An investigation has been carried out into the rheology of chocolate in relation to its flow and mixing features in a real industrial environment. The chocolate manufacturing plant of Rowntree at York provided a base for this study. The project aims were: a) to measure the viscous and time dependent properties of chocolate. b) to explain the observed flow properties in relation to the constituents of chocolate. c) to determine the shear rate which, for a given recipe, yields a minimum stable viscosity (of particular commercial value). d) to assess the type of mixer able to provide this duty. The experimental work involved rheological studies with concentric cylinder and tubular viscometers, operated to measure viscosity as a function of shear rate and shearing time. The chocolate samples studied were taken from various points in the manufacture process at Rowntree, York. Model chocolate systems were made from cocoa liquor, and sugar with cocoa butter, which were studied to underpin the basic mechanisms of the flow properties of the total chocolate. Shear thinning in milk chocolate has been shown to be accounted for by surface coating and fat release from the cocoa cellular material. Analysis of the sugar and cocoa butter system gave large hysteresis loops which may be explained as due to agglomeration of the sugar particles. The level of hysteresis was found to be related to the polarity of the liquid phase, such that a more polar fluid results in less hysteresis. Laboratory experiments have revealed that the level of work input to give permanent viscosity reduction for milk chocolate is dependent on the measuring shear rate. The level of optimum shear input for the measuring range 10 to 130 sec 1 is 645 sec for 30 minutes. The apparent viscosity measured at lower shear rates requires much longer ([approx]100 minutes). / Yorkreco, Nester York Ltd.

Water is often found adhering to surfaces in droplet form. Droplets can develop as a result of precipitation, condensation, or chemical reactions. Drops are retained or held on a surface due to a retention force exerted on the drop by the surface. This retention force is a function of the surface tension of the liquid, drop geometry, and the contact angle between the drop and the surface. When external or body forces exceed this retention force the drop begins to move. This thesis seeks to understand and quantify the forces present at the point of droplet departure once it begins to move under an applied force. The conditions of drop departure in shear flow are explored for five microstructured superhydrophobic surfaces, one smooth hydrophobic surface, and one carbon nanotube (CNT) surface. Surface solid fractions range from 0.05 - 1.00, and static contact angles range from 121.4 - 160.6°. Droplet volumes of 5, 10, 20, 30, 40 and 50 µL are tested on each surface. For each experiment, a shear airflow is applied to a droplet placed on a surface. Shear air velocities start at zero and are increased at a consistent speed until the droplet departs. Highspeed imaging is used to track the droplets shape and position with respect to time, and a mass flowmeter is used to track bulk air velocity with respect to time. Particle imaging velocimetry (PIV) measurements were carried out to characterize the velocity profile of the shear airflow, and an appropriate velocity profile is calculated for any given flowrate by interpolating/extrapolating within PIV measurements. The condition of drop departure is defined as the point at which a droplet's acceleration no longer oscillates about zero and instead increases monotonically. As the applied shear force increases until drop departure occur, measurements of droplet base length, height, and cross section area (as viewed from the side) indicate that these quantities remain approximately constant throughout the length of the test. Measurements of advancing and receding contact angles are reported at the point of departure, with increasing contact angle hysteresis (difference between advancing and receding contact angles) observed until departure occurs. Contact angle hysteresis is shown to be a good indicator of droplet mobility. Measurements of bulk air velocity upstream of the droplet and measurements of the average air velocity over the height of the droplet are both reported at the point of departure. Bulk air velocity at the point of departure is shown to vary with droplet volume, while the average air velocity over the droplet height at the point of departure is shown to be independent of droplet volume. Both measures of air velocity decrease with decreasing surface solid fraction, and decrease most rapidly at low solid fractions. Retention forces are calculated using a retention force factor and vary from 10 - 64 µN. Retention force is shown to be roughly constant for a given droplet base length. An appropriate coefficient of drag is calculated in the range of 0.55 to 2.66 for droplet Reynolds numbers of 225 - 908. The coefficient of drag is shown to be independent of droplet Reynolds number, and to be approximately constant for a given droplet Bond number.

Possibilities for increasing the upper limit of floatable particle sizs in the froth flotation process have been examined since the early beginnings of mineral flotation. The economic implications of such an incresae are far ranging; from decreased grinding costs and increased recoveries to simplified flow-sheet design and increased throughput, all leading to increased revenue. Bubble-particle detachment has been studied to better understand the factors influencing the strength of attachment and the energies involved. Direct measurements of bubble particle detachment were performed using a hanging balance apparatus (KSV Sigma 70 tensiometer) and using a submerged hydrophobic plate in water. Three experiments were used; direct force measurement of bubble-particle detachment, detachment force and energy of a bubble from a submerged hydrophobic plate, and detachment force and energy of a cetyltrimethylammonium bromide coated silica sphere from a flat bubble. Octadecyltrichlorosilane was used as a hydrophobic coating in the first two experimental methods. These experiments were recorded with a CCD camera to identify the detachment processes involved. Energies for both methods were calculated and divided into the two main steps of the detachment process: Three-Phase-Contact pinning and three phase contact line sliding. The first step represents the energy barrier which must be overcome before detachment can begin. It is directly related to contact angle hysteresis. Detachment occurs during the second step, where the solid-vapor interface is replaced by solid-liquid and liquid-vapor. This step corresponds to the work of adhesion. The effects of surface tension, contact angle and hysteresis were well demonstrated with the three experimental methods. Good correlation was found between theoretical work of adhesion and measured energies. / Master of Science

Headwater streams change in wet length in response to storm events and seasonal moisture conditions. These low-order channels with temporary flow are pervasive across arid and humid environments yet receive little attention in comparison to perennial waterways. This dissertation examines headwater stream length dynamics at multiple spatial and temporal scales across the Appalachians. I mapped wet stream length in four Appalachian physiographic provinces--the Appalachian Plateau, Blue Ridge, New England, and Valley and Ridge--to characterize seasonal expansion and contraction of the wet network at a broad, regional scale. Conversely, most existing field studies of stream length in headwaters are limited to a single study area or geographic setting. Field mappings showed that wet stream length varies widely within the Appalachians; network dynamics correlated with regional geology as well as local site lithology, geologic structure, and the depth, size, and spatial distribution of surficial sediment deposits. I used the field data to create logistic regression models of the wet network in each physiographic province at high and low runoffs. Topographic metrics derived from elevation data were able to explain the discontinuous pattern of headwater streams at different flow conditions with high classification accuracy. Finally, I used flow intermittency sensors in a single Valley and Ridge catchment to record channel wetting and drying at a high temporal resolution. The sensors indicated stream length hysteresis during storms with low antecedent moisture, with a higher wet network proportion on the rising limb than on the falling limb of events. As a result, maximum network extension can precede peak runoff by minutes to hours. Accurate maps of headwater streams and an understanding of wet network dynamics through time are invaluable for applications surrounding watershed management and environmental policy. These findings will contribute to the burgeoning research on temporary streams and are additionally relevant for studies of runoff generation, biogeochemical cycling, and mass fluxes of material from headwaters. / Ph. D. / During a rain storm, we may think of streams increasing in depth, width, and velocity. However, we may not necessarily envision streams also getting longer. Headwaters, which form the upstream extremities of river systems, consist of many temporary streams that expand and contract in length due to storms and changes in seasonal moisture conditions. Headwaters are spatially expansive, comprising a majority of total river length, and serve as a primary control on downstream water quality. Therefore, understanding stream length dynamics can inform policy and land use decisions to effectively conserve and manage headwater regions and protect water sources for human use and consumption. This dissertation examines changes in stream length across four study areas of the Appalachian Mountains. I mapped the wet, or active, stream network multiple times at different flow conditions in each study area. Stream length dynamics varied considerably across the Appalachians and demonstrated the same range of network expansion and contraction as other studies observed in diverse settings around the world. Wet stream length greatly depended on regional and local geology. I then sought to predict the location of wet streams at high and low flows using metrics such as slope and drainage area that I calculated from digital elevation information. Comparisons with the field maps I made showed that simple terrain metrics explained the location, length, and disconnected nature of wet networks in each province with high accuracy. I also observed stream length dynamics during storm events in one watershed using sensors that recorded the presence or absence of water. These observations demonstrated that stream length was often higher for a given flow at the beginning of a storm on the rising limb than on the falling limb when flow was decreasing, particularly if conditions were dry before the storm. The findings of this dissertation contribute to existing knowledge of temporary streams and are relevant for future studies investigating the hydrology, biology, and ecology of headwaters.

Rubber friction is an important aspect to tire engineers, material developers and pavement engineers because of its importance in the estimation of forces generated at the contact, which further helps in optimizing tire and vehicle performances, and to estimate tire wear. It mainly depends on the material properties, contact mechanics and operating condition. There are two major contributions to rubber friction, due to repeated viscoelastic deformation from undulations of surface called hysteresis and due to Vander Waals interaction of the molecules called adhesion. The study focuses on analytical modeling of friction for stationary sliding of rubber block on rough surfaces. Two novel approaches are discussed and compared. Frictional shear stress is obtained from the energy dissipated at the contact interface due to the elastic deformations of rubber block at different length scales. Contact mechanics theories based on continuity approach combined with stochastic processes to estimate the real contact area, mean penetration depth and true stresses at contact depending on operating conditions. Rubber properties are highly temperature dependent. Temperature model developed based on heat diffusion relation is integrated to consider the effects of temperature rise due to frictional heating. Model results are validated with theoretical results of literature. Simulation results of friction model is obtained for Compound A sliding on rough surface. Material properties are obtained using Dynamic Mechanical Analysis and Time temperature superposition. Influence of the friction models under different conditions are discussed. Model results are validated with experimental data from Dynamic friction tester on a 120-grit surface followed by future works. / Master of Science / Friction is a complex phenomenon that occurs in all tribological application. It is termed as the ratio of the shear force resisting the motion of the component to the normal force acting on the component. Microscopic observation has observed the importance of the effective contact area and roughness of the substrates in the influence of the friction. Rubber friction is an important aspect to tire engineers, material developers and pavement engineers because of its importance in the estimation of forces generated at the contact, which further helps in optimizing tire and vehicle performances, and to estimate tire wear. Because of the viscoelastic nature of rubber, the friction in rubber is much more complicated than observed for elastic materials and hence depends on the material properties apart from contact mechanics and operating condition. There are two major contributions to rubber friction, due to repeated viscoelastic deformation from undulations of surface called hysteresis and due to Vander Waals interaction of the molecules called adhesion. The study focuses on analytical modeling of friction for stationary sliding of rubber block on rough surfaces. Two novel approaches are discussed and compared. Frictional shear stress is obtained from the energy dissipated at the contact interface due to the elastic deformations of rubber block at different length scales. Contact mechanics theories based on continuity approach combined with stochastic processes to estimate the real contact area, mean penetration depth and true stresses at contact depending on operating conditions. Rubber properties are highly temperature dependent. Temperature model developed based on heat diffusion relation is integrated to consider the effects of temperature rise due to frictional heating. Model results are validated with theoretical results of literature. Simulation results of friction model is obtained for Compound A sliding on rough surface. Material properties are obtained using Dynamic Mechanical Analysis and Time temperature superposition. Influence of the friction models under different conditions are discussed. Model results are validated with experimental data from Dynamic friction tester on a 120-grit surface followed by future works.

The importance of applying unsaturated soil mechanics concepts to geotechnical engineering design has been widely recognized. Soil water characteristic curve (SWCC) and hydraulic conductivity function (HCF) are vital soil properties that govern engineering behavior of unsaturated soils. In this study, a transient water release and imbibitions method (TRIM) is used to measure the SWCC and HCF under drying and wetting states, which accommodates integrated experimental and modeling techniques. The results of saturated hydraulic conductivity tests through flexible wall method are then used as input parameters for simulating experimental data. In general, the model provides a satisfactory fit to experimental data. Soil water characteristic curves (SWCCs) and hydraulic conductivity functions (HCFs) are presented for a variety of soils that were prepared at different molding water contents and compactive efforts. The influences of dry density, molding water content, and hysteresis have been investigated. Dry density affects soil-water characteristic in terms of its air-entry value (AEV), rate of drying, and size of the hysteresis loop. The test results indicate that the SWCC and HCF obtained in terms of volumetric water content is more sensitive to the changes in dry density than molding water content. Based on cohesive soil results, some statistical relations are proposed to estimate wetting-path SWCC and HCF parameters from more easily measured drying curves. Changes in the van Genuchten's fitting parameters and residual volumetric water content are investigated for both drying and wetting conditions, with changes in the kaolin clay content. / Master of Science / Traditional soil mechanics practice has experienced considerable changes during the past few decades. Within that period, the necessity of unsaturated soil mechanics has gradually emerged and become a part of geotechnical engineering practice. Soil water characteristic curve (SWCC) and hydraulic conductivity function (HCF) are very important properties in the assessment of unsaturated soil behaviors. A transient water release and imbibitions method (TRIM) is used to investigate unsaturated soil properties of a variety of test soils under laboratory conditions. TRIM integrates a testing program and a modeling technique to measure SWCC and HCF concurrently for both drying (water release upon matric suction increase) and wetting (water imbibition upon matric suction decrease) conditions. Compaction, which is a classical application involving unsaturated soil, has the preferred practice for improving the mechanical and hydraulic properties of a soil. The structure and fabric of compacted material is very dependent on the compacted conditions, including compactive effort and molding water content. This paper evaluates the influence of such mentioned factors on the SWCC and HCF. The test results indicate that the SWCC and HCF obtained in terms of volumetric water content is more sensitive to the changes in compactive effort than molding water content. Hysteresis phenomena, the difference in the relationship between the water content of the soil and the corresponding water potential under drying and wetting path, is investigated. Based on cohesive soil results, some statistical relations are proposed to estimate wetting-path SWCC and HCF parameters from more easily measured drying curves.

Monitoring of aquatic life is important for assessing long-term impacts on activities associated with fish stock and migration. One promising approach for long-term monitoring involves the development of self-powered telemetry devices capable of powering themselves by harnessing energy from the fish body undulations using implanted devices or from fluid motions generated by fish swimming using external devices. One of the latter devices is a broadband low frequency nonlinear bistable energy harvester. This cost-effective harvester has been inspired from the doubly curved leaf blades of a Venus-fly trap. This work ex- amines the static behavior of such a bio-inspired bistable energy harvester by analyzing its force-displacement characteristics. The objective is to identify crucial design parameters to optimize the harvester's performance for potential application in self-powered fish telemetry tags. The unique characteristics of the hysteresis loop and snap-through discontinuity of the bistable structure are investigated using experimentation and finite element analysis. The finite element model is found to qualitatively replicate experimental observations. Addition- ally, geometrical and assembly parameters that affect the force-displacement behavior of the harvester are identified. A sensitivity analysis is performed to determine the effect of the aspect ratio, buckling displacement and thickness of the proposed harvester on the static force-displacement curve. The sensitivity analysis has highlighted that the assembly and geometric parameters of the bistable structure affect multiple aspects of the force-displacement behavior simultaneously. Hence, analytical modeling has been attempted using the theory of lateral torsional buckling to further investigate the complex influence of the said parameters. / Master of Science / With the ongoing pursuit to enhance quality of life and accommodate the needs of a growing population, water resources are increasingly being used for various economic activities such as energy production, fish farming, and transportation, among others. Fish telemetry serves as a valuable tool to understand the long-term ecological impacts of such economic activities to ensure their sustainable growth. Taking inspiration from the leaf blades of the Venus flytrap an innovative, cost-effective nonlinear system with the potential to be integrated into telemetry tags is developed. This unique system scavenges energy from the ambient environment to power telemetry tags thus making telemetry tags self sustaining and removing the reliance on batteries. This study delves into the behavior of this proposed system, aiming to optimize its performance for potential use in self-powered fish telemetry tags. Through a comprehensive approach involving experimentation, numerical simulations, and analytical modeling, key design parameters influencing the efficiency of the energy harvester are identified. The findings highlight how assembly and geometric factors impact the performance of the system. This research offers insights that could lead to significant advancements in aquatic life monitoring technology, facilitating more effective and sustainable management of water resources.

In dieser Arbeit wird eine einheitliche physikalische Beschreibung des Feuchtespeicherverhaltens poröser Materialien gegeben, und ein anwendungsorientiertes Modell daraus abgeleitet. Insbesondere wird die Hysteresis der Feuchtespeicherung berücksichtigt. Die thermodynamischen Grundlagen der Feuchtespeicherung werden vollständig abgeleitet. Die Energie des kondensierten Wassers wird durch die Energie der freien Flüssigphase zuzüglich einer Porenwechselwirkungsenergie dargestellt. Um das Kondensationsverhalten zu beschreiben, wird ein thermodynamisches Kondensationspotential eingeführt; dabei werden ein Ungleichgewicht zwischen Kondensatphase und Wasserdampf sowie mehrere unabhängige Wassergehalte im Porensystem zur Darstellung der Hysteresis berücksichtigt. Für verschiedene in der Literatur beschriebene Sorptionsprozesse wird mit einheitlichen Zustandsgrössen das Kondensationspotential berechnet. Die Hysteresis wird als verzögerte Bewegung des Systemzustandes in der Berg- und Tallandschaft des Kondensationspotentials interpretiert. Es wurden an 11 Materialien Sorptionsmessungen im hygroskopischen Luftfeuchtebereich (0-92% RH) durchgeführt: Eine Adsorptionskurve und mehrere Desorptionskurven, sowie eine Langzeitmessung der Feuchteaufnahme bei 92% RH. Aus dem Adsorptions-Desorptionsverhältnis entnimmt man, dass der Hysteresis-Effekt typischerweise etwa 20% ausmacht. Mit den Messungen werden für alle Materialien das Modell der unabhängigen Domänen, das hysteretische thermodynamische Kondensationspotential und das Sorptionskurvensystem parametrisiert. Die Feuchteaufnahme bei dem Langzeitexperiment lässt sich durch eine bimodale Exponentialfunktion beschreiben. Die Kurven von hygroskopischer Adsorption und Desorption werden durch analytische Funktionen angenähert. Die Steigungen der Zwischenkurven werden aus den Steigungen der Hauptkurven berechnet. In gleicher Weise wird auch der überhygroskopische Bereich dargestellt, unter Zuhilfenahme externer Messdaten. Schliesslich ergeben sich zwei getrennt parametrisierte, aneinander angrenzende Sorptionsschleifen für den hygroskopischen und den überhygroskopischen Bereich. Alle Parameter werden so angepasst, dass eine grösstmögliche Übereinstimmung mit dem Domänenmodell erzielt wird. / This work gives a unified physical description of moisture storage in very different porous materials and derives an application-oriented model, especially the hysteresis of moisture storage has been investigated extensively. A full derivation of the thermodynamics of moisture sorption is given. The energy of condensed water is described by the energy of the free liquid plus a pore interaction energy. To describe the condensation behaviour, a thermodynamic condensation potential is introduced. It takes into account a non-equilibrium between condensed water and water vapour as well as several independent moisture contents in the liquid phase to describe the hysteresis. For many different sorption processes described in literature the condensation potential is derived, using always the same state variables. Hysteresis is interpreted as a delayed movement of the system in the hill-and-valley-landscape of the condensation potential. Sorption measurements have been performed for 11 different materials in the hygroscopic region (0-92% RH). One adsorption curve and several desorption curves and also the time dependent moisture sorption at 92% RH in a long-time experiment have been measured. From the adsorption-desorption ratio it can be concluded that the influence of hygroscopic hysteresis is typically about 20%. From the measurement results, for all materials the model of independent domains, the hysteretic condensation potential and the sorption curve system are parameterised. The moisture uptake of the long-time experiment can be described by a bimodal exponential function. The curves of hygroscopic adsorption and desorption are approximated by analytical functions. The slopes of the intermediate curves are calculated from the slopes of the main curves. In the same way the overhygroscopic region is approximated, using external measurement results. Finally a model is presented with two neighbouring sorption loops, one for the hygroscopic, one for the overhygroscopic region. All parameters are fitted to the predictions of the domain model.

Geomagnetic disturbances that result from solar activities can affect technological systems such as power networks. They may cause DC currents in power networks and saturation of the core in power transformers that leads to destruction in the transformer performance. This phenomena result in unwanted influences on power transformers and the power system. Very asymmetric magnetization current, increasing losses and creation of hot spots in the core, in the windings, and the metallic structural parts are adverse effects that occur in transformers. Also, increasing demand of reactive power and malfunction of protective relays menaces the power network stability. Damages in large power transformers and blackouts in networks have occurred due to this phenomenon. Hence, studies regarding this subject have taken the attention of researchers during the last decades. However, a gap of a comprehensive analysis still remains. Thus, the main aim of this project is to reach to a deep understanding of the phenomena and to come up with a solution for a decrease of the undesired effects of GIC. Achieving this goal requires an improvement of the electromagnetic models of transformers which include a hysteresis model, numerical techniques, and transient analysis. In this project, a new algorithm for digital measurement of the magnetic materials is developed and implemented. It enhances the abilities of accurate measurements and an improved hysteresis model has been worked out. Also, a novel differential scalar hysteresis model is suggested that easily can be implemented in numerical methods. Two and three dimensional finite element models of various core types of power transformers are created to study the effect of DC magnetization on transformers. In order to enhance the numerical tools for analysis of low frequency transients related to power transformers and the network, a novel topological based time step transformer model has been outlined. The model can employ a detailed magnetic circuit and consider nonlinearity, hysteresis and eddy current effects of power transformers. Furthermore, the proposed model can be used in the design process of transformers and even extend other application such as analysis of electrical machines. The numerical and experimental studies in this project lead to understanding the mechanism that a geomantic disturbance affects power transformers and networks. The revealed results conclude with proposals for mitigation strategies against these phenomena. / <p>QC 20150210</p>

Laboratory magnetic measurements are used to develop a methodology to characterize the Kiruna-type Rare Earth Elements (REE) bearing apatite iron-oxide deposits at Blötberget in central Sweden. This high-grade ore deposit is known to have sharp boundaries between lens shaped main ore bodies of magnetite-rich ore, and a complex hematite-rich ore associated with pegmatites and skarn formation. The thesis covers laboratory magnetic measurements of 37 samples originating from eight drill cores and reference samples from previously mined area. It focuses on on-covering how the samples relate in terms of magnetic susceptibility, further its dependency on temperature, frequency, field and the orientation. The results are correlated with petrographic analysis previously performed on accompanying thin sections. The measurements show that magnetite with strong susceptibility contribution overshadow the hematite contribution in the samples. Transition changes in susceptibility are noticeable when crossing the Verwey temperature; -153°C, Curie temperature; 580°C and Néel temperature; 680°C. The Morin temperature appears at -60°C, or is missing. Linear relationships are identified between the magnitude difference in susceptibilities across transitions at high temperature and wt% magnetite and hematite have been identified. The Blötberget skarn and hematite-rich ore samples have a higher degree of susceptibility anisotropy than the other ore-types. Blötberget samples are dominated by multidomain characteristics in remanence, saturation and coercivity. High temperature measurements have shown that the magnetite is close to pure. The low temperature measurements suggest hematite is impure or bears a petrological footprint. The study also shows that rich iron ore samples sometimes can be at risk of being overlooked with standard methods of measuring susceptibility / Laboratorietekniska metoder kan användas som ett komplement till malmgeologi och geofysisk prospektering. I denna metodstudie karaktäriseras apatitjärnmalm från Blötberget, nära Grängesberg. En fyndighet bestående av linsformade malmkroppar rika på magnetit och ofta avskilda men komplexa hematitrika stråk. Studien är gjord 37 prover från totalt 8 borrkärnor, och lokaler som tillhörde produktion från gruvverksamhet under 1900-talet. Mätmetoderna fokuserar på att kartlägga malmens magnetiska egenskaper, och hur temperatur, frekvens, fältstyrka samt riktning påverkar dessa. Resultaten jämfördes med tidigare petrografisk studie av tillhörande tunnslip Resultaten visar att magnetit står för merparten av susceptibiliteten i proverna, men att även hematit kan urskiljas och kvantifieras. Temperaturberoende har påvisats vid övergångar för Verwey-temperatur; -153°C, Curie-temperatur; 580 °C, och Néeltemperatur; 680 °C. Den förväntade Morin-temperaturen vid -14°C, påträffades vid -60 °C eller saknas helt för flera av de hematitrika proverna. Magnetiskt anisotropa prover återfinns bland prover som identifierats som skarn eller hematitrika. Magnetisk granulometri visar karaktär av multidomäntyp med låg magnetisk coercivitet och hög satureringsförmåga. Högtemperaturmätningar av susceptibilitet visar på ren magnetit för prover från Blötberget. Samtidigt visar lågtemperaturemätningar att hematit sannolikt har inblandning av titanium eller bär på ett mer komplext förflutet. Studien visar också att det finns en risk i att enbart förlita sig på bulksusceptibilitet för prover rika på malm.