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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
291

Modeling and control of helicopters carrying suspended loads

Adams, Christopher James 05 July 2012 (has links)
Helicopters are often used to transport supplies and equipment. When a heavy load is carried via suspension cables below a helicopter, the load oscillates in response to helicopter motion and disturbance forces, such as wind. This oscillation is dangerous and adversely affects control of the helicopter, especially when carrying large or heavy loads. By adding input shaping to the helicopter's flight controller, the suspended load oscillation caused by helicopter motion is greatly reduced. A significant benefit of this approach is that it does not require measurement of the load position. This thesis contains derivations and analysis of simple planar helicopter-load dynamic models, and these models are verified using experimental data from model-scale, radio-controlled helicopters. The effectiveness of input shaping at eliminating suspended load oscillation is then demonstrated on this experimental hardware. In addition, the design of an attitude command, near-hover flight controller that combines input shaping and a common flight control architecture is illustrated using dynamic models of a Sikorsky S-61 helicopter, and simulation results are shown for example lateral and longitudinal repositioning movements. Results show that applying input shaping to simulated pilot commands greatly improves performance when carrying a suspended load.
292

A Process-Based Model for Beach Profile Evolution

Demir, Huseyin 17 September 2007 (has links)
Beach profile models predict the changes in bathymetry along a line perpendicular to the shoreline. These models are used to forecast bathymetric changes in response to storms, sea level rise or human activities such as dredging and beach nourishment. Process-based models achieve this by simulating the physical processes that drive the sediment transport as opposed to behavior models which simulate observed profile changes without resolving the underlying processes. Some of these processes are wave shoaling and breaking, boundary layer streaming, and offshore-directed undertow currents. These hydrodynamic processes control the sediment processes such as sediment pick-up from the bottom, diffusion of the sediment across the water column and its advection with waves and currents. For this study, newly developed sediment transport and boundary layer models were coupled with existing models of wave transformation, nearshore circulation and bathymetry update, to predict beach profile changes. The models covered the region from the dry land to a depth of 6-8 meters, spanning up to 500 meters in the cross-shore direction. The modeling system was applied at storm time scales, extending from a couple of hours to several days. Two field experiments were conducted at Myrtle Beach, SC, involving the collection of wave, current and bathymetric data as a part of this study. The results were used to calibrate and test the numerical models along with data from various laboratory studies from the literature. The sediment transport model computes the variation of sediment concentrations over a wave period and over the water column, solving the advection-diffusion equation using the Crank-Nicholson finite-difference numerical scheme. Using a new approach, erosion depth thickness and sediment concentrations within the bed were also predicted. The model could predict sediment transport rates for a range of conditions, within a factor of two. It successfully computed the sediment concentration profile over the water column and within the bed and its variation throughout a wave period. Erosion depth and sheet flow layer thickness were also predicted reasonably well. Wave heights across the profile were predicted within ten percent when the empirical wave breaking parameter was tuned appropriately. Mean cross-shore velocities contain more uncertainty, even after tuning. The importance of capturing the location of the maximum, near-bottom, cross-shore velocity when predicting bar behavior was shown. Bar formation, erosion, accretion, onshore and offshore bar movement were all computed with the model successfully
293

Selective Quantification Of Viable Escherichia Coli Cells In Biosolids Upon Propidium Monoazide Treatment By Quantitative Pcr

Taskin, Bilgin 01 February 2011 (has links) (PDF)
Density of fecal coliforms (FC) such as Escherichia coli is the most commonly used indicator of fecal pathogen content of biosolids. When biosolids are disposed off or used for soil amendment, they pose public health risks. So far anaerobic digesters have been considered to be an effective treatment option for pathogen and FC reduction in biosolids. However, recent studies revealed that there is a significant re-growth and reactivation of indicator organisms in biosolids upon dewatering by centrifugation. Although the exact mechanism of FC reactivation is yet to be understood, a few extensive recent studies strongly suggest that FC go into a viable but non-culturable (VBNC) state during anaerobic digestion. Therefore, quantitative detection of live cells among the total in biosolids samples, without using culturing-based approaches, is highly critical from a public health risk assessment perspective. Since recent investigations proved the significant re-growth and reactivation of indicator organisms. Persistence of DNA in the environment after cell death in the range of days to weeks limits the application of DNA-based approaches for the detection of live bacteria. Using selective nucleic acid intercalating dyes such as ethidium monoazide (EMA) and propidium monoazide (PMA) is one of the alternative approaches to detect and quantify the viable cells by quantitative PCR. These compounds have the ability to penetrate only into dead cells with compromised membrane integrity. They intercalate in the DNA via photo-inducible azide groups and in turn inhibit DNA amplification during PCR reactions. PMA has been successfully used in different studies and microorganisms but it has not been evaluated sufficiently for the complex environmental samples such as biosolids. In this study Escherichia coli ATCC 25922 and uidA gene were used as model organism and as target sequence respectively in absolute quantification method with real-time PCR. Experiments with the known quantities of live and dead cell mixtures showed that PMA treatment inhibits PCR amplification from dead cells with over 99% efficiency. The results of this study conclusively demonstrated that PMA-modified PCR could be successfully applied to the biosolids when total suspended solid (TSS) concentration is 2000 mg/L or below.
294

Suspension of Mixtures of Solids in Stirred Tanks: Problem Definition and Model Identification

Ayranci, Inci Unknown Date
No description available.
295

External and Internal Mass Transfer in Biological Wastewater Treatment Systems`

Gapes, Daniel James Unknown Date (has links)
A detailed study has been carried out to demonstrate the importance of external and internal mass transfer on the nitrification rates in three distinct treatment processes: flocculent and granular activated sludge, and suspended carrier reactor (SCR) systems. The major emphasis was on external mass transfer, and the impact of system hydrodynamics on this mechanism. Laboratory-scale flocculent and granular sequencing batch reactors were operated for the nitrification of a synthetic wastewater. A two-stage, continuous, nitrifying SCR was operated using the same wastewater feed. Within each stage, biofilm was grown on two types of commercial carriers- the Natrix C10/10 from ANOX AB (Sweden); and the K1 carrier from Kaldnes Miljøteknologi (Norway). Biofilm carriers obtained from each of these reactors was utilised for the mass transfer investigations. The major findings, and contributions of the work to the field of biological wastewater treatment, are described in the following paragraphs. In order to complete the work, a novel experimental tool, the TOGA (Titrimetric and Off-Gas Analysis) sensor was created, which utilises off-gas mass balancing, coupled with pH titration to provide detailed measurement of biological reaction rates. An original method for off-gas mass balancing was developed, within a reactor that allowed modification of the hydrodynamic conditions using gas phase mixing independent of dissolved oxygen control within the liquid phase. This sensor has already proven to be a highly effective tool not only for the measurement of oxygen but also for carbon dioxide and various nitrogen species, and has application for numerous other compounds present in the gas phase of biological reactors (e.g. hydrogen, methane). The application of the TOGA sensor signals to the nitrification process was demonstrated, which enabled the online measurement of oxygen, ammonia, and nitrite reaction rates. The TOGA sensor development underpinned the majority of the subsequent experimental work within this thesis. Dissolved oxygen microelectrodes were also used, enabling microscale measurements to be made in conjunction with the macroscale TOGA sensor analyses. Combined with size and microbiological analyses a detailed study of mass transfer and reaction was able to be carried out on the various systems. For suspended aggregate systems (flocs and granules): A spherical particle model was developed and used to predict the potential for external mass transfer limitation in flocs and granules. The significance of this limitation was confirmed experimentally, by observing changes in reaction rate or concentration boundary layer (in the TOGA sensor or microelectrode study, respectively) upon modification of the system’s flow conditions. Despite this flow effect being small, and only observable under low bulk liquid substrate concentrations, the external mass transfer limitation was concluded to be significant for biological flocs and granules even at higher substrate concentrations. As particle size and the maximum volumetric reaction rate of the biomass increases, external mass transfer effects become increasingly significant. The work highlights the impact of mass transfer limitation on the measurement of Monod half saturation coefficients (KS) in flocs and granules. Without accounting for external or internal mass transfer limitation, KS is seriously overestimated and becomes a lumped parameter, reflecting not only the microbial response but also the mass transfer limitations observed within the system under study. To avoid confusion or generation of erroneous results, care should be taken in defining, measuring and utilising the half saturation coefficient in biological systems where the biomass is not present as individual cells or extremely small flocs. For Suspended Carrier Reactor systems: External and internal mass transfer are both concluded to be important rate limiting steps within suspended carrier reactors. The demonstration of a significant impact of fluid flow conditions on the nitrification rates highlights the impact of external mass transfer limitation within these systems. Application of a one-dimensional biofilm model to the experimental results led to the conclusion that there is little difference between the external mass transfer limitation of the two different carrier types, for carriers grown under the same environmental conditions. However, there was a significantly higher areal nitrification rate observed on the Natrix carriers compared to the Kaldnes carriers. It is the biofilm structure that is critically important in characterising the mass transfer steps. Systems operated under high nitrogen loads, producing filamentous biofilms on the carrier surface, were found to have larger external mass transfer coefficients and responses to changes in fluid flow than those carriers which were operated under nitrogen-limited conditions (producing a flatter, more gel-like biofilm). The structure of the biofilm colonising the carrier surface was far more important in defining the mass transfer coefficient than the actual carrier type used. In a remarkably similar trend to that of the external mass transfer coefficient, the biofilm morphology was again significantly more important than carrier type in determining both the magnitude and response to fluid flow of the gas-liquid mass transfer coefficient for oxygen (kLa) calculated within the laboratory TOGA sensor. These findings led to the postulation that direct gas-biofilm interfacial mass transfer mechanism is occurring within the SCR systems. This hypothesis is an alternative to the standard mechanism of gas transfer from the bubble into the liquid phase, and then into the biofilm. Understanding of interfacial transfer is likely to be important for developing the knowledge of SCR processes. Overall, both external and internal mass transfer phenomena have been demonstrated to create important rate limitations to suspended aggregate systems (flocs and granules) and biofilms grown in suspended carrier reactors. This significantly advances the conceptual understanding of these biological treatment processes.
296

External and Internal Mass Transfer in Biological Wastewater Treatment Systems`

Gapes, Daniel James Unknown Date (has links)
A detailed study has been carried out to demonstrate the importance of external and internal mass transfer on the nitrification rates in three distinct treatment processes: flocculent and granular activated sludge, and suspended carrier reactor (SCR) systems. The major emphasis was on external mass transfer, and the impact of system hydrodynamics on this mechanism. Laboratory-scale flocculent and granular sequencing batch reactors were operated for the nitrification of a synthetic wastewater. A two-stage, continuous, nitrifying SCR was operated using the same wastewater feed. Within each stage, biofilm was grown on two types of commercial carriers- the Natrix C10/10 from ANOX AB (Sweden); and the K1 carrier from Kaldnes Miljøteknologi (Norway). Biofilm carriers obtained from each of these reactors was utilised for the mass transfer investigations. The major findings, and contributions of the work to the field of biological wastewater treatment, are described in the following paragraphs. In order to complete the work, a novel experimental tool, the TOGA (Titrimetric and Off-Gas Analysis) sensor was created, which utilises off-gas mass balancing, coupled with pH titration to provide detailed measurement of biological reaction rates. An original method for off-gas mass balancing was developed, within a reactor that allowed modification of the hydrodynamic conditions using gas phase mixing independent of dissolved oxygen control within the liquid phase. This sensor has already proven to be a highly effective tool not only for the measurement of oxygen but also for carbon dioxide and various nitrogen species, and has application for numerous other compounds present in the gas phase of biological reactors (e.g. hydrogen, methane). The application of the TOGA sensor signals to the nitrification process was demonstrated, which enabled the online measurement of oxygen, ammonia, and nitrite reaction rates. The TOGA sensor development underpinned the majority of the subsequent experimental work within this thesis. Dissolved oxygen microelectrodes were also used, enabling microscale measurements to be made in conjunction with the macroscale TOGA sensor analyses. Combined with size and microbiological analyses a detailed study of mass transfer and reaction was able to be carried out on the various systems. For suspended aggregate systems (flocs and granules): A spherical particle model was developed and used to predict the potential for external mass transfer limitation in flocs and granules. The significance of this limitation was confirmed experimentally, by observing changes in reaction rate or concentration boundary layer (in the TOGA sensor or microelectrode study, respectively) upon modification of the system’s flow conditions. Despite this flow effect being small, and only observable under low bulk liquid substrate concentrations, the external mass transfer limitation was concluded to be significant for biological flocs and granules even at higher substrate concentrations. As particle size and the maximum volumetric reaction rate of the biomass increases, external mass transfer effects become increasingly significant. The work highlights the impact of mass transfer limitation on the measurement of Monod half saturation coefficients (KS) in flocs and granules. Without accounting for external or internal mass transfer limitation, KS is seriously overestimated and becomes a lumped parameter, reflecting not only the microbial response but also the mass transfer limitations observed within the system under study. To avoid confusion or generation of erroneous results, care should be taken in defining, measuring and utilising the half saturation coefficient in biological systems where the biomass is not present as individual cells or extremely small flocs. For Suspended Carrier Reactor systems: External and internal mass transfer are both concluded to be important rate limiting steps within suspended carrier reactors. The demonstration of a significant impact of fluid flow conditions on the nitrification rates highlights the impact of external mass transfer limitation within these systems. Application of a one-dimensional biofilm model to the experimental results led to the conclusion that there is little difference between the external mass transfer limitation of the two different carrier types, for carriers grown under the same environmental conditions. However, there was a significantly higher areal nitrification rate observed on the Natrix carriers compared to the Kaldnes carriers. It is the biofilm structure that is critically important in characterising the mass transfer steps. Systems operated under high nitrogen loads, producing filamentous biofilms on the carrier surface, were found to have larger external mass transfer coefficients and responses to changes in fluid flow than those carriers which were operated under nitrogen-limited conditions (producing a flatter, more gel-like biofilm). The structure of the biofilm colonising the carrier surface was far more important in defining the mass transfer coefficient than the actual carrier type used. In a remarkably similar trend to that of the external mass transfer coefficient, the biofilm morphology was again significantly more important than carrier type in determining both the magnitude and response to fluid flow of the gas-liquid mass transfer coefficient for oxygen (kLa) calculated within the laboratory TOGA sensor. These findings led to the postulation that direct gas-biofilm interfacial mass transfer mechanism is occurring within the SCR systems. This hypothesis is an alternative to the standard mechanism of gas transfer from the bubble into the liquid phase, and then into the biofilm. Understanding of interfacial transfer is likely to be important for developing the knowledge of SCR processes. Overall, both external and internal mass transfer phenomena have been demonstrated to create important rate limitations to suspended aggregate systems (flocs and granules) and biofilms grown in suspended carrier reactors. This significantly advances the conceptual understanding of these biological treatment processes.
297

Développement d'un système de caractérisation des agrégats et des flocs en suspension / Development of a suspended aggregates and flocs carracterisation system

Wendling, Valentin 06 February 2015 (has links)
L'évolution des caractéristiques des particules en suspension au cours de leur transfert au sein des bassins versants est encore mal connue. Ceci limite actuellement notre aptitude à prédire correctement l'érosion ou les flux de matières en suspension (MES) et rend difficile la proposition de pratiques de gestion adaptées aux réglementations en vigueur. A partir d'expériences en milieu contrôlé, nous avons montré que les particules de sols ont tendance à se désagréger en milieu turbulent. Il semble de plus qu'une augmentation de la concentration en suspension accélère cette désagrégation et conduise à des particules plus fines. Même si l'évolution des particules à l'échelle horaire semble rester de second ordre derrière les caractéristiques des sols sources, il est indispensable de pouvoir vérifier si les particules en suspension se comportent de la même manière en conditions naturelles où des interactions complexes entre processus peuvent avoir lieu. Cependant l'absence de méthode de mesure permettant le suivi des propriétés de transport des sédiments en écoulements très concentrés (de 1 plusieurs centaines de grammes par litre) dans les bassins élémentaires limite notre capacité à hiérarchiser les processus à considérer pour modéliser le transfert sédimentaire ou améliorer la gestion opérationnelle des sédiments. Afin de répondre à ce besoin instrumental, nous avons développé un Système de Caractérisation des Agrégats et des Flocs (SCAF). Cet instrument est conçu pour être incorporé dans les stations de suivi hydro-sédimentaire. La mesure est réalisée immédiatement après prélèvement d'un échantillon de la suspension à caractériser par une série de capteurs optiques qui suivent l'évolution de l'absorbance optique durant la sédimentation de l'échantillon. Nous proposons une méthode de traitement des données optiques donnant accès à la distribution des vitesses de chute de la suspension ainsi qu'à un indice de floculation qui renseigne sur la capacité des MES à floculer durant leur sédimentation. Les distributions de vitesses de chute mesurées sont validées sur une large gamme de matériaux et de régimes de sédimentation, afin de couvrir la variabilité des types de matériaux et des concentrations observées en milieu naturel. Pour des sédiments non cohésifs ou floculant peu durant leur sédimentation les mesures du SCAF s'ajustent sur celles issues des autres méthodes. Pour les suspensions qui floculent durant leur sédimentation, la plupart des méthodes de mesure classiques conduisent à des vitesses de chute non représentatives de la suspension. Nous avons montré que les variations des propriétés optiques des matières en suspension lors de leur floculation impactent nos mesures. La méthode proposée permet cependant de quantifier l'augmentation des vitesses de chute avec la floculation, et d'encadrer l'incertitude des mesures. Pour les mesures à forte concentration (>10 g/l), un front d'entravement peut se former durant la sédimentation, le SCAF mesurant alors précisément les vitesses de chute du front. La mesure des distributions des vitesses de chute et de la cohésion des particules en suspension peut permettre d'identifier différentes populations de particules formant une suspension (grains de sables, flocs, matières fines...). Le suivi de telles informations au sein de bassins versants ouvre de nouvelles perspectives pour aborder la connectivité sédimentaire et s'orienter vers une gestion optimale des flux de MES. / Little is known about the processes that govern the evolution of suspended particle characteristics during their transport through a river basin. This is a main limitation for modelling erosion severity or suspended solids (SS) fluxes. It also leads to difficulties to propose management policies adapted to environmental legislation. Based on experiments in controlled environments, we have shown that soil particles tend to disaggregate in turbulent flows. The increase in SS concentration was associated to an increase of the disaggregation of SS particles, leading to smaller final particle sizes. Laboratory experiments also showed that the variability of the particle sizes due to their evolution over one hour was smaller than the variability due to the soil type from which the particles originated. However it is important to ensure that the suspended particles behave in the same way in natural conditions, where complex interactions between hydraulic, chemical and biological processes can influence their evolution. Up to now no measurement method allows measuring continuously the suspended sediment properties in highly concentrated fluids (from one to hundreds grams per liter), such as those observed in headwater catchments during runoff events. This severely limits the possibility to identify the processes that are important to consider in numerical models. The Aggregate and Floc Characterization System (SCAF) has been developed in order to measure SS properties for a wide range of SS concentrations. It was designed to be easily incorporated into sequential samplers. Immediately after the collection of a sample from the river, the sedimentation of the suspension is recorded by continuous measurements of the absorbance by a series of optical sensors. A method was proposed to processes the raw optical data in order to obtain the settling velocity distribution of the suspension. It also provides a flocculation index representing the tendency of the particles to flocculate during their sedimentation. The calculated settling velocity distributions were validated on a large range of materials and settling regimes in order to cover the natural variability of suspended sediments. For sediments that hardly flocculate during their sedimentation or are non-cohesive, the measurements of the SCAF were similar to those from other methods. In the case of suspensions that strongly flocculate during sedimentation, most of the classical methods give non-representative falling velocities. In this case, the optical property of the particles may vary during settling, affecting the optical measurement. The proposed method allowed quantifying the increase of settling velocity induced by flocculation, and provided confidence intervals for the settling velocities. For high SS concentrations ( > 10 g/l), a settling front can be formed during the sedimentation, which is well characterized by the SCAF. The measurement of the settling velocity distributions and of the flocculation index can be used to identify different particle populations (sand grains, flocs, individual particles) forming a suspension. Monitoring these properties in watersheds offers new insights to explore sediment connectivity within river basins and to optimize water management strategies.
298

Análise comparativa do desempenho de reator anaeróbio híbrido e reator de manto de lodo de fluxo ascendente (UASB) aplicados ao tratamento de esgoto sanitário

Hoyos, Nestor Leonel Muñoz January 2016 (has links)
O presente trabalho teve como objetivo principal avaliar a performance e a estabilidade operacional de uma nova configuração de um reator anaeróbio híbrido (RAH) que combina um filtro anaeróbio de fluxo descendente seguido de uma câmara de manta de lodo de fluxo ascendente comparativamente ao reator UASB nas mesmas condições operacionais aplicados ao tratamento de esgoto sanitário. A avaliação da eficiência de remoção de remoção da matéria orgânica e dos sólidos suspensos nos reatores piloto foi por meio de testes da DQO, DBO, sólidos em suspensão totais (SST) e dos sólidos em suspensão voláteis (SSV).Os reatores UASB e RAH foram operados por um período de 240 dias na fase 1 e 150 dias na fase 2 com vazão afluente de 1,6 m3/h e TDH de 11,8 h. O TDH médio na câmara de entrada do RAH foi de 2,7h e de 9,1h na câmara ascendente de manto de lodo. Os reatores piloto apresentaram capacidade de tratamento para suportar os choques de carga orgânica devido à variabilidade do esgoto bruto. A eficiência de remoção de matéria orgânica em termos de DQO foi de 66% e 59% para o UASB e RAH, a eficiência de remoção de SST atingiu valores de 65% e 63% respectivamente, aliás, o reator UASB apresentando valores superiores de desempenho operacional em quase todos os parâmetros de monitoramento dos processos de digestão anaeróbia os valores médios dos parâmetros DQO, DBO5, SST e SSV não tiveram diferenças estatisticamente significativas. O pH para os sistemas piloto esteve na faixa ideal para o desenvolvimento dos microorganismos anaeróbios (6,5 a 7,5) e a alcalinidade e os AGVs demonstraram estabilidade dos reatores, corroborados pela estabilidade do pH no interior de cada sistema. A velocidade ascensional na câmara de manta de lodo (0,45 m/h) não causou efeito adverso na qualidade do efluente em termos de SST, com valor médio de 39,8 mg/L, na mesma faixa observada no reator UASB (41,6 mg/L). Foi observada menor concentração de biomassa no reator RAH (distribuição vertical) comparativamente ao reator UASB segundo os perfis verticais de lodo, entretanto, este fato não comprometeu a sua eficiência de remoção de matéria orgânica e dos sólidos suspensos. A retirada do lodo de excesso dos sistemas piloto foi baseada na relação STV/ST para estimar a fração de biomassa, a freqüência do descarte foi de 1 vez por mês retirando o equivalente aos 10% do volume de lodo das tomadas que apresentaram uma fração de STV menor que 50%. É viável a implementação da turbidez como parâmetro de detenção de perdida de lodo no efluente dos reatores anaeróbios devido a que a turbidez e os SST apresentaram uma relação direta o que ajudaria a simplificar mecanismos de controle operacional para a toma de decisões nas estações de tratamento, sendo que a turbidez é um parâmetro de leitura rápida “in situ” e poderia advertir do excesso de lodo ao interior do reator. Foram empregados diferentes métodos titrimétricos para a determinação dos AGVs no efluente do RAH e UASB. Após análise dos resultados, recomenda-se o uso do método de KAPP e RIPLEY para a determinação dos AGVs pela simplicidade metodológica e pela rapidez na obtenção do resultado. / This study aimed to evaluate the performance and operational stability of a new configuration of a hybrid anaerobic reactor (RAH) combining an anaerobic filter downflow followed by a sludge blanket chamber upflow compared to UASB in same operating conditions applied to sewage treatment. The evaluation of organic matter removal and removal efficiency of suspended solids in the pilot reactor was by testing COD, BOD, total suspended solids (TSS) and volatile suspended solids (VSS). The RAH and UASB reactors were operated for a period of 240 days in the first phase and 150 days in phase 2 with the inlet flow of 1,6 m3/h and 11,8h TDH. The average TDH RAH in the inlet chamber was 2.7h and 9,1h in ascending chamber sludge blanket. Pilot reactors showed treatment capacity to support organic shock loads due to the variability of raw sewage. The organic matter removal efficiency in terms of COD was 66% and 59% for the UASB and RAH, the TSS removal efficiency reached values of 65% and 63% respectively, by the way, the UASB presenting performance values higher operational in almost all parameters of the monitoring anaerobic digestion processes mean values of the parameters COD, BOD5, TSS and VSS were not statistically significant differences. The pH for the pilot systems was in the ideal range for the development of anaerobic microorganisms (6,5 to 7,5) and alkalinity and Volatile Fatty Acids (VFA) demonstrated stability of reactors corroborated by the pH stability within each system. The upflow velocity in the sludge blanket chamber (0,45 m/h) caused no adverse effect on effluent quality in terms of TSS, with an average of 39,8 mg/L, in the same range observed in UASB (41,6 mg/L). It was observed lower concentration of biomass in the reactor RAH (vertical distribution) compared to UASB second vertical sludge profiles, however, this fact did not compromise its removal efficiency of organic matter and suspended solids. The withdrawal of the pilot systems excess sludge was based on TSV/TS ratio to estimate the biomass fraction, the frequency of disposal was 1 once a month by removing the equivalent of 10% of the outlets sludge volume that had a fraction of TSV less than 50%. The implementation of turbidity as sludge lost detention parameter is viable in the effluent of the anaerobic reactors due to turbidity and TSS showed a direct relationship which would help simplify operational control mechanisms for decision making in treatment plants, wherein the turbidity is a quick read parameter "in situ" and could warn of excess sludge inside the reactor. Different titrimetric methods were employed for the determination of VFA and the effluent from the UASB and RAH. After analyzing the results, we recommend the use of KAPP and RIPLEY method for the determination of VFA by methodological simplicity and speed in obtaining results.
299

Entre a palavra pênsil e a escuta porosa : [investigações sob proposições sonoras]

Stolf, Maria Raquel da Silva January 2011 (has links)
Esta pesquisa apresenta investigações teóricas interseccionais à produção de “proposições sonoras” (agrupadas em CDs de áudio) que podem ser desdobradas em instalações, ações, intervenções, vídeos, fotografias, textos e desenhos. Para tanto, busca-se pensar ressonâncias, intersecções, desvios e deslocamentos entre sons, textos e contextos, propondo articulações entre algumas questões que atravessam minha produção, perguntas que partem das proposições realizadas. São elas: como articular relações entre a palavra (escrita e falada), a leitura e a escuta através de minhas proposições? Como colocar a escrita e a escuta em suspensão? Como oscilar ou suspender um texto? Como propor uma escuta que perceba e pense modulações entre barulho, ruído e rumor? Como propor uma escuta de silêncios? Como são concatenados meus CDs de áudio e de que modo ocorrem os desdobramentos das proposições sonoras em instalações, ações sonoras e vídeos? A nuvem de perguntas acima dialoga com uma série de autores e está atrelada a trabalhos agrupados em três blocos co-implicados: “Palavra pênsil”, “Barulho, ruído e rumor” e “Silêncio acústico”. Nesses blocos, aborda-se: o uso de palavras em proposições artísticas, que pressupõe um processo de escrita em que a palavra ocupa espaço e solicita tempo, que pende e se torna “palavra-partitura”, catalisando desdobramentos sonoros e experiências acústicas; a questão da escuta, propondo-se estremecê-la e exercitá-la como uma escuta que absorve os ruídos do entorno, que percebe e reinventa variações entre barulho, ruído e rumor (palavras-conceitos definidos a partir de suas espessuras etimológicas e a partir das proposições apresentadas); investigações em torno de conceitos de silêncio: o silêncio enquanto suspensão de sentido, rumor incessante e uma espécie de silêncio que transita semanticamente na própria escuta. / This study presents intersectional theoretical research about the production of “sonorous propositions” (grouped in audio CDs) that can be applied in installations, actions, interventions, videos, photographs, texts and designs. To do so, it considers resonances, intersections, deviations and movement between sounds, texts, and contexts, proposing articulations between questions that are raised in my production that spring from the propositions realized. They are: how to articulate relations between the word (written and spoken) and reading and listening through my propositions? How can writing and listening be placed in suspension? How can a text be oscillated or suspended? How can a listening be proposed that perceives and considers modulations between noise, din and rumbling? How can a listening to silences be proposed? How are my audio CDs concatenated and in what way are the sonorous propositions developed in the installations, sonorous actions and videos? This cloud of questions dialogs with a series of authors and is related to works grouped in three related sets: “Suspended word,” “Noise, din and rumble” and “Acoustic silence.” Within these sets the use of words in artistic propositions is approached, which presupposes a writing process in which the word occupies space and solicits time, which becomes suspended and becomes a “word-score,” catalyzing sonorous developments and acoustic experiences; the question of listening proposes to rattle and exercise it as a listening that absorbs the surrounding din, which perceives and reinvents variations between noise, din and rumble (conceptual words defined by their etymological depth and based on the propositions presented); investigations around the concepts of silence: silence as suspension of sense, incessant rumble and a type of silence that semantically travels within listening itself.
300

From atomic level investigations to membrane architecture : an in-depth study of the innovative 3C-SiC/Si/3C-SiC/Si heterostructure / Optimisation d'hétérostructures 3C-Sic/Si/3C-SiC sur substrat Si et fabrication innovante de membranes auto-supporté

Khazaka, Rami 29 November 2016 (has links)
Le polytype cubique du carbure de silicium (3C-SiC) est un matériau très prometteur pour les applications MEMS. En plus de sa tenue mécanique et chimique, il peut être épitaxié sur des substrats Si de faible coût. De plus, l'hétéroépitaxie multiple, c’est-à-dire quand on empile plusieurs couches Si et 3C-SiC peut ouvrir des pistes pour de nouveaux dispositifs à base de 3C-SiC. Vue la complexité de développer de telles hétérostructures, nous avons procédé à l'amélioration de la qualité de chaque couche séparément. De plus, nous avons mené une étude approfondie sur la nature des défauts dans chaque couche. Après le développement de l'hétérostructure complète, nous avons procédé à la fabrication de microstructures à base de cet empilement. Nous présentons une méthode inédite pour former des membranes de 3C-SiC auto-supportées. Cette technique simplifie considérablement le procédé de fabrication de membranes tout en réduisant le temps de fabrication et le coût. En outre, elle aide à surmonter plusieurs problèmes techniques. / Due to its outstanding physico-chemical properties, the cubic polytype of silicon carbide (3C-SiC) gained significant interest in several fields. In particular, this material emerged as a potential candidate to replace Si in MEMS devices operating in harsh environment. The development of 3C-SiC/Si/3C-SiC heterostructures on top of Si substrate can pave the road towards original and novel MEMS devices profiting from the properties of the 3C-SiC. However, such epitaxial system suffers from wide range of defects characterizing each layer. Thus, we first tried to improve the quality of each layer in this heterostructure. This was achieved relying on two levers; (i) the optimization of the growth parameters of each layer and (ii) the understanding of the nature of defects present in each layer. These two key points combined together allowed an in-depth understanding of the limit of improvement of the overall quality of this heterostructure. After the development of the complete heterostructure, the fabrication of 3C-SiC microstructures was performed. Furthermore, we presented an unprecedented method to form free-standing 3C-SiC membranes in-situ during its growth stage. This novel technique is expected to markedly simplify the fabrication process of suspended membranes by reducing the fabrication time and cost.

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