1945年《聯合國憲章》賦予國家有義務針對彼此爭端協議和平解決爭端之方法，並且有權自由選擇和平方法解決爭端。1982年《聯合國海洋法公約》進一步確認《聯合國憲章》的和平解決爭端規範，並在尊重國家主權原則的前提下，特別載明一套關鍵維持世界海洋法制穩定存續的強制爭端解決規定。 中國大陸與東協各國於2002年針對日益激化的南海爭端簽訂《南海各方行為宣言》，其中明文重申《聯合國憲章》以及《海洋法公約》等國際法規範下的和平解決爭端原則。爾後，南海爭端隨著大國政治的發展與抗衡而顯得更加動盪，菲律賓進一步在2013年初將與中國大陸的南海爭端提交到《海洋法公約》強制仲裁程序來解決。因此，本文探討既存的《南海行為宣言》是否構成強制仲裁庭的管轄權障礙，來保障國家有自主選擇爭端解決方式的權利？又《南海行為宣言》在陸菲南海爭端中扮演何種和平解決爭端的角色，並且其意義與不足之處為何？ 在此問題意識下，首先就爭端標的進行分析，採取以國際關係及仲裁庭的角度來檢視陸菲南海爭端的性質。以國際關係的角度來檢視能發揮以下三個作用：一、理解爭端國在國際政治中的實力評估；二、檢視小國採取司法利用，以及與大國結盟以增加抗衡大國之談判籌碼及獲取法律正當性的策略；三、同時考量所涉爭端的政治與法律性質。另一方面，以仲裁庭的角度來檢視則能瞭知法院如何以國際公法原則來判斷爭端性質。 其次整理《海洋法公約》爭端解決機制以及《南海行為宣言》的內容，分析《海洋法公約》強制爭端解決機制設計的立意與《南海行為宣言》的制訂脈絡，得出《南海行為宣言》在《海洋法公約》的規範下僅為一載有「斡旋」精神的協議，爭端解決的責任仍舊交由簽署國解決。 此外，進一步再藉由仲裁庭的裁判，來分析《南海行為宣言》的法律性質。最後本文發現，中國大陸與東協各國所制訂的《南海行為宣言》僅為一重申既存和平解決規範精神的不具法律拘束力之文件，且未替簽署國創設必須由談判來解決爭端的義務。 最後，對於《南海行為宣言》作出整體評價，其彰顯具有國際法所承認之斡旋精神，展現其類似軟法性質的衝突預防之功能，然而《南海行為宣言》不具有法律實質拘束力，因而無法排除基於《海洋法公約》所提起的強制司法管轄。縱然如此，在「跨國法制歷程」概念中，《南海行為宣言》並非毫無建樹，其為透過各國「互動」而產生一行為模式之規範，然而《南海行為宣言》制訂後至仲裁庭啟動期間，並未使得相關國家對該規範進行有力「內化」的工程，使得該項規範的原則無法發揮效用。然此部分之推論尚待進一步詳細論證分析。 綜上所述，本文透過對於《南海行為宣言》之相關分析，認為我方在擬定未來南海政策時應在尊重各國主權原則的前提下，提升自身國家綜合實力以增加對外談判之籌碼，同時應增進國際法中關於和平解決爭端之研究，有效在各種方面落實國際法爭端解決規範的內化進程。

Purpose - This master thesis evaluates the hybrid-electric aircraft project E-Fan X with respect to its economical and environmental performance in comparison to its reference aircraft, the BAe 146-100. The E-Fan X is replacing one of the four jet engines of the reference aircraft by an electric motor and a fan. A turboshaft engine in the cargo compartment drives a generator to power the electric motor. --- Methodology - The evaluation of this project is based on standard aircraft design equations. Economics are based on Direct Operating Costs (DOC), which are calculated with the method of the Association of European Airlines (AEA) from 1989, inflated to 2019 values. Environmental impact is assessed based on local air quality (NOx, Ozone and Particulate Matter), climate impact (CO2, NOx, Aircraft-Induced Cloudiness known as AIC) and noise pollution estimated with fundamental acoustic equations. --- Findings - The battery on board the E-Fan X it is not necessary. In order to improve the proposed design, the battery was eliminated. Nevertheless, due to additional parts required in the new configuration, the aircraft is 902 kg heavier. The turboshaft engine saves only 59 kg of fuel. The additional mass has to be compensated by a payload reduced by 9 passengers. The DOC per seat-mile are up by more than 10% and equivalent CO2 per seat-mile are more than 16% up in the new aircraft. --- Research limitations - Results are limited in accuracy by the underlying standard aircraft design calculations. The results are also limited in accuracy by the lack of knowledge of some data of the project. --- Practical implications - The report contributes arguments to the discussion about electric flight. --- Social implications - Results show that unconditional praise given to the environmental characteristics of this industry project are not justified.

Lead is a known toxin, with the ability to accumulate in the human body from as early as fetal development. Lead exposure is known to cause a myriad of health effects which are more prominent among children. Health effects upon exposure can range from renal and heart disease or potentially cancer in adults to neurotoxicity in children. The continued presence of old lead service lines and plumbing in distribution systems as well as lead-containing solders and brass fixtures in homes may contribute lead to drinking water. Recent studies have highlighted the importance of a predictor known as the chloride-to-sulfate mass ratio (CSMR) in controlling lead release. A ratio above 0.5 – 0.6 theoretically increases the aggressiveness of lead leaching in galvanic settings, while a lower ratio controls lead corrosion. A switch in coagulant type could significantly alter the ratio. However, a coagulant switch could also trigger changes in finished water turbidity and organics, including disinfection by-product (DBP) precursors, as well as impact sludge production. Anecdotal evidence from an Ontario water treatment utility suggested the potential applicability of a newly formulated polymer, cationic activated silica (CAS), in improving DBP precursor removal when used in concurrence with a primary coagulant. No previous scientific research had been dedicated to testing of the polymer. The present research had three primary objectives: The first was to investigate the effect of conventional coagulation with six different coagulants on the chloride-to-sulfate mass ratio as it pertains to lead corrosion in two Ontario source waters of differing quality. Additionally, the effect of coagulant choice on pH, turbidity, and organics removal was investigated. The second objective was aimed at testing potential reductions in CSMR and organics that could be brought about by the use of two polymers, cationic and anionic activated silica (CAS and AAS, respectively), as flocculant aids. Finally, the performance of a high-rate sand-ballasted clarification process was simulated at bench-scale to gauge its performance in comparison with conventional coagulation simulation techniques. The first series of jar-tests investigated the effectiveness of CAS as a primary coagulant on Lake Ontario water. In comparison with the conventional coagulants aluminum sulfate and polyaluminum chloride, CAS did not offer any apparent advantage with respect to turbidity and organics removal. Testing of CAS and AAS as flocculant aids was also conducted. Results from a full factorial experiment focused on CAS testing on Lake Ontario water showed that coagulant dose is the most significant contributor to CSMR, turbidity, DOC removal, and THM control. Generally, improvements resulting from CAS addition were of small magnitude (<15%). Reductions in CSMR were attributed to the presence of the sulfate-containing chemicals alum and sulfuric acid in the CAS formulation. Testing of sulfuric acid-activated AAS on Grand River water showed that pairing of AAS with polyaluminum chloride provides better results than with alum with respect to DOC removal (39% and 27% respectively at 60 mg/L coagulant dose). Highest turbidity removals (>90%) with both coagulants were achieved at the tested coagulant and AAS doses of 10 mg/L and 4 mg/L respectively. CSMR reductions in the presence of AAS were also attributable to sulfate contribution from sulfuric acid. Bench-scale simulation of a high-rate sand-ballasted clarification process on Grand River water showed comparable removal efficiencies for turbidity (80 – 90% at 10 mg/L), and DOC (30 – 40% at 50 mg/L). Finally, six different coagulants were tested on the two source waters for potential applicability in CSMR adjustment in the context of lead corrosion. The two chloride-containing coagulants polyaluminum chloride and aluminum chlorohydrate increased CSMR in proportion to the coagulant dose added, as would be expected. Average chloride contribution per 10 mg/L coagulant dose was 2.7 mg/L and 2.0 mg/L for polyaluminum chloride and aluminum chlorohydrate, respectively. Sulfate-contributing coagulants aluminum sulfate, ferric sulfate, pre-hydroxylated aluminum sulfate, and polyaluminum silicate sulfate reduced CSMR as coagulant dose increased, also as would be expected. The highest sulfate contributors per 10 mg/L dose were pre-hydroxylated aluminum sulfate (6.2 mg/L) and ferric sulfate (6.0 mg/L). The lowest CSMR achieved was 0.6 in Lake Ontario water at a 30 mg/L dose and 0.8 in Grand River water at a 60 mg/L dose. Highest DOC removals were achieved with the chloride-containing coagulants in both waters (35 – 50%) with aluminum chlorohydrate showing superiority in that respect. DOC removals with sulfate-containing coagulants were less, generally in the range of 22 – 41%. Specificity of critical CSMR values to source water needs to be investigated. Additionally, long term effects of sustained high or low CSMR values in distribution systems need to be further looked into. Finally, the effect of interventions to alter CSMR on other water quality parameters influencing lead corrosion such as pH and alkalinity still represent a research deficit.

Lead is a known toxin, with the ability to accumulate in the human body from as early as fetal development. Lead exposure is known to cause a myriad of health effects which are more prominent among children. Health effects upon exposure can range from renal and heart disease or potentially cancer in adults to neurotoxicity in children. The continued presence of old lead service lines and plumbing in distribution systems as well as lead-containing solders and brass fixtures in homes may contribute lead to drinking water. Recent studies have highlighted the importance of a predictor known as the chloride-to-sulfate mass ratio (CSMR) in controlling lead release. A ratio above 0.5 – 0.6 theoretically increases the aggressiveness of lead leaching in galvanic settings, while a lower ratio controls lead corrosion. A switch in coagulant type could significantly alter the ratio. However, a coagulant switch could also trigger changes in finished water turbidity and organics, including disinfection by-product (DBP) precursors, as well as impact sludge production. Anecdotal evidence from an Ontario water treatment utility suggested the potential applicability of a newly formulated polymer, cationic activated silica (CAS), in improving DBP precursor removal when used in concurrence with a primary coagulant. No previous scientific research had been dedicated to testing of the polymer. The present research had three primary objectives: The first was to investigate the effect of conventional coagulation with six different coagulants on the chloride-to-sulfate mass ratio as it pertains to lead corrosion in two Ontario source waters of differing quality. Additionally, the effect of coagulant choice on pH, turbidity, and organics removal was investigated. The second objective was aimed at testing potential reductions in CSMR and organics that could be brought about by the use of two polymers, cationic and anionic activated silica (CAS and AAS, respectively), as flocculant aids. Finally, the performance of a high-rate sand-ballasted clarification process was simulated at bench-scale to gauge its performance in comparison with conventional coagulation simulation techniques. The first series of jar-tests investigated the effectiveness of CAS as a primary coagulant on Lake Ontario water. In comparison with the conventional coagulants aluminum sulfate and polyaluminum chloride, CAS did not offer any apparent advantage with respect to turbidity and organics removal. Testing of CAS and AAS as flocculant aids was also conducted. Results from a full factorial experiment focused on CAS testing on Lake Ontario water showed that coagulant dose is the most significant contributor to CSMR, turbidity, DOC removal, and THM control. Generally, improvements resulting from CAS addition were of small magnitude (<15%). Reductions in CSMR were attributed to the presence of the sulfate-containing chemicals alum and sulfuric acid in the CAS formulation. Testing of sulfuric acid-activated AAS on Grand River water showed that pairing of AAS with polyaluminum chloride provides better results than with alum with respect to DOC removal (39% and 27% respectively at 60 mg/L coagulant dose). Highest turbidity removals (>90%) with both coagulants were achieved at the tested coagulant and AAS doses of 10 mg/L and 4 mg/L respectively. CSMR reductions in the presence of AAS were also attributable to sulfate contribution from sulfuric acid. Bench-scale simulation of a high-rate sand-ballasted clarification process on Grand River water showed comparable removal efficiencies for turbidity (80 – 90% at 10 mg/L), and DOC (30 – 40% at 50 mg/L). Finally, six different coagulants were tested on the two source waters for potential applicability in CSMR adjustment in the context of lead corrosion. The two chloride-containing coagulants polyaluminum chloride and aluminum chlorohydrate increased CSMR in proportion to the coagulant dose added, as would be expected. Average chloride contribution per 10 mg/L coagulant dose was 2.7 mg/L and 2.0 mg/L for polyaluminum chloride and aluminum chlorohydrate, respectively. Sulfate-contributing coagulants aluminum sulfate, ferric sulfate, pre-hydroxylated aluminum sulfate, and polyaluminum silicate sulfate reduced CSMR as coagulant dose increased, also as would be expected. The highest sulfate contributors per 10 mg/L dose were pre-hydroxylated aluminum sulfate (6.2 mg/L) and ferric sulfate (6.0 mg/L). The lowest CSMR achieved was 0.6 in Lake Ontario water at a 30 mg/L dose and 0.8 in Grand River water at a 60 mg/L dose. Highest DOC removals were achieved with the chloride-containing coagulants in both waters (35 – 50%) with aluminum chlorohydrate showing superiority in that respect. DOC removals with sulfate-containing coagulants were less, generally in the range of 22 – 41%. Specificity of critical CSMR values to source water needs to be investigated. Additionally, long term effects of sustained high or low CSMR values in distribution systems need to be further looked into. Finally, the effect of interventions to alter CSMR on other water quality parameters influencing lead corrosion such as pH and alkalinity still represent a research deficit.

Indiana University-Purdue University Indianapolis (IUPUI) / The characterization of the nutrients nitrogen, phosphorus and carbon (NPC) export to streams during storms is an integral part of understanding processes affecting water quality. Despite the fact that excessive levels of these nutrients in the Mississippi River basin adversely affects water quality in the Gulf of Mexico, little research has been conducted on NPC dynamics during storms on larger (>20 km2) agriculturally dominated Midwestern watersheds. This project examined the storm export of nitrate, ammonium, total phosphorus, and dissolved organic carbon (DOC) in the upper Eagle Creek Watershed (UECW) (274 km2) in Central Indiana, USA. Water samples were collected during five winter and spring storms in 2007 and 2008 on the rising and falling limb of the hydrograph, in order to characterize NPC dynamics during storm events. Stream discharge and precipitation was monitored continuously, and major cations were used to examine changes in source water over the duration of the storm and assist in the determination of potential flowpaths. DOC, total P, and TKN (Total Kjeldahl Nitrogen) tended to peak with discharge, while nitrate usually exhibited a slight lag and peaked on the receding limb. Total phosphorus, NH3-, TKN, and DOC appear to be delivered to the stream primarily by overland flow. NO3--N appear to be delivered by a combination of tile drain and macropore flow. Overall UECW displayed smoother nutrient export patterns than smaller previously studied watersheds in the area suggesting that scale may influence nutrient export dynamics. Further research is underway on a 3000 km2 watershed in the area to further examine the role scale may play in nutrient export patterns.

(Synopsis to introductory statement): An introductory statement to five documentary films made by Ian Lang in Australia between 1981 and 1997 exemplifying  a 'democratising' model of sustainable and ethical documentary film production. This document critically reflects on the production process of these films to accompany their submission for the degree of Doctor of Philosophy by Publication at Griffith University. It finds that a contemporary tendency towards 'post-industrial' conditions allows an observational film-maker to negotiate a critical inter-dependence rather than a romantically conceived 'independence' traditional to the genre. [Full thesis consists of introductory statement plus six DVD videodiscs.]