Stuttgart, Univ., Diss., 2007.

Orbits of charged particles under the effect of a magnetic field are mathematically described by magnetic geodesics. They appear as solutions to a system of (nonlinear) ordinary differential equations of second order. But we are only interested in periodic solutions. To this end, we study the corresponding system of (nonlinear) parabolic equations for closed magnetic geodesics and, as a main result, eventually prove the existence of long time solutions. As generalization one can consider a system of elliptic nonlinear partial differential equations whose solutions describe the orbits of closed p-branes under the effect of a "generalized physical force". For the corresponding evolution equation, which is a system of parabolic nonlinear partial differential equations associated to the elliptic PDE, we can establish existence of short time solutions. / Bahnen von geladenen Teilchen, die sich unter dem Einfluss eines Magnetfeldes bewegen, werden in der Mathematik durch magnetische Geodäten beschrieben. Sie ergeben sich als Lösungen eines Systems (nichtlinearer) gewöhnlicher Differentialgleichungen zweiter Ordnung. Wir interessieren uns ausschließich für periodische Lösungen. Dazu studieren wir das zugehörige System (nichtlinearer) parabolischer Differentialgleichungen für geschlossene magnetische Geodäten. Als Hauptresultat beweisen wir die Existenz von Langzeitlösungen. Verallgemeinernd betrachten wir noch ein System von elliptischen nichtlinearen partiellen Differentialgleichungen, dessen Lösungen die Orbiten von geschlossenen p-Branen unter dem Einfluss einer verallgemeinerten physikalischen Kraft beschreiben. Für die entsprechende Evolutionsgleichung, welche ein System von parabolischen nichtlinearen partiellen Differentialgleichungen ist, das dem elliptischen Problem zugeordnet ist, können wir die Existenz von Kurzzeitlösungen beweisen.

The L10 FePt phase belongs to the most promising hard ferromagnetic materials for high density recording media. The main challenges for thin FePt films are: (i) to lower the process temperature for the transition from the soft magnetic A1 to the hard magnetic L10 phase, (ii) to realize c-axes preferential oriented layers independently from the substrate nature and (iii) to control layer morphology supporting the formation of FePt - L10 self-organized isolated nanoislands towards an increase of the signal-to-noise ratio. In this study, dc magnetron sputtered FePt thin films on amorphous substrates were inve-stigated. The work is focalized on the correlation between structural and magnetic properties with respect to the influence of deposition parameters like growth mode (co-sputtering vs. layer – by - layer) and the variation of the deposition gas (Ar, Xe) or pressure (0.3 - 3 Pa). In low-pressure Ar discharges, high energetic particle impacts support vacancies formation during layer growth lowering the phase transition temperature to (320 +/- 20)°C. By reducing the particle kinetic energy in Xe discharges, highly (001) preferential oriented L10 - FePt films were obtained on a-SiO2 after vacuum annealing. L10 - FePt nano-island formation was supported by the introduction of an Ag matrix, or by random ballistic aggregation and atomic self shadowing realized by FePt depositions at very high pressure (3 Pa). The high coercivity (1.5 T) of granular, magnetic isotropic FePt layers, deposited in Ar discharges, was measured with SQUID magnetometer hysteresis loops. For non-granular films with (001) preferential orientation the coercivity decreased (0.6 T) together with an enhancement of the out-of- plane anisotropy. Nanoislands show a coercive field close to the values obtained for granular layers but exhibit an in-plane easy axis due to shape anisotropy effects. An extensive study with different synchrotron X-ray scattering techniques, mainly performed at the ESRF, BM-20 (ROBL-Beamline), pointed out the importance of in-situ investigations to clearly understand the kinetic mechanism of the A1 to L10 transition and ordering and to control FePt nanoclusters evolution.

The L10 FePt phase belongs to the most promising hard ferromagnetic materials for high density recording media. The main challenges for thin FePt films are: (i) to lower the process temperature for the transition from the soft magnetic A1 to the hard magnetic L10 phase, (ii) to realize c-axes preferential oriented layers independently from the substrate nature and (iii) to control layer morphology supporting the formation of FePt - L10 self-organized isolated nanoislands towards an increase of the signal-to-noise ratio. In this study, dc magnetron sputtered FePt thin films on amorphous substrates were inve-stigated. The work is focalized on the correlation between structural and magnetic properties with respect to the influence of deposition parameters like growth mode (co-sputtering vs. layer – by - layer) and the variation of the deposition gas (Ar, Xe) or pressure (0.3 - 3 Pa). In low-pressure Ar discharges, high energetic particle impacts support vacancies formation during layer growth lowering the phase transition temperature to (320 +/- 20)°C. By reducing the particle kinetic energy in Xe discharges, highly (001) preferential oriented L10 - FePt films were obtained on a-SiO2 after vacuum annealing. L10 - FePt nano-island formation was supported by the introduction of an Ag matrix, or by random ballistic aggregation and atomic self shadowing realized by FePt depositions at very high pressure (3 Pa). The high coercivity (1.5 T) of granular, magnetic isotropic FePt layers, deposited in Ar discharges, was measured with SQUID magnetometer hysteresis loops. For non-granular films with (001) preferential orientation the coercivity decreased (0.6 T) together with an enhancement of the out-of- plane anisotropy. Nanoislands show a coercive field close to the values obtained for granular layers but exhibit an in-plane easy axis due to shape anisotropy effects. An extensive study with different synchrotron X-ray scattering techniques, mainly performed at the ESRF, BM-20 (ROBL-Beamline), pointed out the importance of in-situ investigations to clearly understand the kinetic mechanism of the A1 to L10 transition and ordering and to control FePt nanoclusters evolution.

ZnO-based semiconductors were studied by Raman spectroscopy and complementary methods (e.g. XRD, EPS) with focus on semimagnetic alloying with transition metal ions, doping (especially p-type doping with nitrogen as acceptor), and nanostructures (especially wet-chemically synthesized nanoparticles). / ZnO-basierte Halbleiter wurden mittels Ramanspektroskopie und komplementärer Methoden (z.B. XRD, EPS) untersucht mit den Schwerpunkten semimagnetische Legierung mit Übergangsmetallen, Dotierung (vor allem p-Dotierung mit Stickstoff als Akzeptor) und Nanostrukturen (vor allem nass-chemisch hergestellte Nanopartikel).

Polymerverkapselte magnetische Nanopartikel versprechen, in der Zukunft sehr erfolgreich bei Anwendungen in der Biologie und der Medizin eingesetzt werden zu können z. B. in der Krebstherapie und als Kontrastmittel bei der magnetischen Kernspinresonanztomographie. Diese Arbeit zeigt, dass durch die interdisziplinäre Kombination verschiedener Techniken Herstellungsverfahren und Eigenschaften solcher Partikel verbessert werden können. <br /> <br /> Unter Miniemulsionen versteht man wässrige Dispersionen relativ stabiler Öltröpfchen, zwischen 30 und 50 nm Größe. Ein Nanometer (nm) ist der 1.000.000.000ste Teil eines Meters. Ein Haar ist ungefähr 60.000 Nanometer breit.<br /> <br /> Hergestellt werden Miniemulsionen durch Scherung eines Systems bestehend aus Öl, Wasser, Tensid (Seife) und einer weiteren Komponente, dem Hydrophob, das die Tröpfchen stabilisieren soll. Die Polymerisation von Miniemulsionen ermöglicht die Verkapselung anorganischer Materialen z. B. magnetischer Teilchen oder Gadolinium-haltiger Komponenten. Zu Optimierung des Verkapselung, ist es notwendig, die richtige Menge eines geeigneten Tensids zu finden. <br /> <br /> Die magnetischen polymerverkapselten Nanopartikel, die in einer wässrigen Trägerflüssigkeit dispergiert sind, zeigen in Abhängigkeit von Partikelgröße, Zusammensetzung, elektronischer Beschaffenheit, etc. ein sogenanntes superpara- oder paramagnetisches Verhalten. Superpara- oder paramagnetisches Verhalten bedeutet, dass die Flüssigkeiten in Anwesenheit äußerer Magnetfeldern ihre Fließfähigkeit beibehalten. Wenn das Magnetfeld entfernt wird, haben sie keine Erinnerung mehr daran, unter dem Einfluss eines Magnetfeldes gestanden zu haben, d. h., dass sie nach Abschalten des Magnetfeldes selbst nicht mehr magnetisch sind. <br /> <br /> Die Vorteile des Miniemulsionsverfahrens sind der hohe Gehalt und die homogene Verteilung magnetischer Teilchen in den einzelnen Nanopartikeln. Außerdem ermöglicht dieses Verfahren nanostrukturierte Kompositpartikel herzustellen, wie z. B polymerverkapselte Nanopartikel mit Nanoschichten bestehend aus magnetischen Molekülen. / Combining the magnetic properties of a given material with the tremendous advantages of colloids can exponentially increase the advantages of both systems. This thesis deals with the field of magnetic nanotechnology. Thus, the design and characterization of new magnetic colloids with fascinating properties compared with the bulk materials is presented. <br /> <br /> Ferrofluids are referred to either as water or organic stable dispersions of superparamagnetic nanoparticles which respond to the application of an external magnetic field but lose their magnetization in the absence of a magnetic field. <br /> <br /> In the first part of this thesis, a three-step synthesis for the fabrication of a novel water-based ferrofluid is presented. The encapsulation of high amounts of magnetite into polystyrene particles can efficiently be achieved by a new process including two miniemulsion processes. The ferrofluids consist of novel magnetite polystyrene nanoparticles dispersed in water which are obtained by three-step process including coprecipitation of magnetite, its hydrophobization and further surfactant coating to enable the redispersion in water and the posterior encapsulation into polystyrene by miniemulsion polymerization. It is a desire to take advantage of a potential thermodynamic control for the design of nanoparticles, and the concept of &quot;nanoreactors&quot; where the essential ingredients for the formation of the nanoparticles are already in the beginning. The formulation and application of polymer particles and hybrid particles composed of polymeric and magnetic material is of high interest for biomedical applications. Ferrofluids can for instance be used in medicine for cancer therapy and magnetic resonance imaging.<br /> <br /> Superparamagnetic or paramagnetic colloids containing iron or gadolinium are also used as magnetic resonance imaging contrast agent, for example as a important tool in the diagnosis of cancer, since they enhance the relaxation of the water of the neighbouring zones. New nanostructured composites by the thermal decomposition of iron pentacarbonyl in the monomer phase and thereafter the formation of paramagnetic nanocomposites by miniemulsion polymerization are discussed in the second part of this thesis. In order to obtain the confined paramagnetic nanocomposites a two-step process was used. In the first step, the thermal decomposition of the iron pentacarbonyl was obtained in the monomer phase using oleic acid as stabilizer. In the second step, this iron-containing monomer dispersion was used for making a miniemulsion polymerization thereof. <br /> <br /> The addition of lanthanide complexes to ester-containing monomers such as butyl acrylate and subsequent polymerization leading to the spontaneous formation of highly organized layered nanocomposites is presented in the final part of this thesis. By an one-step miniemulsion process, the formation of a lamellar structure within the polymer nanoparticles is achieved. The magnetization and the NMR relaxation measurements have shown these new layered nanocomposites to be very apt for application as contrast agent in magnetic resonance imaging.

We derive the amplitude expansion for a phase-field-crystal (APFC) model that captures the basic physics of magneto-structural interactions. The symmetry breaking due to magnetization is demonstrated, and the characterization of the magnetic anisotropy for a bcc crystal is provided. This model enables a convenient coarse-grained description of crystalline structures, in particular when considering the features of the APFC model combined with numerical methods featuring inhomogeneous spatial resolution. This is shown by addressing the shrinkage of a spherical grainwithin amatrix, chosen as a prototypical system to demonstrate the influence of different magnetizations. These simulations serve as a proof of concept for the modeling of manipulation of dislocation networks and microstructures in ferromagnetic materials within the APFC model.

No description available.

Inductive power transfer (IPT) systems with tolerance to the lateral misalignment are advantageous for enhancing the transmitted power, usability and security of the system. In this thesis, a misalignment tolerant multi-coil design is proposed to supply stationary and dynamic battery-free wireless devices. A compact architecture composed of individually switchable 3 layers of printed coils arranged with overlap for excellent surface coverage. A hybrid architecture based on three compact AC supply modules reduces the supply circuit complexity on the sending Seite 2 von 4side. It detects the position of the receiver coil quickly, controls the activation of the transmitting coils and estimates the next receiver position. The proposed architecture reduces the circuit footprint by a factor of 62% compared to common architectures. A transmitter coil activation strategy is proposed based on the detection of the transmitting coils voltage and communication between sending side and receiving side to detect devices to supply nature and position and to differentiate them from other conductive objects in the sending area to the supplying security. The experimental results prove that the proposed architecture has a good performance for different trajectories when the device speed does not exceed 15 mm/s. Besides, the maximum detection time for the initial device position is about 1.6 s. The maximal time interval to check the transmitter coils is around 0.7 s.:1. INTRODUCTION 2. THEORETICAL BACKGROUND 3. STATE OF THE ART OF MULTI-COIL IPT SYSTEMS 4. NOVEL DESIGN OF A MULTI-COIL IPT SYSTEM 5. MULTI-COIL ACTIVATION PROCEDURE 6. EXPERIMENTAL INVESTIGATIONS 7. CONCLUSION AND OUTLOOK / Induktive Energieübertragungssysteme (IPT) mit Toleranz gegenüber seitlichem Versatz sind vorteilhaft, um die übertragene Leistung, die Nutzbarkeit und die Sicherheit des Systems zu verbessern. In dieser Arbeit wird ein versatztolerantes Multispulen-Design vorgeschlagen, um stationäre und dynamische batterielose drahtlose Geräte zu versorgen. Die kompakte Architektur besteht aus 3 einzeln schaltbaren Schichten gedruckter Spulen, die überlappend angeordnet sind, um eine hervorragende Oberflächenabdeckung zu gewährleisten. Eine hybride Architektur, die auf drei kompakten AC-Versorgungsmodulen basiert, reduziert die Komplexität der Versorgungsschaltung auf der Senderseite. Sie erkennt die Position der Empfängerspule schnell, steuert die Aktivierung der Sendespulen und schätzt die nächste Empfängerposition. Die vorgeschlagene Architektur reduziert den Platzbedarf der Schaltung um einen Faktor von 62 % im Vergleich zu herkömmlichen Architekturen. Es wird eine Aktivierungsstrategie für die Sendespulen vorgeschlagen, die auf der Erkennung der Spannung der Sendespulen und der Kommunikation zwischen Sende- und Empfangsseite basiert, um die Art und Position der zu versorgenden Geräte zu erkennen und sie von anderen leitfähigen Objekten im Sendebereich zu unterscheiden. Die experimentellen Ergebnisse zeigen, dass die vorgeschlagene Architektur eine gute Leistung für verschiedene Trajektorien hat, wenn die Geschwindigkeit der Geräte 15 mm/s nicht überschreitet. Außerdem beträgt die maximale Erkennungszeit für die anfängliche Geräteposition etwa 1,6 s. Das maximale Zeitintervall für die Überprüfung der Senderspulen beträgt etwa 0,7 s.:1. INTRODUCTION 2. THEORETICAL BACKGROUND 3. STATE OF THE ART OF MULTI-COIL IPT SYSTEMS 4. NOVEL DESIGN OF A MULTI-COIL IPT SYSTEM 5. MULTI-COIL ACTIVATION PROCEDURE 6. EXPERIMENTAL INVESTIGATIONS 7. CONCLUSION AND OUTLOOK