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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
181

Minority carrier diffusion length in proton-irradiated indium phosphide using electron-beam-induced current

Hakimzadeh, Roshanak January 1993 (has links)
No description available.
182

SINGLE MOLECULE ELECTRONICS AND NANOFABRICATION OF MOLECULAR ELECTRONIC DEVICES

Rajagopal, Senthil Arun 15 August 2006 (has links)
No description available.
183

Wear behavior of Ti-6Al-4V for Joint Implants manufactured by Electron Beam Melting

Shrestha, Sanjay 25 May 2017 (has links)
No description available.
184

Nonthermal intervention strategies to minimize pathogenic foodborne microorganisms

Grasso, Elizabeth Marie 27 October 2010 (has links)
No description available.
185

Wireless Strain Measurement with Surface Acoustic Wave Sensors

Friedlander, Jeffrey B. 28 July 2011 (has links)
No description available.
186

Carrier transport properties measurements in wide bandgap materials

Cropper, André D. 06 June 2008 (has links)
This dissertation examines the carrier transport properties, diffusion length, effective carrier lifetime, and resistivity in two wide bandgap materials, GaN and diamond. A combination of two methods was used to obtain these transport properties. The two were optical beam induced current (OBIC) and electron beam induced current (EBIC) time of flight transient measurements. These techniques consist of measuring the current response to the drift and diffusion of generated electron-hole pair carriers created by a short-duration pulse of radiation. Under OBIC, a short duration pulsed optical source, with an electron beam excitation pulse time much less than the transit time of the material, was used to generate excess carriers within the absorption depth of the material. The second method of excitation, EBIC involved the use of a modified SEM with a photoemission source (L-EBIC) and a high speed pulsed thermionic electron source (T-EBIC) to generate an electron beam. This electron beam was used to create a large number of electron-hole pairs at various penetration depths within the materials. Measurements on GaN found the diffusion length was 7.84 µm with the L-EBIC and 7.78 µm with the T-EBIC. After annealing at 900°C for 30 min. the GaN diffusion length increased to 9.89 µm (L-EBIC). The dark resistivity was 1.79 x 10¹⁰Ω-cm, and the carrier lifetimes were 1.7 µs with L-EBIC and 3.36 & 3.9 ns with OBIC. The author believed that the L-EBIC result was a good representation of the carrier lifetime within the material, while the shorter OBIC results were due to the combine high surface and interface recombination processes. The diamond dark resistivity was found to be 6.14 x 10¹¹Ω-cm and the diffusion lengths were 94.1 µm and 97 µm from the L-EBIC and T-EBIC respectively. All measurements were within 10 % spread. The real value of this contribution lies in determining the diffusion lengths in GaN and diamond by the EBIC techniques, measuring the effective surface\interface and thin film carrier lifetime of GaN utilizing a combination of OBIC and L-EBIC techniques, and evaluating the dark resistivity in GaN and diamond materials. These measurements can lead to a better understanding and exploitation of the electrophysical behavior of these materials. / Ph. D.
187

Combined Compression and Shear Structural Evaluation of Stiffened Panels Fabricated Using Electron Beam Freeform Fabrication

Nelson, Erik Walter 30 July 2008 (has links)
Unitized aircraft structures have the potential to be more efficient than current aircraft structures. The Electron Beam Freeform Fabrication (EBF3) process can be used to manufacture unitized aircraft structures. The structural efficiency of blade stiffened panels made with EBF3 was compared to panels made by integrally machining from thick plate. The panels were tested under two load cases in a combined compression-shear load test fixture. One load case tested the panels' responses to a higher compressive load than the shear load. The second load case tested the panels' responses to an equal compressive and shear load. Finite element analysis was performed to compare with the experimental results. The EBF3 panels failed at a 18.5% lower buckling load than the machined panels when loaded mostly in compression but at an almost two times higher buckling load than the machined panels when the shear matched the compressive load. The finite element analysis was in good agreement with the experimental results prior to buckling. The results demonstrate that the EBF3 process has the capabilities of manufacturing stiffened panels that behave similarly to machined panels prior to buckling. Once the EBF3 panels buckled, the buckled shape of the EBF3 panels was different from the machined panels, generally buckling in the opposite direction of what was observed with the machined panels. This was also expected based on the finite element analysis. The different post-buckling response between the two manufacturing techniques was attributed to the residual stress and associated distortion induced during the EBF3 manufacturing process. / Master of Science
188

Microstructure Development During Laser And Electron Beam Welding Of Ti/Ni Dissimilar Joints

Chatterjee, Subhradeep 07 1900 (has links)
Fusion welding of dissimilar metals constitutes a crucial processing stage in a variety of applications, and the use of high energy beams (HEB) like lasers and electron beams for such welding applications has several advantages, such as, precision, narrow heat affected zone, and consequently, low distortion. An understanding of microstructural evolution in the weld is a prerequisite for producing sound joints with desired properties. HEB welding of similar metals have been studied extensively. In contrast, fewer studies have been directed toward understanding the fundamental aspects of solidification of dissimilar welds. This thesis presents an effort in that direction by exploring microstructural evolution in Ti/Ni dissimilar welds. Welding of Ti/Ni serves to illustrate the fundamental differences that distinguish dissimilar welding from the welding of similar metals. These are: (i) Thermophysical properties of the base metals are, in general, different, and this can have important consequences in the heat transfer conditions. (ii) Composition can vary over an wide range, the extreme being for the case of a pure binary couple, and the solid–liquid interface cannot be defined by a single liquidus isotherm. (iii) In addition to the surface energy driven Marangoni convection, a strong solutal convection can arise due to a large difference in the density of the base metals. (iv) Nucleation of phases assumes greater importance, especially in systems with intermediate phases. We have carried out laser and electron beam welding (LW and EBW) experiments in a butt welding geometry to join Ti/Ni dissimilar couples. Weld microstructures were characterised using scanning and transmission electron microscopy (SEM and TEM); composition information was obtained from energy dispersive spectroscopy (EDS) of Xrays in the SEM. In addition to the pure binary couple, we have also studied electron beam welding of Ti/Ni with a thin Ta interlayer. We summarise our findings in each set of experiments in the following sections. Laser welding of Ti/Ni We have studied partial penetration welds obtained within the range of experimental parameters used in our study. These welds show the following interesting features: 1. The welds are asymmetric with respect to the initial joint. Despite its higher melting point, Ti melts more than Ni due to its lower thermal diffusivity, making the average composition of the weld richer in Ti (Ti–40at.%Ni). 2. Composition changes very steeply near the fusion interfaces in both Ti and Ni with associated microstructural changes. The variation is of much lesser magnitude in the rest of the weld, reflecting a well mixed melt pool on a macroscopic scale. 3. Growth of base metal grains into the weld pool at the fusion interfaces is severely restricted at both Ti and Ni ends. 4. The Ti fusion interface is marked by a band consisting of Ti2Ni dendrites which grow toward the Ti base metal. 5. Layered structures form at the Ni fusion interface. The sequence of the layers is: solid solution (Ni)→ Ni3Ti→ Ni3Ti+NiTi eutectic → NiTi. We note the absence of the (Ni)+Ni3Ti eutectic in this sequence. 6. NiTi and Ti2Ni are the major phases that appear in the bulk of the weld. Volume fraction and morphology of NiTi vary almost periodically to form microstructural bands. 7. Solid state transformation of NiTi results in the formation of the Rphase and martensite, which reflect the composition heterogeneity in the weld. Sometimes, Ni4Ti3 precipitates are observed also, providing indirect evidence of nonequilibrium solidification. 8. Nitrogen pickup from the atmosphere during welding leads to the formation titanium nitride dendrites in the weld. 9. Solutal convection and buoyancy forces manifest themselves through the segregation of the lighter nitride and Ti2Ni phases toward the top surface of the weld; the heavier liquid forms blocky NiTi in the bottom half of the weld. These observations stand in striking contrast with the microstructures of conventional welds. We have proposed a set of composition and temperature profiles in the weld which reflect the diffusive and advective transport processes; when combined with thermodynamic information from the Ti–Ni phase diagram to yield spatial liquidus temperature profiles, these profiles can adequately explain most of the results. Our observations illustrate the importance of (a) nucleation, and (b) the inhomogeneous nature of the melt in which growth takes place. They also highlight the role of convective currents in bringing about local fluctuations in composition and temperature leading to ‘low velocity bands’. Electron beam welding of Ti/Ni We have carried out full penetration EBW of thin plates of Ti and Ni. The major observations are: (i) Average composition of the weld is in the Ni–rich side of the phase diagram (Ni–40at.%Ti). (ii) Fusion interface microstructures are very similar to that in LW exhibiting restricted base metal growth (although little amount of epitaxy can be seen in the Ni side), growth of Ti2Ni dendrites toward the base metal at the Ti fusion interface and the sequence of layers at the Ni interface: (Ni)→ Ni3Ti→ Ni3Ti+NiTi. Unlike LW, however, Ni3Ti, instead of NiTi, reappeared after the third layer on the Ni side. (iii) General microstructure consists of the Ni3Ti+NiTi eutectic, which appears in several anomalous as well as regular morphologies. (iv) Formation of NiTi is restricted mostly to regions near the Ti fusion interface. (v) Segregation of Ni3Ti was observed in a few places. The most prominent change in the microstructure compared to LW is a shift from the Ti2Ni– NiTi phases in the bulk of the weld to a Ni3Ti+NiTi eutectic structure. This is a direct consequence of the shift in the average composition of the weld to the Ni– rich side. The occurrence of different anomalous and regular eutectic structures bear similarity with bulk undercooling experiments conducted on eutectic systems having a strongly faceting phase as one of its constituents. The asymmetric coupled zone, along with composition and temperature fluctuation due to fluid flow, can be attributed to the origin of these structures. Electron beam welding of Ti/Ni with a Ta interlayer Motivated by the report of superior mechanical properties of Ti/Ni welds with an interlayer of Ta, whose melting point is much higher than those Ni and Ti, we performed EBW experiments using a Ni–Ta– Ti configuration. The key observations are: (i) The process is inherently unsteady in nature, and results in partial and irregular melting of the Ta interlayer. This partial melting essentially divides the weld into Ni–rich and Ti–rich halves. (ii) Microstructure near the fusion interface in Ni and Ti show similarities with that of the pure binary Ti/Ni welds; the phases here, however, contain Ta as a ternary addition. (iii) Microstructure in the Ti–rich half consists of dendrites of the Ni(Ti,Ta) phase with a high Ti:Ta ratio, and an eutectic formed between this phase and a (Ti,Ta)2Ni phase having significant amount of Ta. Two Ni(Ti,Ta) type phases dominate the microstructure in the Ni–rich half: the phase having a higher Ti:Ta ratio forms cells and dendrites, whereas the one of a lower Ti:Ta ratio creates an interdendritic network. (iv) Regions near the unmolten Ta layer in the middle show the formation of a sawtoothlike Ta–rich faceted phase of composition (Ta,Ti)3Ni2. Since very scarce thermodynamic data exist for the Ni–Ta–Ti ternary system, we have taken cues from the binary phase diagrams to understand the microstructural evolution. Such extrapolation, although successful to some extent, fails where phases which have no binary equivalents start to appear. In summary, in this thesis, we explore microstructural evolution in the Ti/Ni dissimilar welds under the different settings of laser and electron beam welding processes. This study reveals a variety of phenomena occurring during dissimilar welding which lead to the formation of an extensive range of microstructural features. Although a few questions do remain, most results can be rationalised by drawing from, and extending the knowledge gained from previous studies by introducing physical and thermodynamic arguments.
189

Fabrication of Nanostructures by Low Voltage Electron Beam Lithography

Adeyenuwo, Adegboyega P. Unknown Date
No description available.
190

Pr$_{1-x}$Ca$_x$MnO$_x$ for Catalytic Water Splitting - Optical Properties and In Situ ETEM Investigations

Mildner, Stephanie 05 August 2015 (has links)
Gegenstand der vorliegenden Dissertation ist die Untersuchung von Ca-dotierten PrMnO3 (PCMO) als Katalysator für die (photo)elektrochemische Wasseroxidation. Im Fokus der Untersuchungen stehen die folgenden elementaren Schritte des Gesamtprozesses: i) Die optische Absorption in PCMO wird zunächst als Funktion der Ca-Dotierung und der Temperatur untersucht mit dem Ziel, den Einfluß von Korrelationseffekten auf die optischen Eigenschaften zu verstehen. Die präsentierten Ergebnisse zeigen, dass die Bildung kleiner Polaronen im PCMO als Folge starker Korrelationswechselwirkungen in breites Absorptionsmaximum im Nah-Infrarot bis sichtbarem Energiebereich verursacht, welches im Rahmen eines Photonen-assistierten Polaronenhüpfprozesses und einer Anregung zwischen Jahn-Teller-aufgespaltenen Zuständen diskutiert wird. Weiterhin legt die Dotierungsabhängigkeit der Spektren nahe, dass O 2p und Mn 3d Hybridzustände die Fermienergie-nahe elektronische Struktur bestimmen, wobei der relative Anteil von O 2p mit der Ca-Dotierung variiert. ii) Der aktive Zustand von PCMO in Kontakt mit Wasser bzw. Wasserdampf wird mit Hilfe von Zyklovoltammetrie und in situ ‚environmental‘ Transmissionselektronenmikroskopie (ETEM) für verschiedene Dotierlevels untersucht. Die Ergebnisse beider Methoden ergeben, dass die katalysierte Wasseroxidation gemäß $2\text{H}_2\text{O} \rightarrow \text{O}_2 + 4 \text{H}^+$ mit einem Korrosionsprozess in Form einer Pr/Ca Verarmung und Amorphisierung der PCMO-Elektrode konkurriert. Die höchste katalytische Aktivität sowie Korrosionsstabilität werden im mittleren Dotierungsbereich gefunden. Auf Basis der in situ ETEM Ergebnisse wird außerdem gezeigt, dass durch Zufügen von Monosilan zu Wasserdampf-basierten Elektrolyten im ETEM eine Elektronenstrahl-induzierte Wasseroxidation an aktiven PCMO Oberflächen über die Sekundärreaktion $\text{SiH}_4+2\text{O}_2\rightarrow\text{SiO}_2+2\text{H}_2\text{O}$ nachgewiesen werden kann. Elektronenenergieverlustspektroskopie von PCMO vor und nach der Reaktion in Wasserdampf ergeben, dass der aktive Zustand von PCMO die Bildung und Ausheilung von Sauerstoffleerstellen im Rahmen einer Interkalation des bei der Wasseroxidation freiwerdenden Sauerstoffs beinhaltet. Die Rolle des Elektronenstrahls als Triebkraft für die Wasseroxidation im ETEM wird mithilfe von Elektronenholographie und elektrischen Experimenten sowie theoretischer Modellierung basierend auf Sekundärelektronenemissionen als ein positives Elektronenstrahl-induziertes elektrisches Potential identifiziert.

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