Made available in DSpace on 2017-07-10T18:13:27Z (GMT). No. of bitstreams: 1 Fernanda de A Gurski.pdf: 1608576 bytes, checksum: 475c7482fe1de32140a798e3ebb23954 (MD5) Previous issue date: 2011-08-12 / The heterogeneity of substrate in streams promotes the colonization and diversity of benthic organisms. Among them, Chironomidae larvae are one of the most abundant in aquatic ecosystems. This study aimed at determining the composition, richness, diversity and the existence of distribution patterns of Chironomidae larvae in different microhabitats of preserved streams of Atlantic Forest. Samplings were performed in February and August 2010, with a Surber-type sampler. The environmental variables analyzed were not significantly different between sampled streams, but the taxonomic richness of Chironomidae larvae was distinct between the microhabitats. In the total, 6,429 Chironomidae larvae were identified and classified into 96 taxa belonging to the subfamilies Chironominae, Tanypodinae and Ortocladiinae. The analyses of density, richness, evenness and diversity, in relation to the months, sites and microhabitats, have pointed out statistically significant differences in the larval distribution for the different microhabitats. Among them, the highest richness was observed in the deposits of litter, and the highest number of exclusive species took place in the pool regions. Thus, the composition and structure of the Chironomidae assemblage is directly related to the availability and heterogeneity of habitats in streams. / A heterogeneidade de substratos em riachos favorece a colonização e diversidade dos organismos bentônicos. Entre estes, as larvas de Chironomidae são uns dos mais abundantes em diversos ecossistemas aquáticos. Este trabalho teve como objetivo determinar a composição, a riqueza, a diversidade e a existência de padrões na distribuição de larvas de Chironomidae, em diferentes microhabitats de riachos preservados da Mata Atlântica. As coletas foram realizadas em fevereiro e agosto de 2010, com um amostrador tipo Surber. As variáveis ambientais analisadas não foram significativamente diferentes entre os riachos amostrados, porém a riqueza taxonômica de larvas de Chironomidae foi distinta entre os microhabitats. Foram identificadas 6.469 larvas de Chironomidae distribuídas em 96 táxons pertencentes às subfamílias Chironominae, Tanypodinae e Ortocladiinae. As análises de densidade, riqueza, equitabilidade e diversidade desta assembleia em relação aos meses, pontos e microhabitats indicaram diferenças, estatisticamente significativas, na distribuição das larvas apenas para os diferentes microhabitats. Entre eles, a maior riqueza foi observada nos depósitos de folhiços e os maiores números de espécies exclusivas ocorreram nas regiões de remansos. Assim, a composição e estrutura da assembleia de Chironomidae está diretamente relacionada à disponibilidade e à heterogeneidade de habitats em riachos.

Ce travail de thèse porte sur l'étalement de fluides complexes. Il met en évidence la riche phénoménologie d'un acte simple : celui d'étaler avec un racloir (rigide ou souple) une émulsion ou une solution de polymères sur un substrat. Pour chacun des fluides modèles étudiés, nous nous sommes focalisés expérimentalement sur l'observation de l'écoulement au cours de l'entraînement de la solution. Dans des conditions données d'étalement, il apparaît qu'une émulsion o/w peut s'inverser via plusieurs mécanismes de déstabilisation, ou encore, dans le cas d'une solution de polymères, exhiber une instabilité de sa ligne de contact, donnant naissance à des filaments de tailles et de longueurs d'ondes spécifiques. Nous montrons que les différents paramètres d'étalement, comme par exemple la hauteur du racloir, la vitesse d'étalement, les propriétés du substrat ou encore la rhéologie des solutions, doivent être pris en compte pour construire des diagrammes de phase d'étalement séparant les domaines d'existence des instabilités observées (régime de recouvrement partiel), des domaines où la solution transite vers le recouvrement total du substrat. D'autre part, nous tirons l'avantage de ces instabilités pour nous permettre de déposer de façon contrôlée des structures variées, offrant d'intéressantes perspectives en termes d'applications. / This study shows the rich phenomenology of a simple act : spreading complex solutions such as emulsion and polymer solution on a plate, by using a rigid and flexible blade respectively. Here, we experimentally study the flow of the solution over the course of its spreading. During the spreading and in certain conditions, different phenomena occur, namely, emulsion inversion in the case of o/w emulsion or a contact line instability in the case of the polymer solution, which gives rise to the formation of polymer filaments with a well-defined wavelength and characteristic sizes. We showed, thanks to spreading phase diagrams, that the the existence of the instability (partial wetting regime) is separated to a domain where the solution cover the substrate. Spreading parameters such as the height of the scraper, spreading velocity or properties of the fluids turns out to be crucial. Finally, we take advantage of the instabilities to print a variety of interesting patterns for further applications.

Diploma thesis named Steam turbine in the combi cycle deals with design of low pressure part of three-body turbine and it’s lateral outlet throat to the air condenser. Before the design itself, the thermal schema of entire turbine is calculated. Than follows the detail draft, the strength calculations are included as well. Turbine has any technological consumption of steam or any regenerativ consumption. Turbine will be suplly to Panama. The thesis includes following drawings: cut of flowing part, design of outlet throat and fixing of inner body in outer body of low pressure part. The diploma thesis is created for Doosan Škoda Power company.

This master’s thesis is focuses on flow theory and optimizing current state of air distribution in theater hall by CFD simulations. A part of this thesis is project solution of one variant.

Ce projet de thèse porte sur le traitement de films de graphène dans la post-décharge en flux de plasmas micro-ondes d’azote à pression réduite. Différentes considérations de contamination de surface des échantillons se sont avérées cruciales pour ce travail. Par exemple, en présence d’hydrocarbures, les traitements dans les différentes régions de la post-décharge montrent des profils de production de dommages, d’incorporation d’azote et de fonctionnalisation de contaminants distincts. Le traitement agressif qu’offre la post-décharge proche résulte en la formation de complexes amorphes graphène-hydrocarbures responsables d’une forte hausse de la teneur en azote (jusqu’à 49%) pour des désordres modérés (D:G = 1.3). Pour les traitements dans la post-décharge lointaine, les hydrocarbures jouent un rôle de couche protectrice permettant une incorporation monotone (jusqu’à 18%) à très faible dommage (D:G < 0.3). Les espèces azotées sont néanmoins faiblement liées de sorte que le transfert vers un substrat de SiO2 engendre une perte importante (> 80%) de la teneur en azote. Des considérations d’inhomogénéité de surface des films de graphène ont motivé le développement d’une nouvelle méthode d’analyse des cartographies Raman obtenues par un imageur hyperspectral. L’étude des spectres Raman au niveau des domaines versus aux joints de grains ont permis de mettre en évidence un mécanisme d’auto-réparation des joints de grains relié à l’anisotropie de la migration des adatomes de carbone en surface. L’accumulation de ceux-ci aux joints de grains mène à une émission d’adatomes responsable de l’annihilation de paires de Frenkel. Dans les plasmas azotés, il s’avère que ce mécanisme est également responsable d’une incorporation sélective d’azote aux domaines de croissance du graphène. Lorsque amorphisé, le dopage sélectif s’estompe puisque le transport des adatomes de carbone aux joints de grains, ainsi que l’accumulation essentielle au processus d’auto-réparation, deviennent entravés. Finalement, la recombinaison en surface d’atomes d’azote et la désexcitation de métastables N2(A) sont identifiés comme principaux agents pour la production de dommages dans la post-décharge en flux d’azote. Un modèle d’incorporation impliquant la formation de dommages et l’adsorption d’atomes d’azote est proposé. En présence d’espèces oxydantes dans la post-décharge d’azote, la formation de dommages demeure limitée par les populations de N et de N2(A). / This thesis project deals with the treatment of graphene films in the flowing afterglow of microwave nitrogen plasmas at reduced pressure. Various surface contamination considerations were found to be crucial for this work. For example, in the presence of hydrocarbons, the treatments in the different regions of the afterglow show distinct damage production, nitrogen incorporation and contaminant functionalization profiles. The aggressive treatment offered by the early afterglow results in the formation of amorphous graphene-hydrocarbon complexes responsible for a sharp increase in the nitrogen content (up to 49%) at moderate disorders (D: G = 1.3). For the treatments in the late afterglow, the hydrocarbons act as a protective layer, allowing a monotonic incorporation (up to 18%) with very low damage (D: G < 0.3). Nitrogenous species are found to be weakly bound so that transfer to an SiO2 substrate generates a significant loss (>80%) of the nitrogen content. Considerations of surface inhomogeneity of graphene films have motivated the development of a new analysis method of Raman maps obtained by hyperspectral imager. The study of Raman spectra at growth domain versus grain boundary has revealed a self-healing mechanism of grain boundaries linked to the anisotropy of the migration of carbon adatoms at the surface. The accumulation of these at grain boundaries leads to an emission of atoms responsible for the annihilation of Frenkel pairs. In nitrogenous plasmas, this mechanism is also found to be responsible for the selective incorporation of nitrogen into the growth domains of the graphene. For amorphous graphene, selective doping fades as the transport of carbon adatoms to grain boundaries, and therefore the accumulation essential to the self-healing process, becomes impeded. Finally, the surface recombination of nitrogen atoms and the de-excitation of metastable N2(A) are identified as the main agents defect generation in the nitrogen flowing afterglow. An incorporation model involving the formation of damage and adsorption of nitrogen atoms is proposed. In the presence of oxidizing species in the nitrogen afterglow, damage formation remains limited by populations of N and N2(A).

Over the past decades, public concern about global environmental change has grown, following the progressive increase in both frequency and intensity of extreme events. Even though the problem is global, it has proved to have very different societal and environmental impacts at local level, further widening the gap between disadvantaged and advantaged communities, according to the degree of vulnerability of their social, economic and environmental systems. Among the various anthropogenic activities, the agricultural sector is particularly linked to global environmental change by a two-way relationship: on the one hand, intensive mono-cultures, together with intensive livestock production, compromise the environment and produce huge CO$_2$ emissions (one of the most important factors behind global warming); on the other hand, smallholder farming is one of the most endangered sectors by global environmental change, precisely because it depends heavily on the natural resources of the territory, including favourable weather and climate. Scientific research, supported by international institutions, has been working on this subject for several decades, analysing phenomena at global and local scale and providing medium and long-term forecasts capable of directing economic and political strategies. Such complex investigations become even more complex in contexts lacking reliable environmental data, where their low-quality and low representativeness weaken their reliability, compromising the reliability of the outcomes as well. This thesis seeks to respond to the increasing need of realistically addressing environmental phenomena that threaten rural communities and the environment on which they depend in low-income countries, by investigating two of the main environmental factors affecting tropical farming practices: river-floodplain dynamics and climate change. Despite data-related constraints, the environment of tropical rural areas still provides a unique opportunity to study several near-natural processes, such as the morphodynamics of mostly free-flowing rivers. Especially in foothill regions, unconfined or partially confined conditions of tropical rivers allow evaluating the natural dynamics of erodible river corridors, with erosion and accretion shaping their interactions with the adjacent floodplain and related human activities. At the same time, the complex terrain characterizing the river valleys at the foothills of high mountain chains also offers the opportunity to study interesting local meteorological processes, especially considering the interaction between synoptic-scale dynamics and local convective phenomena. In this context, local bottom-up initiatives and new and tailored-to-context strategies for adaptation to the ongoing environmental change are deepened following a multidisciplinary approach. This PhD research has been framed within an international cooperation project entitled “Sustainable Development and Fight against Climate Change in the Upper Huallaga basin (Peru)”, promoted by Mandacarù ONLUS, and funded by the Autonomous Province of Trento. The project aimed to enhance the resilience of the local farmers of the Upper Huallaga valley (Peru), facing the consequences of climate change and implementing new agricultural initiatives with a special attention to plantain and banana fields. Thanks to the support of the involved partners (Redesign by PROMER s.a.c., the Universidad Agraria Nacional de la Selva de Tingo Maria, in Peru, and the Edmund Mach Foundation of San Michele all’Adige, in Italy), the project provided the opportunity to carry out a consistent set of fieldwork activities over an 8-months period collecting hydro-morphological data, interviewing the local population, and installing two weather stations. The PhD thesis has been structured along two main parts, related to to the assessment of climate change effects on local agricultural practices, and the interplay between river-floodplain dynamics and floodplain agriculture. The part on the assessment of climate change includes two main research elements. First, a novel approach is used to evaluate climate change in data-scarce contexts: non-conventional data sources (population survey) are compared with conventional data sources (few local historical weather stations and global reanalysis data series – ERA5), to better account for the sub-daily time scale (local conventional sources only provide daily data), correlating weather changes perceived by farmers (more thunderstorms and longer drought periods) with climate variations deduced from quantitative data. Second, after having determined the most impacting meteorological variables on crops through the survey, a weather early-warning system has been developed to provide agro-meteorological forecasts to the \textit{bananeros} (banana farmers) of the Upper Huallaga valley. The system, based on the Weather Research and Forecasting (WRF) model, and enhanced with the assimilation of real-time observations from local meteorological stations installed during the project fieldwork, issues an alert when the predicted wind speed exceeds thresholds related to potential damage to the harvest, and spreads the warning via text messages. Such alerting system contains several novel features in relation to the socio-environmental context, allowing to discuss its potential for replication in analogous, vulnerable situations. The part on river-floodplain dynamics also includes two main research elements. First, a remote-sensing analysis is conducted at reach scale in two different reaches of the Huallaga River, quantifying geomorphological river trajectories and land use changes in the adjacent floodplain. The outcomes show that river morphology reacts differently depending on the agricultural systems (extensive or intensive) in the nearby floodplain, revealing a high geomorphological sensitivity of such a near-natural, highly dynamic river reach. Second, riverine agriculture within the erodible river corridor is analysed in association with riverine islands dynamics, at the geomorphic unit scale, evaluating the morphological evolution and agricultural suitability of two cultivated fluvial islands. The three main drivers of agricultural suitability within river erodible corridors, i.e. river disturbance, cultivation windows of opportunity, and soil suitability are quantified, allowing to generalize a process-based conceptual model of riverine islands as complex-adaptive-systems.

Une sonde électrostatique de Langmuir cylindrique a été utilisée pour caractériser une post-décharge d’un plasma d’ondes de surface de N2-O2 par la mesure de la densité des ions et électrons ainsi que la température des électrons dérivée de la fonction de distribution en énergie des électrons (EEDF). Une densité maximale des électrons au centre de la early afterglow de l’ordre de 1013 m-3 a été déterminée, alors que celle-ci a chuté à 1011 m-3 au début de la late afterglow. Tout au long du profil de la post-décharge, une densité des ions supérieure à celle des électrons indique la présence d’un milieu non macroscopiquement neutre. La post-décharge est caractérisée par une EEDF quasi maxwellienne avec une température des électrons de 0.5±0.1 eV, alors qu’elle grimpe à 1.1 ±0.2 eV dans la early afterglow due à la contribution des collisions vibrationnelles-électroniques (V-E) particulièrement importantes. L’ajout d’O2 dans la décharge principale entraîne un rehaussement des espèces chargées et de la température des électrons suivi d’une chute avec l’augmentation de la concentration d’O2. Le changement de la composition électrique de la post-décharge par la création de NO+ au détriment des ions N2+ est à l’origine du phénomène. Le recours à cette post-décharge de N2 pour la modification des propriétés d’émission optique de nanofils purs de GaN et avec des inclusions d’InGaN a été étudié par photoluminescence (PL). Bien que l’émission provenant des nanofils de GaN et de la matrice de GaN recouvrant les inclusions diminue suite à la création de sites de recombinaison non radiatifs, celle provenant des inclusions d’InGaN augmente fortement. Des mesures de PL par excitation indiquent que cet effet n’est pas attribuable à un changement de l’absorption de la surface de GaN. Ceci suggère un recuit dynamique induit par la désexcitation des métastables de N2 suite à leur collision à la surface des nanofils et la possibilité de passiver les défauts de surface tels que des lacunes d’azote par l’action d’atomes de N2 réactifs provenant de la post-décharge. L’incorporation d’O2 induit les mêmes effets en plus d’un décalage vers le rouge de la bande d’émission des inclusions, suggérant l’action des espèces d’O2 au sein même des nanostructures. / A cylindrical electrostatic Langmuir probe was used to characterize the flowing afterglow of a N2-O2 surface wave plasma. The spatial distribution of the number density of positive and electrons as well as the EEDF were measured. A maximum of the number density of electrons in the mid 1013 m-3 was obtained in the center of the early afterglow, while it decreased at 1011 m-3 early in the late afterglow, thus indicating non-macroscopically neutral media all along the flowing afterglow. It is characterized by an EEDF close to a Maxwellian with an electron temperature of 0.5±0.1 eV, while it increased at 1.1±0.2 eV in the early afterglow due to the contribution of important vibration-electron collisions. After addition of small amounts of O2 in the main N2 microwave discharge, the charged particles densities and electron temperature first strongly increased then decreased with increasing O2 concentration. A change in the charged population in the afterglow by the creation of NO+ to the detriment of the N2+ ions is responsible of this phenomenon. This N2 flowing afterglow was later used for plasma-induced modification of pure GaN nanowires and InGaN/GaN dot-in-a-wire heterostructures and characterized by PL. While the band edge emission from GaN nanowires and the GaN matrix of the InGaN/GaN nanowires strongly decreased due to the creation of non-radiative recombination centers in the near-surface region, the emission from the InGaN inclusions strongly increased. PL excitation measurements show that this increase cannot be explained by a plasma-induced shift of the GaN absorption edge. Instead a dynamical annealing process induced by the desexcitation of N2 metastables following their collision with the nanowire surface and the passivation of surface defects such as nitrogen vacancies by the highly reactive nitrogen atoms in the afterglow are responsible of the increase of the PL intensity. The addition of O2 gives the same results as the pure N2 treatment, but a redshift of the emission band related to the InGaN inclusions is also observed, suggesting an important contribution of the oxygen species.

New decline curve models have been developed to overcome the boundary-dominated flow assumption of the basic Arps’ models, which restricts their application in ultra-low permeability reservoirs exhibiting long-duration transient flow regimes. However, these new decline curve analysis (DCA) methods are still based only on production rate data, relying on the assumption of stable flowing pressure. Since this stabilized state is not reached rapidly in most cases, the applicability of these methods and the reliability of their solutions may be compromised. In addition, production performance predictions cannot be disassociated from the existing operation constraints under which production history was developed. On the other hand, DCA is often carried out without a proper identification of flow regimes. The arbitrary application of DCA models regardless of existing flow regimes may produce unrealistic production forecasts, because these models have been designed assuming specific flow regimes. The main purpose of this study was to evaluate the possible benefits provided by including flowing pressures in production decline analysis. As a result, it have been demonstrated that decline curve analysis based on pressure-normalized rates can be used as a reliable production forecasting technique suited to interpret unconventional wells in specific situations such as unstable operating conditions, limited availability of production data (short production history) and high-pressure, rate-restricted wells. In addition, pressure-normalized DCA techniques proved to have the special ability of dissociating the estimation of future production performance from the existing operation constraints under which production history was developed. On the other hand, it was also observed than more consistent and representative flow regime interpretations may be obtained as diagnostic plots are improved by including MBT, pseudovariables (for gas wells) and pressure-normalized rates. This means that misinterpretations may occur if diagnostic plots are not applied correctly. In general, an improved forecasting ability implies greater accuracy in the production performance forecasts and more reliable reserve estimations. The petroleum industry may become more confident in reserves estimates, which are the basis for the design of development plans, investment decisions, and valuation of companies’ assets.

No description available.

The diploma thesis is focused on the appropriate dosage of rejuvenating agents in asphalt mixtures with high content of RAP. The empirical and functional laboratory tests are described in the theoretical part. The practical part deals with the estimation of the optimal amount of rejuvenating agents by means of laboratory tests so that the rheological properties of the degraded asphalt binder can be restored by suitable dosing into the RAP. As part of the TAČR ZÉTA project, an experimental section of asphalt mixture containing 50 % of the RAP and an appropriate amount of the rejuvenating agents was created. The aim of the thesis is to find an optimal dosage of the rejuvenating agents in the samples of the RAP and laboratory aged asphalt binder of gradation 50/70, to determine the effectiveness of selected rejuvenating agents and to monitor changes in the parameters of the experimental section during the period of time.