Doping allows us to modify semiconductor materials for desired properties such as conductivity, bandgap, and / or lattice parameter. A small portion replacement of the highly mismatched isoelectronic dopants with the host atoms of a semiconductor can result in drastic variation of its structural, optical, and / or electronic properties. Here, the term "mismatch" describes the properties of atom size, ionicity, and / or electronegativity. This thesis presents the fabrication of two kinds of highly mismatched semiconductor alloys, i.e., Ge(1-x)Sn(x) and GaAs(1-x)N(x). The structural and optical properties of the prepared Ge(1-x)Sn(x) and GaAs(1-x)N(x) have been investigated. The results suggest an efficient above-solubility doping induced by non-equilibrium methods of ion implantation and ultrashort annealing. Pulsed laser melting promotes the regrowth of monocrystalline Ge(1-x)Sn(x), whereas flash lamp annealing brings about the formation of high quality GaAs(1-x)N(x) with room temperature photoluminescence. The bandgap modification of Ge(1-x)Sn(x) and GaAs(1-x)N(x) has been verified by optical measurements of spectroscopic ellipsometry and photoluminescence, respectively. In addition, effective defect engineering in GaAs has been achieved by flash lamp annealing, by which a quasi-temperature-stable photoluminescence at 1.3 µm has been obtained. / Dotierung ermöglicht es, die Eigenschaften von Halbleitermaterialien, wie Leitfähigkeit, aber auch Bandabstand und / oder Gitterkonstanten gezielt zu verändern. Wenn ein Halbleiter mit einer kleinen Menge unterschiedliche Fremdatome dotiert wird, kann dies in einer drastischen Modifikation der strukturellen, optischen und / oder elektronischen Eigenschaften resultieren. Der Begriff "unterschiedlich" bedeutet hier die Eigenschaften von Atomgröße, Ioniztät und / oder Elektronegativität. Diese Doktorarbeit beschreibt die Herstellung von zwei Arten von stark fehlangepassten Halbleiterlegierungen: Ge(1-x)Sn(x) und GaAs(1-x)N(x). Die strukturellen und optischen Eigenschaften von Ge(1-x)Sn(x) und GaAs(1-x)N(x) wurden untersucht. Die Ergebnisse deuten auf eine effiziente Dotierung oberhalb der Löslichkeit, induziert durch die Nicht-Gleichgewichtsverfahren Ionenimplantation und Ultrakurzzeit-Ausheilung. Gepulstes Laserschmelzen ermöglicht das Nachwachsen von monokristallinem Ge(1-x)Sn(x), während die Blitzlampenausheilung in der Bildung von GaAs(1-x)N(x) hoher Qualität mit Photolumineszenz bei Raumtemperatur resultiert. Die Änderung der Bandlücke von Ge(1-x)Sn(x) und GaAs(1-x)N(x) wurde durch die optischen Methoden der spektroskopischen Ellipsometrie und Photolumineszenz verifiziert. Darüber hinaus konnte in ausgeheiltem GaAs eine quasi-temperaturstabile Photolumineszenz bei 1,3 µm beobachtet werden.

Das selektive Laserschmelzen (SLM) erlaubt komplexe Geometrien zu fertigen, die, z. B. in Form von integrierten Kühlkanälen, bei Werkzeugen von großer Bedeutung sind. Aktuell werden in der Industrie hauptsächlich Aluminium-, Stahl-, Titan-, Nickel- und Kobaltchromlegierungen mit SLM verarbeitet. Für die additive Fertigung sind Stähle interessant, die besondere Eigenschaften aufweisen. So wird für Konstruktionsbauteile größtenteils korrosionsbeständiger Stahl verwendet. Ein weiteres Anwendungsfeld ist die Herstellung von Werkzeugen. Die besonderen Ansprüche an die mechanischen Eigenschaften, die für Werkzeuge benötigt werden, erfüllen die Werkzeugstähle. Durch die Neigung zu Rissbildung und Verzug resultiert eine herausfordernde Verarbeitbarkeit im SLM-Prozess. Werkzeugstähle wurden bisher auf Grund dieser Herausforderungen selten mit SLM prozessiert. Es besteht daher ein großer Bedarf die Zusammenhänge zwischen dem Prozess, der Verarbeitbarkeit, dem entstehenden Gefüge und den resultierenden Eigenschaften aufzuklären. In dieser Arbeit werden die Mikrostruktur und die mechanischen Eigenschaften dreier hochfester Stahllegierungen, verarbeitet im SLM-Prozess, untersucht. Eine Legierungsentwicklung, speziell auf die Anforderungen des SLM-Prozesses zugeschnitten, ermöglicht, das volle Potenzial des SLM-Prozesses auszuschöpfen. Die Verarbeitbarkeit der neu entwickelten Legierung im SLM-Prozess konnte erfolgreich gegenüber den Ausgangslegierungen verbessert werden.

Additive Manufacturing, and specifically powder bed fusion processes, have advanced rapidly in recent years. Selective Laser Melting in particular has been adopted in a variety of industries from biomedical to aerospace because of its capability to produce complex components with numerous alloys, including stainless steels, nickel superalloys, and titanium alloys. Post-processing is required to treat or solve metallurgical issues such as porosity, residual stresses, and surface roughness. Because of the geometric complexity of SLM produced parts, the reduction of surface roughness with conventional processing has proven especially challenging. In this Thesis, two processes, abrasive flow machining and ultrasonic shot peening, are evaluated as surface finishing processes for selective laser melted 316L. Results of these experiments indicate that AFM can reliably polish as-built internal passages to 1 µm Ra or better but is unsuitable for passages with rapidly expanding or contracting cross-sections. AFM can also polish relatively small passages, but lattice components may prove too complex for effective processing. USP cannot achieve such low surface roughness, but it is a versatile process with multiple advantages. Exterior surfaces were consistently processed to 1.7 to 2.5 µm Ra. Interior surfaces experienced only partial processing and demonstrated high geometric dependence. USP significantly hardened the surface, but steel media hardened the surface better than ceramic media did. Both AFM and USP are recommended processes for the surface finishing of SLM manufactured parts. Good engineering judgement is necessary to determine when to use these processes and how to design for post-processing.

Selective laser melting (SLM), is a type of additive manufacturing, which selectively melts a pre-spread layer of metal powders and produce a part by a layer-on-layer manner. SLM has demonstrated a great potential to reduce size and weight in hydraulic manifolds. However, a theoretical base is lacking since friction loss is unclear in a SLMed fluid passage. In this study, various fluid passages without supports, from diameters from 4 mm to 16 mm, were produced horizontally using SLM. The profile was measured using a 3D scanner and surface roughness was measured using a confocal laser scanning microscope. Friction factor was studied using simulation, experiments, and classical theory. The hydraulic diameter of the SLMed passages is smaller than the design diameter. Surface roughness is extremely high on the top part of the inner wall while the rest part is around 10 μm. Such trends are irrelevant of passage diameters. Friction factors in SLMed passage is much larger than those predicted using Moody theory, particularly in laminar flow. The transition from laminar flow to turbulent flow appears at a smaller Reynolds number with increased passage diameter. The influence of the profile overweighs that of the surface roughness on friction factor.

Selective laser melting (SLM), one type of metal additive manufacturing (AM) technology, uses a highintensity laser to selectively melt pre-spread metal powders by a layer-on-layer manner. The technology does not only provide a new way of manufacturing but also innovates product design methodology. In this study, a hydraulic block manifold is designed and manufactured using SLM. In this paper, we present an AM-driven design approach of hydraulic manifolds based on a case study. The target is not only to reduce weight but also to enhance fluid flow by optimizing fluid path to reduce pressure drop. The novelty of the research includes developing a design approach of hydraulic manifolds using SLM with a particular focus on fluid flow. Compared to the traditional hydraulic manifold, the weight of the new SLMed hydraulic manifold was reduced by more than 80%, size by half. Pressure loss of the main functional oil circuit was reduced by 31%, illustrating that the new hydraulic manifold design simultaneously achieves lightweight and high performance. This study contributes to providing theoretical guidance to the design of additively manufactured hydraulic components with high performance.

Selective laser melting (SLM) is an additive manufacturing technology. In this thesis, a heat-treatable Al-3.5Cu-1.5Mg-1Si alloy and related materials (composites and hybrid materials) have been successfully fabricated by selective laser melting and characterized in terms of densification, microstructure, heat treatment, mechanical properties as well as tribological and corrosion behavior. Firstly, the fully dense SLM Al-Cu-Mg-Si alloy was fabricated by SLM successfully. The alloy shows a higher yield strength than SLM Al-12Si alloy, and lower wear resistance and corrosion rate than commercial 2024 alloy before and after T6 heat treatment. Secondly, with the aim of designing new alloy compositions and to examine the phases and microstructures of SLM Al-Cu alloys and to correlate their microstructures with the observed mechanical properties, Al-xCu (x = 4.5, 6, 20, 33 and 40 wt. %) alloys have been synthesized in-situ by SLM from mixtures of Al-4.5Cu and Cu powders. The results indicate that the insufficient Cu solute diffusion during the layer-by-layer processing results in an inhomogeneous microstructure around the introduced Cu powders. With increasing Cu content, the Al2Cu phase in the alloys increases improving the strength of the material. These results show that powder mixtures can be used for the synthesis of SLM composites but the reaction between the matrix and the second-phase should be considered carefully. Thirdly, the TiB2/Al-Cu-Mg-Si composite was also designed and fabricated successfully by SLM and it shows a higher strength than the unreinforced SLM alloy before and after T6 heat treatment. Finally, an Al-12Si/Al-3.5Cu-1.5Mg-1Si hybrid with a good interface was fabricated successfully. This hybrid alloy shows a good yield strength and elongation at room temperature, indicating an effective potential of selective laser melting in the field of hybrid manufacturing.

Additiv tillverkning (AM) är en växande tillverkningsteknologi som har många lovande tekniska, ekologiska och ekonomiska aspekter. Selektiv lasersmältning (SLM) är den AM-metod som står i framkanten av den utveckling som sker inom teknologin. SLM har kapabiliteten att tillverka detaljer med jämförbart goda mekaniska egenskaper gentemot konventionella tillverkningsmetoder men drabbas av vanligt förekommande defekter som hämmar dess möjligheter att bli en mer använd bearbetningsmetod i tillverkningsindustrin. I detta arbete, som tar an formen av en State of the Art Rapport, presenteras SLM-metoden på en teknisk nivå, den jämförs med andra AM-metoder samt med konventionell tillverkning, flera metaller och legeringar som finns tillgängliga för bearbetning presenteras och dess senaste utvecklingar samt framtid presenteras och diskuteras. / Additive manufacturing (AM) is a growing manufacturing technology which has many promising technical, ecological, and economical aspects. Selective Laser Melting (SLM) is the AM-method which stands on the forefront of the development which is taking place in this technology. SLM has the capability to produce components with relatively good mechanical characteristics as compared to conventional manufacturing methods. However, the method is suffering from common defects which inhibits its chances to become a more widely-used method in the manufacturing industry. In this work, which takes on the form of a State of the Art Report, the SLM-method is presented on a technical level. It is then put in comparison to other AM-methods and conventional manufacturing as a whole. Some of the metals and alloys available for SLM are listed. The latest developments in SLM are presented and lastly, the future developments of SLM is discussed.

Additive Manufacturing (AM) processes are gaining prominence in industry as they can build parts to near-net-shape with minimal postprocessing. Metal laser AM techniques, such as Selective Laser Melting (SLM), offer rapid cooling rates on the order of 10^5-10^6 K/s. This is due to a highly-focused laser heating a microscopic volume in an otherwise lower-temperature environment. Hence, metal laser AM can manufacture novel, out-of-equilibrium microstructures that cannot be produced in near-net-shapes with other processes. It is desirable to optimize feedstocks for metal AM processes to leverage their advantages. One option of optimizing feedstocks is through in-situ alloying, or by using elemental powders. Elemental powders homogenize over the course of multiple laser passes, or intrinsic heat treatments. However, rapid cooling rates prevent the homogenization of a layer when first printed. To investigate the homogenization process, this thesis used synchrotron X-ray Diffraction (sXRD) to track the phase transformations during the SLM of a 14-layer single wall (single-hatch, multilayered) of Ti-1Al-8V-5Fe (Ti-185) from elemental Ti, Fe and an alloyed AlV powders, capturing frames at 250 Hz. Infrared imaging was performed simultaneously on the surface at 1603.5 Hz to observe the temperature changes at the surface. Post-mortem electron microscopy was performed on cross-sections of the wall perpendicular to the scanning direction to observe the changes in the microstructure with respect to the build direction. Specifically, Electron Dispersive X-Ray Spectroscopy and Electron Backscatter Diffraction were performed to observe the alloying elemental distribution and microstructure of the wall with respect to the build direction. The research performed found that in the melted zone, phase transformation times below 50 ms yielded a partially-alloyed microstructure, with regions concentrated and dilute in alloying elements. Partial mixing was diffusion-induced by laser beam heat and the exothermic heat of mixing of Ti-185 from its constituent elements. Further diffusion during reheating cycles yielded an alloyed microstructure. / Thesis / Master of Applied Science (MASc)

It’s well known that MnAl(C) material consists of a metastable phase (τ) with promising ferromagnetic properties, produced either by controlled cooling from the high-temperature hexagonal ε-phase or rapid cooling that freezes the ε-phase followed by low-temperature annealing. Due to the high cooling rates involved, additive manufacturing (AM) especially selective laser melting (SLM), has been identified as a possible method to retain the high-temperature ε-phase, hence containing a potential capacity to produce permanent magnets upon low-temperature annealing. Moreover, the competency of additive manufacturing to address manufacturing design complexity, material scarcity and tailored properties, yields a great opportunity to produce permanent magnets with suitable magnetic properties for complex applications. This work provides a systematic study on three main aspects; development of printing parameters for improved relative density of as-printed MnAl(C) samples; investigation of the influence of scanning strategies on the crystallographic texture of as-printed and annealed samples; investigation of the influence of annealing time and temperature on τ-phase purity and magnetic properties. It was found that laser remelting (multiple laser exposure) combined with specific scanning strategies is a promising path to enhance the relative density of as-printed samples. Some specific scanning strategies were found to be capable of retaining relatively strong crystallographic textured ε-phase in as-printed samples. Following the annealing process for ε→τ transformation, only a partial transformation of crystallographic texture was observed. Characterization of annealed samples through XRD (x-ray diffraction) and phase fractions calculations through Rietveld refinement reveals that relatively short annealing times and low temperatures result in incomplete ε→τ transformation. In addition, longer annealing times and higher temperatures surpass the complete ε→τ transformation and lead to the formation of equilibrium phases subsequently reducing the magnetic performance. Furthermore, the experimental findings demonstrated a pronounced influence of higher carbon content in the powder, resulting in improved magnetic properties.

Additive manufacturing (AM) is an emerging and interesting technology that enables some of theproduct development projects (PDPs) to produce products that have mechanical and tribologicalproperties comparable to products that are conventionally manufactured. Selective laser melting(SLM) is an additive manufacturing technology that is predominantly used for the production of metalbased components (i.e. it could be pure metal, alloys, and metal matrix composites). This workevaluates and ranks two different steel grades produced with SLM technology in tribological andcutting tool applications at AB Sandvik Coromant. The two steel grades used in this work were Cofree maraging steel alloy and Co-free W360 AMPO alloy. Both the grades are Cobalt free, hencedeveloped as a sustainable alternative for the future. The W360 AMPO alloy is a hot-work tool steelwith high temperature wear resistance and heat resistance. The work covers the characterization ofmicrostructure and chemical composition, mechanical properties, and tribological properties toevaluate the performance of the tool steel grades when used as tool bodies in drilling applications.The microstructure and chemical composition of the additive manufactured and heat-treated tool steelswere analyzed using SEM and EDS. The mechanical properties were evaluated using micro-Vickersindentation and scratch testing while the tribological properties were evaluated using pin-on-disctesting where counter material used was quenched and tempered steel. The application test included asimulated chip wear test using chip breakers (CB’s) and an actual drilling test, both performed at ABSandvik Coromant. To study the effect of surface topography on the adhesion tendency, the simulatedchip wear test was performed on both milled and grounded chip breaker (CB) samples. The drillingtest was done with three different test-set ups; function test, 30° inclined exit, and forced tool life test.The cellular microstructure was observed on Co-free maraging steel alloy sample, while themicrostructure was tempered martensite in W360 AMPO alloy. Elemental analysis revealed thechemical composition of the two steel grades. The measured hardness for both the samples Co-freemaraging steel alloy and W360 AMPO was found to be within the specification of demands (50-52HRC), although the hardness of W360 AMPO was a bit higher than Co-free maraging steel alloy. Theresults of the pin-on-disc tests showed that the wear resistance of the W360 AMPO alloy issignificantly higher than that of the Co-free maraging steel alloy, the tribo-system used was similarwhen compared to the actual application. Also, after analyzing the pin made up of quenched andtempered steel 34CrNiMo6 (SS2541) it can be seen that due to the W360 AMPO sample the volumeloss of the pin is almost 4 times when compared to Co-free maraging steel alloy. The result from thesimulated chip wear test showed that W360 AMPO has better wear characteristics. Adhesion ofworkpiece material (SS2541) was observed on both samples. In the simulated chip wear test, thesurface topography effect was studied by performing a test on milled and grounded CBs. GroundedCBs showed less adhesion tendency compared with milled CBs on both samples but the wearcharacteristics were similar irrespective of the surface roughness. The result from the drilling testshowed wear scar was predominant on a drill with Co-free maraging steel alloy and a drill with W360AMPO alloy was intact. Future possible investigations proposed after findings from experimentalresults may lead to future work.