No description available.

Nous évaluons des films polymères poreux structurés en tant que nouveaux supports pour des photosensibilisateurs de l’oxygène singulet. L’objectif de cette association est l’obtention de matériaux photo-actifs à grande surface d’échange. Ces surfaces polymères, structurées ici en nid d’abeille, sont obtenues par la technique « breath figure » (trad. figure de souffle), à partir de polymères bien définis synthétisés par polymérisation radicalaire contrôlée par des nitroxydes (NMP), par transfert d’atome (ATRP) et par transfert réversible par addition/fragmentation (RAFT). Le photosensibilisateur rose Bengale a été greffé de manière covalente au polymère, soit par post-greffage sur un polymère précurseur, soit par modification d’un monomère fonctionnel puis copolymérisation de ce dernier avec du styrène. Ces différentes synthèses conduisent à des films contenant différents taux de rose Bengale. Les films ont été examinés en microscopie (fluorescence, confocale et champ large, électronique à balayage) afin d’établir la structuration des films et la localisation des espèces fluorescentes. L’efficacité des films polymères pour la photo-oxydation a été testée à l’interface liquide/solide en suivant par spectroscopie UV-visible la dégradation du dihydroxynaphtalène (DHN) ou de l’α-terpinène par l’oxygène singulet produit sous irradiation visible. Les films structurés sont environ cinq fois plus efficaces que les films non-poreux de même composition utilisés dans les mêmes conditions, ce qui s’explique par leur surface spécifique et par la localisation préférentielle du rose Bengale à la surface du matériau. / We evaluate structured porous polymer films as new substrates for photosensitizers of singlet oxygen, with a view to obtaining photo-active materials with high specific exchange areas. Here, honeycomb polymer films are obtained by the breath figure process, using well defined polymers synthesized by nitroxide-controlled radical polymerization (NMP), atom transfer polymerization (ATRP) and reversible addition/fragmentation transfer (RAFT). The photosensitizer, rose Bengal, is either post-grafted covalently to the polymer precursor, or pre-grafted to a monomer functional unit which is copolymerized with polystyrene. These syntheses lead to films with different rose Bengal concentrations. We determine the structure of the films and the location of the fluorescent dye by scanning electron microscopy and widefield and confocal microscopy. Efficiency of production of singlet oxygen was tested at a solid/liquid interface by monitoring the oxidation of dihydroxynaphthalene and α-terpinene, using UV-visible absorption spectroscopy. Honeycomb films are about five times more efficient than non-porous films of the same composition used in the same, as may be explained by their higher specific surface area and the preferential location of the photosensitizer at the film surface.

No description available.

The advancement in the eld of cold-atoms has generated a lot of interest in the condensed matter community. Cold-atom experiments can simulate clean, disor-der/impurity free systems very easily. In these systems, we have a control over various parameters like tuning the interaction between particles by the Feshbach resonance, tuning the hopping between lattice sites by laser intensity and so on. As a result, these systems can be used to mimic various theoretical models, which was hindered because of various experimental limitations. Thus, we have an ex-perimental tool in which we can start with a simple theoretical model and later tune the model experimentally and theoretically to simulate the real materials. This will be helpful in studying the physics of the real materials as we can control interactions as well as the impurities can also be taken care of. But the advance-ment in the eld of cold atoms has seen a roadblock for the fermions in optical lattices. The super uid and anti-ferromagnetic phases has not been achieved for fermions in optical lattices due to the \cooling problem" (entropy issues). In this thesis, we have addressed the issue of the \cooling problem" for fermions in optical lattice systems and studied the system with determinant quantum Monte Carlo technique. We start by giving a general idea of cold-atoms and optical lat-tice potentials, and a brief review of the experimental work going on in the cold-atomic systems. Experimental limitations like \fermionic cooling problem" have been discussed in some detail. Then we proposed a bilayer band-insulator model to circumvent the \entropy problem" and simultaneously increasing the transi-tion temperature for fermions in optical lattices. We have studied the attractive Hubbard model, which is the minimal model for fermions in optical lattices. The techniques that we have used to study the model are mean- eld theory, Gaussian uctuation theory and determinant quantum Monte Carlo numerical technique. . Chapter-1 : provides a general introduction to the ultra-cold atoms, optical lattice and Feshbach resonance. In this chapter we have discussed about cold-atom experiments in optical lattice systems. Here, we have brie y discussed the control over various parameters in the experiments. The goal of these experiments is to realize or mimic many many-body Hamiltonians in experiments, which until now was just a theoretical tool to describe various many-body physics. In the end we give a brief idea for introducing disorder in the cold-atom experiments discuss the limitations of these experiments in realizing the \interesting" super uid and anti-ferromagnetic phases of fermionic Hubbard model in optical lattices. Chapter-2 : gives a brief idea of \Determinant Quantum Monte-Carlo" (DQM C) technique that has been used to study these systems. In this chapter we will discuss the DQM C algorithm and the observables that can be calculated. We will discuss certain limitation of the DQM C algorithm like numerical instability and sign problem. We will brie y discuss how sign problem doesn't occur in the model we studied. Chapter-3 : discusses the way by which we can bypass the \cooling problem" (high entropy state) to get a fermionic super uid state in the cold atom experi-ments. In this chapter we propose a model whose idea hinges on a low-entropy band-insulator state, which can be tuned to super uid state by tuning the on-site attractive interaction by Feshbach resonance. We show through Gaussian uctua-tion theory that the critical temperature achieved is much higher in our model as compared to the single-band Hubbard model. Through detailed variational Monte Carlo calculations, we have shown that the super uid state is indeed the most stable ground state and there is no other competing order. In the end we give a proposal for its realization in the ultra-cold atom optical lattice systems. Chapter-4 : discusses the DQM C study of the model proposed in chapter- 3. Here we have studied the various single-particle properties like momentum distribution, double occupancies which can be easily measured in cold-atom ex-periments. We also studied the pair-pair and the density-density correlations in detail through DQM C algorithm and mapped out the full T U phase diagram. We show that the proposed model doesn't favor the charge density wave for the interaction strengths we are interested in. Chapter-5 : gives a brief idea of the e ect of adding an on-site random disorder in our proposed bilayer-Hubbard model. We study the e ect of random disorder on various single-particle properties which can be easily veri ed in cold-atom ex-periments. We studied the suppression of the pair-pair correlations as we increase the disorder strength in our proposed model. We nd that the critical value of the interaction doesn't change in the weak-disorder limit. We estimated the critical disorder strength needed to destroy the super uid state and argued that the tran-sition from the super uid to Bose-glass phase in presence of disorder lies in the universality class of (d + 1) XY model. In the end, we give a schematic U V phase diagram for our system. Chapter-6 : We studied the bilayer attractive Hubbard model in different lattice geometry, the bilayer honeycomb lattice, both in presence and in absence of the on-site random disorder. We discussed how the pair-pair and density-density cor-relations behave in the presence and absence of disorder. Through the finite-size scaling analysis we see the co-existence of the super fluid and the charge density wave order at half- lling. An in nitesimal disorder destroys the CDW order com-pletely while the super uid phase found to be robust against weak-disorder. We estimated the critical interaction strength, the critical temperature and the critical disorder strength through nite-size scaling, and provide a putative phase diagram for the system considered.

Les matériaux composites prennent une place de plus en plus importante dans la conception et la fabrication des moyens de transport et notamment dans le domaine naval où ils sont particulièrement privilégiés. En effet, ces matériaux sont utilisés pour leur légèreté, insensibilité à la corrosion et leurs caractéristiques mécaniques. Dans le domaine militaire, où l'optimisation des moyens de communication et de protection électromagnétique est primordiale, le développement de matériaux composites dotés de propriétés de reconfigurabilité sous commande(s) externe(s), présente un atout opérationnel majeur pour les parois structurales exploitant ces matériaux. Afin d'explorer cette voie, DCNS et l'Institut d’Électronique et de Télécommunications de Rennes (IETR, UMR-6164) se sont associés. Les travaux de thèse engagés ont pour objectif d'étudier et de développer des matériaux composites présentant des fonctions de reconfigurabilité applicables aux systèmes navals tels que les radômes, les antennes et exploitables pour répondre aux problématiques de furtivité (SER). Une première étude a permis d'explorer les matériaux à base de carbone, présentant une potentielle agilité de leurs caractéristiques diélectriques sous actuateur électrique. Ces matériaux présentent également un fort pouvoir absorbant électromagnétique, tributaire des propriétés diélectriques, elles-mêmes potentiellement reconfigurables. La seconde étude engagée a étudié l'impact des matériaux ferroélectriques, c'est-à-dire des matériaux reconfigurables sous champ électrique, lorsqu'ils sont intégrés comme charge dans une résine d'imprégnation. Ce nouveau matériau composite présente alors une reconfigurabilité de ses caractéristiques diélectriques, rendant commandable en fréquence sa structure hôte. Une troisième étude, exploitant aussi le matériau ferroélectrique a permis l'obtention d'une reconfigurabilité des caractéristiques de réflectivité de panneaux composites grâce au développement de surfaces sélectives en fréquence reconfigurables. De nouvelles propriétés ont ainsi été mises en évidence en hyperfréquences. Enfin, les matériaux d'âmes et spécifiquement les nids d'abeilles diélectriques ont fait l'étude d'une fonctionnalisation pour des applications DC et hyperfréquences. / Composite materials are used for their lightness, high resistance to corrosion and high mechanical properties over large application areas, such as naval, ground and aerial. Collaboration between DCNS group and the Institute of Electronics and Telecommunications of Rennes (IETR, UMR-6164) has been initiated to develop smart composite materials with tunable properties at microwaves. Three different routes have been investigated during the thesis work. The first one is based on carbon composite material, its electromagnetic absorbing ability and its potential dielectric tunability. For this, we develop composite materials loaded with various carbon particles (carbon nanotube, graphene, black carbon). Next, to elaborate smart composite materials, a ferroelectric material has been used as filler. The dielectric characteristics of such materials can be tuned under external biasing for example. Thus we develop an active composite material under various external actuators for naval application, and especially for new reconfigurable frequency selective surface (RFSS). Finally dielectric honeycomb materials have been specifically elaborated and studied to develop smart properties for DC and microwave applications. During this work, three different prototypes improving composite materials in naval area have been performed: reconfigurable radome, RCS reduction, and antenna isolation.

Main goals of this master thesis are following: to perform the state of the art research of overpressure constructions (especially space habitats, plane fuselages); to create an own concept of the functional inside ending (hole) in the sandwich panel for a door; to perform stress-strain analysis of this concept; to perform the design optimalization of this concept in order to minimise the weight. To solve the problems above software Ansys 17.2 is chosen, because it allows to: model the material of the honeycomb core of sandwich panel as homogenous linear orthotropic material; evaluate reserve factors of all critical limit states; perform the design optimalization; perform Monte Carlo simulation. First and second design optimalizations discover, that with defined parameters: 0,635 mm width of aluminium sandwich face sheets and inner overpressure 0,1 MPa, a creation of the model, that would be safe by changing the values of design variables is not possible. Specifically, the maximum value of shear stress on the glued areas between aluminium face sheets and honeycomb core is higher than the shear strength of the glue. Therefore, two new concepts are created. First for inner pressure 0,03 MPa and bigger width of aluminium face sheets 3,175 mm, second for inner pressure 0,02 MPa and same width of aluminium face sheets 0,635 mm. For both these concepts, an overall reserve factor is calculated. First, the value of an overall reserve factor is calculated deterministically. Secondly, the value of an overall reserve factor is calculated stochastically considering the variance of material properties of the honeycomb core ± 10 % by Monte Carlo simulation. An overall reserve factor of the concept with inner pressure 0,02 MPa is determined as 1,21. An overall reserve factor of the concept with inner pressure 0,03 MPa is determined as 1,20. The weight of the concept for inner pressure 0,03 MPa is though 4 times bigger than the weight of the concept for inner pressure 0,02 MPa. In the concept for inner pressure 0,02 MPa the maximum value of HMH stress in aluminium components is critical, stochastically considered material properties of the honeycomb core don’t have a significant influence on this value. In the concept for inner pressure 0,03 MPa the value of maximum shear stress on the glued areas between aluminium face sheets and the honeycomb core is critical, stochastically considered material properties of the honeycomb core have a significant influence on this value. In the concept for inner pressure 0,03 MPa an absolute error of overall reserve factor is 8 % (overall reserve factor calculated deterministically was 1,28) which is significant. Monte Carlo simulation is also used to find that the value of Poisson ratio XY of the honeycomb core doesn’t have statistically significant influence on all limit states. Value of the reserve factor of the honeycomb core is higher than 2 in both concepts. Monte Carlo simulation discovers that this value can be significantly lower. Using Tsai-Wu failure criteria the reserve factor in the concept for inner pressure 0,02 MPa is determined as 2,72 deterministically x 2,41 stochastically (absolute error 31 %), in the concept for inner pressure 0,03 MPa the reserve factor is determined as 6,85 deterministically x 6,17 stochastically (absolute error 68 %).

Wave propagation is a phenomenon resulting from high transient loadings where the duration of the load is in µ seconds range. In aerospace and space craft industries it is important to gain knowledge about the high frequency characteristics as it aids in structural health monitoring, wave transmission/attenuation for vibration and noise level reduction. The wave propagation problem can be approached by the conventional Finite Element Method(FEM); but at higher frequencies, the wavelengths being small, the size of the finite element is reduced to capture the response behavior accurately and thus increasing the number of equations to be solved, leading to high computational costs. On the other hand such problems are handled in the frequency domain using Fourier transforms and one such method is the Spectral Finite Element Method(SFEM). This method is introduced first by Doyle ,for isotropic case and later popularized in developing specific purpose elements for structural diagnostics for inhomogeneous materials, by Gopalakrishnan. The general approach in this method is that the partial differential wave equations are reduced to a set of ordinary differential equations(ODEs) by transforming these equations to another space(transformed domain, say Fourier domain). The reduced ODEs are usually solved exactly, the solution of which gives the dynamic shape functions. The interpolating functions used here are exact solution of the governing differential equations and hence, the exact elemental dynamic stiffness matrix is derived. Thus, in the absence of any discontinuities, one element is sufficient to model 1-D waveguide of any length. This elemental stiffness matrix can be assembled to obtain the global matrix as in FEM, but in the transformed space. Thus after obtaining the solution, the original domain responses are obtained using the inverse transform. Both the above mentioned manuscripts present the Fourier transform based spectral finite element (FSFE), which has the inherent aliasing problem that is persistent in the application of the Fourier series/Fourier transforms. This is alleviated by using an additional throw-off element and/or introducing slight damping in to the system. More recently wave let transform based spectral finite element(WSFE) has been formulated which alleviated the aliasing problem; but has a limitation in obtaining the frequency characteristics, like the group speeds are accurate only up-to certain fraction of the Nyquist(central frequency). Currently in this thesis Laplace transform based spectral finite elements(LSFE) are developed for sandwich members. The advantages and limitations of the use of different transforms in the spectral finite element framework is presented in detail in Chapter-1. Sandwich structures are used in the space craft industry due to higher stiffness to weight ratio. Many issues considered in the design and analysis of sandwich structures are discussed in the well known books(by Zenkert, Beitzer). Typically the main load bearing structures are modeled as beam sand plates. Plate structures with kh<1 is analysed based on the Kirch off plate theory/Classical Plate Theory(CPT) and when the bending wavelength is small compared to the plate thickness, the effect of shear deformation and rotary inertia needs to be included where, k is the wave number and h is the thickness of the plate. Many works regarding the wave propagation in sandwich structures has been published in the past literature for wave propagation in infinite sandwich structure and giving the complete description of dispersion relation with no restriction on frequency and wavelength. More recently exact analytical solution or simply supported sandwich plate has been derived. Also it is seen by comparison of dispersion curves obtained with exact (3D formulation of theory of elasticity) and simplified theories (2D formulation as generalization of Timoshenko theory) made on infinite domain and concluded that the simplified theory can be reliably used to assess the waveguide properties of sandwich plate in the frequency range of interest. In order to approach the problems with finite domain and their implementation in the use of general purpose code; finite degrees of freedom is enforced. The concept of displacement based theories provides the flexibility in assuming different kinematic deformations to approach these problems. Many of the displacement based theories incorporate the Equivalent Single Layer(ESL) approach and these can capture the global behavior with relative ease. Chapter-2 presents the Laplace spectral finite element for thick beams based on the First order Shear Deformation Theory (FSDT). Here the effect of different choices of the real part of the Laplace variable is demonstrated. It is shown that the real part of the Laplace variable acts as a numerical damping factor. The spectrum and dispersion relations are obtained and the use of these relations are demonstrated by an example. Here, for sandwich members based on FSDT, an appropriate choice of the correction factor ,which arises due to the inconsistency between the kinematic hypothesis and the desired accuracy is presented. Finally the response obtained by the use of the element is validated with experimental results. For high shock loading cases, the core flexibility induces local effects which are very predominant and this can lead to debonding of face sheets. The ESL theories mentioned above cannot capture these effects due to the computation of equivalent through the thickness section properties. Thus, higher order theories such as the layer-wise theories are required to capture the local behaviour. One such theory for sandwich panels is the Higher order Sandwich Plate theory (HSaPT). Here, the in-plane stress in the core has been neglected; but gives a good approximation for sandwich construction with soft cores. Including the axial inertial terms of the core will not yield constant shear stress distribution through the height of the core and hence more recently the Extended Higher order Sandwich Plate theory (EHSaPT) is proposed. The LSFE based on this theory has been formulated and is presented in Chapter-4. Detailed 3D orthotropic properties of typical sandwich construction is considered and the core compressibility effect of local behavior due to high shock loading is clearly brought out. As detailed local behavior is sought the degrees of freedom per element is high and the specific need for such theory as compared with the ESL theories is discussed. Chapter-4 presents the spectral finite element for plates based on FSDT. Here, multi-transform method is used to solve the partial differential equations of the plate. The effect of shear deformation is brought out in the spectrum and dispersion relations plots. Response results obtained by the formulated element is compared and validated with many different experimental results. Generally structures are built-up by connecting many different sub-structures. These connecting members, called joints play a very important role in the wave transmission/attenuation. Usually these joints are modeled as rigid joints; but in reality these are flexible and exhibits non-linear characteristics and offer high damping to the energy flow in the connected structures. Chapter-5 presents the attenuation and transmission of wave energy using the power flow approach for rigid joints for different configurations. Later, flexible spectral joint model is developed and the transmission/attenuation across the flexible joints is studied. The thesis ends with conclusion and highlighting futures cope based on the developments reported in this thesis.

The diploma thesis is divided into four main parts. The first part deals with the issue of waste management and its energy utilization in waste incineration. Processed harmful substances produced by incineration as well as emission limits. It deals with the types of catalytic carriers, their description, production and more detailed processing of ceramic foam VUKOPOR. The second part is devoted to technologies utilizing catalytic processes and a more detailed specification of the process. In the third part there is processed the calculation methods for pressure losses for individual types of carriers. Fourth, the most extensive part describes the INTEQII experimental device, its technology and construction, as well as the principle of the practical part, measuring of the pressure losses of carriers. It includes the evaluation of pressure losses in separate categories of carriers, such as the bed, HoneyComb and VUKOPOR ceramic foam. Subsequently, a comparison of the pressure losses of all carriers is made relative to the reference size of 1 m. The impact of bonding of VUKOPOR foam samples on the size of pressure losses is discussed. At the end of this section, the suitability of calculation methods for individual carriers is evaluated, depending on the experimental pressure loss data.

Die neuen Fertigungsmöglichkeiten durch die Additive Fertigung ermöglicht es nicht nur topologisch neuartige Bauteile herzustellen, sondern auch Bauteile mit inneren Strukturen zu versehen, die der Bauteilbelastung angepasst sind oder anderen Funktionen Freiräume bieten. Ein Ansatz ist es durchlässige innere Strukturen, z. B. Gitterstrukturen (auch als Lattice Strukturen bezeichnet) einzusetzen und durch die damit geschaffenen großen inneren Flächen eine effiziente Bauteilkühlung zu realisieren. Anhand eines einfachen Beispiels wird durch Simulation und Experiment die Wirkung einer solchen Kühlung gezeigt. Als weiteres Anwendungsbeispiel wird der Einsatz verschiedener innere Strukturen zur festigkeitsgerechten Gestaltung gewichtsoptimierter Bauteile vorgestellt. In beiden Fällen wird die Gestaltung mit Hilfe von FE-Modellen experimentell begleitet. / The new manufacturing possibilities offered by additive manufacturing not only allows to produce topologically novel components, but also enables to provide components with internal structures that are adapted to the component load or offer new possibilities for other functions. One approach is to use permeable internal structures, e. g. lattice structures, to realize efficient component cooling through the large internal surfaces created thereby. The effect of such a cooling is demonstrated by simulations and experiments using a simple example. As a further application example, the use of various internal structures for the strength-oriented design of weight-optimized components will be presented. In both cases the design is experimentally accompanied by FE models.

Das Ziel der vorliegenden Arbeit ist es, die technologischen Schritte für die Herstellung eines geschlossenzelligen metallischen Werkstoffs aus Stahl zu untersuchen. Das Eigenschaftsbild dieses neuartigen zellular aufgebauten Werkstoffs soll umfassend beschrieben und mit bereits existierenden Werkstoffkonzepten verglichen werden. Die Grundidee für die Herstellung einer geschlossenzelligen Struktur bildet die Kombination der Technologie zur Herstellung von metallischen Hohlkugeln und Hohlkugelstrukturen mit dem Herstellungsprozesses für Partikelschäume aus expandierbarem Polystyrol (EPS). Dazu ist es notwendig zunächst Grünkugeln herzustellen, wie bei der Technologie der Hohlkugeln, wobei jedoch ein treibmittelhaltiges EPS zum Einsatz kommt, das mit einer Beschichtung aus Metallpulver und Binder versehen wird. Anschließend sollen die Grünkugeln in einer geschlossenen Form zum expandieren gebracht werden. Dazu wird, wie bei der Partikelschaumtechnologie für Teile aus expandierbarem Polystyrol (EPS), Wasserdampf verwendet. Der durch den Temperaturanstieg und das Treibmittel der EPS-Partikel in den Grünkugeln entstehende Innendruck führt zum Aufschäumen und zur Expansion jeder Grünkugel. In der Folge ändert jede Kugel ihre Form so lange, bis sie mit allen Nachbarn einen flächigen, stabilen Kontakt bildet. Der auf diesem Weg erzeugte Grünkörper kann dann entformt und getrocknet werden. Wie bei der Hohlkugeltechnologie muss nachträglich das EPS durch die thermische Entbinderung entfernt und das Metallpulverskelett zu dichten Zellwänden gesintert werden. Für die Umsetzung dieser Idee ist es erforderlich, ein geeignetes Bindersystem für die Metallpulver-Binder-Beschichtung zu entwickeln, welches die Formänderung während des Schäumprozess unbeschädigt übersteht, sowie den Schäumprozess entsprechend anzupassen. Damit wäre die Möglichkeit gegeben, einen geschlossenzelligen metallischen Werkstoff herzustellen. Er würde die Vorteile einer geschlossenzelligen Struktur und die Materialvielfalt der pulvermetallurgischen Technologie der Hohlkugelherstellung (insbesondere in Bezug auf Stähle und andere höherschmelzende Werkstoffe) miteinander verbinden. In Vorversuchen wurde bereits gezeigt, dass die der Arbeit zugrunde liegenden Ideen realisierbar sind. Mit der vorliegenden Arbeit wird jedoch erstmals die vollständige Kette der technologischen Schritte hinsichtlich der relevanten Einflussgrößen untersucht, wobei großen Wert auf eine Umsetzbarkeit auch im industriellen Maßstab gelegt wird. Für den praktischen Einsatz des geschlossenzelligen Metallschaums sind seine mechanischen Kennwerte, sowie die sie beeinflussenden Herstellungsparameter von grundlegender Bedeutung. Dazu soll die Charakterisierung der zellularen Struktur und des Gefüges des Zellwandmaterials erfolgen. Hauptsächlich soll das Verformungsverhalten mit Hilfe von Druckversuchen untersucht werden. Die Festigkeitskennwerte, das Energieabsorptionsvermögen und die Steifigkeit des zellularen Werkstoffes sind weitere zu untersuchende Kenngrößen. Anhand der Ergebnisse wird eine Einordnung gegenüber dem Stand der Technik der Metallschäume vorgenommen.