The main aim of this thesis was to assess the status of soil organic carbon in newly shaped soils called Velká podkrušnohorská dump in the Sokolov district and evaluate the information in relation to the physic-chemical properties of soils. Another objective was to determine the relationship between the stable and labile fractions of soil organic carbon. The amount of soil carbon (stable fraction) was measured in the solid soil samples and there was the analysis of basic physic-chemical parameters of the soil performed. The highest concentration of soil carbon was measured in the stand alders and larch. The amount of soil carbon (labile fraction) was measured in the water extract. The highest values were measured in the stand silver birch and alders. Based on this data the quotient of the labile fraction from the stable fraction was determined and the correlation of the labile and stable fractions was made. It was found out that the higher quality soils are located at the leafy trees, but it leads to leaching of organic carbon. The bulk density and coarse-grained soil fraction was determined from the physical properties and these data were used to calculate the stock of soil organic carbon. The highest value was measured in deciduous forests with small-leaved linden, in coniferous forests with larch. The stocks of soil organic carbon were converted into codes by land cover categories and the thematic map was created. It was found out that the leafy trees are much more appropriate for forest restoration, because they are characterized by the rapid initial growth, easily degradable plant litter and stable form humus. Deciduous forests are also characterized by more developed soil substrate, which is however unstable.

The automation of the tramming or load, haul and dump (LHD) procedure, performed by a LHD vehicle, holds the potential to improve productivity, efficiency and safety in the mining environment. Productivity is mainly increased by longer working hours; efficiency is improved by repetitive, faultless and predictable work; and safety is improved by removing the human operator from the harsh environment. However, before the automation of the process can be addressed, a thorough understanding of the process and its duty in the overall mining method is required. Therefore, the current applicable mining methods and their areas of potential automation are given. Since the automation of the LHD vehicle is at the core of this project, its implementation in the tramming process is also justified. Also, the current underground navigation methods are given and their shortcomings are named. It is concluded that infrastructure-free navigation is the only viable solution in the ever-changing mining environment. With that in mind, the feasibility of various navigation sensors is discussed and conclusions are drawn. Both kinematic and dynamic modelling of LHD vehicles are introduced. Various forms of kinematic models are given and their underlying modelling assumptions are named. The most prominent assumptions concern the vehicle’s half-length and the inclusion of a wheel-slip factor. Dynamic modelling techniques, with a strong emphasis on tyre modelling, are also stated. In order to evaluate the modelling techniques, field tests are performed on the articulated vehicles, namely the Wright 365 LHD and the Bell 1706C loader. The test on the Wright 365 LHD gives a good impression of the harsh ergonomics under which the operator has to work. A more thorough test is performed on the Bell 1706C articulated loader. The test results are then compared to simulation results obtained from the kinematic models. Also, the above-named assumptions are tested, evaluated and discussed. A dynamic model is also simulated and discussed. Lastly, two localization and control methods are given and evaluated. The first method is an open-loop nonlinear optimal control strategy with periodic position resetting and the second method is a pathtracking controller. AFRIKAANS : Automatisering van die laai-, vervoer- en dompel- (LVD) prosedure het die potensiaal om die produktiwiteit, effektiwiteit en veiligheid van die mynbedryf te verbeter. Produktiwiteit word hoofsaaklik deur langer werksure verhoog, effektiwiteit word deur herhalende, foutlose en voorspelbare werk verbeter en veiligheid word verbeter omdat menslike operateurs uit die gevaarlike ondergrondse omgewing verwyder word. Voordat aandag aan die automatisering van die prosedure geskenk kan word, moet die prosedure en die algemene mynbedrywighede rakende die prosedure deeglik bestudeer en verstaan word. As gevolg hiervan word die huidige, toepaslike mynboumetodes hier gedokumenteer. Die implementering van ʼn gekoppelde LVD-voertuig in die LVD-prosesword ook geregverdig. Verder word die huidige metodes van ondergrondse navigasie genoem en hulle tekortkominge aangedui. Die gevolgtrekking dat infrastruktuur-vrye navigasie die enigste lewensvatbare navigasiemetode in die immer veranderende ondergrondsemynbouomgewing is, word ook gemaak. In die lig daarvan word ʼn verskeidenheid sensors genoem en bespreek. Kinematiese en dinamiese modellering van ʼn LVD-voertuig word bekendgestel. Verskeie kinematiese modelle en hulle onderliggende aannames word genoem. Die mees prominente aannames is die lengte van die gekoppelde voertuig se hoofdele en die insluiting van ʼn wielglipfaktor. Die tegnieke van dinamiese modellering, met die klem op bandmodellering, word ook gegee. Praktyktoetse op gekoppelde voertuie is ook gedoen om die verskillende modelle te evalueer. Die toets op die Wright 365-LVD bied goeie insig in die strawwe ergonomiese toestande waaronder die operateurs moet werk. ʼn Deeglike toets is op ʼn BELL 1706C- gekoppelde laaier, wat kinematies identies aan ʼn LVD-voertuig is, uitgevoer. Die bevindinge van die toets word met bogenoemde modelsimulasies vergelyk en gevolgtrekkings word gemaak. Laastens word lokalisiering en beheer van ʼn LVDvoertuig behandel. Twee beheermetodes, opelus- nie-lineêre optimale beheer met periodieke herstel en padvolgingbeheer word geëvalueer en bespreek. Copyright / Dissertation (MEng)--University of Pretoria, 2012. / Electrical, Electronic and Computer Engineering / unrestricted

Le site d’Ucanal, dans le Petén au Guatemala près de la frontière avec le Bélize, est un site maya avec une très forte occupation et un grand centre cérémoniel actif durant le Classique terminal, une période où de nombreuses autres cités mayas étaient en ébullition politique ou en train d’être abandonnés. Les jeux de balle faisant partie des centres civiques ont très souvent été fouillés dans des optiques reliées aux activités cérémonielles et à l’élite. Ce mémoire propose d’étudier les déchets provenant des dépotoirs situés en périphérie du jeu de balle afin d’étudier les activités pratiquées par les spectateurs et non juste celles des officiants. Pour ce faire, une analyse globale de tous les artefacts (lithiques, céramiques et fauniques) du jeu de balle #1 du groupe A d’Ucanal a été réalisée. Des analyses de la distribution des artefacts entre les différentes zones du terrain de jeu et entre le terrain de jeu et d'autres contextes du site ont été entreprises afin d'identifier l'éventail possible d'activités associées au terrain de jeu d'Ucanal. Les résultats démontrent qu’en plus des activités rituelles généralement documentées en contexte de jeu de balle, le jeu de balle d’Ucanal est associé à des activités de festins qui impliquent une grande consommation de coquillages possiblement accompagnée de musique et de paris. / The archaeological site of Ucanal, located in the Petén region of Guatemala near the border with Belize, is a Maya site with a large population and active ceremonial centre during the Terminal Classic, a period in which other sites were wrought with political turmoil or were in the process of being abandoned. The ballcourts located in civic centers have often been researched from the perspective of formal ceremonial activities and the elite. This thesis proposes to study the debris from middens located on the outskirts of the Ucanal site ballcourt in order to study the activities practiced by spectators instead of focusing solely on the formal activities within the court itself. To do so, a holistic documentation of all the artifacts (lithic, ceramic and fauna) was conducted from excavations of ballcourt #1 of group A of Ucanal. Artifact distribution analyses between different zones of the ballcourt and between the ballcourt and other areas of the site were undertaken to identify the possible range of activities associated with Ucanal’s ballcourt. The results show that in addition to the ritual activities generally documented in the context of ball games, Ucanal's ballcourt was associated with feasting activities which involved freshwater shells and possibly the accompaniment of music and gambling.

En el Perú, la minería es una de las actividades importantes en el desarrollo del crecimiento económico del país, sin embargo, el uso indiscriminado de los recursos naturales y el impacto ambiental, debido a la extracción del mineral, obligó a las entidades reguladoras como el ANA, OEFA, OSINERGMIN a estandarizar los procesos de extracción y operación. Esto contempla estabilizar ambientalmente los componentes que se encuentran dentro del proceso de extracción del mineral, además, de estabilizar, física, química e hidrológicamente a aquellos que, una vez agotado el recurso (mineral), se transforman en un pasivo que deben ser incorporados de manera estable al medio ambiente (cierre de pasivo). La presente tesis propone evaluar la condición de estabilidad actual del depósito de desmonte de roca N8-PO. La evaluación se realizará usando programación lineal a través del método Simus que recoge los parámetros más importantes para cada condición de estabilidad actual, analizado en el pasivo, el cual será comparada con los factores de seguridad requeridos por las entidades reguladoras y las buenas prácticas de construcción. Para el análisis de estabilidad física se recogerán los resultados del análisis estático y pseudo estático, para el análisis de estabilidad geoquímica, se recogerán los resultados de los ensayos ABA, finalmente, para el análisis de estabilidad hidrológica, se tendrá en cuenta el estudio hidrológico, además de la existencia y condición de estructuras hidráulicas presentes. Los resultados de la evaluación indicarán la condición de estabilidad del pasivo. Por último, los resultados recomendarán también, posibles alternativas de cierre a usar. / In Peru, mining is one of the important activities in the development of the country's economic growth, however, the indiscriminate use of natural resources and the environmental impact, due to mineral extraction, forced regulatory entities such as ANA, OFEA, OSINERGMIN to standardize the extraction and operation processes. This includes not only environmentally stabilizing the components that are within the mineral extraction process, but also, physically, chemically and hydrologically stabilizing those who, once the (mineral) resource has been depleted, become a responsibility that must Stably incorporate into the environment (passive closure). This thesis proposes to evaluate the current stability condition of the N8-PO rock dump and compare with the results of the evaluation that will be carried out with two additional components, of the same characteristics, located near the component under study. The evaluation will be carried out through a program that uses a numerical method that collects the most important parameters for each stability condition, current, analyzed in the dump, which will be compared with the safety factors required by regulatory entities and Good construction practices. In the analysis of the physical stability the results of the static and pseudostatic analysis will be collected, for the analysis of the geochemical stability, the results of the ABA tests will be collected, finally, for the analysis of the hydrological stability, the studies will be taken Hydrology account, as well as the existence and condition of the hydraulic structures present. The evaluation results will indicate the stability condition of the mining component. Finally, the results will also recommend possible closure alternatives that will be used to achieve the desired stability. / Tesis

The goal of the Master thesis is to design a grain container. The thesis involves a possible method of grain storage depending on the quality and condition of the grain and also the ways of filling and emptying the container with all the problems that might occur. The thesis deals for example with a possibility of occurrence of vault and with it associated change of state of stress, or with the pressure surges in the container. The thesis involves an analysis of an appropriate construction solution, a design of the main dimensions of the container and a test calculation of the container ´s strength.

The aim of the thesis was to analyze soil microbial communities of three ecologically different locations, about 25 years old, forestry reclaimed dumps in the Republic of Poland, namely dumps of brown coal mine Bełchatów and sand mines Piaseczno and Szczakowa. I evaluated the degree of dependence of structure and composition of these communities on various substrate grain sizes and the influence of the dominant tree species. These were stands of birch (Betula pendula), pine (Pinus silvestris), oak (Quercus robur) and alder (Alnus glutinosa). Analysis of soil microbial communities was made by evaluating specific phospholipid fatty acids (PLFA) of microorganisms. It is the most appropriate way to implement the relatively rapid analysis of large numbers of samples, since PLFA are easily extractable and act as biomarkers indicating the presence of a number of different microorganisms (fungi, G- and G + bacteria, Actinobacteria, etc.) and thus allowing a qualitative and quantitative assessment of whole microbial communities. PLFA analysis enables to detect a total concentration of PLFA only in living soil microbial biomass. I analyzed 66 soil samples, 33 from an Oe layer and 33 from an A layer, every in three replications, i.e. three replications were collected at each location below each tree...

Waste management (WM) is a prominent issue in the world’s most populated country, India. Lack of WM can have a negative impact on the environment through leachate contamination of water bodies and emissions of greenhouse gases. The purpose of this study was to thoroughly map WM processes in South East India and identify areas with potential for environmental improvement. This was conducted in three steps: by mapping the flows in a WM system in Chennai (India), by qualitatively assessing these flows through a literature review of articles published in the field, and by interviewing representatives from the company that are responsible for the collection and transportation of waste to identify what challenges the process faces and how they can be addressed. The main finding from the study was that the lack of site-specific data made it difficult to quantitatively assess the global warming potential of the process; however, it is possible to make a qualitative analysis. From study visits to the different treatment facilities, it was clear that energy recovery is a technical solution that could reduce the GWP of the process. Additionally, it became clear that the process should be seen as a socio-technical system, as the studied process is currently focusing on developing and improving the social elements of the process. These social elements include getting the residents to segregate their waste through education in schools and door-to-door collection. The results also showed how an improved cultural perception on WM could potentially influence several of the identified challenges in the process and their respective solutions. Finally, the study highlighted the importance of conducting more in-depth research to enable the implementation of an LCA that can contribute with valuable results. / Avfallshantering är en viktig fråga i världens mest befolkade land, Indien. Bristande avfallshantering kan ha en negativ inverkan på miljön genom att lakvatten förorenar vattendrag och utsläpp av växthusgaser. Syftet med den här studien var att noggrant kartlägga en process för avfallshantering i sydöstra Indien och identifiera områden med potential för miljöförbättringar. Detta genomfördes i tre steg: genom att kartlägga flödena i ett avfallshanteringssystem i Chennai (Indien), genom att kvalitativt bedöma dessa flöden genom en litteraturgenomgång av artiklar som publicerats på området och genom att intervjua representanter från det företag som ansvarar för insamling och transport av avfall för att identifiera vilka utmaningar som processen står inför och hur de kan åtgärdas. Det viktigaste resultatet av studien var att bristen på platsspecifika data gjorde det svårt att kvantitativt bedöma processens globala uppvärmningspotential (GWP), men att det var möjligt att göra en kvalitativ analys. Vid studiebesöken vid de olika behandlingsanläggningarna blev det tydligt att energiåtervinning är en teknisk lösning som skulle kunna minska processens GWP. Dessutom blev det tydligt att processen bör ses som ett sociotekniskt system, eftersom den studerade processen för närvarande fokuserar på att utveckla och förbättra processens sociala element. Dessa sociala element omfattar att få invånarna att sortera sitt avfall genom utbildning i skolor och insamling av avfall från dörr till dörr. Resultaten visade också hur en förbättrad kulturell uppfattning om avfallshantering potentiellt skulle kunna påverka flera av de identifierade utmaningarna i processen och deras respektive lösningar. Slutligen betonade studien vikten av att genomföra mer djupgående forskning för att möjliggöra genomförandet av en LCA som kan bidra med värdefulla resultat.

The diploma dissertation deals with description and division of technologies of coal storage yards. A content of it is classification of individual storages thoroughly divided according to their feature. It introduces with measuring equipment used while solving diploma dissertation. Is incorporated herein by a description of the PLC including a description of each associated modules. Further there is clearly mentioned specification of needed data that is necessary to scan for control system of the storage. Within the diploma dissertation was created electrical system documentation data of collection control systems for longitudinal landfill with two universal machines.

The diploma dissertation deals with description and division of technologies of coal storage yards. A content of it is classification of individual storages thoroughly divided according to their feature. It introduces with measuring equipment used while solving diploma dissertation. Is incorporated herein by a description of the PLC including a description of each associated modules. Further there is clearly mentioned specification of needed data that is necessary to scan for control system of the storage. Within the diploma dissertation was created electrical system documentation data of collection control systems for longitudinal landfill with two universal machines.

MENVSC / Department of Ecology and Resource Management / Historically, mining activities have generated vast quantities of abandoned tailings dumps in several regions of South Africa and throughout the world. The management and disposal of huge volumes of tailings dumps has constituted a major challenge to the environment. The current study aims to establish the physicochemical properties and mineralogical characterization of the old copper tailings dump in Musina, to reveal the mobility patterns and attenuation dynamics of potentially toxic or heavy metal species as a function of depth, with a view of assessing their potential environmental impact with respect to surface and ground water systems. This information is crucial in the beneficial utilization of copper tailings in the development of sustainable construction materials as part of reuse approach management system. About twelve tailings samples were collected into polyethylene plastic bags from three established tailings profiles drilled by a hand auger. The collected tailings samples were characterized using standard analytical procedures i.e., X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM-EDS). The transfer of potentially toxic or heavy metal species from tailings to water was evaluated using the standardized batch leaching test (EN 12457) and speciation-equilibrium calculations on the aqueous extracts performed by MINTEQA2. The leachate concentration of cations in the collected tailings samples was determined by inductively coupled mass spectrometry (ICP-MS) and the leachate concentration of anions was determined by ion chromatography (IC). A modified sequential extraction scheme was applied on the selected tailings samples of the drilled tailings profiles to further understand the mode of occurrence, the geochemical partitioning and distribution, real mobility, and environmental bioavailability of potentially toxic or heavy metal species in the tailings and tailings-soil interface. The extracted fractions or phases from sequential scheme were as follows: (F1) water-soluble fraction, (F2) exchangeable fraction, (F3) carbonate fraction, (F4) iron and manganese hydroxide associated fraction, (F5) organic matter and secondary sulphide associated fraction, (F6) primary sulphide bound fraction, and (F7) residual or silicate fraction. The results obtained from the seven steps sequential extraction scheme were validated by the determination vi of percentage recoveries from pseudo-total digestion or total metal content of the original sample. The distribution of major elements and potentially toxic or heavy metal species in different leachate fractions obtained after each step of sequential extraction of the selected tailings samples was determined by inductively coupled plasma mass spectrometry (ICP-MS). The appraised data was used to reveal the impact of atmospheric oxygen and infiltrating rain-water on the chemistry of copper tailings dump by depth profiles. Macroscopic properties revealed that the abandoned Musina copper tailings are fine to medium coarse grained, and range in color from light/dark gray at the upper or shallow depth of the tailings, to dark reddish-brown at the deeper zone where the tailings are mixed with the underlying soil or soil-interface. The drilled respective tailings profiles were uniform and slightly varied in both mineralogical and bulk chemical compositions with tailings depth. Mineralogical analysis showed the following order of mineralogical composition within the respective tailings profiles: quartz> epidote> chlorite> muscovite> calcite> hematite. Chalcopyrite was the only sulphide mineral observed by optical microscopy, although not identified or quantified by XRD and SEM-EDS analysis. The observed discrete chalcopyrite grains were attributed to the primary mined ore (i.e., chalcopyrite, chalcocite and bornite) during past copper mining activities in Musina. The tailings profiles were characterized by a medium alkaline pH (7.97-8.37) that corresponds very well with the tailings leachates or pore-water pH (8.36-8.46). This pH was constant and slightly varied with tailings depth in the respective tailings profiles. The high abundance of alumino-silicate minerals and traces of carbonates as calcite coupled with low sulphide mineral content, suggested a high neutralization capacity of the tailings which was in common agreement with an alkaline nature of the copper tailings dump. The chemical composition of major elements within the respective tailings profiles followed the order: Si>Al>Fe>Ca>Mg>K>Na, and corresponds very well with the mineralogical composition of the tailings, whereby alumino-silicates were the most abundant minerals in the tailings samples. Nevertheless, the solid-phase concentration of metals decreases with increasing tailings depth as Cu>Sr>Zr>Ni>Zn and was incongruent with the mineralogical composition within the respective tailings profiles. The main secondary minerals were calcite and hematite, and their proportion increased with increasing tailings vii depth. In addition, hematite formed coatings on the rims and corners of chlorite as observed from optical microscopy, and retained relatively high amounts of potentially toxic or heavy metals (up to 862 ppm of Cu, up to 36 ppm of Ni, and up to 25 ppm of Zn) at the upper and shallow depth of the respective tailings profiles, where bulk density was high and low porosity. Based on batch leaching tests, the amounts of potentially toxic or heavy metal species released into solution were low (0.27-0.34 μg/L Pb, 0.54-0.72 μg/L Ni, 0.88-1.80 μg/L Zn, and 20.21-47.9 μg/L Cu) and decreases with increasing tailings depth, indicating that, presently, the tailings have a minor impact on heavy metals load transported to the receiving surface and groundwater systems. The low concentration of potentially toxic or heavy metal species in solution is primarily due to their retention by secondary Fe oxide phases (i.e., hematite) and the prevailing medium alkaline pH condition of the tailings leachate or pore-water. The observations are consistent with MINTEQA2 speciation calculations, which predicted the precipitation of secondary phase cuprite (Cu2O) as the main solubility-controlling mineral phase for Cu, Zn, and Ni. Primary factors influencing aqueous chemistry at the site are neutralization and dissolution reactions as a function of pH, precipitation, and sorption into hydrous oxides (hematite and cuprite). Based on sequential extraction results, the leachable concentration of potentially toxic or heavy metal species in the water-soluble, exchangeable and carbonate fractions of the respective tailings profiles was relatively low, except for Cu and Mn. For instance, the leachable concentration of Cu and Mn reached 10.84 mg/kg and 321.7 mg/kg at the tailings-soil interface (3 m) in tailings profile C, respectively. The low concentration of potentially toxic or heavy metal species (Cr, Co, Ni, Zn, Cd, and Pb) in these fractions could be due to the low solubility of minerals bearing these trace elements caused by variations in pore-water pH in the respective tailings profiles. The high concentration of Cu and Mn in these fractions suggests their high mobility and therefore most available for uptake in the environment. Except for Cu>Mn>Cr, the contents of potentially toxic or heavy metal species in the Fe and Mn oxides and organic matter or sulphides bound fractions was low, due to the low viii quantity of these fractions in the tailings, despite their high affinity and sorption capacity for potentially toxic or heavy metal species. Likewise, the residual fraction of the respective tailings profiles contained the highest proportion of potentially toxic or heavy metal species. Although the highest potentially toxic or heavy metal species content was in fractions with limited mobility, care must be taken since any geochemical change or shift in the tailings pH or acidic conditions may cause them to be displaced to more mobile fractions, thereby increasing their mobility and environmental bioavailability. Therefore, physicochemical properties of the tailings including pH and mineralogical composition of the tailings samples were the main substrate controlling the geochemical partitioning and distribution, potential mobility, and environmental bioavailability of potentially toxic or heavy metal species by tailings depth. The knowledge of mobility and eco-toxicological significance of tailings is needed when considering tailings dump disposal or reuse in the environment. The addition of copper tailings at 3 and 28 days successfully improved the compressive strength of cement mortar mixtures incorporating tailings at C5 (5%) and C10 (10%) respectively, although with small margin relative to the control mixture (C0). The maximum strength was 31.15 Mpa attained after 28 curing days, and slightly varied when compared with other compressive strength on copper blended cement mortars mixtures in other countries, used for the development of sustainable construction materials. The chemical composition, physical properties and improved compressive strength on cement mortars mixtures incorporating copper tailings, implies that copper tailings are suitable for the development of sustainable construction materials, thereby ensuring job creation, availability of land for development usage, and the reduction of environmental pollution induced by the abandoned copper tailings dumps.