The present dissertation describes part of the efforts directed towards the development of computational tools to support process modeling. This work is also a further development of the Thermoslag software developed in the Division of Materials Process Science, KTH. The essential parts of the thesis are a) development of a semi-empirical model for the estimation of the molar volumes/densities of multicomponent slags with a view to incorporate the same in the model for viscosities and b) further development of the viscosity model for application towards fluorid- containing slags, as for example, mould flux slags. The model for the estimation of molar volume is based on a correlation between the relative integral molar volume of a slag system and the relative integral molar enthalpies of mixing of the same system. The integral molar enthalpies of the relevant systems could be evaluated from the Gibbs energy data available in the Thermoslag software. The binary parameters were evaluated from experimental measurements of the molar volumes. Satisfactory correlations were obtained in the case of the binary silicate and aluminate systems. The model was extended to ternary and multi component systems by computing the molar volumes using the binary parameters. The model predictions showed agreements with the molar volume data available in literature. The model was used to estimate the molar volumes of industrial slags as well as to trace the trends in molar volume due to compositional variations. The advantage of the present approach is that it would enable prediction of molar volumes of slags that are compatible with the thermodynamic data available. With a view to extend the existing model for viscosities to F--containing slags, the viscosities of mould flux slags for continues casting in steel production have been investigated in the present work. The measurements were carried out utilizing the rotating cylinder method. Seven mould fluxes used in the Swedish steel industry and the impact of Al2O3 pick up by mould flux slags on viscosities were included in the study. The results showed that even relatively small additions of Al2O3 are related with a significant increase in viscosity / QC 20101123

M. Tech. (Department of Metallurgical Engineering, Faculty of Engineering and Technology), Vaal University of Technology. / During steel production, a large quantity of waste residue commonly known as slag is produced with a reasonable amount of metals such as calcium and magnesium. Iron and steel slags have various economically viable applications such as fertiliser production, cement production, road construction, land fill and soil reclamation. However, other applications respond to the issue of controlling and degrading high levels of anthropogenic carbon dioxide (CO2) gas emissions by carbonating calcium and magnesium leach solutions from iron and steel slags. One such technological method is the extraction of calcium by means of leaching from iron and steel slag whereby CO2 sequestration is a long-term goal. In contrast, calcium and magnesium leach solutions can produce precipitated carbonates for various uses when carbonated. In addition, it is a crucial step to study the leaching parameters and reliable solvents for the dissolution of calcium and magnesium owing to their contents in iron and steel slags. The aim of this research project was to determine the physico-chemical factors affecting leaching of calcium from blast furnace slag and thereby improve the extent and kinetics of calcium extraction. The chemical and mineralogical study by X-ray fluorescence (XRF) and X-ray diffraction (XRD) respectively, has shown that the blast furnace slag sample under study contained calcium in the form of aluminoakermanite ((Ca,Na)2(Al,Mg,Fe2+)). The minerals identified through XRD are classified as silicates with the host mineral being calcium in recoverable quantities. The initial XRF analysis showed that the slag contained 23.47% Ca, 5.21% Mg and 1.24% Fe with the rest being minor elements. The slag was received at a particle size of 20 mm. Size reduction was conducted in a dry rod mill process to produce a size of 80% -75μm. Particle size distribution was analysed by a simple laboratory sieving method. The leaching tests were conducted in an incubated orbital shaker by applying the one-factor-at-a-time method for a two-hour leaching test. Reaction temperature was controlled at 30, 50, 70 and 100˚C. Ionic strength varied at 0.5, 1.0, 1.5 and 2.0 molar (M). In addition, the solid/liquid ratio was observed in the range 200, 300, 400 and 600 gram/Litre (g/L). Acetic acid (CH3COOH), ammonium sulphate ((NH4)2SO4) and ammonium chloride (NH4Cl) were tested individually as lixiviants under varying temperatures, ionic strengths and solid/liquid ratio. The results showed that extraction of calcium from ironmaking slag by leaching is feasible. 100% Ca was extracted using CH3COOH at 100˚C, 0.5 M, 200 g/L and 120 minutes. As the reaction temperature was increased from 50˚C up to 100˚C, silica gelling was observed, which hindered filtration of a leach liquor from a residue. Silica gelling did not compromise calcium recovery. The increase in lixiviant ionic strength and solid-liquid ratio did not influence calcium recovery. The role of anions during leaching by using ammonium sulphate, ammonium chloride and acetic acid as lixiviants was identified. Sulphate ions were found to have the least influence in the increase in calcium recovery. Acetate ions have a significant role on dissolution of calcium as well as chloride ions. Consequently, the findings showed that temperature is the critical operating parameter that yielded exceptionally high calcium extraction percentages. CH3COOH yielded 80%-90% of calcium extracted under high reaction temperatures. The kinetic data for the effect of reaction temperature leaching data fitted one shrinking core model equation, which described diffusion-controlled leaching reactions. The diffusion controlled by a product layer model was fitted and the activation energy were calculated as 19.4930 kJ/mol for NH4Cl solvent. (NH4)2SO4 and CH3COOH did not fit into any model because of undefined kinetic data and formation of gelatinous silica layer during leaching process. The Arrhenius equation, confirmed that the leaching reaction by NH4Cl solvent fitted diffusion-controlled mechanism.

This essay examines how the meaning of an absurd play may be affected by how the reader understands the text. To address this problem I have turned to Wolfgang Isers theory of reception. Primarily I have taken on that the creation of meaning comes about when the reader fills in blanks in the text. I have also used Martin Esslins work on the theater of the absurd. I have mainly studied his research on Harold Pinter. Based on these two theories I have suggested a interpretation model that focuses on the interaction between reader and text. The interpretation model contains how the reader analyses blanks through observing the wandering view alternatively understanding the implied reader. The interpretation model also discusses how the reader can fill in blanks by using the relationship between character and environment, the final junction, turning points and uncertainties. I tested this interpretation model on Harold Pinters play A kind of Alaska. In my ideation of the play I realized it was about the loneliness of ageing and changing. I used these results to evaluate the usefulness of the interpretation model. / Denna uppsats undersöker hur läsarens uppfattning av en absurdistisk pjäs påverkar dess betydelse. För att angripa det här problemet har jag dels vänt mig till Wolfgang Isers receptions teori. Jag har främst tagit fasta på hur meningskapande sker när läsaren fyller i luckor i texten. Jag har även vänt mig till Martin Esslins forskning om den absurdistiska teatern. Där har jag främst studerat hans undersökning av Harold Pinters dramatik. Utifrån dess två teoretiska ingångar la jag fram ett förslag till en tolkningsmodell som utgår från läsarens interaktion med texten. Tolkningsmodellen innehåller bland annat hur man kan analysera luckor utifrån läsarens rörliga perspektiv alternativt utifrån en underförstådd läsare. Tolkningsmodellen tar också upp hur läsaren kan fylla i luckor genom att använda sig av karaktärens relation till rummet, knutpunkter, vändpunkter och osäkerheter. Jag har testat tolkningsmodellen på Harold Pinters pjäs A kind of Alaska. I min ideation av pjäsen kom jag fram till att den handlade om ensamheten i åldrande och förändring. Jag använde resultatet av analysen för att utvärdera tolkningsmodellens användbarhet.

Made available in DSpace on 2014-10-09T12:52:10Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:01:02Z (GMT). No. of bitstreams: 0 / Dissertacao (Mestrado) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP

Generation of wastes in the form of liquid, solid or gas is inevitable in any industry.Industrial Solid Waste is the waste that is generated from an industrial or manufacturing process and includes the waste generated from non-manufacturing activities as well.Most of these wastes fall under the category of Ashes, Slagsor Sludges. For the present work, three types of secondary lead slag, two types of granulated blast furnace slag (GBS) or iron slag and four types of steel slags were procured and studied.An elaborate study on various characteristics of the slags has been performed. Based on the results, all the possible applications for the individual slags are considered. The performance of the secondary lead slag as an embankment material was analyzed. The slope stability for various conditionswas analyzed using Geo5 and experimentally determined strength parameters. It was found that the material can be used safely for embankment constructions.The CBR values were very good in the range for both GBS and steel slag,thus repeated load triaxial test are done to determine the resilient modulus. k1-k3model was adopted and the regression coefficients were determined. Based on the results the pavement design is done using KENPAVE software. An exercise has been performed to determine the quantity of the conventional material that could be saved, considering the type and size of the pavement. For the aggregate sized steel slag, the tests were done to find the suitability of the material for various applications like, as railway ballast, concrete aggregate, gabion and rip rap stones. And the tests result shows the material to be suitable for these applications and is expected to perform well. Study on morphological parameters reveals that the size and gradation of any material plays an important role in its mechanical behavior, however in the case of slags, this could be tailor made by using appropriate crushers, as per the requirements.

Made available in DSpace on 2014-10-09T12:52:10Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:01:02Z (GMT). No. of bitstreams: 0 / O presente trabalho estuda a viabilidade de utilização da escória de alumínio, que é um rejeito da indústria recicladora de alumínio, atualmente sem valor agregado, como elemento integrante na fabricação de argila expandida. A argila expandida é produzida a partir de argilas que produzam expansão piroplástica, que são utilizadas como agregado leve na fabricação de concreto estrutural e também como artigo decorativo em jardins. Inicialmente foram feitas análises dos materiais de partida, como difração de raios X, microscopia eletrônica de varredura, fluorescência de raios X, análise granulométrica, análise termogravimétrica e análise térmica diferencial da argila. Foram feitas incorporações do rejeito junto à massa de argila, na proporção de 5%, 10%, 15% e 20% em massa. As formulações estudadas foram analisadas quanto à expansão linear, variação de massa, massa específica aparente e absorção de água. Foram feitos também ensaios de lixiviação e solubilização. Os principais resultados obtidos mostraram que é viável o uso da escória de alumínio até aproximadamente 5% em massa, para a produção da argila expandida, com características aceitáveis e dentro das normas vigentes. Palavraschave: reciclagem, escória de alumínio, argila expandida, agregado leve. / Dissertacao (Mestrado) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP

The purpose of this study is to examine the implementation of the Convention on the elimination of all forms of discrimination against women, CEDAW, in Uppsala local council and county council. The aim is to examine how the respondents, in their daily work, understand and implement the convention as well as how they consider the prerequisites for a successful implementation. The study was conducted using qualitative interviews with three civil servants and four politicians. The theoretical approach was implementation theory whose concepts willingness, comprehension and capability were used as tools for the analysis. The results portray CEDAW as a well-known treaty amongst the respondents but at the same time absent in local politics and everyday work. The convention is perceived as an abstract and ideological document which reveals the respondents’ insufficient knowledge about CEDAW as a human rights treaty and the state´s obligation to eliminate discrimination against women. The results also indicate that unclear instructions and responsibility distribution as well as lack of resources, such as time and knowledge, obstruct successful implementation of CEDAW. In conclusion, gender equality is neither a prioritised issue in Uppsala local council and county council and nor seen as a human right.

Η επεξεργασία των νικελιούχων λατεριτικών μεταλλευμάτων της χώρας μας για την παραγωγή σιδηρονικέλιου στη Λάρυμνα συνοδεύεται με την εκπομπή 200000t/y λεπτομερούς σκόνης που συλλέγεται στα συστήματα αντιρρύπανσης των περιστροφικών κάμινων (Π/Κ), μέσης περιεκτικότητας 1.2-1.5% σε Ni και 4-5% σε C. Η διατριβή αυτή συνέβαλε στην ανάπτυξη μεθόδου ανακύκλωσης της σκόνης αυτής με απευθείας αναγωγική της τήξη σε ηλεκτρική κάμινο συννεχούς ρεύματος (DC-HEP) με εμφυσησή της μέσω του κεντρικού διάτρητου γραφιτικού ηλκετρόδιου. Την προκαταρκτική θεωρητική διερεύνηση και τις εργαστηριακές προδοκιμές ακολούθησαν βιομηχανικές δοκιμές στην κάμινο 125t DC-HEP στη χαλυβουργία Georgsmarienhutte της Γερμανίας, όπου έλαβε χώρα τήξη 70t σκόνης και 2.5t φιλομερούς μεταλλεύματος.Η ανάκτηση Ni ήταν πολύ υψηλή 93-99%. Παρήχθησαν χάλυβες χαμηλής κραμάτωσης σε σε Ni καθώς και ποικίλοι τύποι σκωρίας προς διερεύνηση της χρήσης τους στην παραγωγή σύνθετων τσιμέντων Portland και σκωριωτσιμέντων. Πραγματοποιήθηκε μεταλλουργική αξιολόγηση των δοκιμών και αναπτύχθηκε μοντέλο προσομοίωσης της αναγωγικής τήξης της σκόνης. / The tratment of the laterite nickel ferrous ores in Hellas for the production of ferronickel at Larymna is associated with the emission of 200000t/y of fine dust collected in the gas cleaning systems of the rotary kilns (R/Ks), with 1.2-1.5% and 4-5% . Average Ni and C contents respectively . This thesis contributed to the development of a method for the recycling of this dust by means of its direct reduction smelting in a DC-HEP furnace (Direct Current-Hollow Electrode Powder) by its injection through the central hollow graphite electrode. The preliminary theoretical study and the laboratory trials were followed by industrial heat campaigns in the 12st DC-HEP furnace at georgsmarienhutte steelwork in Germany, where around 70t of dust and 2.5t of ore fines were smelted. The Ni-recovery was very high 93-99.9%. Low Nickel alloyed steel grades were produced and various slag types for the investigation of their utilization for the production of composite-portland cements and slag cements. The metallurgical evaluation of the trials was performed and model for the dust reduction smelting process was developed.

With the progress of high alloy steelmaking processes, it is essential to minimize the loss of valuable metals, like chromium and vanadium during the decarburization process, from both economic as well as environmental view points. One unique technique to realize this aim, used in the present work, is the decarburization of high alloy steel grades using oxygen with CO2 in order to reduce the partial pressure of oxygen. In the present work, the investigation on the oxidation of iron-chromium and iron-vanadium molten alloys under CO2-O2 mixtures was carried out and presented in this dissertation. For oxidation study on Fe-Cr molten alloy with CO2-O2 mixtures, on the basis of thermodynamic analysis, energy balance calculation and modeling results, experimental validation in laboratory was carried out, and later on, the oxidation kinetics of Fe-Cr and Fe-Cr-C melts under controlled partial pressure of oxygen was investigated. Thermodynamics calculation and energy balance estimation demonstrated that, it is possible to use CO2 or CO2-O2 mixtures as decarburizers during EAF process and high initial carbon contents in the steel can be adopted at the beginning in order to reduce the cost. A generic model has been developed to describe the overall process kinetics prevailing in metallurgical reactors containing liquid metal and gas bubbles. This model is general and can be extended further to consider any gas liquid reactions in any chemical engineering reactor, and especially the metallurgical ones, like AOD. In the present dissertation, the model is applied in predicting the evolution of Cr and C contents in a Fe-C-Cr melt during injection of different O2-CO2 mixtures. The related simulation results illustrated that CO2 is efficient in Cr retention. In order to verify the modeling results, 1kg induction furnace experiments were carried out in the present laboratory. The results indicated that the predictions of the model are in good agreement with the experimental results. Meanwhile, the experimental results indicated that the Cr-losses can be significantly lowered by replacing the oxygen with CO2 in the injected gas, specifically for Fe-Cr-C melts with carbon levels higher than about 0.8 mass%. Subsequently, the oxidation kinetics of Fe-Cr and Fe-Cr-C melts was investigated under different CO2-O2 mixtures. It is indicated that, the oxidation rate is controlled by the chemical reaction at the initial stage and the reaction rate can be expressed as  at the Cr range of 11-21 mass% in the Fe-Cr melt. For oxidation study on Fe-V liquid alloy, the investigation of the oxidation kinetics was carried out under CO2-O2 mixtures, which is followed by the study on thermodynamic properties of vanadium containing slags. During oxidation of Fe-V melt, in the case of alloys with vanadium contents exceeding 10 mass%, there exists an incubation period before the chemical reactions prevail the process. In addition, the ‘incubation time’ increased with the increase of temperature and the vanadium content, whereas it decreased with the increase of oxygen partial pressure in the oxidant gas. High-temperature mass spectrometric method was used to determine the activity of the vanadium oxide in CaO-MgO-Al2O3-SiO2-V2O3 slags, whereas, the oxidation states of vanadium in the CaO-MgO-Al2O3-SiO2-VOxslag system was studied by XANES method. The results indicated that, higher basicities stabilize higher vanadium oxidation state, whereas, higher temperature stabilizes lower vanadium oxidation state. The present work, which was carried out within the ECO-STEELMAKING project funded by MISTRA via Jernkontoret is expected to lead to implementation of some modifications in high alloy steel production based on fundamental concepts towards more environment-friendly steel processing. / <p>QC20100628</p>

Mineralogical and geochemical characteristics of metallurgical wastes from the Cu-Co smelters situated in the Zambian Copperbelt have been investigated. A number of instrumental analytical methods (XRD, SEM/EDS, EPMA, TEM/EDS) has been used to identify primary and secondary phases in smelter slags and dusts. A set of leaching experiments (CEN/TS 14997 pH-static test, EN 12457 batch test) in combination with geochemical modelling has been performed, with the emphasis on the leaching behaviour of potential contaminants and their release as a function of the pH. The effect of sample preparation on metal leachability from slag was also evaluated, considering the grain size reduction required by the standardised leaching protocols. Environmental and health risk assessments of the dust samples have been performed. It was shown that the main carriers of metals in the studied slags were Cu sulphides (bornite, digenite, chalcocite), Co sulphides (cobaltpentlandite), Co-bearing intermetallic phases and alloys. Copper and cobalt were detected in major silicates and spinels, substituting for Fe or Mg in their structures, and in glass. The presence of secondary metal-bearing phases observed on the slag surfaces indicated the reactivity of the slags on contact with water/atmosphere. It was reported that in...