Le transport des bruts paraffiniques, et tout particulièrement leur remise en écoulement après un arrêt, dans de longues conduites sous-marines soumises à de basses températures, peut être difficile du fait de l'augmentation de leur viscosité. Le comportement rhéologique d´une huile paraffinique modèle, possédant des propriétés macroscopiques d'écoulement analogues à celles des bruts paraffiniques, est d'abord analysé en utilisant la vélocimétrie par imagerie par résonance magnétique associée à des mesures de contrainte de cisaillement au sein d'une géométrie Couette. Nous montrons que lors d'un écoulement forcé à température constante le matériau subit une déstructuration irréversible qui dépend de l'intensité du cisaillement. Ainsi la contrainte apparente critique permettant l'écoulement du matériau dépend de l'histoire thermique et d'écoulement subie par le matériau. Nous étudions ensuite le comportement rhéologique complet de deux bruts réels à partir de différents types de tests rhéométriques (fluages, redémarrage, régime permanent, changement brusque de vitesse) pour différentes histoires d'écoulement, notamment pendant la période de refroidissement. Le comportement détaillé du matériau en régime transitoire ainsi observé peut alors être modélisé. De plus les variations du seuil de contrainte en fonction de l'histoire thermique et de l'écoulement sont aussi décrites, ce qui nous donne le champ de contrainte seuil dans la conduite à l'état initial. Le modèle dans son ensemble est finalement implémenté dans un code de calcul pour simuler le redémarrage de l´écoulement d'un brut paraffinique dans une conduite réelle / Transporting waxy crude oils through long pipelines at low temperatures may be challenging, particularly its flow restart after a pipeline shut-in, due to its viscosity increase. The rheological behavior of a model waxy oil with macroscopic flow properties analogous to waxy crude oils is first analyzed using Magnetic Resonance Imaging velocimetry associated to stress measurements in a Couette geometry. While flowing at constant temperature, major irreversible structure break depending on shear intensity are observed. Thus, the critical apparent shear stress beyond which the material flows depends on the thermal and flow histories of the oil. Next, the rheological behavior of two waxy crude oils is studied using rheometrical tests (creep tests, flow restarts, abrupt changes of shear rate and steady flow) after different flow histories, notably during the cooling process. Then, those experimentally observed trends are modeled. Additionally, a comprehensive study of the yield stress in function of flow and temperature histories is presented. It provides an approach for describing the yield stress field inside the pipeline at the flow restart moment. Finally, the entire rheological model is implemented in the computational code for simulating waxy crude oils flow restart of a real scale pipeline

The thesis deals with the description of the unstable flow of non-Newtonian fluid in a slit-flow rheometer, which negatively affects its behaviour. The initiators of unstable fluid flow are the roughness of the rheometer slit walls, the slip on the rheometer walls, and the influence of the inlet and outlet region geometry of the rheometer slit. The work contains methodical procedures for mathematical consideration of individual unstable fluid flow initiators and design of change of slit geometry of slit-flow rheometer. Part of the work is also a comparison of the most commonly used rheological models, derivation of general relations for the creation of the velocity profile of individual rheological models and their subsequent implementation in the rheological application, which significantly simplifies the process of evaluation of measured data when measured on slit-flow rheometer. This application can be used to determine basic parameters in CFD simulations or as a teaching aid.

Předložená diplomová práce je zaměřená na studium viscoelastického chování kostních past na bázi fosforečnanu vápenatého a vodného roztoku termosenzitivního triblokového kopolymeru, zlepšujícího tokové vlastnosti pasty. V teoretické části je zpracována stručná charakteristika cementů na bázi fosforečnanu vápenatého. Rovněž se zabývá charakteristikou reologických vlastností injektabilních kostních past. Součástí je také stručný přehled aditiv ovlivňujících právě reologické a mechanické vlastnosti past. Experimentální část je zaměřena na charakterizaci triblokového kopolymeru pomocí nukleární magnetické rezonanční spektroskopie a reologie. Dále byly připravovány modifikované fosfátové cementy, u kterých byly posléze studovány viskoelastické vlastnosti. Kostní pasta byla modifikována přídavkem adhezivních sloučenin (dopamin a jodičnan sodný) a antibakteriálním činidlem (selenové nanočástice). Analýza viskoelastických vlastností byla provedena reologickou analýzou, během níž byl primárně sledován proces vytvrzování a tixotropní chování jak nemodifikovaných, tak modifikovaných fosfátových past. Proces vytvrzování probíhal při teplotě 23 °C a 37 °C, imitující fyziologické prostředí. Morfologie fosfátové keramiky byla charakterizována pomocí rastrovací elektronové mikroskopie a velikost částic byla zjištěna pomocí laserového analyzátoru částic. Bylo prokázáno, že výše zmíněná aditiva mají pozitivní vliv na kinetiku procesu vytvrzování kostních past. Selenové nanočástice navíc vylepšily tixotropní chování polymer-fosfátových past. Z tohoto důvodu jsou tyto nové injektabilní kompozitní pasty vhodné pro miniinvazivní chirurgii. Díky aditivům, vykazujících adhezivní vlastnosti, mají potenciál uplatnit se při léčbě zlomenin. Stejně tak se nabízí možnost využít pasty při léčbě osteomyelitidy, a to díky možnému uvolňování antibakteriálních nanočástic.

The thesis focuses on collecting available information about possible ways of using and usage restriction of portland blended cements and portland cements with limestone for production of concrete. The experimental part of the thesis describes the behavior of portland blended cements and portland cements with limestone in aggressive environments. Furthermore, the thesis concerns the dependence of rheological properties of cement pastes of portland cements and portland cements with limestone on type of plasticizing additives.

<div> <div> <div> <p>Transparent alumina is a candidate material for ballistic applications where visible or infrared wavelength transmission is required. However, the transparency of polycrystalline alumina can be limited due to the rhombohedral crystal structure being inherently birefringent. Birefringence causes light scattering at grain boundaries and is detrimental to the transparency. It has been shown experimentally that the application of a high magnetic field during processing can lead to crystallographic alignment and the reduction of birefringent light scattering. This alignment method is effective but is limited in terms of scalability. This research addresses these limitations through the use of simple and cost-effective shear and elongational forming processes such as uniaxial warm pressing and direct ink writing (DIW) for the improvement of final sintered transparency. To further support the improvement of these processes as alternatives and to evaluate the possibility of using powder ratios to improve the alignment, this research will also investigate the sintering behavior during hot-pressing of equiaxed and platelet powders. </p> <p>Platelet ceramic-filled thermoplastic blends were developed and formed into sheets through uniaxial warm pressing. The solids loading (30 – 40 vol.%) and platelet diameter (1.2 and 11μm) were varied to compare effects on viscosity, percent reduction, and final alignment. All ceramic- filled thermoplastic polymer blends exhibited pseudoplastic behavior. Crystallographic alignment of green body samples was quantified by the orientation parameter (r) and grain misalignment angle (full width at half maximum, FWHM) obtained from rocking curve analysis. Blends with 11μm diameter platelets displayed a higher temperature sensitivity constant, better flow properties, and higher alignment compared to blends with 1.2μm diameter platelets. Optimal samples produced with blends containing 30 vol.% of 11μm diameter platelets demonstrated an alignment of r = 0.251 +/- 0.017; FWHM = 11.16° +/- 1.16°. A sample with optimal alignment was hot-pressed to transparency and obtained an in-line transmission of 70.0% at 645nm. The final alignment of this pre-aligned hot-pressed sample (r = 0.254 +/- 0.008; FWHM = 11.38° +/- 0.54°) improved when compared to a non-pre-aligned sample (r = 0.283 +/- 0.005; FWHM = 13.40° +/- 0.38°).</p><p>Additionally, the use of direct ink writing, an additive manufacturing technique, as a viable alignment process for producing transparent alumina was investigated. Highly loaded (> 54 vol.%) equiaxed alumina suspensions were developed with platelet additions ranging from 0-20vol.% of the total solids loading. An increase in the amount of platelet powders from 5-20vol.% increased the dynamic yield stress from 104Pa to 169Pa and decreased in the equilibrium storage modulus from 17,036Pa to 13,816Pa. It was found that the DIW process significantly increased the alignment in one orientation when compared to samples cast from the same suspensions and this behavior may be connected to the rheological properties. Lastly, an optical analysis showed that sample developed with 5vol.% platelet suspensions had higher in-line transmission values across the visible spectrum when compared to samples developed with 20vol.% suspensions. A sample cast from a 5vol.% platelet suspensions had the lowest grain alignment but possessed an in-line transmission of 42.8% at 645nm, which was the highest of the samples produced in this study. An optical loss analysis showed, that this sample has the lowest backwards scattering losses due to residual porosity and this result was supported by the density data. It is suggested that the alignment of the DIW samples is more complex and a more advanced texture analysis will need to be conducted to properly characterize the grain alignment.</p><p>Lastly, the densification behavior of equiaxed and platelet powder ratios with no intentional pre-alignment was investigated. An initial sintering investigation identified the optimum maximum pressure selected for the hot-pressing process as 20MPa. Under the selected hot- pressing parameters, the effects of 0, 25, 50, 75, and 100wt.% equiaxed powder additions on the sintering behavior, optical properties, and grain alignment was investigated. The data showed that an increase in the amount of equiaxed powders decreased the initial powder compact displacements rate. Additionally, an increase in the wt.% equiaxed powders from 0wt% to 75wt% decreases the in-line transmission from 70.9% to 40.2%, respectively at 645nm. Lastly, an increase in the wt.% equiaxed powders from 0wt% to 75wt decreased the alignment from (r = 0.321 +/- 0.005; FWHM = 16.26° +/- 0.40°) to (r = 0.509 +/- 0.022; FWHM = 34.63° +/- 2.61°), respectively.</p></div></div></div>

Cette étude constitue une contribution à la recherche de nouveau matériau composite originaire des ressources naturelles végétales. Elle vise alors à l’exploitation des fibres naturelles extraites de la plante d’Alfa avec une matrice biopolymère thermoplastique de type Mater-Bi® afin d’élaborer des biocomposites. Trois types de fibres courtes extraites de la plante d’Alfa sont préparés ; non traitées et traitées par un traitement alcalin à 1 et 5%. Les diverses techniques utilisées pour la caractérisation des fibres ont révélé une augmentation de la rugosité, du taux de cellulose, de l’indice de cristallinité ainsi de la stabilité thermique après le traitement alcalin. Les matériaux composites sont préparés par extrusion bivis suivi d’une opération d’injection en faisant varier le pourcentage des fibres de 0 à 25%. Les analyses thermiques des biocomposites ont montré un accroissement significatif de la vitesse de cristallisation suite à l'incorporation des fibres d’Alfa ainsi une amélioration de la stabilité thermique pour les matériaux à base de fibres traitées. La résistance à la traction et le module de Young des biocomposites ont augmenté alors que la ténacité et l’allongement à la rupture ont diminué avec l'augmentation du taux de fibres. Les micrographies MEB des surfaces fracturées indiquent une bonne adhésion entre la matrice et les fibres d’Alfa traitées ou non. L’étude de la cinétique de cristallisation des différents biocomposites a prouvé le fort effet nucléant des fibres d’Alfa traitées ou non / This study is a contribution to the search for new composite material from vegetable natural resources. It aims at the exploitation of natural fibers extracted from the Alfa plant with a bioplastic of the Mater-Bi® type in order to develop biocomposites. Three kinds of short fibers extracted from Alfa plant were prepared; untreated, 1% and 5% alkali treated. The various techniques used for fibers characterization showed an increase in the roughness, cellulose level, crystallinity index and thermal stability after the alkali treatment. The composite materials were prepared by twin screw extrusion flowed by an injection operation by varying the fiber contents of 0 to 25%. Thermal analysis showed significant increase of the crystallization rate with the incorporation of Alfa fibers and enhancement of thermal stability by alkali treatment. Modulus and tensile strength of biocomposites also improved whereas toughness and elongation at break decreased upon increasing the fibers fraction. Scanning electron microscopy (SEM) on fractured surfaces indicated good adhesion between the matrix and the treated or untreated Alfa fibers. The study of crystallization kinetics of biocomposites showed strong nucleating effect of treated or untreated Alfa fibers.

Advanced computational methods for the analysis of building structures are used more often in engineering practice. Their use is enforced not only by the demands for aesthetics, functionality and high economy of the construction, but often directly by code provisions and requirements. Therefore, it is necessary to provide for an engineer the robust, but transparent tool, which can be used for an efficient design of structure all over it's design working life. This work deals with the creation of a computational system for time dependent analysis of concrete and composite structures. It is assumed a solid or composite concrete section with possible application of pre-tensioned and/or post-tensioned tendons. Each phase of step-by-step build composite cross-section has a general geometry. The used algorithms give us the possibility of a detailed analysis of the structure in individual construction stages, provide the designer better view on the behavior of structures with respect to concrete aging, shrinkage and creep, relaxation of prestressed tendons and provide an information on the redistribution of internal forces in the structure and in different phases of the cross-section. Stress state of the structure calculated in this way come in useful further in the design and checking of ultimate and serviceability limit states. Results of time dependent analysis are verified by manual calculations and by comparing with the results obtained by simplified methods.

Magnetoactive elastomers (MAEs) are polymer composites containing magnetically soft or hard particles incorporated into an elastomer matrix during the crosslinking procedure. In the presence of a magnetic field, the induced magnetic interactions and the corresponding particle rearrangements significantly alter the mechanical properties in dependence on the initial particle distribution and sample shape. In addition, applying magnetic fields also changes the macroscopic shape of an MAE. This thesis investigates the magneto-mechanical coupled behaviour of MAEs by means of analytical and numerical methods. The effects of particle distribution and sample shape have been studied with the help of a physically motivated model of MAEs that considers dipole-dipole interactions between magnetizable particles. The presence of a magnetic field leads to a mechanical anisotropy in MAEs with isotropic particle distribution, and the induced anisotropy is directed along the orientation of the field. Thus, MAEs exhibit direction-dependent mechanical properties with distinct elastic moduli along and perpendicular to the field direction when the MAE sample is subjected to uniaxial deformation. A good agreement is reported between the physically motivated approach and conventional transversely isotropic material models. Furthermore, we investigate the important interplay between the particle distribution and the sample shape of MAEs, where a simple analytical expression is derived based on geometrical arguments to describe the particle distribution inside MAEs. We show that the enhancement of elastic moduli arises not only from the induced dipole-dipole interactions but also considerably from the change in the particle microstructure. Moreover, the magneto-mechanical behaviour of isotropic MAEs under shear deformations is studied. Three principal geometries of shear deformation are investigated with respect to the orientation of the applied magnetic field. We show that the Cauchy stress tensor of MAEs is not always symmetric due to the generation of a magnetic torque acting on an anisometric MAE sample under shear loadings. The theoretical study of magneto-mechanical behaviour of MAEs confirms that the effect of sample shape is quite significant and cannot be neglected. On the other hand, the initial particle distribution and presumed rearrangements due to the magnetic field additionally influence the material response of MAEs. Finally, the physically motivated model of MAEs could be transformed into an invariants-based model enabling its implementation in commercial finite element software. Therefore, we have uncovered a new pathway to model MAEs based on dipole-dipole interactions, leading to a constitutive relation analogous to the macro-scale continuum approach and revealing a synergy between both modelling strategies.

<p>The dissertation offers a Multiphysics perspective in analyzing emerging metallurgical techniques. Heat transfer, structural deformation, and fluid flow associate with one another in phase-changing materials processing methods. To comprehensively analyze these aspects for an optimized final product, the authors have proposed a numerical mathematical model describing the thermal and geometric progression of the binary alloy casting process. The model is further executed in COMSOL Multiphysics, adapted in two metal manufacturing applications, resistance spot welding (RSW) and binder jet printing (BJP). </p><p>Resistance spot welding is a well-adapted metal sheeting joining technique with comparably limited modeling and simulating research. The heat transfer module and geometric deformation module are applied to the simulation of RSW to discuss the thermal gradient development of the welding zone. The model was further calculated and verified through a case study with Python. </p><p>BJP is a rapidly developing additive manufacturing method. The novel 3D printing technique brings challenges in post-processing geometric control and material selection limitations. Multiphysics simulation serves as an excellent tool in process parameters analysis and quality control. This dissertation focuses on the sintering process of BJP of binary alloy powders. Melting and solidification mathematical models were implemented in COMSOL, where the sintering shrinkage rate could be calculated. The shrinkage rate was further verified through experimental analysis of binder jet printed samples. </p><p>Microstructural analysis on sintered binder jet printed parts was performed to assess the validity of BJP to substitute the die casting method for manufacturing of valvebody. Sintering shrinkage and metallurgical analysis have been performed on the green and sintered BJP samples. After sintering, the final part achieved 98% density, and the integrity of the designed channels was preserved. The shrinkage analysis has indicated the effect of printing orientation and sintering orientation on the geometry and metallurgy of the final products. Microstructure analysis on the cross-sections of the sintered products also indicates the various defects induced from biner jet 3D printing. </p><p>The research aims to provide a systematic rheology analysis of the phase transformation process of binary alloys. The dissertation has connected the physical, mathematical modeling with 15 </p><p><br></p><p>simulative modeling through the rheological evaluation of phase-changing manufacturing techniques. The connections were conclusively verified through empirical studies, including case assessment and experimentation. The research aims to offer universally applicable models that can be applied to phase-changing metal processing techniques. </p>

3D-printing, också känt som additiv tillverkning, är en tillverkningsmetod som har revolutionerat många branscher och har växt stort både inom industrin och för privat användning. Tekniken använder sig utav en lager-på-lager metod för att tillverka olika objekt. Med dagens teknik går det att printa ut föremål av exempelvis metall, plast, betong och ett flertal andra material. Additiv tillverkning av betong ger möjligheten att skapa nya smarta konstruktionslösningar, vilket medför stora materialbesparingar och minskat materialspill. Produktionskostnader och hastighet kan också dra nytta av metoden genom att minska arbetskraft och eliminera kostnader för tillverkning och montering av gjutformar. Den här studien bidrar till en ökad förståelse för vad som krävs för att utveckla ett fungerande betongmaterial för additiv tillverkning. För att additiv tillverkning ska kunna standardiseras, bli mer kommersiellt och få en bredare användning krävs en djupare förståelse av betongens materialegenskaper. Detta eftersom materialet skiljer sig från konventionell betong. Syftet med detta projekt är att utveckla en betongblandning anpassad för additiv tillverkning. En undersökning görs för att hitta (i) en betongblandning med lämpliga mekaniska materialegenskaper och (ii) en betongblandning som är väl anpassad till 3Dskrivare. Det viktigaste för att en betongblandning ska kunna användas för additiv tillverkning är att blandningen kan pumpas genom systemet och extraheras genom munstycket vid tillverkning samt att slutmaterialet visar bra byggbarhet. Pumpbarhet är förutsättningen för att betongen ska kunna användas i en 3D-skrivare. Betongen ska vara tillräckligt smidig för att kunna pumpas ut genom ett munstycke, men även ha en tillräckligt god inre sammanhållning för att inte deformeras efter att den har pumpats ut. Pumpbarhet påverkas till stor del av vilken sorts pumpsystem som används. Resultaten varierar beroende på vilken pump, munstycke och slang som används vid materialtesterna. Det förefaller att en generell blandning anpassad för flera olika pumpsystem är svårt att uppnå. I det här arbetet har sex olika blandningar med olika variationer testats. Detta ledde till 38 blandningar som genomgått olika tester. De blandningarna med bäst resultat efter finjusteringar var blandning 4.1 och 5.1, de visade hög kvalité för pumpbarhet och byggbarhet. Blandning 4.1 innehåller vatten, anläggningscement, starvis 3040, glenium, CERW, krossballast och glasfibrer och blandning 5.1 är likadant fast med flygaska istället för CERW. / 3D printing, also known as additive manufacturing, is a manufacturing method that has revolutionized many industries and has grown widely both in industry and private use. The technique means using a layer-upon-layer method to manufacture different objects. With today's technology, it is possible to print objects of, for example, metal, plastic, concrete and several other materials. Additive manufacturing of concrete structures can be used to create new smart design solutions, which means significant material savings and reduced material waste. Production costs and time reduction may also be achieved using the method due to lower labor requirements and reduced costs for manufacturing and assembling of molds. This study contributes to an increased understanding of what is required to develop a functioning concrete material for additive manufacturing. In order for additive manufacturing to be standardized, become commercial and be broadly used, a deeper understanding of the concrete properties is required. This is because the material used in 3D printing differs from conventional concrete. The purpose of this project is to develop a concrete mixture adapted for additive manufacturing. A survey is made to find (i) a concrete mixture with suitable mechanical material properties, and (ii) a concrete mixture well adapted to 3D printers. The most important thing for a concrete mix to be used for additive production is that the mixture can be pumped through the system and extracted through the nozzle during manufacture and that the final material shows good buildability. Pumpability is a prerequisite for the concrete to be used in a 3D printer. The concrete must be sufficiently flexible to be pumped out through a nozzle, but also have a sufficiently good internal cohesion so as not to deform after it has been pumped out. Pumpability is largely affected by the type of pump system used. The results vary depending on the pump, nozzle and hose used in the material tests. It seems that a general mix adapted to several different pump systems is difficult to achieve. In this work, six different mixtures with different variations have been tested. This led to 38 mixtures that underwent various tests. The mixtures with the best results after fine adjustments were mix 4.1 and 5.1, they showed high quality for pumpability and buildability. Mixture 4.1 contains water, plant cement, starvis 3040, glenium, CERW, crush ballast and glass fibers and mixture 5.1 is similarly fixed with fly ash instead of CERW.