the factors potentially involved in the establishment of a pattern of plant-insect interactions. It is in this perspective that a part of this study was precisely focused on one plant species (Parrotia persica) currently endemic to the Hyrcanian forest (Iran). This forest is supposed to be an analogue forest of the European paleoforests as those studied in this thesis. For now, observations made in Iran tend to corroborate our interpretation. Finally, the studies on plant-insect interactions in past and extant ecosystems, combined with the study of climatic changes, should permit us to better characterize the relations between plants and insects in forests through time.

Four multicyclic complex calderas and smaller ignimbrite shields located within the Altiplano Puna Volcanic Complex of the Central Andes (APVC) erupted 13000 km�� of magma within the last 11 Ma. One of the largest and most complex of these is the Cerro Guacha Caldera. Ar-Ar age determinations and paleomagnetic directions suggest that the Cerro Guacha Caldera was formed by two major eruptions, caldera collapse, resurgence cycles and several smaller eruptions. Two major ignimbrites (> 600 km��) are found with ������Ar-�����Ar from biotites and sanidines of 5.65 �� 0.01Ma for the 1300 km�� (magma volume) Guacha ignimbrite and 3.49 �� 0.01Ma for the 800 km�� Tara Ignimbrite. The last major eruption occurred on the western flank producing the 1.72 �� 0.02 Ma Puripica Chico Ignimbrite with a volume of approximately 10 km��. Characteristic remanent magnetization data (ChRM) for these ignimbrites show that the Guacha has reverse polarity, while the Tara is normally polarized and the magnetic fingerprints have allowed their current full extents to be identified. A conspicuous lineament of volcanic structures in the eastern part of the caldera, bordering a caldera moat, filled out welded ignimbrites and sedimentary lacustrine sequences suggest an earlier 60x40 km outer collapse associated with the Guacha explosive episode. A central graben formed on the Guacha welded ignimbrite is related to a first episode of resurgence. Evidence of a second 30 x15 km inner collapse includes offset of welded Guacha ignimbrites and alignment of lava domes associated with the Tara ignimbrite. A second resurgence episode is suggested by the presence of an uplifted central block consisting primarily of welded Tara ignimbrite. As a whole the three ignimbrites (Guacha, Tara and Puripica Chico) share the same petrological and geochemical characteristics: high-K series, compositional ranges from dacite to rhyolite, with andesitic members present as lavas (for the Guacha and Puripica Chico Ignimbrites) and as pumices (for the Tara Ignimbrite). Highest silica content is found in the Chajnantor dome. Rayleigh modeling for Ba, Rb and Sr suggests at least 60% of crystal fractionation to account for the compositional variation between the Guacha andesite and the Chajnantor dome. Dy/Hb ratio increases with time from the Guacha andesite to the Negreal andesite suggesting stabilization of garnet owing to crustal thickening. Fe-Ti exchange geothermometry for the Tara Ignimbrite yielded log fO��� values ranging from -13.06 to -13.38 and temperatures of 714�� to 801��C. Amphibole geobarometry yielded pressures ranging from 150 to 180 MPa equivalent to 5.3 and 6.4 km depth respectively for the Tara Ignimbrite; the pressures range between 133 to 242 MPa, equivalent to 5.0 to 9.2 km depth for the Guacha Ignimbrite. The zircon saturation method yielded saturation temperatures of 716�� and 705��C for the Guacha and Chajnantor dome respectively and 784��C for the Tara Ignimbrite. The zircon crystallization range for the magmas of the Cerro Guacha Caldera is 1.25 Ma for the Guacha Ignimbrite; 1.09 Ma for the Puripica Chico Ignimbrite and 0.95 Ma for the Tara Ignimbrite. Recycling of antecrystic zircons within the caldera magmas is continuos through time. / Graduation date: 2012

The major purpose of this study is to evaluate the paleoenvironmental and paleoclimatological conditions during the Middle Miocene-Early Pliocene in Kalecik-Ankara by using mineralogical and geochemical proxies from Han&ccedil / ili Formation. To achieve a high-resolution paleoclimate data, 2 stratigraphic sectioning and 1 continous core drilling were examined. Field studies were followed by analytical techniques on the selected representative samples. The mineralogical compositions of the bulk samples and the minerals of the clay fractions were determined by X-ray diffractometer. Scanning electron microscopic analyses were also carried on the specific samples which have the potential to define the important microstructural units. The major and trace elemental compositions were determined by X-ray fluoresence spectrometer. Additionally, the stable isotope compositions of the samples selected from the continous core drilling on Han&ccedil / ili formation were among the major proxies to gather a paleoenvironmental and paleoclimatrological approach. All the proxies employed for this study clearly indicate that mineralogical and geochemical signatures are consistent with each other and can be used for paleoclimatic interpretations. The stable isotope values point that C4 plants were dominant during the deposition of Han&ccedil / ili Formation, while evaporation caused the development of alkaline environment which is seasonally dry with depositional temperature approximately between 25-30&deg / C. During deposition, lava flowand tuff were deposited due to the volcanic activity in the vicinity of the lake. Based on this volcanism, economical bentonite deposits were originated. The lake at which the Han&ccedil / ili formation was deposited, completed its development in a time to time silicate rich and salty-alkaline anvironment.

La formation géologique Mursi est datée à plus de 4 millions d’années, ce qui correspond à la période de l’émergence présumée des australopithèques, premiers hominines présentant une bipédie incontestable. La collection faunique Mursi (N=201) est comparée à celle du membre A de la Formation Shungura (N=300) sur une base taphonomique. La taphonomie est la science dédiée aux modes de formation des fossiles ainsi qu’aux traces laissées par ceux-ci. L’objectif principal de ce mémoire est de vérifier quelles sont les différences et ressemblances entre ces deux assemblages fossiles et d’en tirer des interprétations paléoenvironnementales. Pour chacun des agents taphonomiques (météorisation, piétinement, etc.), les fossiles sont gradés en fonction de stades prédéfinis tirés des écrits scientifiques. Finalement, malgré quelques différences (action des carnivores, intempérisation) on constate que les assemblages sont assez semblables et que, comme prédit par les reconstructions paléoenvironnementales préexistantes, leur lien à l’eau est assez bien démontré (groupes de Voorhies, abrasion). / The Mursi Formation has an age estimated at more than 4 million years, which corresponds to the emergence of the australopithecines, the first indisputably bipedal hominins. The Mursi faunal collection (N=201) is compared taphonomically to that of the Member A of the Shungura Formation (N=300). Taphonomy is the study of the processes that intervene between the death of an animal and its discovery as a fossil. This thesis aims to describe the main differences and similarities of these two collections and to make paleoenvironmental inferences. For each taphonomical agent (weathering, trampling, etc.), fossils are graded using stages established by other researchers. In spite of a few significant differences (carnivore action, weathering), it seems that the two collections are taphonomically similar and their link with water, as predicted by paleoenvironmental reconstructions, is supported (Voorhies groups, abrasion).

During the Late Pliocene, between 3.3 Ma and 2.6 Ma, tectonic events changed ocean basin interactions against a background of shifting orbital forcing mechanisms and a global cooling trend. A climate system that had been locked in a stable, warm state gradually transformed into one typified by the high-amplitude glacial–interglacial fluctuations characteristic of the later Quaternary. The onset of Northern Hemisphere glaciations in the Late Pliocene marks an important step in this transition, due to the role of feedback mechanisms including ice albedo. A crucial factor in this Northern Hemisphere ice sheet expansion is the North Atlantic surface ocean circulation. To evaluate how they are linked, a ca. 200-kyr time slab spanning 2782-2520 ka (Late Pliocene–Early Pleistocene) was analyzed at millennial scale resolution from eastern North Atlantic Deep Sea Drilling Project (DSDP) Site 610 and Integrated Ocean Drilling Program (IODP) Site U1313. The causes of the Plio-Pleistocene climatic turnover are compared to that of the well-documented Marine Isotope Stage (MIS) M2 occurring in the Late Pliocene (3.3 Ma). MIS M2, a severe glacial event seen as a precursor to later Quaternary-style glaciations, was investigated from western North Atlantic DSDP Site 603. Utilizing a same-sample methodology, two paleoceanographic proxies were used: (1) dinocyst assemblages, and (2) foraminiferal geochemistry (δ18O and Mg/Ca). Dinocysts are proven tracers of sea-surface temperature (SST), salinity, nutrient supply, and sea ice cover, and are analyzed here to characterize the overlying water masses at the studied sites. Strong dinocyst assemblage fluctuations attest to variations in the influence of the North Atlantic Current (NAC). Using Mg/Ca ratios for the planktonic foraminifer Globigerina bulloides to determine absolute SSTs allows salinity changes to be reconstructed when combined with stable oxygen isotopes. This study shows a persistent Gulf Stream–NAC in the western North Atlantic during MIS M2, favoring a southern shift of the NAC over a shutdown of the thermohaline circulation. At the newly established Plio-Pleistocene boundary, a profound turnover in dinoflagellate cyst assemblages reveals a shift in ocean mode during MIS 104 (2.6 Ma). Three distinct dinocyst ecozones demonstrate this fundamental reorganization of the North Atlantic circulation.