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Electrical Characterization of Organic Devices and Solar Cells by Impedance SpectroscopyBurtone, Lorenzo 25 July 2014 (has links) (PDF)
In this work, the capacitive response of organic electronic devices is analysed. Particular attention is given to small-molecule organic solar cells, with the purpose of deriving an equivalent circuit for the small-signal response of these devices. The different components characterising the solar cells electrical response are individuated and discussed and a specific physical meaning is associated with each element of the equivalent circuit.
In the experimental section, the capacitive elements of the equivalent circuit are characterised by analysing organic diodes and solar cells. It is found that the capacitance of an organic solar cell is a combination of four components: the dielectric response of the materials, the depletion regions formed at the interfaces, the accumulation of free and trapped charge carriers.
The depletion regions formed in organic doped semiconductors are characterised by analysing organic p/n homojunction diodes composed of Zinc-Phtalocyanine (ZnPc). The results demonstrate that the mechanisms involved in the formation of depletion zones in organic semiconductors can be described by the classical Mott-Schottky theory. This allows to estimate the free charge carrier density of doped layers with capacitance measurements. In addition, the current-voltage characteristics of organic p/n homojunctions are found not to obey the classical Shockley theory.
It is demonstrated that charge carrier tunnelling is the cause of this discrepancy and an analytic model is used to describe the current-voltage characteristics. The accumulation of free charge carriers is found to induce capacitance effects typical of relaxation semiconductors. In presence of unbalanced charge carriers injection, negative capacitance values are observed.
It is shown that in different organic semiconductor devices, the injection of minority charge carriers induces a depletion in the majority concentration, resulting in a negative value of the accumulation capacitance.
Finally, the capacitance associated to trap states in ZnPc:C60 organic solar cells is analysed. The spatial position and occupation mechanisms of the traps are estimated. The trapping mechanism in small-molecule organic solar cells is clarified and the energetic distribution of these trap states is estimated being a Gaussian function with 55 meV width, a density of 3.5 × 1016 cm−3 and centred 0.458 eV below the electron transport level. Trap states are also found to act as recombination centres, limiting the efficiency of organic solar cells.
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Direct Patterning of Optical Coupling Devices in Polymer WaveguidesFinn, Andreas 26 May 2014 (has links) (PDF)
The aim of the present work was to design and fabricate all purpose, positioning-tolerant and efficient interconnects between single-mode fibers and integrated waveguides out of polymers. The developed structures are part of the optical packaging of integrated optical chips. Integrated optics have gathered tremendous interest throughout recent years from research as well as from the industry, and most likely the demand will further grow in the future. Today’s trend is to establish optical data communication not only in far-distance transmission but also in end-user or so called fiber-to-home configurations, or, in the near future, also on board or even chip level. In addition, integrated optical sensors are gaining more and more importance. In the future, lab-on-a-chip systems may be able to simplify and accelerate analysis methods within health care or allow for a continuous monitoring of almost any environmental variable. All these applications call for robust optical packaging solutions. Many integrated optical chips are using a silicon-on-insulator design. Technologies which were originally intended for the manufacturing of integrated circuits can be utilized for the fabrication of such silicon-on-insulator chips. Point-of-care testing, which is a considerable part of bio-sensing, in some cases only allows the use of disposable transducer elements. The fabrication of these transducers, also including almost all other system parts, may be possible using polymers. Alternative fabrication methods like nanoimprint lithography can be applied for the patterning of polymers. With these, the extension of already known working principles or even entirely new device architectures become feasible for mass production.
The direct patterning of polymers by means of nanoimprint was used to fabricate interconnects for integrated waveguides. In contrast to conventional lithography approaches, where a patterned resist layer is used as a masking layer for subsequent process steps, direct patterning allows the immediate use of the structures as functional elements. Firstly, nanoimprint allows diffraction-unlimited patterning with nanometer resolutions as well as the replication of complex three-dimensional patterns. These unique properties were used within this work to pattern shallow gratings atop an integrated waveguide within only one single manufacturing step. The gratings are used as coupling elements and can be utilized either to couple light from external elements to the chip or vice versa. Considerations regarding the optical effects on single-mode polymer waveguides as well as grating couplers were obtained from simulation. They are specific to the chosen design and the used polymer and cannot be found elsewhere so far. Compared to similar designs and fabrication strategies proposed in literature, the ones followed here allow for a higher efficiency.
The dimensions and process windows obtained from simulation did serve as a basis for the subsequent fabrication of the grating couplers. All steps which are necessary to turn the calculated design into reality, ranging from master fabrication, to working mold cast and imprint, are shown in detail. The use of a working mold strategy is of crucial importance for the fabrication process and is discussed in detail. The use of a working mold preserves a costly master and further allows for a cost-efficient production. Parameters which are relevant for the production as well as for the final polymer patterns were analyzed and discussed. On the basis of the obtained data, a process optimization was performed. The optical characterization was also part of the presented work. A comparison with the results obtained from simulation is included and additional effects were revealed. Most of them may be subject to further improvement in future designs.
In summary, the present work contributes to the field of optical packaging. It shows a viable route for the design and fabrication of interconnects of single-mode polymer waveguides. The presented design can be used as a building block which can be placed at almost any positions within an integrated optical chip. The fabrication method includes a minimum number of process steps and is still able to increase performance compared to similar approaches. Moreover, all process steps allow for scaling and are potential candidates for mass production.
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High-rate growth of hydrogenated amorphous and microcrystalline silicon for thin-film silicon solar cells using dynamic very-high frequency plasma-enhanced chemical vapor depositionZimmermann, Thomas 29 January 2014 (has links) (PDF)
Thin-film silicon tandem solar cells based on a hydrogenated amorphous silicon (a-Si:H) top-cell and a hydrogenated microcrystalline silicon (μc-Si:H) bottom-cell are a promising photovoltaic technology as they use a combination of absorber materials that is ideally suited for the solar spectrum. Additionally, the involved materials are abundant and non-toxic which is important for the manufacturing and application on a large scale.
One of the most important factors for the application of photovoltaic technologies is the cost per watt. There are several ways to reduce this figure: increasing the efficiency of the solar cells, reducing the material consumption and increasing the throughput of the manufacturing equipment.
The use of very-high frequencies has been proven to be beneficial for the material quality at high deposition rates thus enabling a high throughput and high solar cell efficiencies. In the present work a scalable very-high frequency plasma-enhanced chemical vapor deposition (VHF-PECVD) technique for state-of-the-art solar cells is developed. Linear plasma sources are applied which facilitate the use of very-high frequencies on large areas without compromising on the homogeneity of the deposition process.
The linear plasma sources require a dynamic deposition process with the substrate passing by the electrodes in order to achieve a homogeneous deposition on large areas. State-of-the-art static radio-frequency (RF) PECVD processes are used as a reference in order to assess the potential of a dynamic VHF-PECVD technique for the growth of high-quality a-Si:H and μc-Si:H absorber layers at high rates.
In chapter 4 the influence of the deposition process of the μc-Si:H i-layer on the solar cell performance is studied for static deposition processes. It is shown that the correlation between the i-layer growth rate, its crystallinity and the solar cell performance is similar for VHF- and RF-PECVD processes despite the different electrode configurations, excitation frequencies and process regimes. It is found that solar cells incorporating i-layers grown statically using VHF-PECVD processes obtain a state-of-the-art efficiency close to 8 % for growth rates up to 1.4 nm/s compared to 0.53 nm/s for RF-PECVD processes.
The influence of dynamic deposition processes on the performance of μc-Si:H solar cells is studied. It is found that μc-Si:H solar cells incorporating dynamically grown i-layers obtain an efficiency of 7.3 % at a deposition rate of 0.95 nm/s. There is a small negative influence of the dynamic deposition process on the solar cell efficiency compared to static deposition processes which is related to the changing growth conditions the substrate encounters during a dynamic i-layer deposition process.
The changes in gas composition during a dynamic i-layer deposition process using the linear plasma sources are studied systematically using a static RF-PECVD regime and applying a time-dependent gas composition. The results show that the changes in the gas composition affect the solar cell performance if they exceed a critical level.
In chapter 5 dynamic VHF-PECVD processes for a-Si:H are developed in order to investigate the influence of the i-layer growth rate, process parameters and deposition technique on the solar performance and light-induced degradation. The results in this work indicate that a-Si:H solar cells incorporating i-layers grown dynamically by VHF-PECVD using linear plasma sources perform as good and better as solar cells with i-layers grown statically by RF-PECVD at the same deposition rate. State-of-the-art stabilized a-Si:H solar cell efficiencies of 7.6 % are obtained at a growth rate of 0.35 nm/s using dynamic VHF-PECVD processes.
It is found that the stabilized efficiency of the a-Si:H solar cells strongly decreases with the i-layer deposition rate. A simplified model is presented that is used to obtain an estimate for the deposition rate dependent efficiency of an a-Si:H/μc-Si:H tandem solar cell based on the photovoltaic parameters of the single-junction solar cells. The aim is to investigate the individual influences of the a-Si:H and μc-Si:H absorber layer deposition rates on the performance of the tandem solar cell.
The results show that a high deposition rate of the μc-Si:H absorber layer has a much higher potential for reducing the total deposition time of the absorber layers compared to high deposition rates for the a-Si:H absorber layer. Additionally, it is found that high deposition rates for a-Si:H have a strong negative impact on the tandem solar cell performance while the tandem solar cell efficiency remains almost constant for higher μc-Si:H deposition rates.
It is concluded that the deposition rate of the μc-Si:H absorber layer is key to reduce the total deposition time without compromising on the tandem solar cell performance. The developed VHF-PECVD technique using linear plasma sources is capable of meeting this criterion while promoting a path to scale the processes to large substrate areas.
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Propagation effects influencing polarimetric weather radar measurements / Ausbreitungseffekte beeinflussen polarimetrische WetterradarmessungenOtto, Tobias 10 August 2011 (has links) (PDF)
Ground-based weather radars provide information on the temporal evolution and the spatial distribution of precipitation on a macroscopic scale over a large area. However, the echoes measured by weather radars are always a superposition of forward and backward scattering effects which complicates their interpretation. The use of polarisation diversity enhances the number of independent observables measured simultaneously. This allows an effective separation of forward and backward scattering effects. Furthermore, it extends the capability of weather radars to retrieve also microphysical information about the precipitation. The dissertation at hand introduces new aspects in the field of polarimetric, ground-based, monostatic weather radars at S-, C-, and X-band. Relations are provided to change the polarisation basis of reflectivities. A fully polarimetric weather radar measurement at circular polarisation basis is analysed. Methods to check operationally the polarimetric calibration of weather radars operating at circular polarisation basis are introduced. Moreover, attenuation correction methods for weather radar measurements at linear horizontal / vertical polarisation basis are compared to each other, and the robustly working methods are identified. / Bodengebundene Wetterradare bieten Informationen über die zeitliche Entwicklung und die räumliche Verteilung von Niederschlag in einer makroskopischen Skala über eine große Fläche. Die Interpretation der Wetterradarechos wird erschwert, da sie sich aus einer Überlagerung von Vorwärts- und Rückwärtsstreueffekten ergeben. Die Anzahl der unabhängigen Wetterradarmessgrößen kann durch den Einsatz von Polarisationsdiversität erhöht werden. Dies ermöglicht eine effektive Trennung von Vorwärts- und Rückwärtsstreueffekten. Desweiteren erlaubt es die Bestimmung von mikrophysikalischen Niederschlagsparametern. Die vorliegende Dissertation betrachtet neue Aspekte für polarimetrische, bodengebundene, monostatische Wetterradare im S-, C- und X-Band. Gleichungen zur Polarisationsbasistransformation von Reflektivitätsmessungen werden eingeführt. Eine vollpolarimetrische Wetterradarmessung in zirkularer Polarisationsbasis wird analysiert. Neue Methoden, die eine Überprüfung der polarimetrischen Kalibrierung von Wetterradarmessungen in zirkularer Polarisationsbasis erlauben, werden betrachtet. Weiterhin werden Methoden zur Dämpfungskorrektur von Wetterradarmessungen in linearer horizontaler / vertikaler Polarisationsbasis miteinander verglichen und Empfehlungen von zuverlässigen Methoden gegeben.
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Resilience of the Critical Communication Networks Against Spreading FailuresMurić, Goran 14 September 2017 (has links) (PDF)
A backbone network is the central part of the communication network, which provides connectivity within the various systems across large distances. Disruptions in a backbone network would cause severe consequences which could manifest in the service outage on a large scale. Depending on the size and the importance of the network, its failure could leave a substantial impact on the area it is associated with. The failures of the network services could lead to a significant disturbance of human activities. Therefore, making backbone communication networks more resilient directly affects the resilience of the area. Contemporary urban and regional development overwhelmingly converges with the communication infrastructure expansion and their obvious mutual interconnections become more reciprocal.
Spreading failures are of particular interest. They usually originate in a single network segment and then spread to the rest of network often causing a global collapse. Two types of spreading failures are given focus, namely: epidemics and cascading failures. How to make backbone networks more resilient against spreading failures? How to tune the topology or additionally protect nodes or links in order to mitigate an effect of the potential failure? Those are the main questions addressed in this thesis.
First, the epidemic phenomena are discussed. The subjects of epidemic modeling and identification of the most influential spreaders are addressed using a proposed Linear Time-Invariant (LTI) system approach. Throughout the years, LTI system theory has been used mostly to describe electrical circuits and networks. LTI is suitable to characterize the behavior of the system consisting of numerous interconnected components. The results presented in this thesis show that the same mathematical toolbox could be used for the complex network analysis.
Then, cascading failures are discussed. Like any system which can be modeled using an interdependence graph with limited capacity of either nodes or edges, backbone networks are prone to cascades. Numerical simulations are used to model such failures. The resilience of European National Research and Education Networks (NREN) is assessed, weak points and critical areas of the network are identified and the suggestions for its modification are proposed.
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Properties of timebased local OctoMapsWeissig, Peter 22 August 2017 (has links) (PDF)
Autonomous navigation of our rough-terrain rovers implies the need of a good representation of their near surrounding. In order to archive this we fuse several of their sensors into one representation called OctoMap. But moving obstacles can produce artefacts, leading to untraversable re- gions. Furthermore the map itself is increasing in size while discovering new places. Even though we are only interested in the near surrounding of the rovers. Our approach to these problems is the usage of timestamps within the map. If a certain region was not updated within a given interval, it will be set to free space or deleted from the map. This first option is an existing solution and the second option reflects our new alternative.
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Design of a Dual Band Local Positioning SystemJoram, Niko 09 November 2015 (has links) (PDF)
This work presents a robust dual band local positioning system (LPS) working in the 2.4GHz and 5.8GHz industrial science medical (ISM) bands. Position measurement is based on the frequency-modulated continuous wave (FMCW) radar approach, which uses radio frequency (RF) chirp signals for propagation time and therefore distance measurements. Contrary to state of the art LPS, the presented system uses data from both bands to improve accuracy, precision and robustness. A complete system prototype is designed consisting of base stations and tags encapsulating most of the RF and analogue signal processing in custom integrated circuits. This design approach allows to reduce size and power consumption compared to a hybrid system using off-the-shelf components. Key components are implemented using concepts, which support operation in multiple frequency bands, namely, the receiver consisting of a low noise amplifier (LNA), mixer, frequency synthesizer with a wide band voltage-controlled oscillator (VCO) having broadband chirp generation capabilities and a dual band power amplifier.
System imperfections occurring in FMCW radar systems are modelled. Effects neglected in literature such as compression, intermodulation, the influence of automatic gain control, blockers and spurious emissions are modeled. The results are used to derive a specification set for the circuit design. Position estimation from measured distances is done using an enhanced version of the grid search algorithm, which makes use of data from multiple frequency bands. The algorithm is designed to be easily and efficiently implemented in embedded systems. Measurements show a coverage range of the system of at least 245m. Ranging accuracy in an outdoor scenario can be as low as 8.2cm. Comparative dual band position measurements prove an effective outlier filtering in indoor and outdoor scenarios compared to single band results, yielding in a large gain of accuracy.
Positioning accuracy in an indoor scenario with an area of 276m² can be improved from 1.27m at 2.4GHz and 1.86m at 5.8GHz to only 0.38m in the dual band case, corresponding to an improvement by at least a factor of 3.3. In a large outdoor scenario of 4.8 km², accuracy improves from 1.88m at 2.4GHz and 5.93m at 5.8GHz to 0.68m with dual band processing, which is a factor of at least 2.8. / Die vorliegende Arbeit befasst sich mit dem Entwurf eines robusten lokalen Positionierungssystems (LPS), welches in den lizenzfreien Frequenzbereichen für industrielle, wissenschaftliche und medizinische Zwecke (industrial, scientific, medical, ISM) bei 2,4GHz und 5,8GHz arbeitet. Die Positionsbestimmung beruht auf dem Prinzip des frequenzmodulierten Dauerstrichradars (frequency modulated continuous wave, FMCW-Radar), welches hochfrequente Rampensignale für Laufzeitmessungen und damit Abstandsmessungen benutzt. Im Gegensatz zu aktuellen Arbeiten auf diesem Gebiet benutzt das vorgestellte System Daten aus beiden Frequenzbändern zur Erhöhung der Genauigkeit und Präzision sowie Verbesserung der Robustheit. Ein Prototyp des kompletten Systems bestehend aus Basisstationen und mobilen Stationen wurde entworfen.
Fast die gesamte analoge hochfrequente Signalverarbeitungskette wurde als anwendungsspezifische integrierte Schaltung realisiert. Verglichen mit Systemen aus Standardkomponenten erlaubt dieser Ansatz die Miniaturisierung der Systemkomponenten und die Einsparung von Leistung. Schlüsselkomponenten wurden mit Konzepten für mehrbandige oder breitbandige Schaltungen entworfen. Dabei wurden Sender und Empfänger bestehend aus rauscharmem Verstärker, Mischer und Frequenzsynthesizer mit breitbandiger Frequenzrampenfunktion implementiert. Außerdem wurde ein Leistungsverstärker für die gleichzeitige Nutzung der beiden definierten Frequenzbänder entworfen.
Um Spezifikationen für den Schaltungsentwurf zu erhalten, wurden in der Fachliteratur vernachlässigte Nichtidealitäten von FMCW-Radarsystemen modelliert. Dazu gehören Signalverzerrungen durch Kompression oder Intermodulation, der Einfluss der automatischen Verstärkungseinstellung sowie schmalbandige Störer und Nebenschwingungen. Die Ergebnisse der Modellierung wurden benutzt, um eine Spezifikation für den Schaltungsentwurf zu erhalten.
Die Schätzung der Position aus gemessenen Abständen wurde über eine erweiterte Version des Gittersuchalgorithmus erreicht. Dieser nutzt die Abstandsmessdaten aus beiden Frequenzbändern. Der Algorithmus ist so entworfen, dass er effizient in einem eingebetteten System implementiert werden kann. Messungen zeigen eine maximale Reichweite des Systems von mindestens 245m. Die Genauigkeit von Abstandsmessungen im Freiland beträgt 8,2cm. Positionsmessungen wurden unter Verwendung beider Einzelbänder durchgeführt und mit den Ergebnissen des Zweiband-Gittersuchalgorithmus verglichen. Damit konnte eine starke Verbesserung der Positionsgenauigkeit erreicht werden. Die Genauigkeit in einem Innenraum mit einer Grundfläche von 276m² kann verbessert werden von 1,27m bei 2,4GHz und 1,86m bei 5,8GHz zu nur 0,38m im Zweibandverfahren. Das entspricht einer Verbesserung um einen Faktor von mindestens 3,3. In einem größeren Außenszenario mit einer Fläche von 4,8 km² verbessert sich die Genauigkeit um einen Faktor von mindestens 2,8 von 1,88m bei 2,4GHz und 5,93m bei 5,8GHz auf 0,68m bei Nutzung von Daten aus beiden Frequenzbändern.
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Neues Planungsverfahren für Anlagen der Leit- und Sicherungstechnik auf Basis durchgängiger elektronischer DatenhaltungBuder, Jens 23 February 2017 (has links) (PDF)
Zur Errichtung und Inbetriebnahme von Anlagen der Leit- und Sicherungstechnik (LST), zu denen beispielsweise Elektronische Stellwerke (ESTW) gehören, sind unter anderem definierte Planungs-, Begutachtungs- und Freigabeschritte zu durchlaufen. Die vorliegende Arbeit thematisiert den LST-Planungsprozess hinsichtlich seiner erforderlichen Abläufe und Komplexität im Vergleich der bisherigen Regelwerksvorgaben mit praktischen Umsetzungen. Auf den Analyseergebnissen einschließlich herausgearbeiteter Probleme aufbauend, werden unter Berücksichtigung aktueller Erkenntnisse aus dem Forschungsprojekt „PlanPro - Durchgängige elektronische Datenhaltung im ESTW-Planungsprozess“ Vorschläge für einen zukünftigen LST-Planungsprozess vorgestellt und wissenschaftlich aufbereitet. Dabei sollen durch den verstärkten Einsatz IT-gestützter Verfahren die Planungsqualität erhöht und die Prozesse insgesamt beschleunigt werden. In der Arbeit werden auch grundlegende Neuerungen mit PlanPro dargestellt, ebenso wie Anforderungen an die LST-Datenbank, die zukünftig eine zentrale Rolle für das Abspeichern und Weitergeben von Planungs- und Bestandsdaten einnehmen wird. Erläuterungen zu einem denkbaren Einführungskonzept sowie eine Schlussbetrachtung runden diese Dissertation ab. / For installation and commissioning of railway signalling equipment, which may include computer-based interlocking (CBI), defined tasks for planning, assess-ment and approval have to be executed. This dissertation analyses the planning process of the railway signalling equipment with regard to its necessary processes and complexity. Additionally, it compares existing legal requirements with their practical realisation. Based on the results of this analysis and their identified problems, proposals for a future planning process for railway signalling equipment will be scientifically prepared and presented. They are taking into account the latest results from the research project "PlanPro - Integrated electronic data storage in electronic interlocking planning process". By the progressive use of IT-based processes, planning quality will be increased and the processes can be accelerated altogether. Thereupon, fundamental changes based on PlanPro are presented. This applies to requirements for the database of railways signalling equipment, which will play a key role for the storage and sharing of planning and inventory data in the future, too. An explanation of a possible introduction concept as well as a conclusion complete this disserta-tion.
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Langzeitverhalten von Schraubenverbindungen mit Stromschienen aus Reinkupfer in der Elektroenergietechnik unter besonderer Berücksichtigung der TemperaturSchlegel, Stephan 25 July 2017 (has links) (PDF)
Elektrische Verbindungen in der Elektroenergietechnik sind aus technologischen und konstruktiven Gründen beim Zusammenschalten von Betriebsmitteln in Schaltanlagen und auf den Übertragungswegen bei Kabeln und Freileitungen notwendig. Als elektrischer Kontakt wird die Berührung zweier stromführender Leiter verstanden. Eine Verbindungsart, die häufig bei Stromschienen eingesetzt wird, ist die Schraubenverbindung.
Um eine Lebensdauer dieser Verbindung von üblicherweise 50 Jahren und mehr zu gewährleisten, ist es notwendig, die Alterung abhängig von der Zeit und der Temperatur zu kennen. Neben dem Kraftabbau und den chemischen Reaktionen / Fremdschichtbildung bei Verbindungen mit Kupfer- oder Aluminiumleitern ist die Interdiffusion bei Bimetallverbindungen und bei Verbindungen mit beschichteten Kontaktpartnern von Bedeutung.
In dieser Arbeit wurde der Kraftabbau bei Schraubenverbindungen mit Stromschienen aus Cu-ETP (Werkstoff-Nr. CW004A) und CuAg0,1P (Werkstoff-Nr. CW016A) im Temperaturbereich zwischen 105 °C und 160 °C untersucht. Es wurde die Kraft und der Widerstand an stromdurchflossenen Verbindungen abhängig von der Zeit bis zu 2,4 Jahren gemessen. Des Weiteren wurde der Einfluss von verschiedenen federnden und nicht federnden Elementen im Verbindungssystem auf den Kraftabbau untersucht. Es wurde eine statische Mindestverbindungskraft bestimmt, der Kraftabbau bis zu einer Lebensdauer von 50 Jahren berechnet und daraus eine Grenztemperatur für diese Verbindungsart bestimmt.
Neben dem Kraftabbau wurde die Alterung durch Interdiffusion an Schraubenverbindungen mit verzinnten und versilberten Cu-ETP Stromschienen im Temperaturbereich zwischen 115 °C und 140 °C untersucht. Es wurde an stromdurchflossenen und im Wärmeschrank gelagerten Verbindungen der Verbindungswiderstand abhängig von der Zeit bis zu 2 Jahren gemessen. Die Langzeitversuche wurden durch mikroskopische Untersuchungen ergänzt, in denen die Dicke der sich gebildeten intermetallischen Phasen gemessen und bewertet wurde.
Ergänzend zu den Langzeituntersuchungen wurden aktuelle Erkenntnisse zu den chemischen Reaktionen / Fremdschichtbildung auf Kupfer-, Silber- und Zinnoberflächen zusammengestellt und bewertet. / Electrical joints are necessary for technological and design reasons to connect electric equipment and to realize the transmission of electrical energy by cables and overhead lines. The contact between two current-flown electrical conductors is called electrical joint. One joint type often used is the bolted joint.
To allow a lifetime of this joint of 50 years and longer it is necessary to know the ageing depend on time and temperature. In addition to ageing by force reduction and the chemical reactions / impurity layers at joints with copper und aluminium conductors, the interdiffusion has a great influence at bi-metal joints and joints with plated conductors.
In this work the force reduction was analysed at bolted joints with bus bars made of Cu-ETP (material number CW004A) and CuAg0.1P (material number CW016A) in a temperature range between 105 °C and 160 °C. The joint force and the joint resistance were measured time-depended at current-flown joints up to 2.4 years. Furthermore the influence on the force reduction by different resilient und non-resilient elements in the joint system was tested. There was a minimum static joint force appointed and the force reduction calculated to a lifetime of 50 years. Out of these results a category temperature for these joints was defined.
Additionally the ageing due to interdiffusion at bolted joints with tin and silver plated Cu-ETP bus bars was analysed at the temperatures 115 °C and 140 °C. At joints aged by current-flown and in the heating cabinet the joint resistance was measured time-dependent up to 2 years. These long-term tests were supplemented by microscopic examinations. The thickness of the grown intermetallic compounds was measured and stated.
Additional to the long-term tests the topical knowledge to chemical reactions / impurity layers at copper, silver and tin surfaces was composed and stated.
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Wearables im industriellen EinsatzZiegler, Jens 18 May 2016 (has links) (PDF)
Die industrielle Instandhaltung ist ein erheblicher Kostenfaktor während der Betriebsphase einer verfahrenstechnischen Produktionsanlage. Insbesondere der Mangel an technischen Möglichkeiten zum Informationsaustausch des Instandhaltungspersonals mit der digitalen Anlage während der Arbeiten im Feld erzeugt hohe Kosten. Durch die entstehenden Medienbrüche sinkt die Qualität der Informationen in der Digitalen Anlage erheblich. Mobile Informationssysteme können diese Medienbrüche beseitigen und die Informationsqualität in der Digitalen Anlage entscheidend verbessern. Das Konzept der Distributed Wearable User Interfaces (DWUI) stellt einen integrierten Ansatz zur flexiblen Zusammenstellung gebrauchstauglicher Benutzungsschnittstellen für komplexe Arbeitsabläufe in widrigen Arbeitssituationen bereit. Diese setzen sich aus Interaktionsgeräten zusammen, die in einem kabellosen körpernahen Funknetzwerk miteinander verbunden sind und in ihrer Kombination die Benutzungsschnittstelle zu einem mobilen System bilden. Die Geräte sind ergonomisch und funktional optimal am Körper des Nutzers verteilt, wobei jedes Gerät eigenständig nutzbar und für eine bestimmte Aufgabe oder einen bestimmten Nutzungskontext optimiert ist. Die Ein- und Ausgaberäume der Geräte werden in einem integrierten Interaktionsraum harmonisiert.
Im Rahmen dieser Arbeit wird zunächst der Nutzungskontext der mobilen IT-gestützten Instandhaltung verfahrenstechnischer Produktionsanlagen im Hinblick auf Nutzungsszenarien und Anwendungsfälle für mobile Informationssysteme festgelegt. Darauf aufbauend werden Anforderungen an derartige Systeme spezifiziert und Gestaltungsgrundlagen und Empfehlungen speziell für DWUI-basierte mobile Informationssysteme erarbeitet. Anschließend wird eine Reihe spezieller Interaktionsgeräte vorgestellt, die verschiedene Interaktionsprinzipien, Techniken und Modalitäten umsetzen. Um diese Geräte in einem kollaborativen DWUI organisieren zu können, wird ein spezielles Kommunikationsprotokoll entworfen und prototypisch umgesetzt. Eine mobile Anwendung zur Instandhaltungsunterstützung wird vorgestellt, welche das DWUI-Kommunikationsprotokoll unterstützt und mit verschiedenen DWUI-Konfigurationen vollständig bedienbar ist. Diese Anwendung wird integriert in ein komplexes Unternehmensnetzwerk, über das sie Zugriff auf industrietypische computergestützte Planungswerkzeuge erhält. Anhand des resultierenden Gesamtsystems werden die prinzipielle Tauglichkeit und die Vorteile des DWUI-Konzepts demonstriert.
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