In dieser Arbeit wurden das feldaktivierte Sinterverhalten sowie das geschwindigkeitsabhängige Druckfestigkeitsverhalten von WC-Co-Hartstoffen mit variierenden Bindergehalten untersucht. Dazu wurde eine Herstellungsroute für kornwachstumshemmerfreie near-nanokristalline WC-Co-Hartstoffe mit der Field Assisted Sintering Technique (FAST) entwickelt und genutzt, um Materialien mit Co-Gehalten von 2 bis 12 Ma.-% zu erzeugen. Gezielte Werkstoffzustände und Probengeometrien sind durch Anpassung des Sinterprozesses herstellbar. Ausgewählte WC-Co-Materialien mit Co-Anteilen von 6 bis 12 Ma.-% wurden unter Einfluss von Beanspruchungsgeschwindigkeit, Spannungszustand und Beanspruchungshäufigkeit hinsichtlich der Druckfestigkeit und des Versagensverhaltens charakterisiert.

This study was carried out to evaluate the performance of Soil Aquifer Treatment (SAT) under different loading regimes, using wastewater of much higher strength than usually encountered in SAT systems, and also to investigate the removal of the endocrine disruptors triclocarban (TCC), estrone (E1), 17¿-estradiol (E2) and 17¿- ethinylestradiol (EE2). SAT was simulated in the laboratory using a series of soil columns under saturated and unsaturated conditions. Investigation of the removal of Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), Dissolved Organic Carbon (DOC), nitrogen and phosphate in a 2 meter long saturated soil column under a combination of constant hydraulic loading rates (HLRs) and variable COD concentrations as well as variable HLR under constant COD showed that at fixed HLR, a decrease in the influent concentrations of DOC, BOD, total nitrogen and phosphate improved their removal efficiencies. It was found that COD mass loading applied as low COD wastewater infiltrated over short residence times would provide better effluent quality than the same mass applied as a COD with higher concentration at long residence times. On the other hand relatively high concentrations coupled with long residence time gave better removal efficiency for organic nitrogen. Phosphate removal though poor under all experimental conditions, was better at low HLRs. In 1 meter saturated and unsaturated soil columns, E2 was the most easily removed estrogen, while EE2 was the least removed. Reducing the thickness of the unsaturated zone had a negative impact on removal efficiencies of the estrogens whereas increased DOC improved the removal in the saturated columns. Better removal efficiencies were also obtained at lower HLRs and in the presence of silt and clay. Sorption and biodegradation were found to be responsible for TCC removal in a 300 mm long saturated soil column, the latter mechanism however being unsustainable. TCC removal efficiency was dependent on the applied concentration and decreased over time and increased with column depth. Within the duration of the experimental run, TCC negatively impacted on treatment performance, possibly due to its antibacterial property, as evidenced by a reduction in COD removals in the column. COD in the 2 meter column under saturated conditions was modelled successfully with the advection dispersion equation with coupled Monod kinetics. Empirical models were also developed for the removal of TCC and EE2 under saturated and unsaturated conditions respectively. The empirical models predicted the TCC and EE2 removal profiles well. There is however the need for validation of the models developed / Netherlands Organisation for International Cooperation in Higher Education (Nuffic) / The Appendix files for this thesis are unavailable online via Bradford Scholars.

Este estudo investigou a aplicação de um AnSBBR com recirculação da fase líquida tratando água residuária a base de glicerina (efluente do processo de produção de biodiesel) para a produção de biohidrogênio, sendo o desempenho do biorreator avaliado de acordo com a influência conjunta do tempo de alimentação, do tempo de ciclo e da concentração afluente. O biorreator teve um volume de meio tratado por ciclo de 1,5 L, volume residual de meio de 2,0 L e volume de suporte inerte com biomassa de 2,1 L, sendo mantido a 30°C durante todo o estudo. O trabalho foi divido em três fases: a Fase I foi realizada para determinar os melhores parâmetros de operação do reator (tipo de inóculo, tipo de glicerina, tipo de suporte, concentração de NaHCO3 e velocidade ascensional) para dar seguimento com a Fase II que estudou apenas o efeito da concentração do afluente, tempo de ciclo e tempo de enchimento. Os parâmetros utilizados na Fase II foram: lodo de abatedouro de aves pré-tratado por HST (Heat Shock Treatment 90°C por 10 minutos) como inóculo, glicerina pura comercial para eliminar interferência de possíveis resíduos, suporte de PEBD (polietileno de baixa densidade) e 100 mg.L-1 de NaHCO3. Na Fase II, foram aplicadas 6 condições experimentais com cargas orgânica volumétrica (COVAS) de 7,7 a 17,1 gDQO.L-1.d-1, combinando diferentes concentrações afluentes (3000, 4000 e 5000 mgDQO.L-1) e tempos de ciclo (4 e 3 h), sendo o tempo de alimentação igual a metade do tempo de ciclo. Os resultados mostraram que houve baixa remoção de DQO (máximo de 38% para amostras filtradas) e que houve predomínio do ácido acético e do ácido butírico em todas as condições. O aumento da XV concentração do afluente e a diminuição do tempo de ciclo favoreceram a produtividade e rendimento molares de hidrogênio nas condições investigadas. O ensaio com melhores resultados foi com carga orgânica de 17,1 gDQO.L-1.d-1 no qual obteve-se 100,8 molH2.m-3.d-1 e 20,0 molH2.kgDQO-1, com 68% de H2 e apenas 3% de CH4 no biogás. Na Fase III, determinou-se a influência do pré-tratamento do inóculo e a viabilidade do sistema tratando glicerina bruta industrial, sendo verificado que o pré-tratamento do lodo por HST melhora ligeiramente a produtividade e rendimento do processo e o uso da glicerina bruta industrial diminuiu consideravelmente a quantidade e qualidade do biogás obtido. / This study investigated the feasibility of an AnSBBR with recirculation of the liquid phase treating glycerin-based wastewater (effluent from biodiesel production process) on biohydrogen production; the performance of the bioreactor was evaluated according the combined influence of fill time, cycle period and influent concentration. The bioreactor had 1.5L of feeding volume per cycle, 2.0 L of residual medium, 2.1 L of inert support and biomass and it was kept at 30°C. This study was divided into three phases. Phase I was conducted to determine the best operational parameters for the reactor (type of inoculum, type of glycerin, type of support for biomass, NaHCO3 concentration and upflow velocity), so Phase II would use these parameters to study only the influence of affluent concentration, cycle time and filling time. The parameters used in Phase II were: sludge from poultry slaughterhouse pretreated by HST (Heat Shock Treatment 90°C for 10 minutes) as inoculum, pure glycerin so there would be no interferences from possible residues, LDPE (low density polyethylene) support, 100 mg.L-1 of NaHCO3 and 10.6 m.h-1 of upflow velocity. Phase II was operated under six conditions with different AOLRS ranging from 7.7 to 17.1 gCOD.L-1.d-1, obtained by the combination of different influent concentrations (3000, 4000 and 5000 mgCOD.L-1) and cycle periods (4 and 3 h), the filling time was equal to half of the cycle lenght. The results showed low COD removal (maximum of 38% for filtrated samples) and high concentrations of acetic acid and butyric acid in all conditions. Increasing the affluent concentration and decreasing the cycle length improved the molar productivy and hydrogen yield in the XVII investigated conditions. The condition with better results was the one operated with 17.1 gCOD.L-1.d-1 of AVOL, it reached 100.8 molH2.m-3.d-1 and 20.0 molH2.kgCOD-1, with 68% of H2 and only 3% of CH4 in its biogas. Phase III determined whether there is a real influence on the pretreatment of the sludge and the feasibility of this system treating industrial glycerin, the results show that the pretreatment of the sludge by HST slightly improves the productivity and the process yield and the wastewater made from industrial glycerin substantially decreased the quantity and the quality of the biogas generated.

A melhor maneira de se caracterizar o comportamento mecânico pós-fissuração dos concretos reforçados com fibras (CRF) para fins estruturais é por meio de ensaios que envolvem a ruptura do material à tração direta. Devido às dificuldades de execução destes, comumente se empregam ensaios de tração indireta, com destaque para os ensaios de flexão com sistema fechado. Entretanto, fatores limitantes, como a superestimação da capacidade resistente do compósito em testes de flexão, têm incentivado o desenvolvimento de outros métodos de ensaio mais fidedignos às características do CRF. Este é o caso do ensaio de compressão de corpo de prova com duplo corte em cunha, abreviado como DEWS (do inglês, Double Edge Wedge Splitting), em que o esforço de tração indireta não está associado a uma flecha, como nos ensaios de flexão, mas sim à própria fissuração da matriz de concreto. No DEWS há a possibilidade de avaliação direta da ortotropia do CRF e seu efeito na resistência pós-fissuração no estado limite de serviço (ELS) e último (ELU). Estudos anteriores sobre este ensaio utilizaram sistema aberto, mas se restringiram a avaliar apenas elevados teores de fibra, o que não traz dificuldades à caracterização da resistência residual no ELS. Este trabalho, contudo, buscou o estudo mais acurado a respeito do ensaio DEWS. Os programas experimentais desenvolvidos empregaram concretos reforçados com baixos teores de fibra de aço. Inicialmente, estudou-se a capacidade do ensaio DEWS em identificar o efeito da orientação das fibras na matriz na resistência pós-fissuração do CRF. Essa análise foi correlacionada com os resultados obtidos a partir de ensaios de flexão de prismas feitos como recomendado pela JSCE-SF4, assim, buscou-se avaliar se este teste promove uma superestimação da capacidade de reforço da fibra. Uma outra avaliação centrou-se no fator da taxa de carregamento de ensaio, realizando-se a metodologia DEWS e o teste de flexão (JSCE-SF4: 1984) sob quatro velocidades distintas, com intuito de verificar seu grau de influência no comportamento do material. A partir dos resultados obtidos, o ensaio DEWS mostrou-se aplicável na avaliação da ortotropia de corpos de prova em concretos reforçados com baixos teores de fibra de aço, mesmo com a utilização de sistema aberto e em velocidade de carregamento acima da proposta em literatura. A extensão da instabilidade pós-fissuração obtida a partir do ensaio DEWS foi menor que a encontrada para o ensaio de flexão de prismas. O estudo mostrou que a capacidade resistente pós-fissuração do CRF no ensaio de flexão pode ser até 300% maior do que a mesma resistência medida na direção transversal do prisma. / The best way to characterize the post-cracking behaviour of fibre reinforced concretes (FRC) for structural proposes is through direct tensile tests. As direct tensile tests are difficult to conduce, usually indirect tensile tests are employed, especially bending tests with closed-loop control. However, limiting factors, as the strength capacity overestimation of composites under flexural beams tests had motivated the development of another test procedure aiming to obtain responses closer to FRC basic characteristics. This is the case of Double Edge Wedge Splitting test (DEWS). In this test, the indirect tensile stress is not associated with a deflection - as is common in bending tests - but it is related with the cracking opening of concrete matrix. The DEWS test brings the possibility of direct evaluation of the FRC orthotropic behaviour and its effect in the post-crack strength at the serviceability (SLS) and ultimate (ULS) limit estates. Previous researches about DEWS test were done using open-loop control, but they were limited to higher fibre content. These do not provide difficulties about the residual strength characterization at the SLS. Thus, this study carried out an accurate experimental analysis about DEWS. This experimental programme used only fibre reinforced concrete with low steel fibre volume fractions. The first analysis was based in the DEWS test capacity for identification of the effect of predominant fibre orientation into matrix in the post-crack strength of the FRC. This analysis was linked with the flexural test made with prismatic specimens as recommended by JSCE-SF4 in order to evaluate if it promotes an overestimation of the fibre reinforcement capacity. The other evaluation focused on the test loading rate factor by doing DEWS test and bending test (JSCE-SF4:1984) under four different rates in order to verify its influence on the material behaviour. The results shown that DEWS test was capable to identify the fibre alignment into FRC specimens with low fibre content, even using open-loop control and increasing the load rate. The extension of the instability region on DEWS test response was lower than the provided by the flexural tests. The study also showed that the flexural test could overestimate the post-crack strength capacity of the FRC up 300% in relation to the transversal direction.

Le microscope à force atomique (AFM) est un outil privilégié pour sonder la matière à l'échelle nanométrique. Dans cette thèse, nous l'utilisons comme instrument de mesure de force. Nous montrons que la mesure des fluctuations thermiques des ressorts permet de déterminer précisément leur raideur à condition d'utiliser un modèle qui prend en compte la forme des modes et la méthode de détection. A l'aide de nouvelle méthodes d'analyse des courbes de rétraction, nous étudions la conformation de polymères et de copolymères adsorbés, ainsi que l'interaction spécifique entre un complexe du nickel (Ni-NTA) et l'acide aminé histidine. Nous mettons en évidence des comportements inattendus en présence de liens multiples et nous en proposons une interprétation basée sur un équilibre entre formations et ruptures des liaisons. Nous présentons des premiers résultats expérimentaux concernant la transition conformationnelle de la polylysine sous étirement.

A melhor maneira de se caracterizar o comportamento mecânico pós-fissuração dos concretos reforçados com fibras (CRF) para fins estruturais é por meio de ensaios que envolvem a ruptura do material à tração direta. Devido às dificuldades de execução destes, comumente se empregam ensaios de tração indireta, com destaque para os ensaios de flexão com sistema fechado. Entretanto, fatores limitantes, como a superestimação da capacidade resistente do compósito em testes de flexão, têm incentivado o desenvolvimento de outros métodos de ensaio mais fidedignos às características do CRF. Este é o caso do ensaio de compressão de corpo de prova com duplo corte em cunha, abreviado como DEWS (do inglês, Double Edge Wedge Splitting), em que o esforço de tração indireta não está associado a uma flecha, como nos ensaios de flexão, mas sim à própria fissuração da matriz de concreto. No DEWS há a possibilidade de avaliação direta da ortotropia do CRF e seu efeito na resistência pós-fissuração no estado limite de serviço (ELS) e último (ELU). Estudos anteriores sobre este ensaio utilizaram sistema aberto, mas se restringiram a avaliar apenas elevados teores de fibra, o que não traz dificuldades à caracterização da resistência residual no ELS. Este trabalho, contudo, buscou o estudo mais acurado a respeito do ensaio DEWS. Os programas experimentais desenvolvidos empregaram concretos reforçados com baixos teores de fibra de aço. Inicialmente, estudou-se a capacidade do ensaio DEWS em identificar o efeito da orientação das fibras na matriz na resistência pós-fissuração do CRF. Essa análise foi correlacionada com os resultados obtidos a partir de ensaios de flexão de prismas feitos como recomendado pela JSCE-SF4, assim, buscou-se avaliar se este teste promove uma superestimação da capacidade de reforço da fibra. Uma outra avaliação centrou-se no fator da taxa de carregamento de ensaio, realizando-se a metodologia DEWS e o teste de flexão (JSCE-SF4: 1984) sob quatro velocidades distintas, com intuito de verificar seu grau de influência no comportamento do material. A partir dos resultados obtidos, o ensaio DEWS mostrou-se aplicável na avaliação da ortotropia de corpos de prova em concretos reforçados com baixos teores de fibra de aço, mesmo com a utilização de sistema aberto e em velocidade de carregamento acima da proposta em literatura. A extensão da instabilidade pós-fissuração obtida a partir do ensaio DEWS foi menor que a encontrada para o ensaio de flexão de prismas. O estudo mostrou que a capacidade resistente pós-fissuração do CRF no ensaio de flexão pode ser até 300% maior do que a mesma resistência medida na direção transversal do prisma. / The best way to characterize the post-cracking behaviour of fibre reinforced concretes (FRC) for structural proposes is through direct tensile tests. As direct tensile tests are difficult to conduce, usually indirect tensile tests are employed, especially bending tests with closed-loop control. However, limiting factors, as the strength capacity overestimation of composites under flexural beams tests had motivated the development of another test procedure aiming to obtain responses closer to FRC basic characteristics. This is the case of Double Edge Wedge Splitting test (DEWS). In this test, the indirect tensile stress is not associated with a deflection - as is common in bending tests - but it is related with the cracking opening of concrete matrix. The DEWS test brings the possibility of direct evaluation of the FRC orthotropic behaviour and its effect in the post-crack strength at the serviceability (SLS) and ultimate (ULS) limit estates. Previous researches about DEWS test were done using open-loop control, but they were limited to higher fibre content. These do not provide difficulties about the residual strength characterization at the SLS. Thus, this study carried out an accurate experimental analysis about DEWS. This experimental programme used only fibre reinforced concrete with low steel fibre volume fractions. The first analysis was based in the DEWS test capacity for identification of the effect of predominant fibre orientation into matrix in the post-crack strength of the FRC. This analysis was linked with the flexural test made with prismatic specimens as recommended by JSCE-SF4 in order to evaluate if it promotes an overestimation of the fibre reinforcement capacity. The other evaluation focused on the test loading rate factor by doing DEWS test and bending test (JSCE-SF4:1984) under four different rates in order to verify its influence on the material behaviour. The results shown that DEWS test was capable to identify the fibre alignment into FRC specimens with low fibre content, even using open-loop control and increasing the load rate. The extension of the instability region on DEWS test response was lower than the provided by the flexural tests. The study also showed that the flexural test could overestimate the post-crack strength capacity of the FRC up 300% in relation to the transversal direction.

Este estudo investigou a aplicação de um AnSBBR com recirculação da fase líquida tratando água residuária a base de glicerina (efluente do processo de produção de biodiesel) para a produção de biohidrogênio, sendo o desempenho do biorreator avaliado de acordo com a influência conjunta do tempo de alimentação, do tempo de ciclo e da concentração afluente. O biorreator teve um volume de meio tratado por ciclo de 1,5 L, volume residual de meio de 2,0 L e volume de suporte inerte com biomassa de 2,1 L, sendo mantido a 30°C durante todo o estudo. O trabalho foi divido em três fases: a Fase I foi realizada para determinar os melhores parâmetros de operação do reator (tipo de inóculo, tipo de glicerina, tipo de suporte, concentração de NaHCO3 e velocidade ascensional) para dar seguimento com a Fase II que estudou apenas o efeito da concentração do afluente, tempo de ciclo e tempo de enchimento. Os parâmetros utilizados na Fase II foram: lodo de abatedouro de aves pré-tratado por HST (Heat Shock Treatment 90°C por 10 minutos) como inóculo, glicerina pura comercial para eliminar interferência de possíveis resíduos, suporte de PEBD (polietileno de baixa densidade) e 100 mg.L-1 de NaHCO3. Na Fase II, foram aplicadas 6 condições experimentais com cargas orgânica volumétrica (COVAS) de 7,7 a 17,1 gDQO.L-1.d-1, combinando diferentes concentrações afluentes (3000, 4000 e 5000 mgDQO.L-1) e tempos de ciclo (4 e 3 h), sendo o tempo de alimentação igual a metade do tempo de ciclo. Os resultados mostraram que houve baixa remoção de DQO (máximo de 38% para amostras filtradas) e que houve predomínio do ácido acético e do ácido butírico em todas as condições. O aumento da XV concentração do afluente e a diminuição do tempo de ciclo favoreceram a produtividade e rendimento molares de hidrogênio nas condições investigadas. O ensaio com melhores resultados foi com carga orgânica de 17,1 gDQO.L-1.d-1 no qual obteve-se 100,8 molH2.m-3.d-1 e 20,0 molH2.kgDQO-1, com 68% de H2 e apenas 3% de CH4 no biogás. Na Fase III, determinou-se a influência do pré-tratamento do inóculo e a viabilidade do sistema tratando glicerina bruta industrial, sendo verificado que o pré-tratamento do lodo por HST melhora ligeiramente a produtividade e rendimento do processo e o uso da glicerina bruta industrial diminuiu consideravelmente a quantidade e qualidade do biogás obtido. / This study investigated the feasibility of an AnSBBR with recirculation of the liquid phase treating glycerin-based wastewater (effluent from biodiesel production process) on biohydrogen production; the performance of the bioreactor was evaluated according the combined influence of fill time, cycle period and influent concentration. The bioreactor had 1.5L of feeding volume per cycle, 2.0 L of residual medium, 2.1 L of inert support and biomass and it was kept at 30°C. This study was divided into three phases. Phase I was conducted to determine the best operational parameters for the reactor (type of inoculum, type of glycerin, type of support for biomass, NaHCO3 concentration and upflow velocity), so Phase II would use these parameters to study only the influence of affluent concentration, cycle time and filling time. The parameters used in Phase II were: sludge from poultry slaughterhouse pretreated by HST (Heat Shock Treatment 90°C for 10 minutes) as inoculum, pure glycerin so there would be no interferences from possible residues, LDPE (low density polyethylene) support, 100 mg.L-1 of NaHCO3 and 10.6 m.h-1 of upflow velocity. Phase II was operated under six conditions with different AOLRS ranging from 7.7 to 17.1 gCOD.L-1.d-1, obtained by the combination of different influent concentrations (3000, 4000 and 5000 mgCOD.L-1) and cycle periods (4 and 3 h), the filling time was equal to half of the cycle lenght. The results showed low COD removal (maximum of 38% for filtrated samples) and high concentrations of acetic acid and butyric acid in all conditions. Increasing the affluent concentration and decreasing the cycle length improved the molar productivy and hydrogen yield in the XVII investigated conditions. The condition with better results was the one operated with 17.1 gCOD.L-1.d-1 of AVOL, it reached 100.8 molH2.m-3.d-1 and 20.0 molH2.kgCOD-1, with 68% of H2 and only 3% of CH4 in its biogas. Phase III determined whether there is a real influence on the pretreatment of the sludge and the feasibility of this system treating industrial glycerin, the results show that the pretreatment of the sludge by HST slightly improves the productivity and the process yield and the wastewater made from industrial glycerin substantially decreased the quantity and the quality of the biogas generated.

Municipal wastewater treatment plants (WWTP) are important infrastructural components in a society and also important for sustainability. In a WWTP the most common treatment configuration is mechanical, biological, and chemical treatment of the wastewater. The treatments reduce nutrients and organic matter before the water is transferred to the recipient. During wastewater treatment, sludge is produced and then stabilized in an anaerobic digestion (AD) process.  The Käppala Association operates the third largest WWTP in Sweden. In the future the Käppala plant is expecting an increased number of connected households and also stricter sludge hygienization regulations. This implies that current strategies for the WWTP have to be developed. One idea has been to use a thermophilic AD process instead of mesophilic AD.Thermophilic AD has previously been shown to have higher capacities, lower hydraulic retention times (HRT) and increased pathogenic destruction compared to their mesophilic counterpart. A common negative aspect for a thermophilic process has been process instability.  In this study a 5 m3 pilot plant rented from Research Institutes of Sweden (RISE) was used to evaluate maximal organic loading rate (OLR) for a stable thermophilic AD process using mixed sludge as substrate. Four HRT were chosen, and each HRT was maintained for 3 retention times. Laboratory analyzes of the raw and digested sludge and on-line monitoring were performed regularly to collect information about process stability and efficiency. The pilot plant was controlled through a surveillance system where operating parameters were introduced. The main objectives of this study were to investigate how an increase of OLR affected pH, alkalinity, and volatile fatty acid (VFA) content and also how the alkalinity and VFA affected the process stability. Gas composition, gas production, degree of digestion (DD) and foaming were also investigated throughout this study. Results showed that VFA initially increased, and alkalinity decreased when every OLR increase occurred. The VFA and alkalinity returned to lower values after the process was given time to recover during constant OLR. The OLR increase caused slight variations in process pH but not enough for process failure. Increased OLR did not seem to have a large impact on the DD since it seemed to remain between 40-50% throughout the entire study. Composition monitoring showed an increased hydrogen sulfide content in the gas as a consequence of increased OLR. An OLR increase also lead to a volumetric gas production (VGP) and volumetric methane production (VMP) increase while efficiency of the AD process was seen to decrease when evaluating specific gas production (SGP) and specific methane production (SMP). The conclusion of the study was that a stable thermophilic AD process using mixed sludge as substrate could be operated with an OLR of 6.55 ± 0.06 kg VS m-3d-1and a HRT of 7 days. Maximal OLR for a stable thermophilic AD process was never achieved due to the process remaining relatively stable the entire experimental period. The process recovered from signs of instability during all HRT-transition times indicating it can maintain all investigated OLR. / Kommunala avloppsreningsverk är en viktig infrastruktur i ett samhälle och även viktigt för hållbarheten. I ett avloppsreningsverk renas spillvatten genom mekaniska, biologiska och kemiska behandlingar processteg. Behandlingarna minskar näringsämnen och organiskt material innan vattnet rinner ut i recipienten. Vid rening av avloppsvatten erhålls slam. Slammet kan användas som substrat för en anaerobisk nedbrytningsprocess. Käppalaförbundet driver det tredje största reningsverket i Sverige. I framtiden förväntas antal anslutna hushåll till reningsverket att öka samt strängare slamhanteringskrav appliceras. Detta innebär att nuvarande slamstrategi måste utvecklas. En idé är att tillämpa en termofilrötnings process. En termofil rötningsprocess har visat sig ha högre kapacitet, lägre uppehållstider och ökad patogen reduktion i jämförelse med en mesofil rötning. En nackdel med termofil rötning är den försämrade processtabiliteten.  I denna studie har en 5 m3 pilotanläggning inhyrd från RISE använts för att utvärdera den maximala organiska belastningen för en stabil termofil rötningsprocess med blandslam som substrat. Fyra uppehållstider valdes och varje uppehållstid hölls tre gånger. Regelbundna analyser av rå och rötslam utfördes för att erhålla information om process stabilitet och effektivitet. Pilotanläggningen styrdes genom ett människa-maskingränssnitt där driftparametrar matades in. Huvudmålen för studien var att se hur en ökning av organisk belastning påverkade pH, alkaliniteten och halt av flyktiga fettsyror samt att undersöka alkalinitetens och halten av flyktiga fettsyrors påverkan på processtabiliteten. Påverkan av en ökad organisk belastning på gas sammansättning, gasproduktion, rötningsgrad har även undersökts. Resultaten visade att flyktiga fettsyror initialt ökade och alkaliniteten minskade vid en belastnings ökning. Flyktiga syror och alkalinitet återgick till mer stabila värden efter processen fick återhämta sig vid en konstant belastning. Belastningsökningen orsakade små variationer i pH värdet men inte tillräckligt för att orsaka processkollaps. En ökad belastning verkade inte ha någon större påverkan på rötningsgraden då den låg runt 40–50% hela rötningsperioden. Skumutvecklingen visade sig inte heller vara ett problem. Resultaten visade även att väte sulfid ökade i gasen när en belastningsökning gjordes. Den volymetriska gas och metan produktionen ökade vid en ökad OLR medan specifika gas och metan produktionen minskade. Slutsatsen var att en stabil termofil rötningsprocess av blandslam kan drivas med en organisk belastning på 6.55 ± 0.06 kg VS m-3d-1 och en uppehållstid på 7 dagar. Maximal belastning för stabil termofil rötningsprocess uppnåddes dock ej då processen förblev relativt stabil under alla undersökta uppehållstider. Processen återhämtade sig även efter tecken på instabilitet vilket indikerar att AD processen kan behålla stabilitet vid de undersökta belastningar.

A 2000 mm long saturated laboratory soil column was used to simulate soil aquifer treatment under saturated conditions to assess the removal of chemical and biochemical oxygen demand (COD and BOD), dissolved organic carbon (DOC), nitrogen and phosphate, using high strength artificial wastewater. The removal rates were determined under a combination of constant hydraulic loading rates (HLR) and variable COD concentrations as well as variable HLR under a constant COD. Within the range of COD concentrations considered (42 mg L(-)(1)-135 mg L(-)(1)) it was found that at fixed hydraulic loading rate, a decrease in the influent concentrations of dissolved organic carbon (DOC), biochemical oxygen demand (BOD), total nitrogen and phosphate improved their removal efficiencies. At the high COD concentrations applied residence times influenced the redox conditions in the soil column. Long residence times were detrimental to the removal process for COD, BOD and DOC as anoxic processes and sulphate reduction played an important role as electron acceptors. It was found that total COD mass loading within the range of 911 mg d(-)(1)-1780 mg d(-)(1) applied as low COD wastewater infiltrated coupled with short residence times would provide better effluent quality than the same mass applied as a COD with higher concentration at long residence times. The opposite was true for organic nitrogen where relatively high concentrations coupled with long residence time gave better removal efficiency.

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