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An immersed boundary method for particles and bubbles in magnetohydrodynamic flowsSchwarz, Stephan 03 July 2014 (has links) (PDF)
This thesis presents a numerical method for the phase-resolving simulation of rigid particles and deformable bubbles in viscous, magnetohydrodynamic flows. The presented approach features solid robustness and high numerical efficiency. The implementation is three-dimensional and fully parallel suiting the needs of modern high-performance computing.
In addition to the steps towards magnetohydrodynamics, the thesis covers method development with respect to the immersed boundary method which can be summarized in simple words by From rigid spherical particles to deformable bubbles. The development comprises the extension of an existing immersed boundary method to non-spherical particles and very low particle-to-fluid density ratios. A detailed study is dedicated to the complex interaction of particle shape, wake and particle dynamics.
Furthermore, the representation of deformable bubble shapes, i.e. the coupling of the bubble shape to the fluid loads, is accounted for. The topic of bubble interaction is surveyed including bubble collision and coalescence and a new coalescence model is introduced.
The thesis contains applications of the method to simulations of the rise of a single bubble and a bubble chain in liquid metal with and without magnetic field highlighting the major effects of the field on the bubble dynamics and the flow field. The effect of bubble coalescence is quantified for two closely adjacent bubble chains.
A framework for large-scale simulations with many bubbles is provided to study complex multiphase phenomena like bubble-turbulence interaction in an efficient manner.
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Flow-directed solution self-assembly of block copolymers in microfluidic devicesWang, Chih-Wei 07 May 2012 (has links)
The self-assembly of polystyrene-stabilized cadmium sulfide nanoparticles (PS-CdS) with amphiphilic stabilizing chains of polystyrene-block-poly(acrylic acid) (PS-b-PAA) into colloidal quantum dot compound micelles (QDCMs) is studied on two-phase gas-liquid segmented microfluidic reactors. The resulting particle sizes are found to arise from the interplay of shear-induced coalescence and particle breakup, depending on a combination of chemical and flow conditions. Variation of water content, gas-to-liquid ratio, and total flow rate, enable control of QDCM sizes in the range of 140 – 40 nm.
The flow-variable shear effect on similar microfluidic reactors is then applied to direct the solution self-assembly of a PS-b-PAA block copolymer into various micelle morphologies. The difference between off-chip and on-chip morphologies under identical chemical conditions is explained by a mechanism of shear-induced coalescence enabled by strong and localized on-chip shear fields, followed by intraparticle chain rearrangements to minimize local free energies. Time-dependent studies of these nanostructures reveal that on-chip kinetic structures will relax to global equilibrium given sufficient time off-chip. Further investigations into the effect of chemical variables on on-chip shear-induced morphologies reveal a combination of thermodynamic and kinetic effects, opening avenues for morphology control via combined chemical (bottom-up) and shear (top-down) forces. An equilibrium phase diagram of off-chip micelle morphologies is constructed and used in conjunction with kinetic considerations to rationalize on-chip mechanisms and morphologies, including cylinders and vesicles, under different chemical conditions.
Finally, we extend our strategy of two-phase microfluidic self-assembly of PS-b-PAA to the loading of fluorescent hydrophobic probes (pyrene and naphthalene) with different affinities for the PS core. The on-chip loading approach provides a fast alternate to the slow off-chip method, with implications for the potential development for point-of-care devices for drug loading. On-chip loading results indicate that loading efficiencies are dependent on water content and, to a lesser extent, on flow rate; the results also suggest that the on-chip morphologies of the PS-b-PAA micelles are an important factor in the loading efficiencies. / Graduate
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Dynamics of Surfactants at Soft Interfaces using Droplet-Based MicrofluidicsRiechers, Birte 21 December 2015 (has links)
No description available.
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[en] MODELLING OF STEP-PATH TYPE FAILURE MECHANISMS IN FRACTURED ROCK SLOPE USING DISCRETE ELEMENTS / [pt] MODELAGEM DO MECANISMO DE RUPTURA TIPO STEP-PATH EM TALUDES ROCHOSOS FRATURADOS ATRAVÉS DO MÉTODO DOS ELEMENTOS DISCRETOSLUIS ARNALDO MEJIA CAMONES 26 February 2018 (has links)
[pt] Diferentes mecanismos de ruptura são considerados no momento de avaliar a estabilidade de um maciço rochoso fraturado. Entre estes, os mecanismos de ruptura tipo planar, em cunha e tombamentos têm sido
estudados intensivamente, existindo atualmente modelos matemáticos que permitem avaliá-los. Estes mecanismos de ruptura são restritos a taludes pequenos e com fraturas contínuas, nas quais o deslizamento ocorre ao longo destas descontinuidades. Em casos de taludes de grande altura ou
quando a persistência das fraturas é pequena em relação à escala do talude, o fraturamento torna-se descontínuo. Neste caso, o mecanismo de ruptura mais provável é o tipo Step-Path, o qual, a superfície de ruptura é formada por fraturas que se propagam através da rocha intacta juntando-se entre elas. Este fenômeno de união de fraturas é chamado de coalescência. Análises de estabilidade, como os probabilísticos ou por equilíbrio limite, são usados atualmente para avaliar estes tipos de rupturas, não se tendo ainda o desenvolvimento de um modelo numérico que possa representá-lo e reforçar estas teorias. O presente trabalho avalia o uso do Método dos Elementos Discretos na modelagem do mecanismo de ruptura tipo step- path, realizando uma análise de estabilidade que permita comparar os seus resultados com o método de equilíbrio limite. Foi utilizado o programa PFC nas versões 2D e 3D, assim como o programa FracGen para a geração de fraturas tridimensionais. A análise tridimensional foi feita mediante um acoplamento PFC3D-FracGen. A pesquisa inclui a análise e modelagem dos fenômenos de coalescência em amostras, assim como a influência da anisotropia na resistência das rochas em ensaios triaxiais. / [en] Different failure mechanisms are considered when a fracturated rock mass is valued. Some of them are being subject of accurate study, like planar failure mechanism, wedges and toppling, which are currently valued by mathematical models. These failure mechanisms are restricted to small slopes and with continue fractures, where the sliding occurs along these discontinuities. To height slopes or when the fracture persistence is smaller than the slope scale, the fracturing becomes discontinuous. In this case, the
most probable failure mechanism to happen is the step-path type, in which the failure surface is composed by fractures that propagate through the intact rock and that are joined together. This phenomenon of fracture union is known as coalescence. Stability analysis, like probability analysis or limit equilibrium analysis are currently utilized to evaluate this kind of failures, but its important to develop a numerical model to represent and reinforce these theories. This work aims to evaluate the use of Discrete Element Method to model step-path failure mechanism on a stability analysis and to compare the results with limit equilibrium method. The program used to simulate the slope is PFC (2D and 3D) and the program FracGen was used to generate three-dimensional fractures. Three-dimensional analysis was done by a coupling between PFC3D and FracGen. The research includes the analysis and modeling of coalescence phenomenon on rock samples, as well as the analysis of the anisotropy influence on rock strength obtained
from triaxial tests.
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Frittage photonique de lignes imprimées à base de nanoparticules : optimisation des propriétés électriques et mécaniques pour l’interconnexion de circuits intégrés sur substrats flexibles. / Photonic sintering of nanoparticles based printed tracks : optimization of electrical and mechanical properties for the interconnection of integrated circuits on flexible substrates.Baudino, Olivier 26 November 2015 (has links)
Le recuit photonique est une technologie émergente basée sur la conversion instantanée del’énergie lumineuse absorbée par les nanoparticules (NPs) en chaleur. Dans ces travaux, il estdéployé sur des pistes d’interconnexions imprimées sur support souple par jet de matière, àpartir d’une encre de NPs d’argent (Ø=25nm).Une étude des paramètres du procédé a permis d’établir le lien entre ces derniers (énergie,fréquence) et la résistance carrée (120m!/ ) induite. Celui-ci a été confirmé grâce à unemodélisation thermique multicouches et au développement d’une instrumentation inéditemesurant, toutes les 4μs, les variations de la résistance pendant le recuit photonique (quelquesms). La stabilisation de la résistance corrélée avec les propriétés optiques du film est optimalepour une exposition de 2-3J/cm² induisant un échauffement à environ 200°C.L’analyse de la microstructure des films par diffraction des rayons X met en évidence le lienentre la croissance des cristallites et la résorption des défauts. La minimisation de la résistanceélectrique est corrélée à la croissance du collet entre les nanoparticules par diffusion atomiquede surface. De plus, une meilleure cohésion des NPs améliore la dureté par rapport au recuit àl’étuve.La résistance électrique de contact (200m!) entre les plots d’interconnexion d’une puce ensilicium et les pistes imprimées a été mesurée grâce à un montage dédié de mesure électriqueau nano-indendeur. Les forces à appliquer (300mN par bump) / Photonic sintering is an emerging technology based on the instantaneous conversion ofabsorbed light energy by nanoparticles (NPs) into heat. In this work, it is used oninterconnections printed on flexible substrates by inkjet printing of a metal silver nanoinkwith particle mean diameter of Ø=25nm.A process parameters study has allowed us to link them (energy, frequency) with theinduced sheet resistance (120m!/ ). This has been confirmed through thermal modeling ofthe multilayer system, and also by monitoring the resistance variations in-situ duringphotonic sintering (a few ms) using an innovative characterization tool, allowingmeasurements every 4 μs. The electrical resistance stabilization correlated with the opticalproperties of the film was found to be optimal for an exposition of 2-3J/cm², whichcorresponds to heating up to approximately 200°C.Films microstructure analysis with X-ray diffraction enlightens the link between crystallitescoarsening and defaults density reduction. The minimization of electrical resistivity iscorrelated with neck growth between nanoparticles trigged by surface atomic diffusion.Moreover, a stronger cohesion between NPs improves the mechanical hardness compared toclassical oven curing.The electrical contact resistance (200m!) between a silicon chip interconnection bumpand printed tracks is measured thanks to an in-house setting for electrical measurement withthe nanoindenter. The level of forces to apply (300mN per bump) is optimized and transferredto a thermocompression by industrial equipment. A set of prototypes are fabricated andconfirm the compatibility of these technologies with a future industrial integration.
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Model development for simulating bubble coalescence in disperse bubbly flows with the Euler-Lagrange approachYang, Xinghao 09 November 2021 (has links)
This thesis presents the investigation of an Euler-Lagrange framework for modeling bubble coalescence in dispersed bubbly flows. The interaction between bubbles may be caused by several mechanisms. Among them, the random motion due to turbulent fluctuations is normally of major significance. One focus of this work is to apply a bubble dispersion model for modeling turbulence-induced coalescence, occurring in a certain percentage of collision events. Large bubbles appear due to coalescence, and their disturbance to the liquid phase is not negligible in most circumstances. However, the point-mass Euler-Lagrange method requires the bubble or particle size to be much smaller than the cell size when the interphase coupling is considered. Otherwise, numerical instabilities may arise. Therefore, interpolation methods between the Euler and the Lagrange phase for finite-size bubbles that are bigger than or of the same size as numerical cells are studied.
The Euler-Lagrange method describes the continuous phase on the Euler grid, and the dispersed phase is treated as Lagrange points in the simulation. Bubble motion is governed by an ordinary differential equation for the linear momentum considering different forces. The turbulent dispersion of the dispersed phase is reconstructed with the continuous random walk (CRW) model. Bubble-bubble collisions and coalescence are accounted for deterministically. The time-consuming search for potential collision partners in dense bubbly flows is accelerated by the sweep and prune algorithm, which can be utilized in arbitrary mesh types and sizes. If the interphase coupling is considered in the simulations, the spatially distributed coupling method is used for the Lagrange-to-Euler coupling. For the Euler-to-Lagrange coupling, a new approach is proposed.
To evaluate the dispersion and coalescence models, one-way coupled simulations of bubbly pipe flows at low Eötvös numbers are conducted. Validation against the experiments demonstrates that the one-way coupled EL-CRW dispersion model can well reproduce the bubble distribution in a typical dense bubbly pipe flow. Good agreement of the bubble size distribution at the pipe outlet between the simulation and the experiment is obtained.
Two-way coupled simulations are performed to validate the interpolation methods. A combination of coupling approaches is employed in a square bubble column reactor to examine the general validity for a large-scale bubbly flow. Combining the proposed interpolation scheme with the dispersion and bubble interaction models, the coalescence and breakage in bubbly flows are studied in a turbulent pipe flow. The predicted bubble size distribution shows a good match to the measurement. The results are independent of the mesh resolution in the studied range from point-mass simulations to finite-size situations.:Nomenclature
1 Introduction
1.1 Motivation and background for the thesis
1.2 Outline
2 Equations for modeling bubbly flows
2.1 Governing equations of the continuous phase
2.2 Governing equations of the dispersed phase
2.3 Modifications to the bubble force equations
2.3.1 One-way coupled simulations with RANS modeling
2.3.2 Two-way coupled simulations
2.4 Generation of fluctuations
2.4.1 Different approaches to dispersion modeling
2.4.2 Normalized continuous random walk model
2.4.3 Employing the mean velocity field to determine forces
3 Bubble collision, coalescence and breakup
3.1 Previous studies and requirement of the interaction modeling
3.2 Detection of collisions with the sweep and prune algorithm
3.3 Coalescence modeling
3.3.1 Condition of bubble coalescence
3.3.2 Model of Kamp et al. [2001]
3.3.3 Model of Hoppe and Breuer [2018]
3.3.4 Model of Schwarz et al. [2013]
3.3.5 Comparison of coalescence models
3.4 Breakup modeling
3.4.1 Turbulence induced breakups
3.4.2 Post-breakup treatment
4 Interpolation techniques for two-way coupled simulations
4.1 Lagrange-to-Euler coupling
4.1.1 Introduction to the spatially distributed coupling
4.1.2 Intersection plane method
4.1.3 Subcell method
4.1.4 Random points method
4.2 Euler-to-Lagrange coupling
4.2.1 Approaches for computing the undisturbed velocity
4.2.2 Coarser grid method
4.2.3 Averaging the fluid velocity in front of the bubble
4.2.4 Velocity from upstream disk
4.2.5 Gradient of the undisturbed liquid velocity
5 One-way coupled simulation of bubble dispersion and resulting interaction
5.1 Implementation and verification of the continuous random walk model
5.2 Bubble dispersion in turbulent channel flows
5.3 Bubble dispersion and interaction in turbulent pipe flows
5.3.1 Overview of studied cases
5.3.2 Results of the bubble dispersion
5.3.3 Results of the bubble coalescence
6 Two-way coupled simulation of finite-size bubbles
6.1 Flow solver and algorithm
6.2 Assessing the Lagrange-to-Euler coupling methods
6.2.1 Previous studies
6.2.2 Simulation setups for a single bubble in quiescent liquid
6.2.3 Results and discussion
6.3 Assessing the Euler-to-Lagrange coupling methods
6.3.1 Simulation of two bubbles rising inline
6.3.2 Simulation of a bubble rising in linear shear flows
6.4 Large-eddy simulation for a square bubble column
6.5 Bubble coalescence in a turbulent pipe flow
7 Conclusions and outlook
Appendices
A.1 Equations of turbulence models
A.2 Numerical implementation of the full CRW drift term
A.3 Results of bubble coalescence modeling for case B to case E
A.4 Search algorithm of the upstream disk method
Bibliography / Diese Arbeit stellt die Untersuchung eines Euler-Lagrange-Rahmens zur Modellierung der Blasenkoaleszenz in dispergierten Blasenströmungen vor. Die Interaktion zwischen Blasen kann durch mehrere Mechanismen verursacht werden. Unter ihnen sind die zufälligen Bewegungen aufgrund von turbulenten Fluktuationen von großer Bedeutung. Ein Schwerpunkt dieser Arbeit ist die Anwendung eines Blasendispersionsmodells zur Modellierung der turbulenzinduzierten Koaleszenz, die in einem bestimmten Prozentsatz der Kollisionsereignisse auftritt. Große Blasen entstehen durch Koaleszenz und ihre Störung der flüssigen Phase ist in den meisten Fällen nicht zu vernachlässigen. Die Punkt-Masse-Euler-Lagrange-Methode erfordert jedoch, dass die Blasengröße viel kleiner als die Zellgröße ist, wenn die Interphasenkopplung berücksichtigt wird. Andernfalls kann es zu numerischen Instabilitäten kommen. Daher werden Interpolationsmethoden zwischen den zwei Phasen untersucht.
Die kontinuierliche Phase wird auf dem Euler-Gitter beschrieben und die dispergierte Phase wird als Punkte behandelt. Die Blasenbewegung wird durch eine gewöhnliche Differentialgleichung unter Berücksichtigung verschiedener Kräfte bestimmt. Die turbulente Dispersion der Blasen wird mit dem CRW-Modell (continuous random walk) rekonstruiert. Blasen-Blasen-Kollisionen werden deterministisch berücksichtigt. Die Suche nach potentiellen Kollisionspartnern wird durch den Sweep- und Prune-Algorithmus beschleunigt, der in beliebigen Gittertypen und -größen eingesetzt werden kann. Wird die Interphasenkopplung berücksichtigt, so wird für die Lagrange-zu-Euler-Kopplung die spatially distributed coupling verwendet. Für die Euler-zu-Lagrange-Kopplung wird ein neuer Ansatz vorgeschlagen.
Um die Dispersions- und Koaleszenzmodelle zu bewerten, werden Einweg-gekoppelte Simulationen von blasenbeladenen Rohrströmungen bei niedriger Eötvös-Zahl durchgeführt. Die Validierung zeigt, dass das einseitig gekoppelte EL-CRW-Dispersionsmodell die Blasenverteilung in einer typischen dichten, blasenbeladenen Rohrströmung gut reproduzieren kann. Es wird eine gute Übereinstimmung der Blasengrößenverteilung am Rohrauslass zwischen der Simulation und dem Experiment erzielt.
Zur Validierung der Interpolationsmethoden werden Zweiweg-gekoppelte Simulationen durchgeführt. Eine Kombination von Kopplungsansätzen wird in einem Blasensäulenreaktor eingesetzt, um die allgemeine Gültigkeit zu untersuchen. Durch Kombination des vorgeschlagenen Interpolationsschemas mit den Dispersions- und Blasenwechselwirkungsmodellen werden die Koaleszenz und der Zerfall in einer turbulenten blasenbeladenen Rohrströmung untersucht. Die berechnete Blasengrößenverteilung zeigt eine gute Übereinstimmung mit der Messung und erweist sich als unabhängig von der Netzauflösung im untersuchten Bereich von PunktMasse-Simulationen bis zu Situationen mit Blasen endlicher Größe.:Nomenclature
1 Introduction
1.1 Motivation and background for the thesis
1.2 Outline
2 Equations for modeling bubbly flows
2.1 Governing equations of the continuous phase
2.2 Governing equations of the dispersed phase
2.3 Modifications to the bubble force equations
2.3.1 One-way coupled simulations with RANS modeling
2.3.2 Two-way coupled simulations
2.4 Generation of fluctuations
2.4.1 Different approaches to dispersion modeling
2.4.2 Normalized continuous random walk model
2.4.3 Employing the mean velocity field to determine forces
3 Bubble collision, coalescence and breakup
3.1 Previous studies and requirement of the interaction modeling
3.2 Detection of collisions with the sweep and prune algorithm
3.3 Coalescence modeling
3.3.1 Condition of bubble coalescence
3.3.2 Model of Kamp et al. [2001]
3.3.3 Model of Hoppe and Breuer [2018]
3.3.4 Model of Schwarz et al. [2013]
3.3.5 Comparison of coalescence models
3.4 Breakup modeling
3.4.1 Turbulence induced breakups
3.4.2 Post-breakup treatment
4 Interpolation techniques for two-way coupled simulations
4.1 Lagrange-to-Euler coupling
4.1.1 Introduction to the spatially distributed coupling
4.1.2 Intersection plane method
4.1.3 Subcell method
4.1.4 Random points method
4.2 Euler-to-Lagrange coupling
4.2.1 Approaches for computing the undisturbed velocity
4.2.2 Coarser grid method
4.2.3 Averaging the fluid velocity in front of the bubble
4.2.4 Velocity from upstream disk
4.2.5 Gradient of the undisturbed liquid velocity
5 One-way coupled simulation of bubble dispersion and resulting interaction
5.1 Implementation and verification of the continuous random walk model
5.2 Bubble dispersion in turbulent channel flows
5.3 Bubble dispersion and interaction in turbulent pipe flows
5.3.1 Overview of studied cases
5.3.2 Results of the bubble dispersion
5.3.3 Results of the bubble coalescence
6 Two-way coupled simulation of finite-size bubbles
6.1 Flow solver and algorithm
6.2 Assessing the Lagrange-to-Euler coupling methods
6.2.1 Previous studies
6.2.2 Simulation setups for a single bubble in quiescent liquid
6.2.3 Results and discussion
6.3 Assessing the Euler-to-Lagrange coupling methods
6.3.1 Simulation of two bubbles rising inline
6.3.2 Simulation of a bubble rising in linear shear flows
6.4 Large-eddy simulation for a square bubble column
6.5 Bubble coalescence in a turbulent pipe flow
7 Conclusions and outlook
Appendices
A.1 Equations of turbulence models
A.2 Numerical implementation of the full CRW drift term
A.3 Results of bubble coalescence modeling for case B to case E
A.4 Search algorithm of the upstream disk method
Bibliography
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An immersed boundary method for particles and bubbles in magnetohydrodynamic flowsSchwarz, Stephan 03 July 2014 (has links)
This thesis presents a numerical method for the phase-resolving simulation of rigid particles and deformable bubbles in viscous, magnetohydrodynamic flows. The presented approach features solid robustness and high numerical efficiency. The implementation is three-dimensional and fully parallel suiting the needs of modern high-performance computing.
In addition to the steps towards magnetohydrodynamics, the thesis covers method development with respect to the immersed boundary method which can be summarized in simple words by From rigid spherical particles to deformable bubbles. The development comprises the extension of an existing immersed boundary method to non-spherical particles and very low particle-to-fluid density ratios. A detailed study is dedicated to the complex interaction of particle shape, wake and particle dynamics.
Furthermore, the representation of deformable bubble shapes, i.e. the coupling of the bubble shape to the fluid loads, is accounted for. The topic of bubble interaction is surveyed including bubble collision and coalescence and a new coalescence model is introduced.
The thesis contains applications of the method to simulations of the rise of a single bubble and a bubble chain in liquid metal with and without magnetic field highlighting the major effects of the field on the bubble dynamics and the flow field. The effect of bubble coalescence is quantified for two closely adjacent bubble chains.
A framework for large-scale simulations with many bubbles is provided to study complex multiphase phenomena like bubble-turbulence interaction in an efficient manner.
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Multifunktionsfeldeffekttransistoren zur Strömungs-, Chemo- und Biosensorik in Lab on a Chip-SystemenTruman Sutanto, Pagra 14 December 2007 (has links)
In dieser Arbeit wird eine neue Methode und ein neuartiges FET -Sensorelement zum Nachweis von Flüssigkeitsbewegungen vorgestellt, das zudem bei Bedarf auch als Chemo- oder Biosensor fungieren kann. Das Einsatzspektrum von FET-basierten Sensoren in Lab on a Chip-Systemen wird dadurch entscheidend erweitert. Bei dem entwickelten FET-Sensor Bauelement handelt es sich um einen normally-on n-leitenden Dünnschichtfeldeffekttransistor mit Ti-Au-Kontakten, basierend auf Silicon-on-Insulator- Substraten, wobei das natürliche Oxid des Siliziumfilms als Schnittstelle zum Elektrolyten bzw. zur Flüssigkeit verwendet wird. Der mit 10exp16 Bor Atomen pro cm³ p-dotierte Siliziumdünnfilm hat eine Dicke von nur 55 nm und ist durch eine 95 nm dicke Siliziumdioxidschicht vom darunterliegenden Siliziumsubstrat von 600 µm Dicke elektrisch isoliert. Aufgrund der geringen Schichtdicke durchdringt die feldempfindliche Raumladungs- bzw. Verarmungszone die gesamte Dünnschicht, so dass durch Anlegen einer Backgatespannung am Substrat der spezifische Widerstand und die Empfindlichkeit des Bauelements eingestellt werden können. Grundlegende ISFET-Funktionalitäten wie die Empfindlichkeit auf Änderungen der Ionenstärke und des pH-Wertes werden nachgewiesen und ein ENFET-Glukosesensor realisiert. Zudem wird im Hinblick auf die Separation von Emulsionen der Nachweis erbracht, dass die Benetzung mit Hexan und Toluol eine Änderung der spezifischen Leitfähigkeit bewirkt, und die Empfindlichkeit des Bauelements nach Beschichtung mit einem hydrophoben Methacrylatcopolymerfilm erhalten bleibt. Hinsichtlich der Verwendung des FET-Sensor Bauelements zum Nachweis von Flüssigkeitsbewegungen wird zunächst ein theoretisches Modell entwickelt, dessen Kernaussage ist, dass sich in einem rechteckigen Kanal der relative Bedeckungsgrad mit Flüssigkeit direkt proportional zum Drainstrom des FET-Sensors verhält. Basierend auf diesem theoretischen Modell, welches experimentell belegt wird, können mittels eines einzelnen FET-Sensors Füllstand und Füllgeschwindigkeit bzw. bei bekannter Füllgeschwindigkeit Kapillarvolumen und Kapillargeometrie bestimmt werden. Abweichungen von der direkten Proportionalität erlauben zudem, Rückschlüsse auf die Benetzungseigenschaften der Kapillaren und die Dynamik an der Halbleitergrenzfläche zu ziehen. Ist ein Sensorelement vollständig mit Flüssigkeit bedeckt, wird mittels Lösungsmitteltropfen als Markerobjekten die Strömungsgeschwindigkeit bestimmt. Ändert sich die Ionenkonzentration im Elektrolyten als Funktion der Strömungsgeschwindigkeit, so kann die Strömungsgeschwindigkeit durch Messung der Ionenkonzentration mittels FET-Sensor ebenfalls ermittelt werden. Als wichtigster Demonstrator für die Verwendung des FET-Sensors wird ein komplexes Lab on a Chip-System zur Separation von Emulsionen auf chemisch strukturierten Oberflächen entwickelt, bei dem der Separationsvorgang mittels FET-Sensorarray verfolgt werden kann. Zur einfachen Herstellung chemisch modifizierter Oberflächen für die Separationsexperimente werden die Abscheidung von nanoskaligen hydrophoben Methacrylatcopolymerfilmen und die selektive Fluorsilanisierung von Oberflächen sowie deren Lösungsmittelbeständigkeit in Wasser, Toluol und Aceton untersucht. Dabei zeigt sich, dass die Hydrophobie nach Lösungsmittelbehandlung weitestgehend erhalten bleibt, Wasserrückstände im Methacrylatfilm aber zu einer reversiblen Schichtdegradation führen können. Als Modellsystem werden Hexan-Wasser- bzw. Toluol-Wasser-Emulsionen verwendet, die auf Oberflächen getrennt werden, deren eine Seite hydrophil, und deren andere Seite hydrophob ist (Stufengradient). Der Separationsprozess beruht auf der großen Affinität des Wassers hin zu polaren Oberflächen, wobei das wenig selektive Lösungsmittel zur unpolaren Seite gedrängt wird. Zur Erlangung eines tieferen Verständnisses des Prozesses werden die Tropfenkoaleszenz und der Einfluss geometrischer Beschränkungen untersucht. Die Versuche werden sowohl auf offenen Oberflächen als auch im Spalt, unter Verwendung von hydrophilen und hydrophoben Oberflächen, durchgeführt. Es zeigt sich, dass sich die Dynamik der Tropfenkoaleszenz im Spalt umgekehrt zur Dynamik auf offenen Oberflächen verhält. Dies wird mittels eines hierzu entwickelten theoretischen Modells erklärt, welches die Minimierung der Oberflächenenergie und Hystereseeffekte einbezieht. Das Lab on a Chip-System schließlich besteht aus einem mit Siliziumnitrid beschichteten FET-Sensorchip, auf den eine Separationszelle aufgeklebt ist. Neben dem Einlass für die Emulsion ist ein weiterer Einlass vorhanden, durch den Salzsäure für eine pH-Reaktion zugegeben werden kann. Der gesamte Separationsprozess sowie die anschließende pH-Reaktion, lassen sich bequem am PC anhand der Änderung der Stromstärke der einzelnen Sensoren verfolgen und analysieren. Wichtige Ergebnisse hier sind: 1) Mittels eines quasi 1-dimensionalen Sensorarrays kann der Verlauf einer Flüssigkeitsfront in einem 2-dimensionalen Areal überwacht bzw. dargestellt werden. 2) Anhand der Signatur des Signalverlaufs bei pH-Änderung und Flüssigkeitsbewegung, können beide Prozesse unterschieden werden. Der Sensor kann also zum Nachweis von Flüssigkeitsbewegungen und zugleich als Chemosensor eingesetzt werden. Es wurde also nicht nur ein neuartiges, äußerst robustes, chemikalienbeständiges und biokompatibles Multifunktionssensorelement mit Abmessungen im Mikrometer- bis Millimeterbereich entwickelt, sondern auch eine neue Methode entwickelt, mit der es möglich ist, sowohl (bio-)chemische Reaktionen als auch die Bewegung von Flüssigkeiten in Lab on a Chip-Systemen nachzuweisen.
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Fundamental investigation to improve the quality of cold mix asphaltKhan, Abdullah January 2016 (has links)
Cold mix asphalt (CMA) emulsion technology could become an attractive option for the road industry as it offers lower startup and equipment installation costs, energy consumption and environmental impact than traditional alternatives. The adhesion between bitumen and aggregates is influenced by diverse parameters, such as changes in surface free energies of the binder and aggregates or the presence of moisture or dust on the surface of aggregates, mixing temperatures, surface textures (including open porosity), nature of the minerals present and their surface chemical composition, as well as additives in the binder phase. The performance of cold asphalt mixtures is strongly influenced by the wetting of bitumen on surfaces of the aggregates, which is governed by breaking and coalescence processes in bitumen emulsions. Better understanding of these processes is required. Thus, in the work this thesis is based upon, the surface free energies of both minerals/aggregates and binders were characterized using two approaches, based on contact angles and vapor sorption methods. The precise specific surface areas of four kinds of aggregates and seven minerals were determined using an approach based on BET (Brunauer, Emmett and Teller) theory, by measuring the physical adsorption of selected gas vapors on their surfaces and calculating the amount of adsorbed vapors corresponding to monolayer occupancy on the surfaces. Interfacial bond strengths between bitumen and aggregates were calculated based on measured surface free energy components of minerals/aggregates and binders, in both dry and wet conditions. In addition, a new experimental method has been developed to study bitumen coalescence by monitoring the shape relaxation of bitumen droplets in an emulsion environment. Using this method, the coalescence of spherical droplets of different bitumen grades has been correlated with neck growth, densification and changes in surface area during the coalescence process. The test protocol was designed to study the coalescence process in varied environmental conditions provided by a climate-controlled chamber. Presented results show that temperature and other variables influence kinetics of the relaxation process. They also show that the developed test procedure is repeatable and suitable for studying larger-scale coalescence processes. However, possible differences in measured parametric relationships between the bitumen emulsion scale and larger scales require further investigation. There are several different research directions that can be explored for the continuation of the research presented in this thesis. For instance, the rationale of the developed method for analyzing coalescence processes in bitumen emulsions rests on the assumption that the results are applicable to large-scale processes, which requires validation. A linear relationship between the scales is not essential, but it is important to be able to determine the scaling function. Even more importantly, qualitative effects of the investigated parameters require further confirmation. To overcome the laboratory limitations and assist in the determination of appropriate scaling functions further research could focus on the development of a three-dimensional multiphase model to study coalescence processes in more detail, including effects of surfactants, pH and other additives such as mineral fillers and salts. Additionally, better understanding of the breaking process and water-push out could help significantly to optimize CMA mix design. Different methods, both numerical and experimental could be explored for this. / Cold mix asphalt (CMA) eller kall asfaltbetong med hjälp av emulsionsteknik kan vara ett attraktivt alternativ för vägbyggnadsindustrin då det möjliggör lägre uppstart- och investeringskostnader, lägre energiförbrukning och mindre miljöpåverkan än traditionella alternativ. Adhesionen mellan bindemedel och stenpartiklarna påverkas av ett flertal parametrar, så som förändring i fri ytenergi hos både bindemedel och partiklar i närvaro av fukt eller damm på stenytorna, blandningstemperatur, yttextur (inklusive ytporositet), mineralegenskaper och ytornas kemiska sammansättning lika väl som tillsatsmedel i bindemedlen. Beteendet hos kall asfaltbetong är starkt påverkad av vätningsegenskaperna hos bindemedlet när det kommer i kontakt med stenmaterialet och detta i sin tur är beroende på bitumenemulsionens brytegenskaper och förmåga att blandas. Bättre förståelse av dessa processer är av största vikt. I detta arbete är avhandlingen baserad på fri ytenergi hos både mineraler/aggregat och bindemedel, baserat på kontaktvinkel och på ångabsorptionsmetoder. Den exakta specifika ytan hos fyra typer av aggregat och sju mineraler undersöktes med en metod baserad på BET (Brunauer, Emmett och Teller):s teorier genom att mäta den fysiska adsorptionen av utvalda gaser på ytorna och beräkna mängden adsorberad ånga som korresponderade mot ytlagret. Styrkan hos kontaktytornas bindning mellan bindemedlet och stenaggregaten beräknades baserat på mätningar av den fria ytenergin hos bägge ingående komponenterna, dels i torrhet dels i våta omgivningar. Som tillägg har en ny experimentell metod utvecklats för att studera bitumens blandbarhet genom att studera bitumendroppars relaxation i en emulsionsmiljö. Genom att använda denna metod har korelationen mellan sväriska droppar av bitumen undersökts mot förändringen i ytans area under blandningsprocessen. Testprotokollet utformades för att studera blandningsprocessen i varierande miljöer i en klimatkammare. Presenterade resultat visar att temperatur och andra variabler påverkar de kinetiska förhållandena vid relaxationsprocessen. De visar även att den utvecklade testmetoden är repeterbar och passar för studier av storskaliga blandningsprocesser. Det bör dock påpekas att vidare studier krävs för att påvisa skillnaderna mellan bitumenemulsionsskalan och större skalor. Framtida forskning kommer att koncentreras på utveckling av tredimensionella multifasmodeller för att studera blandningsförlopp på en mer detaljerad nivå, inkluderande effekter på ytaktiva ämnen, pH-värden och andra additativ så som mineralfiller och salt. Som tillägg kommer nyttan av nya karaktäriseringsmetoder att utvärderas, så som lågvikelspridning av neutroner eller kombinationer av röntgen, neutronradiologi och datortomografi, för att studera brytmekanismer hos bitumenemulsioner vid kontakt med mineraler och aggregat. / <p>QC 20160901</p>
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Mixed Hydrophilic/Hydrophobic Fiber Media for Liquid-Liquid CoalescenceKulkarni, Prashant S. 01 August 2011 (has links)
No description available.
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