While Andosols have a proven capacity to buffer acid inputs, their long-term chemical response to elevated acid deposition remains poorly known. In this respect, the high anion retention capacity of Andosols constitutes a key parameter. Yet, the mechanisms involved in anion retention, especially sulphate, are still a matter of scientific debate. In this study, we report on the impacts of volcanogenic S and acid depositions on (i) the sulphate distribution and (ii) the processes involved in the neutralisation of the acid inputs, in two distinct soil series located downwind from Masaya volcano (Nicaragua), one of the world's largest natural source of SO2. The first series corresponds to weathered Eutric Andosols rich in allophanic constituents and the second series to weakly developed Vitric Andosols rich in volcanic glass. Long-term acid gas emission by Masaya volcano has led to important changes in the chemistry of the Andosols downwind. Sustained acid inputs have decreased the pH and exchangeable base cations contents in both Vitric and Eutric soils. These soils also show substantial S enrichment (up to 5470 mg S kg-1). However, these changes do not affect the soil acid neutralising capacity of the solid phase (ANCs) in a significant way. Despite the larger ANCs of the Vitric comparatively to the Eutric Andosols, soil pH was less in the Vitric than in the Eutric Andosols. This is related to the naturally and kinetically different mechanisms involved in the regulation of the volcanogenic acid fluxes: mineral weathering (slow kinetics) is the dominant process in Vitric Andosols, whereas cation exchange and sulphate sorption (rapid kinetics) significantly contribute to regulate proton consumption in Eutric Andosols. Formation of basic aluminium sulphate (BAS) [(K,Na)nAlx(OH)y(SO4)z] minerals in soils exposed to volcanogenic S-rich acid inputs was inferred from the results of selective extraction experiments (NH4F, KH2PO4 and oxalate). Precipitation of BAS probably constitutes the most effective inorganic SO42- retention mechanism (9-51% of total S), SO42- adsorption onto soil constituents (1-36% of total S) and occlusion into short-range ordered minerals (0-22% of total S), probably governed by ferrihydrite, constituted additional effective inorganic SO42- retention processes. Using transmission electron microscopy coupled with energy-dispersive analysis, we provide the first direct evidence of BAS minerals in soils. BAS minerals can form in these Andosols, because of the large inputs of H+ and SO2 and the availability of readily weatherable volcanic glass, which acts as an effective source of Al. Surface precipitation, i.e. two-dimensional chemisorption followed by three-dimensional nucleation and precipitation, rather than direct precipitation from solution, is likely the formation pathway of BAS particles in these soils. / Malgré une capacité importante à neutraliser les apports acides, le fonctionnement à long terme des Andosols est aussi susceptible d'être affecté par les dépôts acides. A cet égard, la capacité de rétention anionique élevée des Andosols constitue un paramètre clef. Or, les mécanismes de rétention des anions, en particulier du sulfate, demeurent un sujet controversé.Nous étudions ici les effets de dépôts acides et soufrés d'origine volcanique sur (i) la distribution du sulfate et (ii) les processus impliqués dans la neutralisation des apports acides, dans deux séries d'Andosol contrastées exposées aux émissions du volcan Masaya (Nicaragua), une des principales sources naturelles de SO2 atmosphérique. La première série comprend des Andosols Vitriques possèdant une réserve importante de minéraux altérables de nature vitreuse et la seconde est constituée d'Andosols Eutriques, plus évolués, possèdant des teneurs élevées en minéraux secondaires à organisation cristalline à courte distance. Les émissions prolongées de gaz acides provenant du volcan Masaya modifient fortement la chimie des sols exposés à ces apports. Ainsi, le pH et les teneurs en cations échangeables des Andosols Vitriques et Eutriques diminuent alors que la concentration totale en S augmente (jusqu'à 5470 mg S kg-1) en réponse aux apports d'acides. Par contre, la capacité de la phase solide de ces sols à neutraliser l'acidité (ANCs) n'est pas significativement affectée. Malgré une ANCs plus élevée dans les Andosols Vitriques comparativement aux Andosols Eutriques, le pH de ces sols est plus faible parce que les mécanismes impliqués dans la régulation des flux de protons sont différents: ceux-ci s'opèrent principalement par des réactions lentes d'altération minérale dans les Andosols Vitriques et par des réactions rapides impliquant l'échange ionique et la sorption d'anions sulfates dans les Andosols Eutriques. Sur base d'extractions sélectives (NH4F, KH2PO4 et oxalate), l'immobilisation sous forme de minéraux hydroxy-alumino-sulfatés [(K,Na)nAlx(OH)y(SO4)z] apparaît comme le mécanisme de rétention du SO42- inorganique le plus important (9-51% du S total), l'adsorption du SO42- à la surface de constituants du sol (1-36% du S total) et le piégeage du SO42- (0-22% du S total), vraisemblablement au sein d'oxydes de fer mal cristallisés, constituent également des processus efficaces de rétention du sulfate inorganique. Nous mettons en évidence par observation directe, pour la première fois, la présence de minéraux hydroxy-alumino-sulfatés dans des sols par microscopie électronique à transmission couplée à une sonde analytique EDS. La formation de ces minéraux est elle-même favorisée par l'apport considérable de sulfate d'origine volcanique et l'hydrolyse intense des verres qui libère l'aluminium en solution. La précipitation à la surface des phases adsorbantes plutôt que la précipitation directe en solution semble être le mécanisme de formation des minéraux hydroxy-alumino-sulfatés dans ces sols.

Situee dans le Bassin des Mascareignes (Ocean Indien Occidental), l'Ile de la Reunion se compose de deux massifs volcaniques : le Piton des Neiges (3069 m) éteint et très érodé, au NW et le piton de la Fournaise (2631 ml) actuellement en activité. au SE . Ce mémoire se compose de deux parties : 1ère partie: EVOLUTION VOLCAND-STRUCTURALE DU MASSIF DU PITON DES NEIGES: aspect descriptif des structures - .observations géologiques (cartes et coupes). 2ème partie ESSAI * D' INTERPRETATION MECANIQUE DES STRUCTURES DU PITON DES NEIGES : - Mécanismes de formation des caldeiras du Piton des Neiges et structure de la croûte océanique au droit de l'Ile de la Réunion . 2 - Etat des connaissances sur les structures de l ' Océan Indien Occidental et relations avec les structures aériennes du volcan du Piton des Neiges. CONCLUSION: Origine de l 'Ile de la Réunion hot spot ou fracture crustale ?

名古屋大学年代測定総合研究センターシンポジウム報告

Stratigraphie et pétrographie des éléments du socle et de la couverture de la région du Canavese. Les roches ultrabasiques de Baldissero et du Piemonte sont replacées dans la série du socle. L'accent est mis sur les ressemblances entre le socle du Canavese et celui des Alpes méridionales. Des terrains du secondaire et plio-quaternaire constituent la couverture. Les schistes de Bio et de Levone se distinguent par leur caractère métamorphique de la série fondamentale lombarde. Ils pourraient appartenir à l'unité des schistes lustres. Etude tectonique de la région; présence de phases de fracturation de cisaillements. Mise en place du massif ultrabasique. La zone du Canavese apparait comme un élément distal du sillon lombard dans une position tectonique particulière.

Forecasting eruptions using volcano seismology is a subject that affects the lives and property of millions of people around the world. However, there is still much to learn about the inner workings of volcanoes and how this relates to the chance of eruption. This dissertation attempts to increase the breadth of knowledge aimed at helping to understand when a volcano is likely to erupt and how large that eruption might be. Chapters 2 and 3 focus on a technique that uses changes in the local stress field beneath a volcano to determine the source of these changes and help forecast eruptions, while Chapter 4 focuses on a technique that shows great potential to be used to image magma chambers beneath volcanoes by using receiver functions. In Chapters 2 and 3 the source mechanisms of shallow volcano-tectonic earthquakes recorded at Mount St. Helens are investigated by calculating hypocenter locations and fault plane solutions (FPS) for shallow earthquakes recorded during two eruptive periods (1981-1986 and 2004-2008) and two non-eruptive periods (1987-2004 and 2008-2011). FPS show a mixture of normal, reverse, and strike-slip faulting during all periods, with a sharp increase in strike-slip faulting observed in 1987-1997 and an increase in normal faulting between 1998 and 2004 and again on September 25-29, 2004. FPS P-axis orientations (a proxy for ó1) show a ~90° rotation with respect to regional ó1 (N23°E) during 1981-1986 and 2004-2008, bimodal orientations (~N-S and ~E-W) during 1987-2004, and bimodal orientations at ~N-E and ~S-W from 2008-2011. These orientations are believed to be due to pressurization accompanying the shallow intrusion and subsequent eruption of magma as domes during 1981-1986 and 2004-2008, and the buildup of pore pressure beneath a shallow seismogenic volume during 1987-2004 and 2008-2011. Chapter 4 presents a study using receiver functions, which show the relative response of the Earth beneath a seismometer. Receiver functions are produced by deconvolving the vertical component of a seismogram from the horizontal components. The structure of the ground beneath the seismometer can then be inferred from the arrivals of P-to-S converted phases. Receiver functions were computed for the Katmai Volcanic Group, Alaska, at two seismic stations (KABU and KAKN) between January 2005 and July 2011. Receiver functions from station KABU clearly showed the arrival of the direct P-wave and the arrival from the Moho; however, receiver functions from station KAKN did not show the arrival from the Moho. In addition, changes in the amplitude and polarity of arrivals on receiver functions suggested that the structure beneath both KABU and KAKN was complex. Station KABU is likely underlain by dipping layers and/or anisotropy, while station KAKN may lie over a basin structure, an attenuating body, or some other highly complex structure. However, it is impossible to say for certain what the structure is under either station as the azimuthal coverage is poor and thus the structure is unable to be modeled. This dissertation also includes a section (Chapter 6) on the assessment of spreadsheet-based modules used in two Introductory Physical Geology courses at the University of South Florida (USF). When faculty at USF began using spreadsheet-based modules to help teach students math and geology concepts the students complained that they spent more time learning how to use Excel than they did learning the concepts presented in the modules. To determine whether the sharp learning curve for Excel was hindering learning we divided the students in two Introductory Physical Geology courses into two groups: one group was given a set of modules which instructed them to use Excel for all calculations; the other group was simply told to complete the calculations but was not instructed what method to use. The results of the study show that whether or not the students used Excel had very little to do with the level of learning they achieved. Despite complaints that Excel was hindering their learning, students in the study attained high gains for both the math and geology concepts presented in the modules whether they used Excel or not.

This work focuses on crustal interaction in magmatic systems, drawing on experimental petrology and elemental and isotope geochemistry. Various magma-chamber processes such as magma-mixing, fractional crystallisation and magma-crust interaction are explored throughout the papers comprising the thesis. Emphasis is placed on gaining insights into the extent of crustal contamination in ocean island magmas from the Canary Islands and the processes of magma-crust interaction observed both in nature and in experiments. This research underscores that the compositions of ocean island magmas, even primitive types which are classically used as probes of the mantle, are susceptible to modification by crustal contamination. The principal mechanisms of contamination identified from work on both Tenerife and Gran Canaria (Canary Islands) are assimilation and partial melting of the pre-existing island edifice and intercalated sediments by newly arriving magma (i.e. “island recycling”). The information that we can gain from studying solidified magma and entrained crustal xenoliths concerning the rates and mechanisms of crustal assimilation is, however, limited. To address this shortcoming, a series of time-variable crustal carbonate assimilation experiments were carried out at magmatic pressure and temperature using natural materials from Merapi volcano, Indonesia. A temporally constrained reaction series of carbonate assimilation in magma has hence been constructed. The experiments were analysed using in-situ techniques to observe the progressive textural, elemental, and isotopic evolution of magma-carbonate interaction. Crucially, carbonate assimilation was found to liberate voluminous crustally-derived CO2 on a timescale of only seconds to minutes in the experiments. This points to the role of rapid crustal degassing in volcanic volatile budgets, and, pertinently, in magnifying hazardous volcanic behaviour. This thesis, therefore, delivers detailed insights into the processes of magma-crust interaction from experiments and geochemistry. The outcomes confirm that crustal processes are significant factors in both, i) ocean island magma genesis, and ii) magma differentiation towards compositions with greater explosive potential which can, in turn, manifest as hazardous volcanism. / Felaktigt tryckt som Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 707

The origin of compositional gaps in volcanic deposits remains controversial. In Akaroa Volcano (9.6 to 8.6 Ma), New Zealand, a dramatic compositional gap exists between basaltic and trachytic magmas. Previously, the formation of more evolved magmas has been ascribed to crustal melting. However, the interpretation of new major and trace element analysis from minerals and bulk-rocks coupled with the mechanics of crystal-liquid separation offers an alternative explanation that alleviates the thermal restrictions required for crustal melting models. In a two-stage model, major and trace element trends can be reproduced by polybaric crystal fractionation from dry melts (less than 0.5 wt.% H2O) at the QFM buffer. In the first stage, picritic basalts are separated from an olivine-pyroxene dominant mush near the crust-mantle boundary (9 to 10 kbar). Ascending magmas stagnated at mid-crustal levels (5 to 6 kbar) and fractionated an olivine-plagioclase assemblage to produce the alkali basalt-hawaiite trend. In the second stage, trachyte melt is extracted from a crystal mush of hawaiite to mugearite composition at mid-to-upper crustal levels (3 to 5 kbar) after the melt has crystallised 50 vol.%. The fractionated assemblage of plagioclase, olivine, clinopyroxene, magnetite, and apatite is left in a cumulate residue which corresponds to the mineral assemblage of sampled ultramafic enclaves. The results of trace element modelling of Rayleigh fractionation using this extraction window is in close agreement with the concentrations measured in trachyte (= liquid) and enclaves (= cumulate residue). The compositional gap observed in the bulk-rock data of eruptive products is not recorded in the feldspar data, which show a complete solid solution from basalt and co-magmatic enclaves to trachyte. Complexly zoned plagioclases further suggest episodical magma recharge events of hotter, more mafic magmas, which lead to vigorous convection and magma mixing. In summary, these models indicate that the Daly Gap of Akaroa Volcano formed by punctuated melt extraction from a crystal mush at the brittle-ductile transition.

No description available.

Prokaryotic microorganisms, which are at the base of deep-sea hydrothermal vent food webs, adapt rapidly to environmental fluctuations. This study aimed at comparing bacterial communities in contrasting hydrothermal habitats to better understand compositional adaptations to local conditions. I first used small subunit (SSU) ribosomal RNA (rRNA) gene sequences to compare mat-forming bacterial communities associated with iron oxides at two hydrothermal vent sites on the Tonga Arc, southwest Pacific. Operational taxonomic units (OTUs), defined at 97% sequence similarity, were affiliated to a great diversity of autotrophic and heterotrophic groups. Metabolically diverse Gammaproteobacteria dominated the sample from Volcano 19, collected at 992 m depth. The sample from Volcano 1, collected at 197 m depth, was dominated by iron-oxidizing bacteria from the class Zetaproteobacteria. The depth of the sampling sites was proposed to explain clone library dissimilarities. In the following studies, I compared bacterial communities associated with the vestimentiferan tubeworm Ridgeia piscesae, a foundation species at the Juan de Fuca Ridge. Samples of the polychaete were collected from tubeworm habitats in contrasting flow regimes that influenced temperature and hydrogen sulphide concentrations. Free-living bacteria were analyzed using both sequencing and 454 pyrosequencing of the SSU rRNA gene. Statistical analyses suggested a predictable pattern of bacterial community composition for the two habitats, with higher proportions of sulphur and hydrogen oxidizers in High Flow and more heterotrophic groups in Low Flow environments. Temperature, available energy for metabolism, and stability of the habitat were suggested to explain these distinctive bacterial communities. Symbiotic assemblages were investigated using the same sequencing methods together with catalyzed reporter deposition-fluorescence in situ hybridization (CARD-FISH). Gammaproteobacteria dominated all sequence libraries, followed by Epsilonproteobacteria. CARD-FISH confirmed the co-occurrence of these groups within R. piscesae trophosomes. Statistical analyses indicated distinctive membership and structure of trophosome assemblages between sampling sites. Analysis of R. piscesae juvenile showed distinctive structural properties when compared to adult individuals, but similar membership, within sampling sites. These results suggested that the composition of trophosome assemblages might be affected by specific physical and chemical conditions at each vent site and that a selection process might occur during R. piscesae’s development. / Graduate / 0410 / 0416 / 0329 / nathalieforget@gmail.com

Le massif du Menderes, essentiellement gneissique en son coeur, est entouré d'une ceinture de micaschistes. Au Sud, une bande de près de 50 km de large, formant la couverture du massif, succéde aux micaschistes. Elle comporte des terrains calcaires métamorphiques (marbres de Mugla) d 'âge paléozolque et mésozolque dont la structure est grosso modo Sud Ouest, Nord Est. Des lambeaux de calcaires non transformés, datés du Crétacé , supérieur, en place sur les marbres au Nord Est de Mugla, donnent un âge anté-crétacé au métamorphisme. Plus au Sud, un grand contact anormal incliné vers le Sud Est sépare l'enveloppe calcaire du massif du Menderes d'un ensemble comprenant, en discordance sous les péridotites, des formations sédimentaires et volcaniques écaillées. Les ultramafites, constituées de harzburgites monotones traversées par des dykes diabasiques, affleurent sur de vastes espaces couvrant plus de 3 000 km2, leur puissance dépasse fréquemment 1500 m, elles n'ont pour cou* verture qu'un Miocène supérieur - Pliocène lacustre. L'âge de leur mise en place est discuté: il est Tertiaire inférieur pour V. KOVENKO (1949), anté-Crétacé moyen pour G. VAN der KAADEN (1960). Les terrains sédimentaires et volcaniques sous-jacents aux péridotites sont visibles en bordure du contact anormal sur la couverture du massif du Menderes, notamment dans les écailles au Nord de Karabortlen G. VAN der KAADEN (1954), P. de GRACIANSKY (1964). Ils réapparaissent largement au Sud Est, entre Köycegiz et Fethiye grlâce à une tectonique cassante qui a récemment affecté les péridotites. - Les écailles de Karabörtlen comportent des faciès métamorphiques issus de roches sédimentaires (marbres, séricitoschistes, calcschistes, quartzites, amphibolites) ou de roches effusives (faciès épidote ) amphibolite, spilites glaucophanisés) . - Entre Köycegiz et Fethiye, les formations écaillées, en contact anormal dans cette région sur un Flysch éocène ne sont plus métamorphiques, on y observe des calcaires datés du Permien au Paléocène, des calcaires argileux, des grès, des radiolarites et des laves (spilites, diabases) qui se sont mises en place au Crétacé moyen (G. VAN der KAADEN 1960). C'est précisément dans cette partie, au Nord Ouest de Fethiye, que se trouve notre terrain d'étude.