The performance of solid oxide fuel cells (SOFCs) at the cell and system levels is studied using computer simulation. At the cell level, a new model combining the cell micro and macro models is developed. Using this model, the microstructural variables of porous composite electrodes can be linked to the cell performance. In this approach, the electrochemical performance of porous composite electrodes is predicted using a micro-model. In the micro-model, the random-packing sphere method is used to estimate the microstructural properties of porous composite electrodes from the independent microstructural variables. These variables are the electrode porosity, thickness, particle size ratio, and size and volume fraction of electron-conducting particles. Then, the complex interdependency among the multi-component mass transport, electron and ion transports, and the electrochemical and chemical reactions in the microstructure of electrodes is taken into account to predict the electrochemical performance of electrodes. The temperature distribution in the solid structure of the cell and the temperature and species partial pressure distributions in the bulk fuel and air streams are predicted using the cell macro-model. In the macro-model, the energy transport is considered for the cell solid structure and the mass and energy transports are considered for the fuel and air streams. To demonstrate the application of the cell level model developed, entitled the combined micro- and micro-model, several anode-supported co-flow planar cells with a range of microstructures of porous composite electrodes are simulated. The mean total polarization resistance, the mean total power density, and the temperature distribution in the cells are predicted. The results of this study reveal that there is an optimum value for most of the microstructural variables of the electrodes at which the mean total polarization resistance of the cell is minimized. There is also an optimum value for most of the microstructural variables of the electrodes at which the mean total power density of the cell is maximized. The microstructure of porous composite electrodes also plays a significant role in the mean temperature, the temperature difference between the hottest and coldest spots, and the maximum temperature gradient in the solid structure of the cell. Overall, using the combined micro- and micro-model, an appropriate microstructure for porous composite electrodes to enhance the cell performance can be designed. At the system level, the full load operation of two SOFC systems is studied. To model these systems, the basic cell model is used for SOFCs at the cell level, the repeated-cell stack model is used for SOFCs at the stack level, and the thermodynamic model is used for the balance of plant components of the system. In addition to these models, a carbon deposition model based on the thermodynamic equilibrium assumption is employed. For the system level model, the first SOFC system considered is a combined heat and power (CHP) system that operates with biogas fuel. The performance of this system at three different configurations is evaluated. These configurations are different in the fuel processing method to prevent carbon deposition on the anode catalyst. The fuel processing methods considered in these configurations are the anode gas recirculation (AGR), steam reforming (SR), and partial oxidation reformer (POX) methods. The application of this system is studied for operation in a wastewater treatment plant (WWTP) and in single-family detached dwellings. The evaluation of this system for operation in a WWTP indicates that if the entire biogas produced in the WWTP is used in the system with AGR or SR fuel processors, the electric power and heat required to operate the plant can be completely supplied and the extra electric power generated can be sold to the electrical grid. The evaluation of this system for operation in single-family detached dwellings indicates that, depending on the size, location, and building type and design, this system with all configurations studied is suitable to provide the domestic hot water and electric power demands. The second SOFC system is a novel portable electric power generation system that operates with liquid ammonia fuel. Size, simplicity, and high electrical efficiency are the main advantages of this environmentally friendly system. Using a sensitivity analysis, the effects of the cell voltage at several fuel utilization ratios on the number of cells required for the SOFC stack, system efficiency and voltage, and excess air required for thermal management of the SOFC stack are studied.

Το αντικείμενο της διατριβής αυτής είναι η μελέτη της διαστρωματικής (cross-layer) προσέγγισης ανάπτυξης ασύρματων δικτύων κατανεμημένης λειτουργίας με απαιτήσεις επικοινωνίας πραγματικού χρόνου και περιορισμένους διαθέσιμους πόρους. Επιπλέον βασικό στόχο αποτελεί και η σχεδίαση, πρόταση αντίστοιχης αρχιτεκτονικής η οποία στοχεύει στη βέλτιστη διαχείριση διαθεσίμων δικτυακών πόρων σε καταστάσεις συμφόρησης του δικτύου και κατά συνέπεια στην βελτίωση της απόδοσης αυτού. Μέσα από μελέτες στα πλαίσια της διατριβής αναδεικνύεται η σημασία του φαινομένου συμφόρησης ως κύριου παράγοντα σπατάλης δικτυακών πόρων καθώς και οδήγησης του δικτύου σε κατάσταση κορεσμού με αρνητική επίπτωση σε όλες τις παραμέτρους απόδοσης του δικτύου. Στόχος, λοιπόν, της προτεινόμενης επικοινωνιακής αρχιτεκτονικής είναι η αποφυγή του φαινομένου συμφόρησης έτσι ώστε το δίκτυο να οδηγείται δυναμικά σε ένα σταθερό σημείο απόδοσης (όσο αυτό είναι δυνατό) το οποίο θα επιτρέπει στο δίκτυο να αποδίδει όσο το δυνατόν καλύτερα αποφεύγοντας τη ίδια στιγμή άσκοπη σπατάλη πόρων. Βασική παράμετρος στη σχεδίαση αποτελεί η συμβατότητα τόσο ως προς σημαντικό εύρος διαθέσιμων πρωτοκόλλων σε διάφορα επίπεδα, όσο και ως προς τη δυνατότητα συνύπαρξης κόμβων που ενσωματώνουν την προτεινόμενη αρχιτεκτονική με κόμβους χωρίς αυτήν. Η προτεινόμενη αρχιτεκτονική υλοποιήθηκε στα πλαίσια γνωστού και αξιόπιστου δικτυακού εξομοίωση. Αξιολόγηση της υλοποίησης αυτής μέσα από μεγάλο αριθμό πειραμάτων έδειξε επίτευξη του στόχου καθώς το φαινόμενο της συμφόρησης αντιμετωπίστηκε σε όλες τις περιπτώσεις με σημαντικά οφέλη στην απόδοση του δικτύου και διαχείριση των πόρων. Επιπλέον, λόγω του μεγάλου βαθμού παραμετροποίησης αποτελεί ιδανική βάση για μελλοντικές προεκτάσεις. / This objective of this dissertation is the study of cross-layer approach applied on the development of distributed wireless networks with real-time response demands and scarce available resources. Furthermore, another main goal is the design and proposal of a respective network architecture aiming at optimum resource management under congestion scenarios and therefore maximization of network performance. Through various studies undertaken in the context of this dissertation the importance of the congestion problem is presented as a main factor leading the network to resource waste and saturation conditions negatively affecting all network performance metrics. Consequently, this dissertation aims in proposing a cross-layer architecture able to detect and tackle congestion phenomenon by dynamically retaining network performance at a steady state (as than is possible) where network performs optimally and resource waste in minimized. Among others, a main parameter is retaining compatibility with a wide range of widely used protocols of various layers as well compatibility concerning the coexistence in the same network of stations supporting with stations not supporting the proposed architecture. The proposed architecture is implemented in the context of widely known and used network simulator. Evaluation of this implementation through numerous simulations showed that the objectives are met since congestion phenomenon is tackled in most cases with significant benefits concerning network performance and resource management. Furthermore, due to the high parametrization degree it constitutes a very good base for future expansions.

Systems-level homelessness report cards are an intricate part of managing and resolving homelessness within a community. Homelessness report cards can be used to both educate communities around the complexities of homelessness and capture pertinent data required to formulate evidence-based strategies towards ending (rather than managing) homelessness. The process of developing and implementing homelessness report cards can be fraught with challenges relating to: limited resources; fragmented information; and political roadblocks. To help reduce the potential of these roadblocks, a system-level Homelessness Outcome Reporting Normative framework (the “HORN Framework”) was developed. The HORN Framework is based on a literature review and synthesis of the best-practice, systems-level homelessness report card development and implementation methods. The framework was then tested in a case study with the Greater Victoria Coalition to End Homelessness (GVCEH), through the creation of their 2010 Greater Victoria Homelessness Report Card. The framework and case study results are presented in this thesis.

The performance of solid oxide fuel cells (SOFCs) at the cell and system levels is studied using computer simulation. At the cell level, a new model combining the cell micro and macro models is developed. Using this model, the microstructural variables of porous composite electrodes can be linked to the cell performance. In this approach, the electrochemical performance of porous composite electrodes is predicted using a micro-model. In the micro-model, the random-packing sphere method is used to estimate the microstructural properties of porous composite electrodes from the independent microstructural variables. These variables are the electrode porosity, thickness, particle size ratio, and size and volume fraction of electron-conducting particles. Then, the complex interdependency among the multi-component mass transport, electron and ion transports, and the electrochemical and chemical reactions in the microstructure of electrodes is taken into account to predict the electrochemical performance of electrodes. The temperature distribution in the solid structure of the cell and the temperature and species partial pressure distributions in the bulk fuel and air streams are predicted using the cell macro-model. In the macro-model, the energy transport is considered for the cell solid structure and the mass and energy transports are considered for the fuel and air streams. To demonstrate the application of the cell level model developed, entitled the combined micro- and micro-model, several anode-supported co-flow planar cells with a range of microstructures of porous composite electrodes are simulated. The mean total polarization resistance, the mean total power density, and the temperature distribution in the cells are predicted. The results of this study reveal that there is an optimum value for most of the microstructural variables of the electrodes at which the mean total polarization resistance of the cell is minimized. There is also an optimum value for most of the microstructural variables of the electrodes at which the mean total power density of the cell is maximized. The microstructure of porous composite electrodes also plays a significant role in the mean temperature, the temperature difference between the hottest and coldest spots, and the maximum temperature gradient in the solid structure of the cell. Overall, using the combined micro- and micro-model, an appropriate microstructure for porous composite electrodes to enhance the cell performance can be designed. At the system level, the full load operation of two SOFC systems is studied. To model these systems, the basic cell model is used for SOFCs at the cell level, the repeated-cell stack model is used for SOFCs at the stack level, and the thermodynamic model is used for the balance of plant components of the system. In addition to these models, a carbon deposition model based on the thermodynamic equilibrium assumption is employed. For the system level model, the first SOFC system considered is a combined heat and power (CHP) system that operates with biogas fuel. The performance of this system at three different configurations is evaluated. These configurations are different in the fuel processing method to prevent carbon deposition on the anode catalyst. The fuel processing methods considered in these configurations are the anode gas recirculation (AGR), steam reforming (SR), and partial oxidation reformer (POX) methods. The application of this system is studied for operation in a wastewater treatment plant (WWTP) and in single-family detached dwellings. The evaluation of this system for operation in a WWTP indicates that if the entire biogas produced in the WWTP is used in the system with AGR or SR fuel processors, the electric power and heat required to operate the plant can be completely supplied and the extra electric power generated can be sold to the electrical grid. The evaluation of this system for operation in single-family detached dwellings indicates that, depending on the size, location, and building type and design, this system with all configurations studied is suitable to provide the domestic hot water and electric power demands. The second SOFC system is a novel portable electric power generation system that operates with liquid ammonia fuel. Size, simplicity, and high electrical efficiency are the main advantages of this environmentally friendly system. Using a sensitivity analysis, the effects of the cell voltage at several fuel utilization ratios on the number of cells required for the SOFC stack, system efficiency and voltage, and excess air required for thermal management of the SOFC stack are studied.

Submitted by Andre Luis de Castro (ancastro@gmail.com) on 2017-08-05T12:57:36Z No. of bitstreams: 1 TESE - O FANTASMA NA MAQUINA - ANDRE CASTRO - Versao Final - 2017.pdf: 2023758 bytes, checksum: f1d27c99ae1d44a54e033be627f867ba (MD5) / Approved for entry into archive by Maria Tereza Fernandes Conselmo (maria.conselmo@fgv.br) on 2017-08-07T16:59:07Z (GMT) No. of bitstreams: 1 TESE - O FANTASMA NA MAQUINA - ANDRE CASTRO - Versao Final - 2017.pdf: 2023758 bytes, checksum: f1d27c99ae1d44a54e033be627f867ba (MD5) / Made available in DSpace on 2017-08-07T17:23:48Z (GMT). No. of bitstreams: 1 TESE - O FANTASMA NA MAQUINA - ANDRE CASTRO - Versao Final - 2017.pdf: 2023758 bytes, checksum: f1d27c99ae1d44a54e033be627f867ba (MD5) Previous issue date: 2017-07-11 / The increasing complexity of the State, in particular the use of new information and communication technologies have led to the emergence of new types of bureaucracies such as system-level bureaucracy and screen-level bureaucracy. The first is composed of specialists who develop information systems for public policies, while the screen-level bureaucracy is formed by middle-level and street bureaucrats who act at the end of the provision of public services, depending on the systems to perform the work. The present work has as object of study the analysis of the relations between these bureaucracies in the implementation of public policies, with emphasis on the coordination problem. In this inter bureaucratic relationship, communities of practice, discretion and expertise are important analytical elements, since they allow the creation of strategies of action by the actors and the coordination of the policy. The theoretical references on bureaucracy and implementation of public policies were constructed not only in classical texts such as Weber (2007), Wildavsky and Pressman (1973) and Lipsky (1980) that discuss the relations between bureaucracies in the implementation of But also in the more recent work by Guy Peters (1998) and Bovens and Zouridis (2002) on the coordination and role of ICTs in policies. From a methodological point of view, it is a case study comparing two public policies that differ in the way in which the relations between system level bureaucracy and screen level bureaucracy occur. In the two informal, mutually dependent, close and complementary, informal learning networks allow actors to create and use action strategies that contribute to coordination. The distinction between policies has occurred in the identification of greater coordination problems in education policy. The explanation first relates to the substantive difference of the tax collection policy, which is of greater importance to the government and has a greater maturity in the development of information systems than other secretariats, which provides greater expertise and more collaborative relationships. Empirical evidences related to the organizational characteristics of the secretariats contribute to explain this distinction, such as: the greater turnover of the bureaucrats of the Department of Education (SEED); The separate physical location of the education systems and teams development team, different from what occurs at the Treasury Department (SEFA). / A complexidade crescente do Estado, em particular, o uso de novas tecnologias de informação e comunicação, tem gerado novos tipos de burocracias, como a system-level bureaucracy (SYB) e a screen-level bureaucracy (SCB). A primeira é composta por especialistas que desenvolvem sistemas de informação para as políticas públicas, enquanto a SCB é formada por burocratas de nível médio e de rua que atuam na ponta da prestação de serviços públicos, dependendo dos sistemas para realizar seu trabalho. O presente trabalho tem como objeto de estudo a análise das relações entre essas burocracias na implementação de políticas públicas, com destaque para a problemática da coordenação. As referências teóricas sobre burocracia e implementação de políticas públicas foram construídas a partir de Weber (2007), Wildavsky e Pressman (1973) e Lipsky (1980) que discutem as relações entre burocracias na implementação de políticas públicas, e também se baseou em trabalhos mais recentes de Guy Peters (1998) e Bovens e Zouridis (2002), concernentes à coordenação e ao papel das TICs nas políticas. Do ponto de vista metodológico, trata-se de um de caso comparado entre duas políticas públicas: a de arrecadação fiscal e de educação básica do estado do Paraná enfocando os processos de desenvolvimento de sistemas de informação com a participação da CELEPAR (Companhia de Tecnologia da Informação e Comunicação do estado do Paraná). Tais políticas se diferenciam pela forma como ocorrem as relações entre a SYB e a SCB. Nas duas políticas, redes informais de aprendizado, mutuamente dependentes, próximas e complementares, permitem aos atores a criação e utilização de estratégias de ação que contribuem com a coordenação. A distinção entre as políticas se deu na identificação de maiores problemas de coordenação na política de educação. A explicação relaciona-se primeiro, à diferença substantiva da política de arrecadação fiscal, que possui maior importância para o governo e maturidade maior no desenvolvimento de sistemas de informação se comparado a outras secretarias, que confere maior expertise e relações mais colaborativas. Características organizacionais das secretarias contribuem para explicar as implicações dessa distinção, como a rotatividade maior dos burocratas da Secretaria de Educação (SEED); a localização física separada da equipe de desenvolvimento de sistemas e equipes da educação, diferente do que ocorre na Secretaria da Fazenda (SEFA).

The aim of the diploma thesis is to identify Russia's Foreign Policy change in the first decade of the 21st century. It focuses on the three most important strategic documents of the Russian Federation, the presidential decrees signed by Vladimir Putin and Dmitri Medvedev (The Foreign Policy Concepts of the Russian Federation from 2000 and 2008, The National Security Concept of the Russian Federation from 2000, The National Security Strategy of the Russian Federation from 2009 and The Military Doctrines from 2000 and 2010). Through Discourse analysis it concludes that Russia has moved to strenghtening norms of international law and multilateral cooperation between the years 2000 and 2010, it no longer uses confrontational expressions and prefers a multi-vector foreign policy accenting the Asian vector. Russia also proves to be more self-confident and ambitious. We expect a more active role in the world affairs from Russia in the second decade of the 21st century.

Network-on-chip (NoC) based multi-processor systems-on-chip (MPSoCs) are promising candidates for future multi-processor embedded platforms, which are expected to be composed of hundreds of heterogeneous processing elements (PEs) to potentially provide high performances. However, together with the performances, the systems complexity will increase, and new high level design techniques will be needed to efficiently model, simulate, debug and synthesize them. System-level design (SLD) is considered to be the next frontier in electronic design automation (EDA). It enables the description of embedded systems in terms of abstract functions and interconnected blocks. A promising complementary approach to SLD is the use of models of computation (MoCs) to formally describe the execution semantics of functions and blocks through a set of rules. However, also when this formalization is used, there is no clear way to synthesize system-level models into software (SW) and hardware (HW) towards a NoC-based MPSoC implementation, i.e., there is a lack of system design automation (SDA) techniques to rapidly synthesize and prototype system-level models onto heterogeneous NoC-based MPSoCs. In addition, many of the proposed solutions require large overhead in terms of SW components and memory requirements, resulting in complex and customized multi-processor platforms. In order to tackle the problem, a novel model-based SDA flow has been developed as part of the thesis. It starts from a system-level specification, where functions execute according to the synchronous MoC, and then it can rapidly prototype the system onto an FPGA configured as an heterogeneous NoC-based MPSoC. In the first part of the thesis the HeartBeat model is proposed as a model-based technique which fills the abstraction gap between the abstract system-level representation and its implementation on the multiprocessor prototype. Then details are provided to describe how this technique is automated to rapidly prototype the modeled system on a flexible platform, permitting to adjust the system specification until the designer is satisfied with the results. Finally, the proposed SDA technique is improved defining a methodology to automatically explore possible design alternatives for the modeled system to be implemented on a heterogeneous NoC-based MPSoC. The goal of the exploration is to find an implementation satisfying the designer's requirements, which can be integrated in the proposed SDA flow. Through the proposed SDA flow, the designer is relieved from implementation details and the design time of systems targeting heterogeneous NoC-based MPSoCs on FPGA is significantly reduced. In addition, it reduces possible design errors proposing a completely automated technique for fast prototyping. Compared to other SDA flows, the proposed technique targets a bare-metal solution, avoiding the use of an operating system (OS). This reduces the memory requirements on the FPGA platform comparing to related work targeting MPSoC on FPGA. At the same time, the performance (throughput) of the modeled applications can be increased when the number of processors of the target platform is increased. This is shown through a wide set of case studies implemented on FPGA. / <p>QC 20140609</p>

L'interférence entre stations de base est considérée comme le principal facteur limitant les performances des réseaux cellulaires. Nous nous intéressons aux différents schémas de coordination multi-point (CoMP) proposés dans la norme LTE-A pour y faire face, en tenant compte de l'aspect dynamique du trafic et de la mobilité des utilisateurs. Les résultats sont obtenus par l'analyse mathématique de modèles markoviens et par des simulations du système. Nous montrons l'importance de l'algorithme d'ordonnancement sur les performances en présence d'utilisateurs mobiles, pour des services de téléchargement de fichier et de streaming vidéo. Nous proposons un nouvel algorithme d'ordonnancement basé sur la dé-priorisation des utilisateurs mobiles se trouvant en bord de cellule, afin d'améliorer l'efficacité globale du système. Nous montrons ensuite qu'il est intéressant d'activer la technique dite Joint Processing uniquement dans un réseau à forte interférence, son activation dans un réseau à faible interférence pouvant conduire à une dégradation des performances. Nous proposons un nouveau mécanisme de coordination où une cellule ne coopère que lorsque sa coopération apporte un gain moyen de débit suffisant pour compenser les pertes de ressources engendrées. Nous considérons enfin la technique de formation de faisceaux coordonnée. Nous montrons notamment que la coordination n'est pas nécessaire lorsque l'on dispose d'un grand nombre d'antennes par station de base, un simple mécanisme d'ordonnancement opportuniste permettant d'obtenir des performances optimales. Pour un nombre limité d’antennes parstation de base, la coordination est nécessaire afin d’éviter l’interférence entre les faisceaux activés, et permet des gains de performance substantiels. / Interference is still the main limiting factor in cellular networks. We focus on the different coordinated multi-point schemes (CoMP) proposed in the LTE-A standard to cope with interference, taking into account the dynamic aspect of traffic and users’ mobility. The results are obtained by the analysis of Markov models and system-level simulations. We show the important impact of the scheduling strategy on the network performance in the presence of mobile users considering elastic traffic and video streaming. We propose a new scheduler that deprioritizes mobile users at the cell edge, in order to improve the overall system efficiency. We show that it is interesting to activate Joint Processing technique only in a high-interference network, its activation in a low-interference network may lead to performance degradation. We propose a new coordination mechanism, where a cell cooperates only when its cooperation brings a sufficient mean throughput gain, which compensates the extra resource consumption. Finally, we show that the coordination of beams is not necessary when a large number of antennas is deployed at each base station; a simple opportunistic scheduling strategy provides optimal performance. For a limited number of antennas per base station,coordination is necessary to avoid interference between the activated beams, allowing substantial performance gains.

<p dir="ltr">Composite Plate Shear Wall/ Concrete Filled (C-PSW/CF), also referred to as SpeedCore walls, are being used as innovative shear wall commercial high-rise buildings. These walls offer advantages such as modularity and construction schedule contraction. The cross-section of C- PSWs/CF consists of concrete infill sandwiched between the steel faceplates, where the steel plates are tied together by steel tie bars. Elevated temperatures will result in a deterioration in the mechanical properties of steel and concrete during a fire event in buildings. Such degradation can lead to stability-related failure of structural components. Composite floors are connected to these walls through simple shear connections. The floor-to-wall connections will be exposed to elevated temperatures, which may result in connection failure and progressive collapse of structures.</p><p dir="ltr">Designing SpeedCore walls without fire protection raises concerns regarding the performance of other structural components connected to SpeedCore walls under fire loading including composite floor systems and wall-to-floor connections. Numerical studies conducted on the connections and the floor systems indicated that these structural components undergo thermal compression forces during heating and tensile forces during the cooling phases of a fire event. The goal of this research was to develop an approach for performance-based fire resistance design of complete floor systems consisting of SpeedCore walls, composite floor slabs, and wall-to-floor connections.</p><p dir="ltr">This research includes experimental and numerical analyses to gain insight into the behavior of the floor-to-SpeedCore wall connections under fire and gravity loading. The specimens included steel beams connected to SpeedCore walls through simple shear connections. Three types of floor-to-wall connections were tested including connections with through-plate, reinforcing plate, and unreinforced plate. The parameters considered in the test matrix included: connection type, temperature, loading angle, and loading direction. These parameters in the test matrix were based on results obtained from previous numerical and experimental studies in the literature. The experimental results can fill the existing knowledge gap on floor-to-wall connections for steel-concrete composite members, develop design recommendations, and benchmark numerical models.</p><p dir="ltr">Numerical models were developed to simulate the behavior of the connections (member level) and whole structures (structure level) at ambient and elevated temperatures. Finite Element (FE) analysis and Component-based Models (CB) were utilized to develop the numerical models. The developed models were benchmarked by comparing the obtained numerical results with experimental data reported in the literature. FE models have been validated at two different levels, namely member level, and system level. The performance of the designed connection for the archetype structures was studied using benchmarked FE and CB models. The behavior of various wall-to-floor connections with different steel plate (C-PSW/CF) detailing was investigated.</p><p dir="ltr">Benchmarked numerical models were used to perform a parametric study to evaluate the performance of these connections. UP connection detail was used to perform the study due to its promising experimental performance, which does not need any special detail or plate reinforcement. The study was performed by evaluating the effects of critical parameters on the connection behavior namely, bolt size, target temperature, loading angles, and loading direction</p>

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