Climate change is a global challenge that requires proactive action from municipalities, companies, and other organizations to prioritize sustainability in their daily operations. In the past few decades, life cycle assessment (LCA) approach has been successfully applied for environmental assessments in the drinking water sector. In this study, this approach has been used to present a comparative evaluation of the potential environmental impacts associated with nine different process alternatives for future drinking water production at Norrvatten. This study is a pioneering one that explores the potential of LCA as a decision support tool to prioritize and optimize environmental impacts during the operational phase in Swedish drinking water production. The nine alternatives are designed for the year 2050 to meet the average daily demand of 208 MLD for the 14 municipalities in the northern Stockholm region that Norrvatten supplies with drinking water. Out of the nine alternatives, the alternative based on direct filtration of raw water on nanofiltration membranes came out as the most environmentally friendly solution due to the use of renewable electricity from hydro and wind power. The results indicate that the potential environmental impacts are dominated by the use of chemicals in all alternatives, which in turn depends on the energy sources used for chemical production that are mostly dominated by fossil-based non-renewable sources. The impacts due to transportation and energy consumption are relatively less in Swedish drinking water production. Moreover, filtration through granulated activated carbon (GAC) is the most environmentally damaging treatment step, but regeneration of saturated GAC induces positive impacts in all alternatives. Among environmental impact categories, categories related to fine particulate matter formation; global warming, human carcinogenic toxicity, and human non-carcinogenic toxicity are the most significant in all alternatives. Several of the treatment technologies included in the nine alternatives, such as Nanofiltration, have only been tested on a pilot scale and have not been used for drinking water production at Norrvatten. So this study should be followed up and supplemented with better representative inventory data relevant to the Swedish context in order to contribute more effectively in making the future Swedish drinking water production more sustainable and environmentally friendly. Also, this study is based on the most recently available data that may not be valid in 2050 and the latest trends to substitute non-renewable energy sources with renewable sources may reduce the impacts due to chemical production and transportation in the future. Moreover, this LCA study does not include any aspects of water quality and treatment costs. Hence, while comparing different alternatives, the quality of the treated water and its production cost must also be taken into account. / Klimatförändringar är en global utmaning som kräver proaktivt agerande från kommuner, företag och andra organisationer för att prioritera hållbarhet i sin dagliga verksamhet. Under de senaste decennierna har livscykelanalys (LCA) använts för miljöbedömningar inom VA-sektorn. I denna studie har detta tillvägagångssätt använts för att presentera en jämförande utvärdering av den potentiella miljöpåverkan som är förknippad med den framtida dricksvattenproduktionen vid Norrvatten. Med hjälp av LCA så jämförs nio olika processalternativ för den framtida produktionen och kan på så sätt bidra till att prioritera och optimera processval utifrån miljösynpunkt. De nio alternativen är utformade för år 2050 för att tillgodose den genomsnittliga dagliga efterfrågan på 208 MLD för de 14 kommuner i norra Stockholmsregionen som Norrvatten försörjer med dricksvatten. Av nio alternativ kom alternativet baserat på direkt filtrering av råvatten på nanofiltreringsmembran som den mest miljövänliga lösningen på grund av användningen av förnybar el från vatten- och vindkraft. Resultaten indikerar att de potentiella miljöeffekterna domineras av användning av kemikalier i samtliga alternativ, vilket i i sin tur beror på de energikällor som används för kemikalieproduktion domineras av fossilbaserade energibärare. Effekterna på grund av transport och energiförbrukning är relativt låg i svensk dricksvattenproduktion. Filtrering genom granulerat aktivt kol (GAC) det mest miljöbelastande behandlingssteget, men regenerering av mättad GAC ger positiva effekter i alla alternativ. Bland kategorier för miljöpåverkan så är kategorier relaterade till bildning av fina partiklar; global uppvärmning, mänsklig cancerframkallande toxicitet och mänsklig icke-cancerogen toxicitet de viktigaste i alla alternativ. Flera av de behandlingstekniker som ingår i de nio alternativen, såsom Nanofiltration, har enbarts testats i pilotskala och inte använts för dricksvattenproduktion vid Norrvatten. Så denna studie bör följas upp och kompletteras med data som är relevanta för förhållanden vid Vättern Denna studie baseras också på tillgängliga data som kanske inte är giltiga 2050 och de senaste trenderna för att ersätta icke förnybara energikällor med förnybara källor som kan minska effekterna på grund av kemisk produktion och transport i framtiden. Dessutom innehåller denna LCA-studie inga aspekter av vattenkvalitet och behandlingskostnader.. Vid jämförelse av olika alternativ måste även kvaliteten på det behandlade vattnet och dess produktionskostnad beaktas.

Cooking stove technologies are crucial for meeting household energy needs, yet many lack access to clean solutions, leading to Household Air Pollution (HAP) and associated health risks. There is an urgent need to understand and mitigate environmental and health challenges posed by traditional stoves burning solid fuels like fuelwood. This thesis examines the environmental and human health impacts of different cooking fuel options using a Life Cycle Assessment (LCA) approach. A case study is developed in the state of Tamil Nadu in India, considering different cooking fuel mix scenarios and sustainable transition in the sector. Key impact categories such as Global Warming Potential (GWP), Fine Particulate Matter Formation, and Human Health are examined. Findings reveal persistent challenges, particularly with solid fuels like firewood, contributing to HAP and adverse health effects. Transitioning to renewable energy sources such as Biogas and Electricity is crucial for mitigating environmental impacts and improving public health outcomes. Eliminating firewood in the Sustainable scenario fuel mix could result in a 43% reduction in GWP, an 87.5% reduction in delicate particulate matter, and a 75% improvement in human health. This study provides insights for policymakers to develop interventions promoting sustainable cooking practices and enhancing community well-being in Tamil Nadu and beyond. / Köksspis-teknologier är avgörande för att tillgodose hushållens matbehov, men miljontals saknar tillgång till rena matlagningslösningar, vilket leder till hushållsluftföroreningar (HAP) och associerade hälsorisker. Det finns ett brådskande behov av att förstå och mildra miljö- och hälsoutmaningar som traditionella spisar, som använder fasta bränslen såsom ved, innebär. Denna avhandling undersöker miljö- och hälsoeffekterna av olika alternativ för matlagningsbränsle med en livscykelanalys (LCA)-ansats. En fallstudie har utvecklats i delstaten Tamil Nadu i Indien, där olika scenarier för blandning av matlagningsbränslen och en hållbar övergång inom sektorn övervägs. Viktiga faktorer som global uppvärmningspotential (GWP), bildning av fint partikulärt material och människors hälsa undersöks noggrant. Resultaten avslöjar ihållande utmaningar, särskilt med fasta bränslen som ved, som bidrar till HAP och negativa hälsoeffekter. Övergången till förnybara energikällor som biogas och elektricitet är avgörande för att mildra miljöpåverkan och förbättra folkhälsan. Att eliminera ved i bränslemixen i det hållbara scenariet kan leda till en 43 % minskning av GWP, en 87,5 % minskning av fintpartikulärt material, och en 75 % förbättring i mänsklig hälsa. Genom att utnyttja insikterna från denna studie kan beslutsfattare och intressenter utveckla riktade insatser för att främja hållbara matlagningspraxis och förbättra välbefinnandet för samhällen i Tamil Nadu och vidare.

This master’s thesis aims to improve the circularity of the electric vehicle (EV) battery value chain, specifically focusing on sustainable waste management of Lithium-Ion Batteries (LIBs) in Europe, particularly Sweden. The research objectives include evaluating and proposing actionable recommendations to enhance circularity, addressing environmental impacts, and supporting the industry’s transition towards a sustainable business model aligned with the new European Union (EU) Battery Regulation, which aims to enhance recycling rates, reduce environmental impact, and secure the recovery of valuable materials. The key research questions addressed are: (1) What initiatives, technologies, or best practices are currently being developed to support circularity and sustainable waste management in the EV battery value chain? (2) How can the circularity of the EV battery value chain be enhanced, particularly in sustainable waste management for LIBs? (3) What environmental impacts, socio-economic opportunities, and challenges exist in a circular value chain in the EV battery industry? The methodology employed a mixed-methods approach, including a literature review and case study, stakeholder interviews, SWOT analysis and life cycle assessment (LCA) using Minviro LCA software to quantify and compare the environmental impacts of state-of-the-art industrial LIB recycling methods. Key findings indicate that several initiatives and technologies are being developed to support circularity, including advanced recycling technologies and second-life applications for batteries. Enhancing circularity requires regulatory support, technological advancements, and stakeholder collaborative efforts. The findings highlight significant potential for extending the lifecycle of EV batteries through re-use, re-purposing, and recycling strategies. The analysis reveals that advancements in recycling technologies and supportive regulatory frameworks can substantially reduce the environmental impact and improve LIB supply chain sustainability. Notably, the LCA results highlight that mechanical and hydrometallurgical recycling processes offer more favourable environmental outcomes than pyrometallurgical methods. Thus, it shows potential for lower environmental impact on greenhouse gas (GHG) emissions and resource depletion, alongside socio-economic opportunities like job creation and economic growth. However, challenges such as technological barriers, economic feasibility, regulatory compliance, and EV battery value chain complexities remain, and these must be addressed. The conclusions drawn from the findings recommend that a combination of regulatory support, technological innovation, and stakeholder collaboration is essential for improving the circularity of the EV battery value chain. The study recommends advancements in recycling technologies, developing efficient testing and certification processes for second-life batteries, and establishing clear regulatory frameworks to facilitate circular economy practices. These measures are crucial for supporting the industry’s shift towards a more sustainable and circular model, ultimately contributing to the EU’s climate neutrality goals by 2050.

The apparel and footwear industry’s contribution to global greenhouse gas (GHG) emissions is one of the fifth largest per industry, equal to that of livestock, after electricity and heat, oil and gas, agriculture, and transportation (Ellen MacArthur Foundation, 2017). For industry-wide emissions reduction, investing in renewable energy and energy efficiency programs across highest impacting life cycle phases offer the most effective solution. However, identifying the highest impacting life cycles phases shows varied results depending on the particular type of business model under examination. This paper responds to the lack of existing data and empirical research on how to accurately measure, report and reduce carbon emissions across the highly complex and globally interconnected apparel value chain. This is done through a single case study investigation of an Icelandic fashion brand. A hybrid approach of a standard Life Cycle Assessment (LCA) and the Sustainable Global Value Chain (SGVC) functions to produce a Hotspot Identification Tool (HIT) to establish a holistic portrayal of business operations in relation to emission impacts and level of controllability across Scopes. The conceptual analysis and qualitative results identify the most relevant emission hotspots to lie within the company’s privately owned manufacturing facilities, as well as the procurement phase, due to its direct connection with and influence on material production, user phase, and end-of-life. The main obstacle in this pursuit is identified as restriction of resources in terms of time, capital and expertise. It is suggested that this be overcome by joining a Multi-Stakeholder Initiative where resources and expertise is pooled in a pre-competitive manner to reach common objectives. The investigation further suggests a need for global fashion brands to leverage their influential position on down- and upstream activities across the value chain, i.e. with their supply chain partners and consumers. I argue that fashion brands play an integral role in supporting local efforts to build a decarbonisation pathway towards climate neutral economies on a global scale.

Uma das formas mais integradas, completas e eficazes para a gestão ambiental de atividades produtivas é baseada no ciclo de vida do produto, sendo a avaliação do ciclo de vida sua principal ferramenta. O produto avaliado é o álcool etílico hidratado combustível, por ser passível de melhorias ambientais durante seu ciclo de vida, alternativo frente aos fósseis e de grande importância estratégica para o Estado de São Paulo e para o Brasil. O objetivo é a avaliação do ciclo de vida do álcool etílico hidratado combustível utilizando o método EDIP (Environmental Development of Industrial Products) e introduzindo as avaliações exergéticas e emergéticas na avaliação e valoração do impacto. A estrutura metodológica está baseada nas normas da série NBR-ISO 14.040 e ISO 14.040. Os resultados do EDIP mostram que a atividade da colheita de cana apresenta o maior potencial de impacto para o consumo de recursos renováveis, o aquecimento global, a formação fotoquímica de ozônio troposférico, a acidificação e a toxicidade humana. O preparo do solo apresenta maior potencial para o consumo de recursos não renováveis e para a ecotoxicidade da água. O trato cultural apresenta maior influência na eutrofização e na ecotoxicidade do solo. Pela exergia, verifica-se que, para cada litro de álcool consumido, há uma perda de exergia pelas emissões atmosféricas de seu ciclo de vida, considerando que 25% da cana colhida seja crua, equivalente à exergia de, aproximadamente, 1,38 litro de álcool. Pela emergia, 69% do consumo de energia solar equivalente é realizado pelo veículo automotor. Portanto, a fim de adequar ambientalmente o ciclo de vida do etanol hidratado combustível, indica-se a eliminação da queimada, a redução do uso de agrotóxicos, de combustível fóssil e formas mais eficientes de uso do álcool combustível. / One of the most integrated, complete and efficacious means for the environmental management of productive activities is based on the life cycle of the product, whose main tool is the life cycle assessment. The assessed product is the hydrated ethylic alcohol fuel because of the environmental improvement possibilities during its life cycle, an alternative for fossil fuel and its great strategic importance to Sao Paulo State and Brazil. The goal is the life cycle assessment of hydrated ethylic alcohol fuel using EDIP (Environmental Development of Industrial Products) method and introducing exergy and emergy methods on the impact assessment and valuation. The methodological structure is based on the norms NBR-ISO 14.040 and ISO 14.040 series. The EDIP results show that the sugar cane harvesting activity presents the highest potential impact for the renewable resources consumption, the global warming, the photochemical ozone formation, the acidification and the human toxicity. The soil preparation activity presents the highest potential for the non-renewable resources and the ecotoxicity in water. The cultivation activity presents the highest potential for the nutrient enrichment and the ecotoxicity in soil. With the exergy method, it is verified that for each liter of alcohol consumed, there is an exergy lost by the atmospheric emissions of its life cycle, considering 25% of the total sugar cane cultivated and harvested is not burned, which is equivalent to the exergy of, approximately, 1.38 liter of alcohol. By the emergy method, 69% of the equivalent solar energy consumption is performed by the vehicle. Therefore, in order to achieve an environmentally benign life cycle of the hydrated ethylic alcohol fuel, it is indicated the sugar cane burning elimination, pesticides and fossil fuel reduction and more efficient manners of using alcohol fuel.

Cette thèse de doctorat, a consisté, dans une première partie, à introduire d’une part, la notion de l’analyse du cycle de vie « ACV » et celle des biocarburants. D’autre part, à présenter l’intérêt d’appliquer une ACV sur des biocarburants afin de valoriser leurs bilans énergétiques et analyser leurs impacts environnementaux face aux carburants conventionnels. Dans une deuxième partie, nous avons comparé, d’un point de vue énergétique et environnemental, 3 scénarios de production d’électricité : 2 scénarios de cogénération (turbine à vapeur et ORC) pour la production d’énergie électrique et thermique à partir de biomasse, et un scénario de cogénération par moteur diesel. Ces scénarios sont comparés à l’aide de deux méthodes orientées « analyse des dommages »: Eco-indicateur 99 (E) et IMPACT2002+Dans une troisième partie, on a abordé la valorisation du biogaz sous forme de carburant dans des moteurs "dual fuel" pour des engins agricoles dans le but de déterminer l’impact environnemental lié à l’utilisation de ce carburant alternatif au diesel par rapport aux autres biocarburants. Les méthodes Eco-indicateur 99 (E) et CML ont été utilisées ici. On a pu ainsi identifier les principaux polluants générés à chaque étape du cycle de vie de l’agrocarburant et les étapes qui ont les plus grands impacts environnementaux et on a identifié, selon nos critères et par rapport au contexte, le scénario énergétique le plus compatible avec le principe de développement durable. / This thesis has consisted in a first part to introduce, on one hand, the concept of each of: lifecycle assessment "LCA" and biofuels, on the other hand, to present the benefits of applying aLCA on biofuels to evaluate their energy balances and to analyze their environmental impactsagainst conventional fuels.In a second part, we compared, from point of view energetic and environmental, 3 scenariosof electricity production: 2 scenarios of cogeneration (steam turbine and ORC) for theproduction of electrical energy and of heat from biomass, and a scenario of cogeneration by adiesel engine, these scenarios have been compared using two damage-oriented analysismethods: Eco-indicator 99 (E) and IMPACT2002 +In a third part, we worked on the evaluation of methane as fuel in "dual fuel" engines foragricultural purpose, the aim was to determine the environmental impact associated with theuse of this alternative fuel for diesel compared to other biofuels. Methods Eco-indicator 99(E) and CML have been used here.We were able to identify the main pollutants generated at each stage of the life cycle ofbiofuel and the steps that have the greatest environmental impacts, and to identify, accordingto our criteria and to the context the energy scenario the most consistent with the principle ofsustainable development.

The production and consumption of information and communication technology (ICT) products and services continue to grow worldwide. This trend is accompanied by a corresponding increase in electricity use by ICT, as well as direct environmental impacts of the technology. Yet a more complicated picture of ICT’s effects is emerging. Positive indirect effects on environmental sustainability can be seen in substitution and optimization (enabling effects), and negative indirect effects can be seen in additional demand due to efficiency improvements (rebound effects). A variety of methods can be employed to model and assess these direct and indirect effects of ICT on environmental sustainability. This doctoral thesis explores methods of modeling and assessing environmental effects of ICT, including electronic media. In a series of five studies, three methods were at times applied in case studies and at others analyzed theoretically. These methods include life cycle assessment (LCA) and complex systems modeling approaches, including System Dynamics (SD) and agent-based (AB) modeling. The first two studies employ the LCA approach in a case study of an ICT application, namely, the tablet edition of a Swedish design magazine. The use of tablets has skyrocketed in recent years, and this phenomenon has been little studied to date. Potential environmental impacts of the magazine’s tablet edition were assessed and compared with those of the print edition. The tablet edition’s emerging version (which is marked by a low number of readers and low reading time per copy) resulted in higher potential environmental impacts per reader than did the print edition. However, the mature tablet edition (with a higher number of readers and greater reading time per copy) yielded lower impacts per reader in half the ten impact categories assessed. While previous studies of electronic media have reported that the main life-cycle contributor to environmental impacts is the use phase (which includes operational electricity use as well as the manufacture of the electronic device), the present study did not support those findings in all scenarios studied in this thesis. Rather, this study found that the number of readers played an important role in determining which life-cycle phase had the greatest impacts. For the emerging version, with few readers, content production was the leading driver of environmental impacts. For the mature version, with a higher number of readers, electronic storage and distribution were the major contributors to environmental impacts. Only when there were many readers but low overall use of the tablet device was the use phase the main contributor to environmental impacts of the tablet edition of the magazine. The third study goes beyond direct effects at product- and service-level LCAs, revisiting an SD simulation study originally conducted in 2002 to model indirect environmental effects of ICT in 15 European countries for the period 2000-2020. In the current study, three scenarios of the 2002 study were validated in light of new empirical data from the period 2000–2012. A new scenario was developed to revisit the quantitative and qualitative results of the original study. The results showed, inter alia, that ICT has a stimulating influence on total passenger transport, for it makes it more cost- and time-efficient (rebound effects). The modeling mechanism used to represent this rebound effect is further investigated in the fourth study, which discusses the feedback loops used to model two types of rebound effects in passenger transport (direct economic rebound and time rebound). Finally, the role of systems thinking and modeling in conceptualizing and communicating the dynamics of rebound effects is examined. The aim of the fifth study was to explore the power of systems modeling and simulation to represent nonlinearities of the complex and dynamic systems examined elsewhere in this thesis. That study reviews previous studies that have compared the SD and AB approaches and models, summarizing their purpose, methodology, and results, based on certain criteria for choosing between SD and AB approaches. The transformation procedure used to develop an AB model for purposes of comparison with an SD model is also explored. In conclusion, first-order or direct environmental effects of ICT production, use, and disposal can be assessed employing an LCA method. This method can also be used to assess second-order or enabling effects by comparing ICT applications with conventional alternatives. However, the assessment of enabling effects can benefit from systems modeling methods, which are able to formally describe the drivers of change, as well as the dynamics of complex social, technical, and environmental systems associated with ICT applications. Such systems methods can also be used to model third-order or rebound effects of efficiency improvements by ICT. / Den ökande produktionen och konsumtionen av produkter och tjänster inom informations- och kommunikationsteknik (IKT) leder till en ökning av den globala elanvändningen samt direkta miljökonsekvenser kopplade till IKT. Men IKT har även indirekta miljömässiga effekter. Dessa kan vara positiva till exempel genom substitutions- och optimeringseffekter eller negativa genom att till exempel ge upphov till ytterligare efterfrågan på grund av effektivisering (så kallade reboundeffekter). Olika metoder kan användas för att modellera och bedöma både direkta och indirekta effekter av IKT. Syftet med denna avhandling är att undersöka metoder för modellering samt att studera miljöeffekter av IKT och elektronisk media med hjälp av livscykelanalys (LCA) och även modellering av komplexa och dynamiska system, samt simuleringsteknik, så som System Dynamics (SD) och agentbaserad (AB) modellering. Avhandlingen omfattar fem artiklar (artikel I-V). Artikel I &amp; II beskriver resultaten från en fallstudie där miljöeffekter kopplade till en svensk tidskrift studeras med LCA. Tidskriftens version för surfplatta samt motsvarande tryckta version studeras och jämförs. Artikel III går ett steg vidare från produktnivåns LCA. Artikeln återkopplar till en SD simuleringsstudie som ursprungligen genomfördes under 2002. Simuleringsstudien gällde framtida miljöeffekter av IKT i 15 europeiska länder med tidspespektivet 2000-2020. I artikeln valideras tre scenarier från simuleringsstudien med hjälp av nya empiriska data från 2000-2012 och ett nytt scenario modelleras. Kvantitativa och kvalitativa resultat från den ursprungliga studien diskuteras. Till exempel visar artikel III att IKT har en stimulerande effekt på den totala persontrafiken genom att göra den mer kostnads- och tidseffektiv (reboundeffekt). Modelleringsmekanismen som används för att representera denna reboundeffekt diskuteras vidare i artikel IV. Artikeln belyser och diskuterar den återkopplingsslinga (feedback-loop) som används för att modellera två typer av reboundeffekter kopplade till persontrafik (direkt ekonomisk rebound och tidsrelaterad rebound) samt jämför med en tidigare studie. Artikel IV behandlar också den roll systemtänkande och modellering kan spela i konceptualisering och kommunikation av reboundeffekters dynamik. För att ytterligare undersöka systemmodelleringens och simuleringens möjligheter att representera icke-linjära komplexa och dynamiska system (exempel på sådana diskuteras i artikel III och IV), sammanställer artikel V tidigare studier som jämför SD och AB-metoder och -modeller.  Studiernas mål och metod summeras och resultaten med avseende på vilka kriterier som presenteras för att välja mellan SD och AB sammanställs. Även processen för att omvandla en befintlig SD-modell till en AB-modell beskrivs. Avhandlingens slutsats är att LCA och systemmodelleringsmetoder kan vara användbara för att studera IKTs direkta effekter så väl som indirekta effekter på miljön. / <p>QC 20150813</p>

En raison de la demande croissante d’énergie dans le monde et des nombreux dommages causés par l’utilisation des énergies fossiles, la contribution des énergies renouvelables a augmenté de manière significative dans le mix énergétique global dans le but de progresser vers un développement plus durable. Dans ce contexte, ce travail vise à l’élaboration d’une méthodologie générale pour la conception de systèmes photovoltaïques, basée sur les principes d’écoconception, en tenant compte simultanément des considérations technico-économiques et environnementales. Afin d’évaluer la performance environnementale des systèmes PV, une technique d’évaluation environnementale basée sur l’Analyse du Cycle de Vie (ACV) a été utilisée. Le modèle environnemental a été couplé d’une manière satisfaisante avec le modèle de conception d’un système PV connecté au réseau pour obtenir un modèle global, apte à un traitement par optimisation. Le modèle de conception du système PV résultant a été développé en faisant intervenir l’estimation du rayonnement solaire reçu dans une zone géographique concernée, le calcul de la quantité annuelle d’énergie produite à partir du rayonnement solaire reçu, les caractéristiques des différents composants et l’évaluation des critères technico-économiques à travers le temps de retour énergétique et le temps de retour sur investissement. Le modèle a ensuite été intégré dans une boucle d’optimisation multi-objectif externe basée sur une variante de l’algorithme génétique NSGA-II. Un ensemble de solutions du Pareto a été généré représentant le compromis optimal entre les différents objectifs considérés dans l’analyse. Une méthode basée sur une Analyse en Composantes Principales (ACP) est appliquée pour détecter et enlever les objectifs redondants de l’analyse sans perturber les caractéristiques principales de l’espace des solutions. Enfin, un outil d’aide à la décision basé sur M- TOPSIS a été utilisé pour sélectionner l’option qui offre un meilleur compromis entre toutes les fonctions objectifs considérées et étudiées. Bien que les modules photovoltaïques à base de silicium cristallin (c-Si) ont une meilleure performance vis-à-vis de la production d’énergie, les résultats ont montré que leur impact environnement est le plus élevé des filières technologiques de production de panneaux. Les technologies en « couches minces » présentent quant à elles le meilleur compromis dans tous les scénarios étudiés. Une attention particulière a été accordée aux processus de recyclage des modules PV, en dépit du peu d’informations disponibles pour toutes les technologies évaluées. La cause majeure de ce manque d’information est la durée de vie relativement élevée des modules photovoltaïques. Les données relatives aux procédés de recyclage pour les technologies basées sur CdTe et m-Si sont introduites dans la procédure d’optimisation par l’écoconception. En tenant compte de la production d’énergie et du temps de retour sur énergie comme critères d’optimisation, l’avantage de la gestion de fin de vie des modules PV a été confirmé. Une étude économique de la stratégie de recyclage doit être considérée et étudiée afin d’avoir une vision plus globale pour la prise de décision. / Because of the increasing demand for the provision of energy worldwide and the numerous damages caused by a major use of fossil sources, the contribution of renewable energies has been increasing significantly in the global energy mix with the aim at moving towards a more sustainable development. In this context, this work aims at the development of a general methodology for designing PV systems based on ecodesign principles and taking into account simultaneously both techno-economic and environmental considerations. In order to evaluate the environmental performance of PV systems, an environmental assessment technique was used based on Life Cycle Assessment (LCA). The environmental model was successfully coupled with the design stage model of a PV grid-connected system (PVGCS). The PVGCS design model was then developed involving the estimation of solar radiation received in a specific geographic location, the calculation of the annual energy generated from the solar radiation received, the characteristics of the different components and the evaluation of the techno-economic criteria through Energy PayBack Time (EPBT) and PayBack Time (PBT). The performance model was then embedded in an outer multi-objective genetic algorithm optimization loop based on a variant of NSGA-II. A set of Pareto solutions was generated representing the optimal trade-off between the objectives considered in the analysis. A multi-variable statistical method (i.e., Principal Componet Analysis, PCA) was then applied to detect and omit redundant objectives that could be left out of the analysis without disturbing the main features of the solution space. Finally, a decision-making tool based on M-TOPSIS was used to select the alternative that provided a better compromise among all the objective functions that have been investigated. The results showed that while the PV modules based on c-Si have a better performance in energy generation, the environmental aspect is what makes them fall to the last positions. TF PV modules present the best trade-off in all scenarios under consideration. A special attention was paid to recycling process of PV module even if there is not yet enough information currently available for all the technologies evaluated. The main cause of this lack of information is the lifetime of PV modules. The data relative to the recycling processes for m-Si and CdTe PV technologies were introduced in the optimization procedure for ecodesign. By considering energy production and EPBT as optimization criteria into a bi-objective optimization cases, the importance of the benefits of PV modules end-of-life management was confirmed. An economic study of the recycling strategy must be investigated in order to have a more comprehensive view for decision making.

L’objectif de ce travail est de développer un cadre méthodologique et générique d’éco-conception de procédés chimiques couplant des outils de modélisation et de simulation traditionnels de procédés (HYSYS, COCO, ProSimPlus et Ariane), d’Analyse du Cycle de Vie (ACV), d’optimisation multiobjectif basée sur des Algorithmes Génétiques et enfin des outils d’aide à la décision multicritère (ELECTRE, PROMETHEE, M-TOPSIS). Il s’agit de généraliser, d’automatiser et d’optimiser l’évaluation des impacts environnementaux au stade préliminaire de la conception d’un procédé chimique. L’approche comprend trois étapes principales. Les deux premières correspondent d’une part aux phases d’analyse de l’inventaire par calcul des bilans de matière et d’énergie et d’autre part à l’évaluation environnementale par ACV. Le problème du manque d’information ou de l’imprécision dans les bases de données classiques en ACV pour la production d’énergie notamment sous forme de vapeur largement utilisée dans les procédés a reçu une attention particulière. Une solution proposée consiste à utiliser un simulateur de procédés de production d’utilités (Ariane, ProSim SA) pour contribuer à alimenter la base de données environnementale en tenant compte de variations sur les conditions opératoires ou sur les technologies utilisées. Des sous-modules « énergie » sont ainsi proposés pour calculer les émissions relatives aux impacts liés à l’utilisation de l’énergie dans les procédés. La troisième étape réalise l’interaction entre les deux premières phases et l’optimisation multi-objectif qui met en jeu des critères économiques et environnementaux. Elle conduit à des solutions de compromis le long du front de Pareto à partir desquelles les meilleures sont choisies à l’aide de méthodes d’aide à la décision. L’approche est appliquée à des procédés de production continus : production de benzène par hydrodéalkylation du toluène HDA et production de biodiesel à partir d’huiles végétales. Une stratégie à plusieurs niveaux est mise en oeuvre pour l'analyse de l'optimisation multi-objectif. Elle est utilisée dans les deux cas d'étude afin d'analyser les comportements antagonistes des critères. / The objective of this work is to propose an integrated and generic framework for eco-design coupling traditional modelling and flowsheeting simulation tools (HYSYS, COCO, ProSimPlus and Ariane), Life Cycle Assessment, multi-objective optimization based on Genetic Algorithms and multiple criteria decision-making methods MCDM (Multiple Choice Decision Making, such as ELECTRE, PROMETHEE, M-TOPSIS) that generalizes, automates and optimizes the evaluation of the environmental criteria at earlier design stage. The approach consists of three main stages. The first two steps correspond respectively to process inventory analysis based on mass and energy balances and impact assessment phases of LCA methodology. Specific attention is paid to the main issues that can be encountered with database and impact assessment i.e. incomplete or missing information, or approximate information that does not match exactly the real situation that may introduce a bias in the environmental impact estimation. A process simulation tool dedicated to production utilities, Ariane, ProSim SA is used to fill environmental database gap, by the design of specific energy sub modules, so that the life cycle energy related emissions for any given process can be computed. The third stage of the methodology is based on the interaction of the previous steps with process simulation for environmental impact assessment and cost estimation through a computational framework. The use of multi-objective optimization methods generally leads to a set of efficient solutions, the so-called Pareto front. The next step consists in identifying the best ones through MCDM methods. The approach is applied to two processes operating in continuous mode. The capabilities of the methodology are highlighted through these case studies (benzene production by HDA process and biodiesel production from vegetable oils). A multi-level assessment for multi-objective optimization is implemented for both cases, the explored pathways depending on the analysis and antagonist behaviour of the criteria.

Cette thèse de doctorat, a consisté, dans une première partie, à introduire d’une part, la notion de l’analyse du cycle de vie « ACV » et celle des biocarburants. D’autre part, à présenter l’intérêt d’appliquer une ACV sur des biocarburants afin de valoriser leurs bilans énergétiques et analyser leurs impacts environnementaux face aux carburants conventionnels. Dans une deuxième partie, nous avons comparé, d’un point de vue énergétique et environnemental, 3 scénarios de production d’électricité : 2 scénarios de cogénération (turbine à vapeur et ORC) pour la production d’énergie électrique et thermique à partir de biomasse, et un scénario de cogénération par moteur diesel. Ces scénarios sont comparés à l’aide de deux méthodes orientées « analyse des dommages »: Eco-indicateur 99 (E) et IMPACT2002+Dans une troisième partie, on a abordé la valorisation du biogaz sous forme de carburant dans des moteurs "dual fuel" pour des engins agricoles dans le but de déterminer l’impact environnemental lié à l’utilisation de ce carburant alternatif au diesel par rapport aux autres biocarburants. Les méthodes Eco-indicateur 99 (E) et CML ont été utilisées ici. On a pu ainsi identifier les principaux polluants générés à chaque étape du cycle de vie de l’agrocarburant et les étapes qui ont les plus grands impacts environnementaux et on a identifié, selon nos critères et par rapport au contexte, le scénario énergétique le plus compatible avec le principe de développement durable. / This thesis has consisted in a first part to introduce, on one hand, the concept of each of: lifecycle assessment "LCA" and biofuels, on the other hand, to present the benefits of applying aLCA on biofuels to evaluate their energy balances and to analyze their environmental impactsagainst conventional fuels.In a second part, we compared, from point of view energetic and environmental, 3 scenariosof electricity production: 2 scenarios of cogeneration (steam turbine and ORC) for theproduction of electrical energy and of heat from biomass, and a scenario of cogeneration by adiesel engine, these scenarios have been compared using two damage-oriented analysismethods: Eco-indicator 99 (E) and IMPACT2002 +In a third part, we worked on the evaluation of methane as fuel in "dual fuel" engines foragricultural purpose, the aim was to determine the environmental impact associated with theuse of this alternative fuel for diesel compared to other biofuels. Methods Eco-indicator 99(E) and CML have been used here.We were able to identify the main pollutants generated at each stage of the life cycle ofbiofuel and the steps that have the greatest environmental impacts, and to identify, accordingto our criteria and to the context the energy scenario the most consistent with the principle ofsustainable development.