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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
561

Quantitative microscopy of coating uniformity

Dahlström, Christina January 2012 (has links)
Print quality demands for coated papers are steadily growing, and achieving coating uniformity is crucial for high image sharpness, colour fidelity, and print uniformity. Coating uniformity may be divided into two scales: coating thickness uniformity and coating microstructure uniformity, the latter of which includes pigment, pore and binder distributions within the coating layer. This thesis concerns the investigation of both types of coating uniformity by using an approach of quantitative microscopy.First, coating thickness uniformity was analysed by using scanning electron microscope (SEM) images of paper cross sections, and the relationships between local coating thickness variations and the variations of underlying base sheet structures were determined. Special attention was given to the effect of length scales on the coating thickness vs. base sheet structure relationships.The experimental results showed that coating thickness had a strong correlation with surface height (profile) of base sheet at a small length scale. However, at a large length scale, it was mass density of base sheet (formation) that had the strongest correlation with coating thickness. This result explains well the discrepancies found in the literature for the relationship between coating thickness variation and base sheet structure variations. The total variance of coating thickness, however, was dominated by the surface height variation in the small scale, which explained around 50% of the variation. Autocorrelation analyses were further performed for the same data set. The autocorrelation functions showed a close resemblance of the one for a random shot process with a correlation length in the order of fibre width. All these results suggest that coating thickness variations are the result of random deposition of particles with the correlation length determined by the base sheet surface textures, such as fibre width.In order to obtain fundamental understandings of the random deposition processes on a rough surface, such as in paper, a generic particle deposition model was developed, and systematic analyses were performed for the effects of particle size, coat weight (average number of particles), levelling, and system size on coating thickness variation. The results showed that coating thickness variation3grows with coat weight, but beyond a certain coat weight, it reaches a plateau value. A scaling analysis yielded a universal relationship between coating thickness variation and the above mentioned variables. The correlation length of coating thickness was found to be determined by average coat weight and the state of underlying surfaces. For a rough surface at relatively low coat weight, the correlation length was typically in the range of fibre width, as was also observed experimentally.Non-uniformities within the coating layer, such as porosity variations and binder distributions, are investigated by using a newly developed method: field emission scanning electron microscopy (FESEM) in combination with argon ion beam milling technique. The combination of these two techniques produced extremely high quality images with very few artefacts, which are particularly suited for quantitative analyses of coating structures. A new evaluation method was also developed by using marker-controlled watershed segmentation (MCWS) of the secondary electron images (SEI).The high resolution imaging revealed that binder enrichment, a long disputed subject in the area, is present in a thin layer of a 500 nm thickness both at the coating surface and at the base sheet/coating interface. It was also found that the binders almost exclusively fill up the small pores, whereas the larger pores are mainly empty or depleted of binder.
562

Quark Distributions and Charged Higgs Boson Production : Studies of Proton Structure and New Physics

Alwall, Johan January 2005 (has links)
The Standard Model describes all elementary particles known today, but at larger energies it will have to be complemented with new particles and interactions. To be able to distinguish new physics at proton colliders such as LHC at CERN, it is essential to have an appropriate description of the colliding protons and their interactions. The study of the proton is important also in itself, to get a better understanding of the non-perturbative aspects of the strong interaction. In paper I-IV of this thesis, a model for the non-perturbative dynamics of quarks and gluons is developed, based on quantum fluctuations in hadrons. The parton distributions of the proton are given by momentum fluctuations, with sea quark distributions generated by fluctuations into baryon-meson pairs. This model can reproduce proton structure function data, as well as measured asymmetries between up and down valence quark distributions and between the anti-up and anti-down sea. It provides an intrinsic charm quark component as indicated by data. It also predicts an asymmetry in the strange sea of the proton, which can explain the NuTeV anomaly first attributed to new physics beyond the Standard Model. Charged Higgs bosons are predicted by several theories for new physics, including Supersymmetry. At proton colliders, the predicted dominant production mechanism is in association with top and bottom quarks. In paper V-VII, different contributions to this production are studied, and an algorithm is developed for combining the two dominant processes gb -> tH+/- and gg -> tbH+/-. The algorithm gives a smooth transition from small to large transverse momenta of the b-quark, which is important when the b-quark is observed. It also gives arguments for the choice of factorisation scale in the process.
563

Impact of residential wood combustion on urban air quality

Krecl, Patricia January 2008 (has links)
Wood combustion is mainly used in cold regions as a primary or supplemental space heating source in residential areas. In several industrialized countries, there is a renewed interest in residential wood combustion (RWC) as an alternative to fossil fuel and nuclear power consumption. The main objective of this thesis was to investigate the impact of RWC on the air quality in urban areas. To this end, a field campaign was conducted in Northern Sweden during wintertime to characterize atmospheric aerosol particles and polycyclic aromatic hydrocarbons (PAH) and to determine their source apportionment. A large day-to-day and hour-to-hour variability in aerosol concentrations was observed during the intensive field campaign. On average, total carbon contributed a substantial fraction of PM10 mass concentrations (46%) and aerosol particles were mostly in the fine fraction (PM1 accounted for 76% of PM10). Evening aerosol concentrations were significantly higher on weekends than on weekdays which could be associated to the use of wood burning for recreational purposes or higher space heat demand when inhabitants spend longer time at home. It has been shown that continuous aerosol particle number size distribution measurements successfully provided source apportionment of atmospheric aerosol with high temporal resolution. The first compound-specific radiocarbon analysis (CSRA) of atmospheric PAH demonstrated its potential to provide quantitative information on the RWC contribution to individual PAH. RWC accounted for a large fraction of particle number concentrations in the size range 25-606 nm (44-57%), PM10 (36-82%), PM1 (31-83%), light-absorbing carbon (40-76%) and individual PAH (71-87%) mass concentrations. These studies have demonstrated that the impact of RWC on air quality in an urban location can be very important and largely exceed the contribution of vehicle emissions during winter, particularly under very stable atmospheric conditions.
564

Study of Generalized Parton Distributions and Deeply Virtual Compton Scattering on the nucleon with the CLAS and CLAS12 detectors at the Jefferson Laboratory (Virginia, USA)

Guegan, Baptiste 27 November 2012 (has links) (PDF)
The Generalized Parton Distributions (GPDs) provide a new description of the nucleon structure in terms of its elementary constituents, the quarks and the gluons. The GPDs give access to a unified picture of the nucleon, correlating the information obtained from the measurements of the Form Factors and the Parton Distribution Functions. They describe the correlation between the transverse position and the longitudinal momentum fraction of the partons in the nucleon.Deeply Virtual Compton Scattering (DVCS), the electroproduction of a real photon on a single quark of the nucleon eN -> e'N'γ, is the most straightforward exclusive process allowing access to the GPDs. A dedicated experiment to study DVCS with the CLAS detector of Jefferson Lab has been carried out using a 5.883 GeV polarized electron beam and an unpolarized hydrogen target, allowing to collect DVCS events in the widest kinematic range ever explored in the valence region : 1 < Q^2 < 4.6 〖GeV〗^2, 0.1 < x_B < 0.58, 0.09 < -t < 3 〖GeV〗^2 .In this work, we present the extraction of three different DVCS observables: the unpolarized cross section, the difference of polarized cross sections and the beam spin asymmetry. We present comparisons with GPD model. We show a preliminary extraction of the GPDs using the latest fitting code procedure on our data, and a preliminary interpretation of the results in terms of parton density.
565

Reliability and cost/worth evaluation of generating systems utilizing wind and solar energy

Gen, Ba 29 August 2005
The utilization of renewable energy resources such as wind and solar energy for electric power supply has received considerable attention in recent years due to adverse environmental impacts and fuel cost escalation associated with conventional generation. At the present time, wind and/or solar energy sources are utilized to generate electric power in many applications. Wind and solar energy will become important sources for power generation in the future because of their environmental, social and economic benefits, together with public support and government incentives. <p>The wind and sunlight are, however, unstable and variable energy sources, and behave far differently than conventional sources. Energy storage systems are, therefore, often required to smooth the fluctuating nature of the energy conversion system especially in small isolated applications. The research work presented in this thesis is focused on the development and application of reliability and economic benefits assessment associated with incorporating wind energy, solar energy and energy storage in power generating systems. A probabilistic approach using sequential Monte Carlo simulation was employed in this research and a number of analyses were conducted with regards to the adequacy and economic assessment of generation systems containing wind energy, solar energy and energy storage. The evaluation models and techniques incorporate risk index distributions and different operating strategies associated with diesel generation in small isolated systems. Deterministic and probabilistic techniques are combined in this thesis using a system well-being approach to provide useful adequacy indices for small isolated systems that include renewable energy and energy storage. The concepts presented and examples illustrated in this thesis will help power system planners and utility managers to assess the reliability and economic benefits of utilizing wind energy conversion systems, solar energy conversion systems and energy storage in electric power systems and provide useful input to the managerial decision process.
566

Sélection de modèle : une approche décisionnelle

Boisbunon, Aurélie 14 January 2013 (has links) (PDF)
Cette thèse s'articule autour de la problématique de la sélection de modèle, étudiée dans le contexte de la régression linéaire. L'objectif est de déterminer le meilleur modèle de prédiction à partir de données mesurées, c'est-à-dire le modèle réalisant le meilleur compromis entre attache aux données et complexité du modèle. La contribution principale consiste en la dérivation de critères d'évaluation de modèles basés sur des techniques de théorie de la décision, plus précisément l'estimation de coût. Ces critères reposent sur une hypothèse distributionnelle plus large que l'hypothèse classique gaussienne avec indépendance entre les observations : la famille des lois à symétrie sphérique. Cette famille nous permet à la fois de nous affranchir de l'hypothèse d'indépendance et d'ajouter une plus grande robustesse puisque nos critères ne dépendent pas de la forme spécifique de la distribution. Nous proposons également une méthode de comparaison des critères dérivés au travers d'une mesure de type Erreur quadratique (MSE), qui permet de déterminer si un critère d'évaluation de modèle est meilleur qu'un autre. La seconde contribution attaque le problème de la construction des différents modèles comparés. Les collections de modèles considérées sont celles issues des méthodes de régularisation parcimonieuses, de type Lasso. En particulier, nous nous sommes intéressés à la Pénalité Concave Minimax (MCP), qui garde la sélection du Lasso tout en corrigeant son biais d'estimation. Cette pénalité correspond cependant à un problème non différentiable et non convexe. La généralisation des outils habituels de sous-différentielles grâce aux différentielles de Clarke a permis de déterminer les conditions d'optimalité et de développer un algorithme de chemin de régularisation pour le MCP. Enfin, nous comparons nos propositions avec celles de la littérature au travers d'une étude numérique, dans laquelle nous vérifions la qualité de la sélection. Les résultats montrent notamment que nos critères obtiennent des performances comparables à ceux de la littérature, et que les critères les plus couramment utilisés en pratique (validation croisée) ne sont pas toujours parmi les plus performants.
567

Análisis de los mecanismos de emisión y de las correlaciones angulares de los productos de interacción del 0-16 a 2,1 gev/a con núcleos de emulsión

Ruiz Jimeno, Alberto 03 June 1978 (has links)
The interactions, with emulsion nuclei, of O-16 ions accelerated at 2.1 GeV/nucleon in the Berkeley accelerator, are analyzed. A phenomenological study of the events, particularly reaction cross sections and multiplicities is exposed to nuclear theories with nucleons acting individually and collectively An study of the angular distributions of the reaction products and their correlations, particularly in the transversal space, is shown. Finally, a discussion of the present parton model of the nucleon structure is done, comparing it with the experimental results.
568

En undersökning om möjligheterna att använda återanvändningsbara pallband till enhetslaster omlastade till träpallar. / An investigation of the possibility to use reusable pallet strapping for unit loads reloaded to wooden pallets.

Björk, Tomas January 2007 (has links)
En undersökning om möjligheterna att använda återandvändningsbara pallband och de ekonomiska förutsättningarna för detta. En genomsökning av vad som finns på marknaden. Beräkning av de krafter som enhetslasten kan utsätta pallbanden för. Utveckling av egna förslag till återanvändningsbart pallband med snabbspänne och bandning på tre sidor. En översikt av de positiva och negativa effekter som blir vid ett byte från dagens bandning med PP-band till ett återanvändningsbart pallband / An investigation of the possibility to use reusable strapping and the economic conditions for this. Going trough what exist on the market. Calculation of the forces that the unit load can expose the strapping for. Developing of own suggestions for reusable strapping with quick buckle and strapping on three sides. A short look at the positive and negative effects that comes from a change from today’s strapping with PP-strap to a reusable strapping.
569

Automatic Markov Chain Monte Carlo Procedures for Sampling from Multivariate Distributions

Karawatzki, Roman, Leydold, Josef January 2005 (has links) (PDF)
Generating samples from multivariate distributions efficiently is an important task in Monte Carlo integration and many other stochastic simulation problems. Markov chain Monte Carlo has been shown to be very efficient compared to "conventional methods", especially when many dimensions are involved. In this article we propose a Hit-and-Run sampler in combination with the Ratio-of-Uniforms method. We show that it is well suited for an algorithm to generate points from quite arbitrary distributions, which include all log-concave distributions. The algorithm works automatically in the sense that only the mode (or an approximation of it) and an oracle is required, i.e., a subroutine that returns the value of the density function at any point x. We show that the number of evaluations of the density increases slowly with dimension. (author's abstract) / Series: Preprint Series / Department of Applied Statistics and Data Processing
570

Reliability and cost/worth evaluation of generating systems utilizing wind and solar energy

Gen, Ba 29 August 2005 (has links)
The utilization of renewable energy resources such as wind and solar energy for electric power supply has received considerable attention in recent years due to adverse environmental impacts and fuel cost escalation associated with conventional generation. At the present time, wind and/or solar energy sources are utilized to generate electric power in many applications. Wind and solar energy will become important sources for power generation in the future because of their environmental, social and economic benefits, together with public support and government incentives. <p>The wind and sunlight are, however, unstable and variable energy sources, and behave far differently than conventional sources. Energy storage systems are, therefore, often required to smooth the fluctuating nature of the energy conversion system especially in small isolated applications. The research work presented in this thesis is focused on the development and application of reliability and economic benefits assessment associated with incorporating wind energy, solar energy and energy storage in power generating systems. A probabilistic approach using sequential Monte Carlo simulation was employed in this research and a number of analyses were conducted with regards to the adequacy and economic assessment of generation systems containing wind energy, solar energy and energy storage. The evaluation models and techniques incorporate risk index distributions and different operating strategies associated with diesel generation in small isolated systems. Deterministic and probabilistic techniques are combined in this thesis using a system well-being approach to provide useful adequacy indices for small isolated systems that include renewable energy and energy storage. The concepts presented and examples illustrated in this thesis will help power system planners and utility managers to assess the reliability and economic benefits of utilizing wind energy conversion systems, solar energy conversion systems and energy storage in electric power systems and provide useful input to the managerial decision process.

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