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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
351

Metricas de Einstein e estruturas Hermitianas invariantes em variedades bandeira / Einstein metrics and invariant Hermitian structures on flag manifolds

Silva, Neiton Pereira da 14 August 2018 (has links)
Orientadores: Caio Jose Colleti Negreiros, Nir Cohen / Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Matematica, Estatistica e Computação Cientifica / Made available in DSpace on 2018-08-14T14:44:13Z (GMT). No. of bitstreams: 1 Silva_NeitonPereirada_D.pdf: 4231710 bytes, checksum: af4dc57e0a7215547662f87d1744bb27 (MD5) Previous issue date: 2009 / Resumo: Neste trabalho encontramos todas as métricas de Einstein invariantes em quatro famílias de variedades bandeira do tipo B1 e C1. Os nossos resultados são consistentes com a conjectura de Wang e Ziller sobre a finitude das métricas de Einstein. O nosso método para resolver as equações de Einstein e baseado nas simetrias do sistema algébrico. Obtemos os sistemas algébricos de Einstein para variedades bandeira generalizadas do tipo B1 C1e G2. Estes sistemas são as condições necessárias e suficientes para métricas invariantes nessas variedades serem Einstein. Os sistemas algébricos que obtivemos generalizam as equações de Einstein obtidas por Sakane nos casos maximais. As equações nos casos Al e Dl foram obtidas por Arvanitoyeorgos. Calculamos o conjunto das trazes para as variedades bandeira generalizadas dos grupos de Lie clássicos. Assim estendemos à essas variedades certos resultados sobre estruturas Hermitianas invariantes obtidos por San Martin, Cohen e Negreiros. / Abstract: In this work we and all the invariant Einstein metrics on four families of ag manifolds of type Bl and Cl. Our results are consistent with the finiteness conjecture of Einstein metrics proposed by Wang and Ziller. Our approach for solving the Einstein equations is based on the symmetries of the algebraic system. We obtain the Einstein algebraic systems for the generalized ag manifolds of type Bl, Cl and G2. These systems are necessary and sufficient conditions for invariant metrics on these manifolds to be Einstein. The algebraic systems that we obtained generalize the Einstein equations obtained by Sakane in the maximal cases. The equations in the cases Al and Dl were obtained by Arvanitoyeorgos. We calculate all the t-roots on the generalized ag manifolds of the classical Lie groups. Thus we extend to these manifolds certain results on invariant structures Hermitian obtained by San Martin, Cohen and Negreiros. / Doutorado / Geometria Diferencial / Doutor em Matemática
352

Sur la géométrie des solitons de Kähler-Ricci dans les variétés toriques et horosphériques / On the geometry of Kähler-Ricci solitons on toric and horospherical manifold

Delgove, François 04 April 2019 (has links)
Cette thèse traite des solitons de Kähler-Ricci qui sont des généralisations naturelles des métriques de Kähler-Einstein. Elle est divisée en deux parties. La première étudie la décomposition solitonique de l’espace des champs de vecteurs holomorphes dans le cas des variétés toriques. La seconde partie étudie de manière analytique les variétés horosphériques en redémontrant par la méthode de la continuité l’existence de solitons de Kähler-Ricci sur ces variétés et en calculant après la borne supérieure de Ricci. / This thesis deal with Kähler-Ricci solitons which are natural generalizations of Kähler-Einstein metrics. It is divided into two parts. The first one studies the solitonic decomposition of the space of holomorphic vector spaces in the case of toric manifold. The second one studies is an analytic way the existence of horospherical Kähler-Ricci solitons on those manifolds and then computes the greatest Ricci lower bound.
353

Towards testing Bell's inequality using atoms correlated in momentum / Vers la réalisation du test d’inégalité de Bell avec les atomes corrèle en impulsion

Imanaliev, Almazbek 30 March 2016 (has links)
Ce manuscrit décrit des expériences d’optique atomique quantique utilisant un détecteur résolu en impulsions d’atomes uniques d’hélium métastable. La première partie du manuscrit décrit la mesure de cohérence de deuxième ordre de la superradiance à partir d’un condensat de Bose-Einstein d’helium métastable. Bien que le condensat soit cohérent et le gain du processus de superradiance élevé, celle-ci montre toujours une statistique thermique comme celle de l’émission spontanée. La suite du manuscrit est dédiée au test de la non localité d’une source atomique corrélée en impulsion. Le schéma du test s’inspire d’une réalisation faite par Rarity et Tapster sur des photons intriqués en impulsion. Les ingrédients principaux d’un tel schéma sont la source atomique générée par instabilité dynamique du condensat dans un réseau optique en mouvement, le contrôle cohérent des atomes par diffraction de Bragg et la mesure de la corrélation des atomes dans les différentes voies de sortie du schéma interférométrique. Un point clé est le contrôle et la manipulation de la phase des ondes atomiques. Le chapitre 3 décrit les tests sur le contrôle cohérent par diffraction de Bragg et leurs résultats encourageants. La nature non classique de notre source atomique est démontrée par l’observation d’une interférence à deux particules en les envoyant sur une séparatrice atomique. Cet analogue atomique de l’expérience de Hong Ou et Mandel est le sujet du dernier chapitre de ce manuscrit. Le résultat de cette expérience ouvre la possibilité du test d’inégalité de Bell avec des particules massives corrélées sur des degrés de liberté externe. / This manuscript describes quantum atom optics experiments using metastable helium atoms with a single-atom momentum resolved detector. In the first part of this manuscript, the second order correlation measurement of the superradiance from a metastable helium Bose-Einstein condensate is presented. The superradiance effect is the collective radiation of dense ensemble where a strong gain of the radiation is expected. We have shown the thermal like statistics of the emission even in the presence of the strong gain. The next part of the manuscript is devoted to the quantum nonlocality test using a pair of atoms entangled in momentum. The protocol we came up with is inspired from the one of Rarity and Tapster with pairs of photons entangled in momentum. The essential ingredients of this protocol are the atomic pair produced by dynamical instability of the Bose-Einstein condensate in a moving optical lattice, the coherent control of the atomic pair by Bragg diffraction and the correlation measurement of the atoms in different output modes of the interferometric protocol. The experimental characterization and preparation of coherent control by Bragg diffraction are presented showing the proof of principle of such a protocol. The last part of the manuscript discusses the realization of the atomic Hong-Ou-Mandel experiment using the same atomic pair with an atomic beamsplitter. The non-classical interference result of this experiment has opened an opportunity for us to realize Bell’s inequality test with massive particles correlated in external degrees of freedom.
354

Retificando uma interpretação: o uso de um artigo de Gaston Bachelard como pretexto para a crítica a interpretação de um experimento crucial

Melo, Jairo de Sousa 23 September 2009 (has links)
Made available in DSpace on 2016-04-27T17:27:30Z (GMT). No. of bitstreams: 1 JAIRO DE SOUSA MELO.pdf: 52195 bytes, checksum: fa611b6f5aac9f7b6b06a3f55339ee20 (MD5) Previous issue date: 2009-09-23 / Basically, this work is about the origins of the Theory of Relativity. However, most importantly, it intends to interpret how and in which ways the Michelson´s experiment may have contributed or not to ideas that led Einstein in developing his seminal theory. Most specifically, this work leans over a text of 1949, by philosopher Gaston Bachelard in which he, in according with common sense of his age, declare that the experiment made by Michelson in 1881 is the starting point of the development of Theory of Relativity. At last, this paper made a comparative analysis of Einstein s own statements and a demonstration that, although the experiment had been crucial to resolve the ether problem, it, that is, its result, doesn t bear any significant value in the theories developed by the physicist, and, beyond that, contrary to what was postulated, the theory explains the failure of the experiment, its null result; and this result didn t lead, in its age, to any postulation about the subjacent principle to Theory of Relativity / Basicamente este trabalho versa sobre as origens da Teoria da relatividade. Mas, sobretudo, busca interpretar como e de que forma o experimento de Michelson pode ter contribuído ou não para as idéias que conduziram Einstein no desenvolvimento de sua teoria seminal. Mais especificamente, o trabalho debruça-se sobre um texto de 1949, do filósofo Gaston Bachelard no qual o mesmo, em concordância com o senso comum de sua época, afirma ter sido o experimento realizado por Michelson em 1881 o ponto de partida para o desenvolvimento da Relatividade. Finaliza este trabalho, uma analise comparativa das declarações do próprio Einstein e uma demonstração de que, embora o experimento tenha sido crucial para o fechamento do problema do éter, ele, ou melhor, seu resultado não tem peso significativo nas teorias desenvolvidas pelo físico, e, muito mais, ao contrário do que se postulava, a teoria explica o insucesso do experimento, seu resultado nulo; e o resultado nulo do experimento não remeteu, em sua época, a nenhuma postulação sobre os princípios subjacentes à Teoria da Relatividade
355

Thermodynamic characterization of heavy fermion systems and low dimensional quantum magnets near a quantum critical point

Radu, Maria Teodora 27 September 2005 (has links) (PDF)
We report experimentally results on the low temperature properties of two classes of materials with a special emphasizes near the QCP induced by substitution and magnetic 1.field: (1) the HF systems YbRh2(Si0.95Ge0.05)2, Yb1-yLayRh2Si2 (y = 0.05, 0.1),and YbIr2Si2 with tetragonal structures and CeIn3-xSnx (x = 0.55, 0.6, 0.65, 0.7, 0.8) with cubic structure; (2) the quantum spin systems: Cs2CuCl4 and Cs2CoCl4. In all the HF compounds we have observed NFL behavior in zero magnetic field close to the QCP. The La substituted system does not show an antiferromagnetic (AFM) transition down to the lowest accessible temperature (0.03 K) while in YbRh2(Si1-xGex)2 with x = 0 and x = 0.05 AFM transitions occur at TN =0.07 K and 0.02 K, respectively. For Yb0.9La0.1Rh2Si2 we observe below 0.07 K saturation of DeltaC/T indicating clearly a LFL state for this concentration. For YbIr2Si2, DeltaC/T saturates below 0.5 K. In contrast to the Yb based compounds in the vicinity of the QCP, CeIn3-xSnx shows no evidence of a divergence in Delta C/T, with B or with x. Furthermore, we used specic heat measurements in the mK temperature range and at high fields (up to 12 T) to probe the phase diagrams in the low dimensional quantum antiferromagnets Cs2CuCl4 and Cs2CoCl4. In applied magnetic field, we have presented experimental evidence that in Cs2CuCl4 the field dependence of the critical temperature Tc(B) ~ (Bc-B)^1-Phi close to the critical field Bc = 8.51 T is well described with Phi=1.5. This is in very good agreement with the exponent expected in the mean-field approximation and support the notion of a Bose-Einstein condensation of magnons in Cs2CuCl4.
356

Gaussian deterministic and probabilistic transformations of bosonic quantum fields: squeezing and entanglement generation

Gagatsos, Christos 17 December 2014 (has links)
The processing of information based on the generation of common quantum optical states (e.g. coherent states) and the measurement of the quadrature components of the light field (e.g. homodyne detection) is often referred to as continuous-variable quantum information processing. It is a very fertile field of investigation, at a crossroads between quantum optics and information theory, with notable successes such as unconditional continuous-variable quantum teleportation or Gaussian quantum key distribution. In quantum optics, the states of the light field are conveniently characterized using a phase-space representation (e.g. Wigner function), and the common optical components effect simple affine transformations in phase space (e.g. rotations). In quantum information theory, one often needs to determine entropic characteristics of quantum states and operations, since the von Neuman entropy is the quantity at the heart of entanglement measures or channel capacities. Computing entropies of quantum optical states requires instead turning to a state-space representation of the light field, which formally is the Fock space of a bosonic mode.<p>This interplay between phase-space and state-space representations does not represent a particular problem as long as Gaussian states (e.g. coherent, squeezed, or thermal states) and Gaussian operations (e.g. beam splitters or squeezers) are concerned. Indeed, Gaussian states are fully characterized by the first- and second-order moments of mode operators, while Gaussian operations are defined via their actions on these moments. The so-called symplectic formalism can be used to treat all Gaussian transformations on Gaussian states, including mixed states of an arbitrary number of modes, and the entropies of Gaussian states are directly linked to their symplectic eigenvalues.<p>This thesis is concerned with the Gaussian transformations applied onto arbitrary states of light, in which case the symplectic formalism is unapplicable and this phase-to-state space interplay becomes highly non trivial. A first motivation to consider arbitrary (non-Gaussian) states of light results from various Gaussian no-go theorems in continuous-variable quantum information theory. For instance, universal quantum computing, quantum entanglement concentration, or quantum error correction are known to be impossible when restricted to the Gaussian realm. A second motivation comes from the fact that several fundamental quantities, such as the entanglement of formation of a Gaussian state or the communication capacity of a Gaussian channel, rely on an optimization over all states, including non-Gaussian states even though the considered state or channel is Gaussian. This thesis is therefore devoted to developing new tools in order to compute state-space properties (e.g. entropies) of transformations defined in phase-space or conversely to computing phase-space properties (e.g. mean-field amplitudes) of transformations defined in state space. Remarkably, even some basic questions such as the entanglement generation of optical squeezers or beam splitters were unsolved, which gave us a nice work-bench to investigate this interplay. <p>In the first part of this thesis (Chapter 3), we considered a recently discovered Gaussian probabilistic transformation called the noiseless optical amplifier. More specifically, this is a process enabling the amplification of a quantum state without introducing noise. As it has long been known, when amplifing a quantum signal, the arising of noise is inevitable due to the unitary evolution that governs quantum mechanics. It was recently realized, however, that one can drop the unitarity of the amplification procedure and trade it for a noiseless, albeit probabilistic (heralded) transformation. The fact that the transformation is probabilistic is mathematically reflected in the fact that it is non trace-preserving. This quantum device has gained much interest during the last years because it can be used to compensate losses in a quantum channel, for entanglement distillation, probabilistic quantum cloning, or quantum error correction. Several experimental demonstrations of this device have already been carried out. Our contribution to this topic has been to derive the action of this device on squeezed states and to prove that it acts quite surprisingly as a universal (phase-insensitive) optical squeezer, conserving the signal-to-noise ratio just as a phase-sensitive optical amplifier but for all quadratures at the same time. This also brought into surface a paradoxical effect, namely that such a device could seemingly lead to instantaneous signaling by circumventing the quantum no-cloning theorem. This paradox was discussed and resolved in our work.<p>In a second step, the action of the noiseless optical amplifier and it dual operation (i.e. heralded noiseless attenuator) on non-Gaussian states has been examined. We have observed that the mean-field amplitude may decrease in the process of noiseless amplification (or may increase in the process of noiseless attenuation), a very counterintuitive effect that Gaussian states cannot exhibit. This work illustrates the above-mentioned phase-to-state space interplay since these devices are defined as simple filtering operations in state space but inferring their action on phase-space quantities such as the mean-field amplitude is not straightforward. It also illustrates the difficulty of dealing with non-Gaussian states in Gaussian transformations (these noiseless devices are probabilistic but Gaussian). Furthermore, we have exhibited an experimental proposal that could be used to test this counterintuitive feature. The proposed set-up is feasible with current technology and robust against usual inefficiencies that occur in optical experiment. <p>Noiseless amplification and attenuation represent new important tools, which may offer interesting perspectives in quantum optical communications. Therefore, further understanding of these transformations is both of fundamental interest and important for the development and analysis of protocols exploiting these tools. Our work provides a better understanding of these transformations and reveals that the intuition based on ordinary (deterministic phase-insensitive) amplifiers and losses is not always applicable to the noiseless amplifiers and attenuators.<p>In the last part of this thesis, we have considered the entropic characterization of some of the most fundamental Gaussian transformations in quantum optics, namely a beam splitter and two-mode squeezer. A beam splitter effects a simple rotation in phase space, while a two-mode squeezer produces a Bogoliubov transformation. Thus, there is a well-known phase-space characterization in terms of symplectic transformations, but the difficulty originates from that one must return to state space in order to access quantum entropies or entanglement. This is again a hard problem, linked to the above-mentioned interplay in the reverse direction this time. As soon as non-Gaussian states are concerned, there is no way of calculating the entropy produced by such Gaussian transformations. We have investigated two novel tools in order to treat non-Gaussian states under Gaussian transformations, namely majorization theory and the replica method.<p>In Chapter 4, we have started by analyzing the entanglement generated by a beam splitter that is fed with a photon-number state, and have shown that the entanglement monotones can be neatly combined with majorization theory in this context. Majorization theory provides a preorder relation between bipartite pure quantum states, and gives a necessary and sufficient condition for the existence of a deterministic LOCC (local operations and classical communication) transformation from one state to another. We have shown that the state resulting from n photons impinging on a beam splitter majorizes the corresponding state with any larger photon number n’ > n, implying that the entanglement monotonically grows with n, as expected. In contrast, we have proven that such a seemingly simple optical component may have a rather surprising behavior when it comes to majorization theory: it does not necessarily lead to states that obey a majorization relation if one varies the transmittance (moving towards a balanced beam splitter). These results are significant for entanglement manipulation, giving rise in particular to a catalysis effect.<p>Moving forward, in Chapter 5, we took the step of introducing the replica method in quantum optics, with the goal of achieving an entropic characterization of general Gaussian operations on a bosonic quantum field. The replica method, a tool borrowed from statistical physics, can also be used to calculate the von Neumann entropy and is the last line of defense when the usual definition is not practical, which is often the case in quantum optics since the definition involves calculating the eigenvalues of some (infinite-dimensional) density matrix. With this method, the entropy produced by a two-mode squeezer (or parametric optical amplifier) with non-trivial input states has been studied. As an application, we have determined the entropy generated by amplifying a binary superposition of the vacuum and an arbitrary Fock state, which yields a surprisingly simple, yet unknown analytical expression. Finally, we have turned to the replica method in the context of field theory, and have examined the behavior of a bosonic field with finite temperature when the temperature decreases. To this end, information theoretical tools were used, such as the geometric entropy and the mutual information, and interesting connection between phase transitions and informational quantities were found. More specifically, dividing the field in two spatial regions and calculating the mutual information between these two regions, it turns out that the mutual information is non-differentiable exactly at the critical temperature for the formation of the Bose-Einstein condensate.<p>The replica method provides a new angle of attack to access quantum entropies in fundamental Gaussian bosonic transformations, that is quadratic interactions between bosonic mode operators such as Bogoliubov transformations. The difficulty of accessing entropies produced when transforming non-Gaussian states is also linked to several currently unproven entropic conjectures on Gaussian optimality in the context of bosonic channels. Notably, determining the capacity of a multiple-access or broadcast Gaussian bosonic channel is pending on being able to access entropies. We anticipate that the replica method may become an invaluable tool in order to reach a complete entropic characterization of Gaussian bosonic transformations, or perhaps even solve some of these pending conjectures on Gaussian bosonic channels.<p> / Doctorat en Sciences de l'ingénieur / info:eu-repo/semantics/nonPublished
357

Thermodynamic characterization of heavy fermion systems and low dimensional quantum magnets near a quantum critical point

Radu, Maria Teodora 13 October 2005 (has links)
We report experimentally results on the low temperature properties of two classes of materials with a special emphasizes near the QCP induced by substitution and magnetic 1.field: (1) the HF systems YbRh2(Si0.95Ge0.05)2, Yb1-yLayRh2Si2 (y = 0.05, 0.1),and YbIr2Si2 with tetragonal structures and CeIn3-xSnx (x = 0.55, 0.6, 0.65, 0.7, 0.8) with cubic structure; (2) the quantum spin systems: Cs2CuCl4 and Cs2CoCl4. In all the HF compounds we have observed NFL behavior in zero magnetic field close to the QCP. The La substituted system does not show an antiferromagnetic (AFM) transition down to the lowest accessible temperature (0.03 K) while in YbRh2(Si1-xGex)2 with x = 0 and x = 0.05 AFM transitions occur at TN =0.07 K and 0.02 K, respectively. For Yb0.9La0.1Rh2Si2 we observe below 0.07 K saturation of DeltaC/T indicating clearly a LFL state for this concentration. For YbIr2Si2, DeltaC/T saturates below 0.5 K. In contrast to the Yb based compounds in the vicinity of the QCP, CeIn3-xSnx shows no evidence of a divergence in Delta C/T, with B or with x. Furthermore, we used specic heat measurements in the mK temperature range and at high fields (up to 12 T) to probe the phase diagrams in the low dimensional quantum antiferromagnets Cs2CuCl4 and Cs2CoCl4. In applied magnetic field, we have presented experimental evidence that in Cs2CuCl4 the field dependence of the critical temperature Tc(B) ~ (Bc-B)^1-Phi close to the critical field Bc = 8.51 T is well described with Phi=1.5. This is in very good agreement with the exponent expected in the mean-field approximation and support the notion of a Bose-Einstein condensation of magnons in Cs2CuCl4.
358

Vers la fabrication d’échantillons permettant la condensation Bose-Einstein de polaritons excitoniques dans des cristaux d’anthracène en microcavités

Robert, Mathieu 08 1900 (has links)
Nous investiguons dans ce travail la création d'échantillons permettant l'étude du comportement des polaritons excitoniques dans les matériaux semi-conducteurs organiques. Le couplage fort entre les états excités d'électrons et des photons impose la création de nouveaux états propres dans le milieu. Ces nouveaux états, les polaritons, ont un comportement bosonique et sont donc capables de se condenser dans un état fortement dégénéré. Une occupation massive de l'état fondamental permet l'étude de comportements explicables uniquement par la mécanique quantique. La démonstration, au niveau macroscopique, d'effets quantiques promet d'éclairer notre compréhension de la matière condensée. De plus, la forte localisation des excitons dans les milieux organiques permet la condensation des polaritons excitoniques organiques à des températures beaucoup plus hautes que dans les semi-conducteurs inorganiques. À terme, les échantillons proposés dans ce travail pourraient donc servir à observer une phase cohérente macroscopique à des températures facilement atteignables en laboratoire. Les cavités proposées sont des résonateurs Fabry-Perot ultraminces dans lesquels est inséré un cristal unique d'anthracène. Des miroirs diélectriques sont fabriqués par une compagnie externe. Une couche d'or de 60 nanomètres est ensuite déposée sur leur surface. Les miroirs sont ensuite mis en contact, or contre or, et compressés par 2,6 tonnes de pression. Cette pression soude la cavité et laisse des espaces vides entre les lignes d'or. Une molécule organique, l'anthracène, est ensuite insérée par capillarité dans la cavité et y est cristallisée par la suite. Dans leur état actuel, les cavités présentent des défauts majeurs quant à la planarité des miroirs et à l'uniformité des cristaux. Un protocole détaillé est présenté et commenté dans ce travail. Nous y proposons aussi quelques pistes pour régler les problèmes courants de l'appareil. / In this work we investigate the creation of samples for the study of the behavior of excitonic polaritons in organic semiconductor materials. The strong coupling between the excited states of electrons and photons implies the creation new eigenstates in the medium. These new states, called polaritons, are composite bosons and are therefore capable of condensing in a strongly degenerated state. A massive occupation of the ground state allows the study of behaviors that are only explainable by quantum mechanics. A macroscopic demonstration of quantum effects offers a rare opportunity for scientific research and discoveries. The strong localization of excitons in organic materials allows condensation of exciton polaritons at temperatures much higher than in inorganic semiconductors. Therefore the samples proposed in this work could ultimately be used to observe a macroscopic coherent phase at temperatures easily attainable in a laboratory. The cavities proposed in this work are Fabry-Perot resonators in which anthracene is inserted and crystalized. The mirrors used in the resonator are dielectric reflectors made by a external company according to our specifications. A gold layer of 60 nm is deposited on their surface. The mirrors are then brought into contact, gold against gold, and compressed by 2.6 tons of pressure. This pressure seals the cavity and leaves voids between the gold lines. An organic molecule, anthracene, is then inserted in by capillary inside the cavity voids and subsequently crystallized by controlled cooling. In their current state cavities have defects regarding the planarity of the mirrors and the uniformity of the crystals. A detailed protocol is presented and discussed in this work.
359

Caractérisation et modélisation de l’aimant organique NIT-2Py

Gauthier, Nicolas 08 1900 (has links)
L'aimant organique NIT-2Py a été caractérisé expérimentalement et ses propriétés ont été simulées numériquement à partir de la théorie de la fonctionnelle de la densité. Le magnétisme dans ce matériau provient de la présence d'un électron non apparié sur chaque molécule qui a ainsi un moment magnétique non nul. Ceci a été confirmé par des simulations sur une molécule isolée. Les molécules de NIT-2Py cristallisent dans le groupe d'espace P21/c avec huit molécules par maille élémentaire pour former la structure cristalline Alpha étudiée dans ce document. Le moment effectif de la susceptibilité et l'entropie magnétique totale montre que ce matériau est un système de spins 1/2 avec un spin par molécule. Les mesures de chaleur spécifique ont mis en évidence la présence de deux phases magnétiques ordonnées à basse température qui sont séparées par un plateau en aimantation. Une première phase est observée à des champs magnétiques inférieurs à 2.2 T et a une température de transition de 1.32 K en champ nul. Les mesures de susceptibilité magnétique et d'aimantation ont permis d'établir que cette phase ordonnée est antiferromagnétique. Ceci est confirmé par les simulations numériques. La deuxième phase est induite par le champ magnétique avec une température de transition de 0.53 K à 6 T. L'information disponible sur cette phase est limitée et l'étude du système à l'extérieur des phases ordonnées en donne une meilleure compréhension. Un modèle de spins S=1/2 isolés et de dimères S=0 isolés reproduit bien les mesures d'aimantation et de chaleur spécifique au-dessus de 3 K. L'application d'un champ magnétique réduit l'écart d'énergie entre le singulet et le triplet du dimère jusqu'au croisement qui se produit à 6 T. La phase induite émerge précisément à ce croisement et on spécule l'existence d'un condensat de Bose-Einstein des états triplets. / The organic magnet built from NIT-2Py molecules has been characterized experimentally and its properties have been simulated using density functional theory. In this material, an unpaired electron carrying a magnetic moment on each molecule is responsible for the magnetism. This has been confirmed by numeric simulations on an isolated molecule. NIT-2Py molecules crystallize in space group P21/c with eight molecules per unit cell to form crystalline phase Alpha studied in this document. The effective moment obtained from magnetic susceptibility and the total magnetic entropy show that this material is a spin 1/2 system with one spin per molecule. Specific heat measurements have highlighted the presence of two magnetically ordered phases at low temperature, which are separated by a plateau in magnetization. A first phase is observed at magnetic field lower than 2.2 T and has a transition temperature of 1.32 K in zero field. Magnetic susceptibility and magnetization measurements have established that this ordered phase is antiferromagnetic. This is confirmed by numeric simulations. The second phase is induced by a magnetic field and has a transition temperature of 0.53 K at 6 T. Information concerning the field induced phase is limited and a study of the system above the transition temperatures helps to gain a better understanding. A model of isolated spins S=1/2 and isolated dimers S=0 reproduces nicely the specific heat and magnetization data above 3 K. The application of a magnetic field reduces the energy gap between the singlet and the triplet of the dimer and the crossover between these levels is observed at 6 T. The field induced phase emerges precisely at this crossover suggesting the occurrence of a Bose-Einstein condensation of triplets states.
360

Formação de sólitons em condensados de Bose-Einstein e em meios ópticos / Formation of solitons in Bose-Einstein condensates and in photorefractive media

Khamis, Eduardo Georges 13 October 2010 (has links)
Diferentes tipos de sólitons têm sido observados em meios ópticos não-lineares, e seus comportamentos individuais descritos pela equação não-linear de Schrödinger e pela equação não-linear de Schrödinger generalizada, em diferentes dimensões e geometrias. Entretando, há situações onde muitos sólitons são gerados formando uma densa rede de sólitons. Nestes casos, é impossível desprezar as interações entre os sólitons e temos que considerar a evolução da estrutura como um todo. A teoria das ondas de choque dispersivas em meios fotorrefrativos e a teoria da difração não-linear de intensos feixes de luz propagando-se em meios fotorrefrativos com um fio refletor incorporado a esse meio foi desenvolvida, e verificamos que está em excelente acordo com nossas simulações numéricas. No caso da formação de sólitons em condensados, fizemos cálculos numéricos realísticos dentro da aproximação de campo médio usando a equação de Gross-Pitaevskii, incluindo também um potencial de confinamento, um potencial móvel e um potencial dipolar. A maioria dos resultados puderam ser comparados com experimentos recentes. / Different kinds of solitons have already been observed in various nonlinear optical media, and their behavior has been explained in the frameworks of such mathematical models as the nonlinear Schrödinger and generalized nonlinear Shrödinger equations for different dimensions and geometries. However, there are situations when many solitons are generated so that they can comprise a dense soliton train. In such situations, it is impossible to neglect interactions between solitons and one has to consider the evolution of the structure as a whole rather than to trace the evolution of each soliton separately. The theory of optical shock waves in photorefractive media and the theory of nonlinear diffraction of light beams propagating in photorefractive media with embedded reflecting wire was developed and agrees very well with our numerical simulations. In the condensate soliton formation case, we did numerical calculations in the mean field approach using the Gross-Pitaevskii equation, adding a trap potential and a moving potential and a potential of the dipole-dipole interaction. The main results were also checked by recent experiments.

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