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This study focuses on the environmental impact assessment of trace elements concentrations in spent shale, which is the main residual besides gas and steam from the utilization of oil shale. The study area El-Lajjun covers 28 km2, located in the centre of Jordan approximately 110 km south of Amman. It belongs mainly to the Wadi Mujib catchment and is considered to be one of the most important catchments in Jordan. The Wadi El-Lajjun catchment area (370 km2) consists of two main aquifer systems: The intermediate aquifer (Amman Wadi As Sir Aquifer or B2/A7) and the deep sandstone aquifer (Kurnub/Ram Group Aquifer). The B2/A7 aquifer (Upper Cretaceous) is considered as the main source of fresh water in Jordan. El-Lajjun oil shale was deposited in a sedimentary basin and comprises massive beds of brown-black, kerogen-rich, bituminous chalky marl. The oil shale was deposited in shallow marine environment. It is by definition a sedimentary rock containing organic material in the rock matrix. The shale oil extraction is an industrial process to decompose oil shale and to convert the kerogen into shale oil by hydrogenation, pyrolysis or by a thermal dissolution. Several classifications of extraction technologies are known; the classification with respect to the location where the extraction takes place distinguishes between off-site, on-site, and in situ. The oil shale utilization may have serious repercussions on the surrounding environment if these issues are not investigated and evaluated carefully. Ten representative oil shale rock samples with a total weight about 20 kg were collected from different localities of oil shale exposures in the study area. A standardized laboratory Fischer Assay test was performed with the samples to determine oil shale characteristics and to obtain spent shale, which was used in this study for further investigations. Sequential extraction was used to evaluate the changes in the mobility and distribution of the trace elements: Ti, V Cr, Co, Zn, As Zr, Cd, Pb and U. Column leaching experiments were performed to simulate the leaching behavior of the above elements from oil shale and spent shale to evaluate the possible influence on the groundwater in the study area. The concentrations in the leachate were below the maximum contaminant levels of the Environmental Protection Agency (EPA) for drinking water and the Jordanian standards for drinking water. An immobilization method by using Kaolin was applied to reduce the mobilization and bioavailability of the trace elements fraction that are contained in the spent shale. Immobilization was evaluated as a function of liquid-solid ratio (solid-liquid partitioning) and as a function of pH. A comparison between the results obtained from column leaching experiments and the results that were obtained from immobilization for the oil shale and spent shale samples indicated that the immobilization reduced the mobility of the trace element except for Ti, V, and Cr. However, even the concentrations of these elements were lower than the maximum acceptable limits of the Jordanian Standard Specifications for waste water. The catchment of the study area (Wadi El-Lajjun catchment) is ungauged. Therefore, the soil conservation service (SCS) runoff curve number method was used for predicting direct runoff from rainfall. The results obtained showed that the infiltration of water is very small (approximately 0.6 cm/year) and rarely can´t reach the groundwater through the oil shale beds. Thus, a contamination of groundwater is unlikely under normal conditions. DRASTIC was used to assess groundwater vulnerability for the B2/A7 aquifer with respect to pollution by oil shale utilization. The aquifer vulnerability map shows that the area is divided into three zones: low (risk index 10-100; intermediate (risk index 101–140) and high groundwater vulnerability (risk index 141-200). The high risk areas are small and mainly located in the northeastern corner of the El-Lajjun graben, where the hydraulic conductivity is relatively high and rocks are highly fractured and faulted. The water table of the deep sandstone aquifer (Kurnub/Ram group) in the El-Lajjun area is relatively deep. At least two geological formations above the Kurnub aquifer are aquitards and protect the deep aquifer. However, the area is highly fractured and thus there is a certain possibility for contact with surface pollutants. Finally, further research with respect to trace elements including REE elements and isotopes in the intermediate and deep sandstone aquifers are highly recommended. Isotopic signatures will be very helpful to investigate to which extend hydraulic connections between the aquifers exist. Further and in particular mineralogical studies on the spent shale and the possibilities for industrial utilization are recommended because huge quantities of spent shale are expected. Because most oil shale extraction technologies especially the power generation require considerable amounts of water detailed studies on water supply for the oil shale treatment have to be performed.

Purpose - This bachelor thesis compares high-speed rail (HSR) transport with air transport. The investigation considers physical fundamentals, energy consumption, environmental impact, infrastructure and investment, market situations, passenger's selection criteria to choose transportation options, and overall economics. --- Methodology - The thesis combines an investigation of physical principles with a literature review. --- Findings - Steel wheels on steel rails show by far less rolling resistance to support the train's weight than drag due to lift (induced drag) to support the aircraft's weight. This leads to less energy consumption. HSR trains use electricity from an overhead line. Hence, the environmental impact of HSR also depends much on how the electricity is produced. Airplanes only need an air traffic control environment to connect airports. In contrast, HSR needs infrastructure to connect stations. The amount of necessary infrastructure depends on the geological conditions. For example, crossing mountains means high investment. Longer passages over water are infeasible for HSR. High-speed rail is superior to air transport when connecting megacities because the trains have higher transport capacity, offer higher service frequencies and mission reliability, shorter total travel time, shorter access time to stations, shorter unproductive waiting time in stations and potentially lower travel costs. HSR is a strong competitor to airline services and has replaced some short range flights. A comparison of HSR in different world regions shows differences in the market situation and in passenger's selection criteria for transportation options. --- Research limitations - The potential of high-speed rail was investigated mainly on busy routes with high service frequencies. A comprehensive network comparison between high-speed trains and airplanes was not done and could lead to somewhat different results. --- Practical implications - The report tries to contribute arguments to the discussion about alternatives to air travel. --- Social implications - With more knowledge people can make an educated choice between transport options, can vote with their feet, and can take a firm position in the public discussion. --- Originality/value - A general comparison of HSR and air transport from physical fundamentals to economics seemed to be missing.

This study focuses on the environmental impact assessment of trace elements concentrations in spent shale, which is the main residual besides gas and steam from the utilization of oil shale. The study area El-Lajjun covers 28 km2, located in the centre of Jordan approximately 110 km south of Amman. It belongs mainly to the Wadi Mujib catchment and is considered to be one of the most important catchments in Jordan. The Wadi El-Lajjun catchment area (370 km2) consists of two main aquifer systems: The intermediate aquifer (Amman Wadi As Sir Aquifer or B2/A7) and the deep sandstone aquifer (Kurnub/Ram Group Aquifer). The B2/A7 aquifer (Upper Cretaceous) is considered as the main source of fresh water in Jordan. El-Lajjun oil shale was deposited in a sedimentary basin and comprises massive beds of brown-black, kerogen-rich, bituminous chalky marl. The oil shale was deposited in shallow marine environment. It is by definition a sedimentary rock containing organic material in the rock matrix. The shale oil extraction is an industrial process to decompose oil shale and to convert the kerogen into shale oil by hydrogenation, pyrolysis or by a thermal dissolution. Several classifications of extraction technologies are known; the classification with respect to the location where the extraction takes place distinguishes between off-site, on-site, and in situ. The oil shale utilization may have serious repercussions on the surrounding environment if these issues are not investigated and evaluated carefully. Ten representative oil shale rock samples with a total weight about 20 kg were collected from different localities of oil shale exposures in the study area. A standardized laboratory Fischer Assay test was performed with the samples to determine oil shale characteristics and to obtain spent shale, which was used in this study for further investigations. Sequential extraction was used to evaluate the changes in the mobility and distribution of the trace elements: Ti, V Cr, Co, Zn, As Zr, Cd, Pb and U. Column leaching experiments were performed to simulate the leaching behavior of the above elements from oil shale and spent shale to evaluate the possible influence on the groundwater in the study area. The concentrations in the leachate were below the maximum contaminant levels of the Environmental Protection Agency (EPA) for drinking water and the Jordanian standards for drinking water. An immobilization method by using Kaolin was applied to reduce the mobilization and bioavailability of the trace elements fraction that are contained in the spent shale. Immobilization was evaluated as a function of liquid-solid ratio (solid-liquid partitioning) and as a function of pH. A comparison between the results obtained from column leaching experiments and the results that were obtained from immobilization for the oil shale and spent shale samples indicated that the immobilization reduced the mobility of the trace element except for Ti, V, and Cr. However, even the concentrations of these elements were lower than the maximum acceptable limits of the Jordanian Standard Specifications for waste water. The catchment of the study area (Wadi El-Lajjun catchment) is ungauged. Therefore, the soil conservation service (SCS) runoff curve number method was used for predicting direct runoff from rainfall. The results obtained showed that the infiltration of water is very small (approximately 0.6 cm/year) and rarely can´t reach the groundwater through the oil shale beds. Thus, a contamination of groundwater is unlikely under normal conditions. DRASTIC was used to assess groundwater vulnerability for the B2/A7 aquifer with respect to pollution by oil shale utilization. The aquifer vulnerability map shows that the area is divided into three zones: low (risk index 10-100; intermediate (risk index 101–140) and high groundwater vulnerability (risk index 141-200). The high risk areas are small and mainly located in the northeastern corner of the El-Lajjun graben, where the hydraulic conductivity is relatively high and rocks are highly fractured and faulted. The water table of the deep sandstone aquifer (Kurnub/Ram group) in the El-Lajjun area is relatively deep. At least two geological formations above the Kurnub aquifer are aquitards and protect the deep aquifer. However, the area is highly fractured and thus there is a certain possibility for contact with surface pollutants. Finally, further research with respect to trace elements including REE elements and isotopes in the intermediate and deep sandstone aquifers are highly recommended. Isotopic signatures will be very helpful to investigate to which extend hydraulic connections between the aquifers exist. Further and in particular mineralogical studies on the spent shale and the possibilities for industrial utilization are recommended because huge quantities of spent shale are expected. Because most oil shale extraction technologies especially the power generation require considerable amounts of water detailed studies on water supply for the oil shale treatment have to be performed.

Micro-pollutants such as 17β-estradiol (E2) have been detected in different water resources and their negative effects on the environment and organisms have been demonstrated. It is essential to confirm the presence of micro-pollutants in different environments by biosensors and to remove these compounds. In this thesis, E2-binding target structures were used to investigate the underlying binding properties. E2-binding protein, DNA-, and PNA-aptamere (peptide nucleic acid) structures were used as targets to determine physicochemical interactions. The protein dataset consist of 35 publicly accessible three-dimensional structures of E2-protein complexes, from which six representative binding sites could be selected. There is no three-dimensional structure information for an E2-specific DNA aptamer, thus it was modeled using a coarse-grained modeling method. Using sequence information additional DNA aptamers were modeled. The E2 ligand was positioned close to the potential binding area of the aptamer structures, the underlying complexes were investigated by a molecular dynamics simulation, and the interactions were examined by an interaction profiler tool for each time step. A PNA generator was developed that can convert DNA and RNA in silico to more robust, but chemically equivalent PNA. This generator was used to transform the E2-specific DNA aptamer into PNA for binding studies with E2. All formed complexes were investigated with respect to the following non-covalent interaction types: hydrogen bonds, water-mediated hydrogen bonds, π-stacking, and hydrophobic interactions. Ten functional groups could be derived which formed the conserved interactions to E2. The study contributes to the understanding of the behavior of ligands that bind through different target structures in an aqueous solution and to the identification of binding specific interaction partners. The results of this thesis can be used to design novel synthetic receptor and filter systems.

Abandoned non-reclaimed marl mine dumps of the cement factory in the Novorossiysk industrial agglomeration (NW Caucasus, Russia) are hazardous because of fugitive dust emissions, erosion and possible occurrence of a debris-flow disaster. Having high sorption capacity, dust accumulates pollutants contained in the atmospheric air and subsequently precipitates on the topsoil. Soil and plant sampling and chemical analysis (> 200 specimens) revealed the geochemical anomalies of Pb, Zn, Cu, Ba and Sr. Land zoning based on accumulated environmental damage indicators and the debris-flow technical risk was performed to assess environmental threats. The designed mine dump reclamation includes soil stabilisation by application of geosynthetic cover, hydro-seeding of soil improvers and seeds of herbaceous plants on the slopes, and anti-erosion plantation of cades and smoke trees at subhorizontal surfaces.

The cumulative dissertation at hand addresses the question of how promising the successful implementation of the WFD is. Since research on implementation deficits has so far mainly considered national and sub-national levels, regional and local scales are taken centre stage within the dissertation. The Hase river catchment, which is located in one of Germany s most intensive livestock areas, serves as an example. The thesis shows that the procedural character of the WFD and regulative uncertainties give way to interpretation and action leeway, which will be pivotal to judgement on implementation success at lower levels. Moreover, the consistent operationalisation of nitrate limits in particular has led to major difficulties during implementation in Germany from which restraints can be expected for the preparation of river basin management plans and the program of measures. As to the regional level, implementation restraints also upraise due to socio-economic dependencies from agriculture and a high identification of the regional population with this economic sector have placed agriculture in a powerful position. In conclusion, one can state that various implementation restraints occur and the cause of these can be found at all scales European, sub-national and regional. The results of this dissertation concerning the multi-level system reveal that the relationship and interaction of the various scales will be given increased attention during the implementation process of European environmental policy. Besides the national and sub-national scale, the regional and local levels will be of equal importance. The question of suitable scales for implementation decisions and measures also offers pivotal approaches to undertake future research. Further research needs occur with new regional studies at national and international scales, with regard to the future of water protection in the course of the reform of German federalism and the current debate on climate change.

Untersucht werden die sozioökonomischen und kulturellen Voraussetzungen für die Biogastechnik in der Landwirtschaft. Besondere Aufmerksamkeit gilt den Auswirkungen auf den Ressourcen- und Klimaschutz. Biogasanlagen sind als integrative Technik konzipiert. Sie lassen sich in die regionalen und lokalen Kreisläufe einfügen mit positiven Effekten für die Natur und Umwelt. Doch inzwischen gehen diese ökologischen Eigenschaften der Biogastechnik durch ihre Ausrichtung auf maximalen Output verloren. Ausgangspunkt der Betrachtung ist die Theorie einer ökologischen Modernisierung der Gesellschaft, die spezifisch auf die Landwirtschaft übertragen wird. Die Verbindung von Modernität und Ökologie wird als eine zentrale Frage der Zukunft der Agrarwirtschaft und der ländlichen Räume gestellt. Die Erweiterung des Rationalisierungsbegriffs auf ethische und normative Fragen des Umwelt- und Naturschutzes stellt eine Herausforderung für die modernen Landwirte dar. Die widersprüchlichen Anforderungen, die den Landwirten gestellt worden waren - ökonomische Effizienz einerseits, ökologische Erfordernisse andererseits - hatten zur Krise des Bewusstseinzustands des Agrarmenschen beigetragen. Eine Typologie des ökologisch-modernen Landwirts dient der späteren Analyse von Gruppen der Energiewirte, die in der Empirie identifiziert wurden. Im Sinne einer ökologischen Reform der Landwirtschaft hebt sich die Gruppe der Umsteiger besonders hervor. Dazu gehören solche Biogasanlagenbetreiber, die die ökologischen Innovationen wegen langfristiger ökonomischer Vorteile einführen und sich damit auch in ihrer neuen gesellschaftlichen Rolle als Ressourcenmanager gestärkt wissen. Es stellt sich die Frage, wie diese Landwirte in ihrem Beitrag zur Entwicklung dezentraler Energieerzeugung gefördert werden sollten.

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