One of the most prominent measurable parameters of the development of phases and phase transformations in inorganic systems are undoubtedly the volume changes of silicate matrix. The study of volume changes is crucial in the terms of usable durability of final product. They represent shrinkage or expansion of the material and may lead to significant decrease of technological and ecological parameters and often to complete destruction of these materials. Most often the volume changes can be observed when cement is used as a binder and in concretes, mortars, artificial aggregates and other similar materials. There are many methods to detect, define and determine the volume changes qualitatively or quantitatively. The development of phases was investigated as a part of the dissertation thesis and hence the volume changes were observed under the conditions closest to the real state in the construction industry. The raw materials and admixtures were selected which model the content of hazardous components present in conventional materials (both natural and secondary), used in construction and the relationship with volume changes was searched and demonstrated. The contacts for measuring the volume changes were attached to test surfaces of specimens and the physical - mechanical tests (volume changes, phase changes, strength, etc.), chemical analysis and ecotoxicity tests depending on the length of hydration were performed.

The thesis deals with composite systems, with a focus on matrix resistant to extreme conditions. The aim of this work was to research and development matrix, resistant to high temperatures, typical in case of fire. Used theoretical knowledge were realized with subsequent laboratory research. Attention was paid matrices based binder mixed with any alkali activation of alternative raw materials and geopolymers. Scattered reinforcement featured polypropylene fibers. The subject of the practical part of the two alternatives, including a matrix based on basic ingredients - cement, alternative raw materials - high fly ash, blast furnace slag, geopolymer and polymeric components incl. combinations thereof. Laboratory research conducted by determining the fundamental material properties such as density, strengths, etc., after heat exposure. The developed materials were subjected to a temperature 1400 ° C. The conclusion was selected several recipes that were based on the resulting values found to be optimal.

The aim of this thesis is the design of laboratory crusher of mineral raw materials. This work is focused on the research of possible types of machinery for crushing process, list of shredders available at domestic and foreign markets, selection of the principle of diminution of mineral resources, the choice of approach, suggestion of calculation of the chosen design, creating a 3D model and drawings, making the strength analysis for selected parts, risk analysis.

The diploma thesis deals with development of a new progressive anchor material on the polymer base. Nowadays, it is effort to utilize secondary raw materials in building industry as much as possible both from an environmental aspects in order to save primary energy sources and the reduction of waste and also due to economic reasons. Therefore, there is an effort to utilize high amount of suitable and appropriately treated secondary raw materials into the anchor materials. The main aim of this work is to develop high quality anchor material characterized by excellent ratio between speed and strength growth, high chemical resistance, thermal resistance and particularly minimal shrinkage. This new material is designed especially for anchoring building structures heavy machines steel barriers and other elements.

Global energy transitions and rises in demand for critical raw materials (CRMs) are predicted to reshape global politics in yet uncertain but profound ways. With CRMs being vital for Europe’s decarbonization process, the present study sets out to examine the EU’s geopolitical discourse by taking an inquisitive yet critical stance focusing particularly on the new “geopolitical” Commission’s geopolitical reasoning on CRMs. Building upon critical geopolitics, a discourse analysis was conducted on 9 European Commission communications (2019–2020). Three key observations were made: first, a ‘geopolitical’ and ‘assertive’ EU is crucial in an increasingly ‘fragile’, ‘polarized’ and ‘competitive’ world. Second, securing CRMs is a ‘security question’, requiring ‘strategic approaches and partnerships’, notably with ‘resource–rich regions’ and particularly with Africa. Third, the EU’s narrative is ambiguous. While classical geopolitical assumptions are distinguishable, it remains questionable whether the EU will depart from its familiar path of liberal cooperation, multilateralism and trade when scouting for CRMs, although its role as a “benign ally” can be questioned. Further studies on the EU’s geopolitical reasoning, along with its actual practice in the area of CRMs, are warranted. Likewise, a critical reading of reports and foresight preceding EU policymaking is encouraged, to better comprehend how the EU’s dominating geopolitical discourse on CRMs and subsequent practice is produced in the first place.

Scanning electron microscopy based automated mineralogy (SEM-AM) is a combined analytical tool initially designed for the characterisation of ores and mineral processing products. Measurements begin with the collection of backscattered electron (BSE) images and their handling with image analysis software routines. Subsequently, energy dispersive X-ray spectra (EDS) are gained at selected points according to the BSE image adjustments. Classification of the sample EDS spectra against a list of approved reference EDS spectra completes the measurement. Different classification algorithms and four principal SEM-AM measurement routines for point counting modal analysis, particle analysis, sparse phase search and EDS spectral mapping are offered by the relevant software providers. Application of SEM-AM requires a high-quality preparation of samples. Suitable non-evaporating and electron-beam stable epoxy resin mixtures and polishing of relief-free surfaces in particles and materials with very different hardness are the main challenges. As demonstrated by case examples in this contribution, the EDS spectral mapping methods appear to have the most promising potential for novel applications in metamorphic, igneous and sedimentary petrology, ore fingerprinting, ash particle analysis, characterisation of slags, forensic sciences, archaeometry and investigations of stoneware and ceramics. SEM-AM allows the quantification of the sizes, geometries and liberation of particles with different chemical compositions within a bulk sample and without previous phase separations. In addition, a virtual filtering of bulk particle samples by application of numerous filter criteria is possible. For a complete mineral phase identification, X-ray diffraction data should accompany the EDS chemical analysis. Many of the materials which potentially could be characterised by SEM-AM consist of amorphous and glassy phases. In such cases, the generic labelling of reference EDS spectra and their subsequent target component grouping allow SEM-AM for interesting and novel studies on many kinds of solid and particulate matter which are not feasible by other analytical methods.

Wood-polymer composite is a relatively new type of material that combines shattered wood mass and a thermoplastic polymer. This material is utilized especially as an alternative to hard wood in the area of non-bearing exterior elements, as it reaches better properties in terms of the basic durability and low maintenance. Raw material composition and processing of the composite enable to provide a significant modification with further matters leading to an improvement of the end-product properties. Research and development in this field focuses predominantly on the utilization of such modifying additives that either enhance the resistance to weathering or are of the recycled nature, as a significant part of the raw material mixture comprises the constituent obtained from non-renewable resources. The aim of the thesis is the evaluation of the influence of the wood-polymer composite modification separately at two levels. First of them is the modification to matrix by using a recycled polymer, the second one comprises the modification of the wood flour with a secondary spherical filler. Both types of modified composites have been assessed in terms pf the prime characteristics and the resistance to adverse ambient.

Current mass consumption and production patterns have led to an unsustainable use of natural resources, including freshwater, which is one the most crucial natural resources for people and the planet. Agricultural production systems are alone responsible for 72 percent of all global water withdrawals. Therefore, companies with an agricultural supply chain, such as IKEA, play an important role in minimising the negative impacts on water due to agricultural production. In order to do so, companies need to conduct assessments to become aware of their contribution and thereafter develop water targets and strategies on how to mitigate and minimise the company’s water impacts. Several different guidances, methodologies, and tools aiding companies in how to do this have recently been developed, however there is not yet one common established methodology. Therefore, this research project aimed to test and evaluate a new assessment methodology and tool for IKEA, by conducting a water risk assessment on water availability of the sourcing locations of two of IKEA’s key agricultural raw materials: soy and palm oil, and identifying mitigation possibilities, in order to aid in the company’s further work with achieving a sustainable water management and material sourcing, and developing water targets and strategies. Soy is a prioritised raw material to work with in terms of environmental and social risk, and through the conducted water risk assessment, a high risk for water depletion was identified in many of the company’s most likely sourcing locations. The water risk assessment results for palm oil indicated no significant risk for water depletion in any of the sourcing locations. The high water depletion risk scores of the hotspots were found to most likely be due to several different causes, both climatic conditions and anthropogenic activities, including agriculture. Therefore, it was identified that there are possibilities for a company, such as IKEA, to aid in mitigating the water availability challenge of the hotspots through the company’s agricultural supply chain. For example, a few agricultural management practices for increasing the water use efficiency suitable for the different hotspots could be recommended and incentivised by the company to the local farmers of the hotspot sourcing locations. The WRA methodology used in this research project, following the guidance for setting enterprise water targets by Reig et al. (2021), was assumed suitable for IKEA to use and incorporate into a more comprehensive environmental assessment methodology for agricultural raw materials in order to develop water targets and strategies. The Aqueduct Food tool was assumed to be a robust tool for water risk assessment, and can be a suitable tool for IKEA to use to quickly gain a high-level picture of a material, location or water risk of specific interest. The water risk assessment results will mainly be useful in the future, when more comprehensive environmental assessments of agricultural raw materials have been conducted, and the water use has been assessed to a greater extent. Future research is needed to be conducted in order to confirm the results and recommendations of this research project, as well as to further complement the results for the needs of IKEA. This future research includes conducting field studies of the identified hotspots and the operations of the local farms, and conducting an equivalent water risk assessment of the two materials and sourcing locations on the water quality. / Nuvarande masskonsumtion och produktionsmönster har lett till en ohållbar användning av naturresurser, inklusive sötvatten, som är en av de mest avgörande naturresurserna för människor och planeten. Jordbruk står ensam för 72 procent av alla globala vattenuttag. Därför har företag med en jordbruksförsörjningskedja, som IKEA, en viktig roll i att hjälpa till att minska de negativa effekterna på vatten från jordbruk. För att kunna göra det behöver företag utföra bedömningar för att bli medvetna om sin vattenpåverkan och därefter utveckla vattenmål och strategier för hur de kan minimera den påverkan. Det har nyligen utvecklats flera olika vägledningar, metodiker och verktyg som hjälper företag att göra detta, men det finns ännu inte en gemensam etablerad metodik. Därför hade detta forskningsprojekt som syfte att testa och utvärdera en ny bedömningsmetodik och ett nytt verktyg för IKEA, genom att genomföra en riskbedömning av vattentillgången för produktionsplatserna för två av IKEAs viktigaste jordbruksråmaterial: soja och palmolja, och genom en litteraturstudie identifiera möjligheter att minska vattenpåverkan, för att bidra till företagets fortsatta arbete med att uppnå en hållbar vattenanvändning och materialförsörjning i jordbruksförsörjningskedjan och att utveckla vattenmål och strategier. Soja är ett prioriterat råmaterial att arbeta med gällande miljömässiga och sociala risker, och genom den genomförda bedömningen av vattenrisker identifierades en hög risk för vattenbrist på många av de produktionsplatser som företaget mest troligen köper in ifrån. Riskbedömningsresultaten för palmolja indikerade ingen signifikant risk för vattenbrist på någon av de produktionsplatser som företaget troligen köper in ifrån. Den höga risken för vattenbrist i de identifierade hotspotsen visade sig troligen bero på flera olika orsaker, både klimatförhållanden och antropogena aktiviteter, inklusive jordbruk. Därför identifierades det att det finns möjligheter för ett företag, som IKEA, att kunna hjälpa till att mildra vattentillgänglighetsutmaningen i hotspotsen genom företagets jordbruksförsörjningskedja. Till exempel kan ett par olika jordbruksförvaltningsmetoder för att öka vattenanvändningseffektiviteten som är lämpliga för de olika hotspotsen rekommenderas och uppmuntras av företaget till de lokala bönderna. Den WRA-metodik som används i detta forskningsprojekt, som följde vägledningen för att sätta upp vattenmål för företag av Reig et al. (2021), antogs lämplig för IKEA att använda och integrera i en mer omfattande miljöbedömningsmetodik för jordbruksråmaterial för att utveckla vattenmål och strategier. Aqueduct Food-verktyget antogs vara ett robust verktyg för riskbedömning för vatten och kan vara ett lämpligt verktyg för IKEA att använda för att snabbt få en översikt av ett material, en plats eller en vattenrisk av specifikt intresse. Riskbedömningsresultaten kommer främst att vara användbara i framtiden, när mer omfattande miljöbedömningar av jordbruksråvaror har gjorts och vattenanvändningen har bedömts i större utsträckning. Framtida forskning behövs för att bekräfta resultaten och rekommendationerna i detta forskningsprojekt, samt för att ytterligare komplettera resultaten för IKEAs behov. Denna framtida forskning inkluderar att genomföra fältstudier av de identifierade hotspotsen och de lokala sojafarmernas verksamhet, och att genomföra en likvärdig riskbedömning för vatten av de två materialen och produktionsplatserna som utförts i detta forskningsprojekt för vattenkvaliteten.

Ziel der vorliegenden Arbeit war die Durchführung sowie die Untersuchung ausgewählter Verfahrenswege zur chemischen und thermischen Vernetzung von Polysacchariden und Proteinen aus nachwachsenden Rohstoffen. Darüber hinaus wurden Hypothesen zu den Anwendungsmöglichkeiten der untersuchten vernetzten Polymere erstellt. Hierfür wurden mit analytischen Methoden die physiko-chemischen sowie die technofunktionellen Eigenschaften der Rohstoffe und der vernetzten Biopolymeren untersucht. Verglichen wurden z.B. die IR-Spektren der Ausgangsmaterialien mit denen des vernetzten Biopolymers. Mittels Reaktivextrusion wurden Formkörper hergestellt, deren Eigenschaften durch den Einsatz von geeigneten Weichmachern beeinflusst werden können. Die Temperatur des Extruders sollte möglichst niedrig gehalten werden, d.h. geringer als 90 °C, um unerwünschte Bräunungsreaktionen zu vermeiden. Bei den chemischen Vernetzungen wurden fünf verschiedene Vernetzungsmittel eingesetzt: Glutaraldehyd, Maleinsäureanhydrid, Maleinsäurediethylester, Bernsteinsäureanhydrid und Methylendiphenyldiisocyanat. Die Proben aus der Vernetzung mit Glutaraldehyd weisen einen wasserbindenden Charakter auf und können beispielsweise Einsatz als Hydrogele finden. Die mit Diisocyanaten vernetzten Proben härten im Wasser und können als Füllmaterial Einsatz in der Bauindustrie finden. Aufgrund der starken Vernetzung sind die Proben unlöslich und für die meisten erfolgt der Zersetzungsprozess ab 200 °C. Im Sinne einer Werkstoffbeschreibung wurden alle Proben als Duroplaste eingestuft, da sie keine thermoplastische Eigenschaft aufweisen. Mit dieser Arbeit werden Grundlagen für die Erforschung von Verfahrenswegen für die chemische sowie für die thermische Vernetzung von Polysacchariden und Proteinen gelegt. Die gewonnenen Erkenntnisse können für weitere Arbeiten genutzt werden. / In the present work, the possibilities of conjugation or interactions between polysaccharides, especially hemicelluloses and proteins from different sources of renewable raw materials have been investigated. Sources of polysaccharides are oat spelts xylan and maize spindles. Proteins like acid casein from cow milk and cruciferin, a rapeseed protein isolate, from the canola plant have been used. For the chemical crosslinking, homo-bifunctional reagents (crosslinkers) like glutaraldehyde, maleic anhydride, maleic acid diethyl ester, succinic anhydride, and methylene diphenyl diisocyanate were used. These reagents can react with functional groups of the biopolymers- the hydroxyl groups in the hemicelluloses and amino groups in the proteins. For a thermolinked conjugation of the biopolymers, the reactive extrusion was used as mechanical technique. Both types of biopolymers were successfully blended in a mini-Extruder to form sticks. The plastics characteristics of the sticks could be influenced by the addition of suitable softeners. The extrusion temperature must be kept as low as possible, to avoid the appearance of unwanted brown reactions. To investigate the conjugation of the polysaccharides with casein or cruciferin, the IR spectra of the raw materials with those of the crosslinked biopolymers were compared. Application possibilities of the resulted crosslinked biopolymers have been proposed. Most of the samples are insoluble due to the strong networking after the crosslinking reactions. Their thermal decomposition starts at temperatures around 200 °C. All the samples have been classified as duroplasts since they do not exhibit a thermoplastic characteristic. The work complements basic research about chemical and thermal conjugation between polysaccharides and proteins from renewable raw materials.

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