Evapotranspiration ET is a dominant Earth System process that couples the water and energy cycles at the earth surface. The pressure of global environmental changes foster the broad scientific aim to understand impacts of climate and land-use on evapotranspiration under transient conditions. In this work, the spatial scale of river catchments is addressed through data analysis of hydrological and meteorological archives with ET classically derived through water balance closure. Through a synthesis of various catchments with different climatic forcings and hydrological conditions, the core objectives of this thesis are: - Did environmental changes in the past, such as climatic- or land-use and land cover (LULC) changes, result in detectable non-stationary changes in the hydro-climate time series? - How can the impacts of climatic- from LULC changes on the hydroclimatology of catchments be separated? - What are the factors that control the sensitivity of ET and streamflow to external changes? These research questions are addressed for the climatic scales of long-term annual averages and seasonal conditions which characterise the hydroclimatology of river catchments. Illustrated by a rich hydro-climatic archive condensed for 27 small to medium sized river catchments in Saxony, a method is proposed to analyse the seasonal features of river flow allowing to detect shifting seasons in snow affected river basins in the last 90 years. Observations of snow depth at these same times lead to the conclusion, that changes in the annual cycle of air temperature have a large influence on the timing of the freeze-thaw in late winter and early spring. This causes large changes in storage of water in the snow pack, which leads to profound changes of the river regime, particularly affecting the river flow in the following months. A model-based data analysis, based on the fundamental principles of water and energy conservation for long-term average conditions, is proposed for the prediction of ET and streamflow, as well as the separation of climate related impacts from impacts resulting from changes in basin conditions. The framework was tested on a large data set of river catchments in the continental US and is shown to be consistent with other methods proposed in the literature. The observed past changes highlight that (i) changes in climate, such as precipitation or evaporative demand, result in changes of the partitioning within the water and energy balance, (ii) the aridity of the climate and to a lesser degree basin conditions determine the sensitivity to external changes, (iii) these controlling factors influence the direction of LULC change impacts, which in some cases can be larger than climate impacts. This work provides evidence, that changes in climatic and land cover conditions can lead to transient hydrological behaviours and make stationary assumptions invalid. Hence, past changes present the opportunity for model testing and thereby deriving fundamental laws and concepts at the scale of interest, which are not affected by changes in the boundary conditions. / Die Verdunstung ist ein maßgeblicher Prozess innerhalb des Klimasystems der Erde, welche den Wasserkreislauf mit dem Energiehaushalt der Erde verbindet. Eine zentrale wissenschaftliche Herausforderung ist, zu verstehen, wie die regionale Wasserverfügbarkeit durch Änderungen des Klimas oder der physiographischen Eigenschaften der Landoberfläche beeinflusst wird. Mittels einer integrierten Datenanalyse von vorhandenen langjährigen Archiven hydroklimatischer Zeitreihen werden die folgenden wissenschaftlichen Fragestellungen dieser Dissertation diskutiert: - Haben beobachtete Änderungen der Landoberfläche und des Klimas zu nachweisbaren, instationären hydroklimatischen Änderungen geführt? - Lassen sich die hydroklimatischen Auswirkungen von Klimaänderungen und Änderungen der Landoberfläche voneinander unterscheiden? - Welche Faktoren beeinflussen die Sensitivität von Abfluss und Verdunstung auf Veränderungen der klimatischen und physiographischen Randbedingungen? Hierbei fokussiert sich die Arbeit auf Änderungen im langjährige Mittel und im Jahresgang von hydroklimatischen Variablen auf der räumlichen Skala von Flusseinzugsgebieten. Zur Untersuchung des hydrologischen Regimes wurde ein harmonischer Filter angewandt, der es erlaubt, die Eintrittszeit des Jahresgangs (Phase) zu quantifizieren. Diese klimatologische Kenngröße wurde für eine Vielzahl von Einzugsgebieten in Sachsen untersucht, wobei sich vor allem für die Gebiete in den Kammlagen des Erzgebirges signifikante Veränderungen ergaben. Es konnte gezeigt werden, dass die signifikante Phasenverschiebung der Temperatur seit Ende der 1980er Jahre zu einer verfrühten Schneeschmelze und dadurch zu einem Rückgang des Abflusses bis in die Sommermonate hinein geführt hat. Desweiteren wurde eine modellbasierte Datenanalyse entwickelt, welche auf Massen- und Energieerhalt von Einzugsgebieten im langjährigen Mittel beruht. Das entwickelte Konzept erlaubt es, Auswirkungen von Klimaänderungen von anderen Effekten, welche z.B. durch Landnutzungsänderungen bedingt sind, abzugrenzen und zu quantifizieren. Die Ergebnisse einer Sensitivitätsanalyse dieses Konzeptes sowie die Anwendung auf einen umfangreichen hydroklimatischen Datensatz der USA zeigen: (i) Veränderungen im Wasser- oder Energiedargebot beeinflussen auch die Aufteilung der Wasser- und Energieflüsse. (ii) Die Aridität des Klimas und nachgeordnet die physiographischen Faktoren bestimmen die Sensitivität von Verdunstung und Abfluss. (iii) Beide Faktoren beeinflussen die Stärke und Richtung der Auswirkungen von physiographischen Änderungen. (iv) Anthropogene Veränderungen der Landoberfläche führten zum Teil zu stärkeren Auswirkungen als klimatisch bedingte Änderungen. Zusammenfassend zeigt sich, dass Änderungen von Landnutzung und Klima zu Verschiebungen im Wasserhaushalt führen können und damit auch die Annahme von Stationarität verletzen. Hydroklimatische Veränderungen bieten aber auch eine Gelegenheit zum Testen von Theorien und Modellen, um somit die grundlegenden Zusammenhänge zu erkennen, welche nicht durch Änderungen der Randbedingungen hinfällig werden.

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The Wadi Dhuliel catchment/ North east Jordan, as any other arid area has distinctive hydrological features with limited water resources. The hydrological regime is characterized by high variability of temporal and spatial rainfall distributions, flash floods, absence of base flow, and high rates of evapotranspiration. The aim of this Ph.D. thesis was to apply lumped and distributed models to simulate stream flow in the Wadi Dhuliel arid catchment. Intensive research was done to estimate the spatial and temporal rainfall distributions using remote sensing. Because most rainfall-runoff models were undertaken for other climatic zones, an attempt was made to study limitations and challenges and improve rainfall-runoff modeling in arid areas in general and for the Wadi Dhuliel in particular. The thesis is divided into three hierarchically ordered research topics. In the first part and research paper, the metric conceptual IHACRES model was applied to daily and storm events time scales, including data from 19 runoff events during the period 1986-1992. The IHACRES model was extended for snowfall in order to cope with such extreme events. The performance of the IHACRES model on daily data was rather poor while the performance on the storm events scale shows a good agreement between observed and simulated streamflow. The modeled outputs were expected to be sensitive when the observed flood was relatively small. The optimum parameter values were influenced by the length of a time series used for calibration and event specific changes. In the second research paper, the Global Satellite Mapping of Precipitation (GSMaP_MVK+) dataset was used to evaluate the precipitation rates over the Wadi Dhuliel arid catchment for the period from January 2003 to March 2008. Due to the scarcity of the ground rain gauge network, the detailed structure of the rainfall distribution was inadequate, so an independent from interpolation techniques was used. Three meteorological stations and six rain gauges were used to adjust and compare with GSMaP_MVK+ estimates. Comparisons between GSMaP_MVK+ measurements and ground rain gauge records show distinct regions of correlation, as well as areas where GSMaP_MVK+ systematically over- and underestimated ground rain gauge records. A multiple linear regression (MLR) model was used to derive the relationship between rainfall and GSMaP_MVK+ in conjunction with temperature, relative humidity, and wind speed. The MLR equations were defined for the three meteorological stations. The ‘best’ fit of the MLR model for each station was chosen and used to interpolate a multiscale temporal and spatial distribution. Results show that the rainfall distribution over the Wadi Dhuliel is characterized by clear west-east and north-south gradients. Estimates from the monthly MLR model were more reliable than estimates obtained using daily data. The adjusted GSMaP_MVK+ dataset performed well in capturing the spatial patterns of the rainfall at monthly and annual time scales, while daily estimation showed some weakness for light and moderate storms. In the third research paper, the HEC-HMS and IHACRES rainfall runoff models were applied to simulate a single streamflow event in the Wadi Dhuliel catchment that occurred in 30-31.01.2008. Both models are considered suitable for arid conditions. The HEC-HMS model application was done in conjunction with the HEC-GeoHMS extension in ArcView 3.3. Streamflow estimation was performed on hourly data. The aim of this study was to develop a new framework of rainfall-runoff model applications in arid catchment by integrating a re-adjusted satellite derived rainfall dataset (GSMaP_MVK+) to determine the location of the rainfall storm. Each model has its own input data sets. HEC-HMS input data include soil type, land use/land cover map, and slope map. IHACRES input data sets include hourly rainfall and temperature. The model was calibrated and validated using observed stream flow data collected from Al-Za’atari discharge station. IHACRES shows some weaknesses, while the flow comparison between the calibrated streamflow results agrees well with the observed streamflow data of the HEC-HMS model. The Nash-Sutcliffe efficiency (Ef) for both models was 0.51, and 0.88 respectively. The application of HEC-HMS model in this study is considered to be satisfactory.

The Wadi Dhuliel catchment/ North east Jordan, as any other arid area has distinctive hydrological features with limited water resources. The hydrological regime is characterized by high variability of temporal and spatial rainfall distributions, flash floods, absence of base flow, and high rates of evapotranspiration. The aim of this Ph.D. thesis was to apply lumped and distributed models to simulate stream flow in the Wadi Dhuliel arid catchment. Intensive research was done to estimate the spatial and temporal rainfall distributions using remote sensing. Because most rainfall-runoff models were undertaken for other climatic zones, an attempt was made to study limitations and challenges and improve rainfall-runoff modeling in arid areas in general and for the Wadi Dhuliel in particular. The thesis is divided into three hierarchically ordered research topics. In the first part and research paper, the metric conceptual IHACRES model was applied to daily and storm events time scales, including data from 19 runoff events during the period 1986-1992. The IHACRES model was extended for snowfall in order to cope with such extreme events. The performance of the IHACRES model on daily data was rather poor while the performance on the storm events scale shows a good agreement between observed and simulated streamflow. The modeled outputs were expected to be sensitive when the observed flood was relatively small. The optimum parameter values were influenced by the length of a time series used for calibration and event specific changes. In the second research paper, the Global Satellite Mapping of Precipitation (GSMaP_MVK+) dataset was used to evaluate the precipitation rates over the Wadi Dhuliel arid catchment for the period from January 2003 to March 2008. Due to the scarcity of the ground rain gauge network, the detailed structure of the rainfall distribution was inadequate, so an independent from interpolation techniques was used. Three meteorological stations and six rain gauges were used to adjust and compare with GSMaP_MVK+ estimates. Comparisons between GSMaP_MVK+ measurements and ground rain gauge records show distinct regions of correlation, as well as areas where GSMaP_MVK+ systematically over- and underestimated ground rain gauge records. A multiple linear regression (MLR) model was used to derive the relationship between rainfall and GSMaP_MVK+ in conjunction with temperature, relative humidity, and wind speed. The MLR equations were defined for the three meteorological stations. The ‘best’ fit of the MLR model for each station was chosen and used to interpolate a multiscale temporal and spatial distribution. Results show that the rainfall distribution over the Wadi Dhuliel is characterized by clear west-east and north-south gradients. Estimates from the monthly MLR model were more reliable than estimates obtained using daily data. The adjusted GSMaP_MVK+ dataset performed well in capturing the spatial patterns of the rainfall at monthly and annual time scales, while daily estimation showed some weakness for light and moderate storms. In the third research paper, the HEC-HMS and IHACRES rainfall runoff models were applied to simulate a single streamflow event in the Wadi Dhuliel catchment that occurred in 30-31.01.2008. Both models are considered suitable for arid conditions. The HEC-HMS model application was done in conjunction with the HEC-GeoHMS extension in ArcView 3.3. Streamflow estimation was performed on hourly data. The aim of this study was to develop a new framework of rainfall-runoff model applications in arid catchment by integrating a re-adjusted satellite derived rainfall dataset (GSMaP_MVK+) to determine the location of the rainfall storm. Each model has its own input data sets. HEC-HMS input data include soil type, land use/land cover map, and slope map. IHACRES input data sets include hourly rainfall and temperature. The model was calibrated and validated using observed stream flow data collected from Al-Za’atari discharge station. IHACRES shows some weaknesses, while the flow comparison between the calibrated streamflow results agrees well with the observed streamflow data of the HEC-HMS model. The Nash-Sutcliffe efficiency (Ef) for both models was 0.51, and 0.88 respectively. The application of HEC-HMS model in this study is considered to be satisfactory.

Arid regions, that have a terrestrial share of 30 %, heavily rely on groundwater for do-mestic, industrial and irrigation purposes. The reliance on groundwater has partly turned into a dependency in areas where the increasing population number and the expansion of irrigated agricultural areas demand more groundwater than is naturally replenished. Yet, spatial and temporal information on groundwater are often scarce induced by the facts that groundwater is given a low priority in many national budgets and numerous (semi-) arid regions in the world encompass large and inaccessible areas. Hence, there is an urgent need to provide low-cost alternatives that in parallel cover large spatial and temporal scales to gain information on the groundwater system. Remote sensing holds a tremendous potential to represent this alternative. The main objective of this thesis is the improvement of existing and the development of novel remote sensing applications to infer information on the scarce but indispensable resource groundwater at the example of the Dead Sea. The background of these de-velopments relies mainly on freely available satellite data sets. I investigate 1) the pos-sibility to infer potential groundwater flow-paths from digital elevation models, 2) the applicability of multi-temporal thermal satellite data to identify groundwater discharge locations, 3) the suitability of multi-temporal thermal satellite data to derive information on the long-term groundwater discharge behaviour, and 4) the differences of thermal data in terms of groundwater discharge between coarse-scaled satellite data and fine-scaled airborne data including a discharge quantification approach. 1) I develop a transparent, reproducible and objective semi-automatic approach us-ing a combined linear filtering and object based classification approach that bases on a medium resolution (30 m ground sampling distance) digital elevation model to extract lineaments. I demonstrate that the obtained lineaments have both, a hydrogeological and groundwater significance, that allow the derivation of potential groundwater flow-paths. These flow-paths match results of existing groundwater flow models remarkably well that validate the findings and shows the possibility to infer potential groundwater flow-paths from remote sensing data. 2) Thermal satellite data enable to identify groundwater discharge into open water bodies given a temperature contrast between groundwater and water body. Integrating a series of thermal data from different periods into a multi-temporal analysis accounts for the groundwater discharge intermittency and hence allows obtaining a representa-tive discharge picture. I analyse the constraints that arise with the multi-temporal anal-ysis (2000-2002) and show that ephemeral surface-runoff causes similar thermal anomalies as groundwater. To exclude surface-runoff influenced data I develop an au-tonomously operating method that facilitates the identification. I calculate on the re-maining surface-runoff uninfluenced data series different statistical measures on a per pixel basis to amplify groundwater discharge induced thermal anomalies. The results reveal that the range and standard deviation of the data series perform best in terms of anomaly amplification and spatial correspondence to in-situ determined spring dis-charge locations. I conclude on the reason that both mirror temperature variability that is stabilized and therefore smaller at areas where spatio-temporal constant groundwater discharge occurs. 3) The application of the before developed method on a thermal satellite data set spanning the years 2000 to 2011 enables to localise specific groundwater discharge sites and to semi-quantitatively analyse the temporal variability of the thermal anomalies (termed groundwater affected area - GAA). I identify 37 groundwater discharge sites along the entire Dead Sea coastline that refine the so far coarsely given spring areas to specific locations. All spatially match independent in-situ groundwater discharge observations and additionally indicate 15 so far unreported discharge sites. Comparing the variability of the GAA extents over time to recharge behaviour reveals analogous curve progressions with a time-shift of two years. This observation suggests that the thermally identified GAAs directly display the before only assumed groundwater discharge volume. This finding provides a serious alternative to monitor groundwater discharge over large temporal and spatial scales that is relevant for different scientific communities. From the results I furthermore conclude to observe the before only assumed and modelled groundwater discharge share from flushing of old brines during periods with an above average Dead Sea level drop. This observation implies the need to not only consider discharge from known terrestrial and submarine springs, but also from flushing of old-brines in order to calculate the total Dead Sea water budget. 4) I present a complementary airborne thermal data set recorded in 01/2011 over the north-western part of the Dead Sea coast. The higher spatial resolution allows to refine the satellite-based GAA to 72 specific groundwater discharge sites and even to specify the so far unknown abundance of submarine springs to six sites with a share of <10 % to the total groundwater discharge. A larger contribution stems from newly iden-tified seeping spring type (24 sites) where groundwater emerges diffusively either ter-restrial or submarine close to the land/water interface with a higher share to the total discharge than submarine springs provide. The major groundwater contribution origi-nates from the 42 identified terrestrial springs. For this spring type, I demonstrate that 93 % of the discharge volume can be modelled with a linear ordinary least square re-gression (R2=0.88) based on the thermal plume extents and in-situ measured discharge volumes from the Israel Hydrological Service. This result implies the possibility to determine discharge volumes at unmonitored sites along the Dead Sea coast as well that can provide a complete physically-based picture of groundwater discharge magni-tude to the Dead Sea for the first time.:1 Introduction 1.1 Remote sensing applications on groundwater 1.1.1 Classical aspects 1.1.2 Modern aspects 1.2 Motivation and main objectives 1.3 Why the western catchment of the Dead Sea? 1.4 Overview 2 The western catchment of the Dead Sea 2.1 Geological and Structural Overview 2.2 Groundwater system 2.3 Groundwater inputs 2.4 Dead Sea 3 Groundwater flow-paths 3.1 Prologue 4 Method development for groundwater discharge identification 4.1 Prologue 5 Localisation and temporal variability of groundwater discharge 5.1 Prologue 6 Qualitative and quantitative refinement of groundwater discharge 6.1 Prologue 7 Conclusion and Outlook 7.1 Main results and implications 7.2 Outlook References Appendix

Die Auswirkungen des Braunkohlenbergbaus auf den Gebietswasserhaushalt bilden seit 1990 einen Schwerpunkt der regional- und fachplanerischen Auseinandersetzungen. Dabei fokussieren sich die Problemfelder aufgrund der Fläche, Dauer und Intensität der bergbaulichen Eingriffe auf den „Südraum Leipzig“.

Evapotranspiration ET is a dominant Earth System process that couples the water and energy cycles at the earth surface. The pressure of global environmental changes foster the broad scientific aim to understand impacts of climate and land-use on evapotranspiration under transient conditions. In this work, the spatial scale of river catchments is addressed through data analysis of hydrological and meteorological archives with ET classically derived through water balance closure. Through a synthesis of various catchments with different climatic forcings and hydrological conditions, the core objectives of this thesis are: - Did environmental changes in the past, such as climatic- or land-use and land cover (LULC) changes, result in detectable non-stationary changes in the hydro-climate time series? - How can the impacts of climatic- from LULC changes on the hydroclimatology of catchments be separated? - What are the factors that control the sensitivity of ET and streamflow to external changes? These research questions are addressed for the climatic scales of long-term annual averages and seasonal conditions which characterise the hydroclimatology of river catchments. Illustrated by a rich hydro-climatic archive condensed for 27 small to medium sized river catchments in Saxony, a method is proposed to analyse the seasonal features of river flow allowing to detect shifting seasons in snow affected river basins in the last 90 years. Observations of snow depth at these same times lead to the conclusion, that changes in the annual cycle of air temperature have a large influence on the timing of the freeze-thaw in late winter and early spring. This causes large changes in storage of water in the snow pack, which leads to profound changes of the river regime, particularly affecting the river flow in the following months. A model-based data analysis, based on the fundamental principles of water and energy conservation for long-term average conditions, is proposed for the prediction of ET and streamflow, as well as the separation of climate related impacts from impacts resulting from changes in basin conditions. The framework was tested on a large data set of river catchments in the continental US and is shown to be consistent with other methods proposed in the literature. The observed past changes highlight that (i) changes in climate, such as precipitation or evaporative demand, result in changes of the partitioning within the water and energy balance, (ii) the aridity of the climate and to a lesser degree basin conditions determine the sensitivity to external changes, (iii) these controlling factors influence the direction of LULC change impacts, which in some cases can be larger than climate impacts. This work provides evidence, that changes in climatic and land cover conditions can lead to transient hydrological behaviours and make stationary assumptions invalid. Hence, past changes present the opportunity for model testing and thereby deriving fundamental laws and concepts at the scale of interest, which are not affected by changes in the boundary conditions.:Kurzfassung Abstract List of Manuscripts Symbols and abbreviations List of Symbols List of abbreviations 1 Introduction 1.1 Motivation and relevance 1.1.1 Scientific importance of evapotranspiration 1.1.2 Pressure of human driven changes 1.1.3 Practical importance of evapotranspiration 1.2 Scope 1.2.1 Focus on the catchment scale 1.2.2 Changes in the hydroclimatology of river catchments 1.2.3 Hydro-climate data analysis 1.3 Objectives and research questions 1.3.1 Shifting seasons in hydrology 1.3.2 Long-term annual average changes of evapotranspiration and streamflow 1.3.3 Methodological requirements 1.4 Structure of the thesis 2 Long term variability of the annual hydrological regime 2.1 Introduction 2.1.1 Motivation 2.1.2 Seasonal changes in hydrologic records 2.1.3 Regional climate in Saxony 2.1.4 Objective and structure 2.2 Methods 2.2.1 Annual periodic signal extraction 2.2.2 The runoff ratio and its annual phase 2.2.3 Descriptive circular statistics 2.2.4 Detection of nonstationarities, trends and change points 2.3 Data 2.4.1 Estimation and variability of the timing of the runoff ratio 2.4.2 Temporal variability of the timing 2.4.3 Does temperature explain trends in seasonality of runoff ratio? 2.4.4 Trend analysis in snow dominated basins 2.4.5 Uncertainty and significance of the results 2.5 Conclusions 2.A Preparation of basin input data 2.A.1 Precipitation 2.A.2 Temperature and snow depth data 3 Evaluation of water-energy balance frameworks 3.1 Introduction 3.2 Theory 3.2.1 Coupled water and energy balance 3.2.2 The ecohydrologic framework for change attribution 3.2.3 Applying the climate change hypothesis to predict changes in basin evapo transpiration and streamflow 3.2.4 Derivation of climatic sensitivity using the CCUW hypothesis 3.2.5 The Budyko hypothesis and derived sensitivities 3.3 Sensitivity analysis 3.3.1 Mapping of the Budyko functions into UW space 3.3.2 Mapping CCUW into Budyko space 3.3.3 Climatic sensitivity of basin evapotranspiration and streamflow 3.3.4 Climate-vegetation feedback effects 3.4 Application: three case studies 3.4.1 Mississippi River Basin (MRB) 3.4.2 Headwaters of the Yellow River Basin (HYRB) 3.4.3 Murray-Darling River Basin (MDB) 3.5 Conclusions 3.5.1 Potentials and limitations 3.5.2 Insights on the catchment parameter 3.5.3 Validation 3.5.4 Perspectives 3.A Derivation of the climate change direction 4 Climate sensitivity of streamflow over the continental United States 4.1 Introduction 4.1.1 Motivation 4.1.2 Hydro-climate of the continental US 4.1.3 Aims and research questions 4.2 Methods 4.2.1 Ecohydrological concept to separate impacts of climate and basin changes 4.2.2 Streamflow change prediction based on a coupled water-energy balance framework 4.2.3 Streamflow change prediction based on the Budyko hypothesis 4.2.4 Statistical classification of potential climate and basin change impacts 4.3 Data 4.4 Results and discussion 4.4.1 Hydro-climate conditions in the US 4.4.2 Climate sensitivity of streamflow 4.4.3 Assessment of observed and predicted changes in streamflow 4.4.4 Uncertainty discussion 4.5 Conclusions 4.A Mathematical derivations for the Mezentsev function 5 Summary and conclusions 5.1 Shifting seasons in hydrology 5.1.1 Major findings 5.1.2 Socio-economic and political relevance 5.1.3 Limitations and possible directions for further research 5.2 Long-term annual changes in ET and streamflow 5.2.1 Major findings 5.2.2 Socio-economic and political relevance 5.2.3 Limitations and further research 5.3 General conclusions and outlook 5.3.1 Regional and temporal limits and validity 5.3.2 Hydrological records carry signals of climate and land use change 5.3.3 Statistical significance of past changes 5.3.4 Improvements in assessing ET 5.3.5 Remote sensing 5.3.6 Learning from the past to predict the future? Bibliography Danksagung Erklärung / Die Verdunstung ist ein maßgeblicher Prozess innerhalb des Klimasystems der Erde, welche den Wasserkreislauf mit dem Energiehaushalt der Erde verbindet. Eine zentrale wissenschaftliche Herausforderung ist, zu verstehen, wie die regionale Wasserverfügbarkeit durch Änderungen des Klimas oder der physiographischen Eigenschaften der Landoberfläche beeinflusst wird. Mittels einer integrierten Datenanalyse von vorhandenen langjährigen Archiven hydroklimatischer Zeitreihen werden die folgenden wissenschaftlichen Fragestellungen dieser Dissertation diskutiert: - Haben beobachtete Änderungen der Landoberfläche und des Klimas zu nachweisbaren, instationären hydroklimatischen Änderungen geführt? - Lassen sich die hydroklimatischen Auswirkungen von Klimaänderungen und Änderungen der Landoberfläche voneinander unterscheiden? - Welche Faktoren beeinflussen die Sensitivität von Abfluss und Verdunstung auf Veränderungen der klimatischen und physiographischen Randbedingungen? Hierbei fokussiert sich die Arbeit auf Änderungen im langjährige Mittel und im Jahresgang von hydroklimatischen Variablen auf der räumlichen Skala von Flusseinzugsgebieten. Zur Untersuchung des hydrologischen Regimes wurde ein harmonischer Filter angewandt, der es erlaubt, die Eintrittszeit des Jahresgangs (Phase) zu quantifizieren. Diese klimatologische Kenngröße wurde für eine Vielzahl von Einzugsgebieten in Sachsen untersucht, wobei sich vor allem für die Gebiete in den Kammlagen des Erzgebirges signifikante Veränderungen ergaben. Es konnte gezeigt werden, dass die signifikante Phasenverschiebung der Temperatur seit Ende der 1980er Jahre zu einer verfrühten Schneeschmelze und dadurch zu einem Rückgang des Abflusses bis in die Sommermonate hinein geführt hat. Desweiteren wurde eine modellbasierte Datenanalyse entwickelt, welche auf Massen- und Energieerhalt von Einzugsgebieten im langjährigen Mittel beruht. Das entwickelte Konzept erlaubt es, Auswirkungen von Klimaänderungen von anderen Effekten, welche z.B. durch Landnutzungsänderungen bedingt sind, abzugrenzen und zu quantifizieren. Die Ergebnisse einer Sensitivitätsanalyse dieses Konzeptes sowie die Anwendung auf einen umfangreichen hydroklimatischen Datensatz der USA zeigen: (i) Veränderungen im Wasser- oder Energiedargebot beeinflussen auch die Aufteilung der Wasser- und Energieflüsse. (ii) Die Aridität des Klimas und nachgeordnet die physiographischen Faktoren bestimmen die Sensitivität von Verdunstung und Abfluss. (iii) Beide Faktoren beeinflussen die Stärke und Richtung der Auswirkungen von physiographischen Änderungen. (iv) Anthropogene Veränderungen der Landoberfläche führten zum Teil zu stärkeren Auswirkungen als klimatisch bedingte Änderungen. Zusammenfassend zeigt sich, dass Änderungen von Landnutzung und Klima zu Verschiebungen im Wasserhaushalt führen können und damit auch die Annahme von Stationarität verletzen. Hydroklimatische Veränderungen bieten aber auch eine Gelegenheit zum Testen von Theorien und Modellen, um somit die grundlegenden Zusammenhänge zu erkennen, welche nicht durch Änderungen der Randbedingungen hinfällig werden.:Kurzfassung Abstract List of Manuscripts Symbols and abbreviations List of Symbols List of abbreviations 1 Introduction 1.1 Motivation and relevance 1.1.1 Scientific importance of evapotranspiration 1.1.2 Pressure of human driven changes 1.1.3 Practical importance of evapotranspiration 1.2 Scope 1.2.1 Focus on the catchment scale 1.2.2 Changes in the hydroclimatology of river catchments 1.2.3 Hydro-climate data analysis 1.3 Objectives and research questions 1.3.1 Shifting seasons in hydrology 1.3.2 Long-term annual average changes of evapotranspiration and streamflow 1.3.3 Methodological requirements 1.4 Structure of the thesis 2 Long term variability of the annual hydrological regime 2.1 Introduction 2.1.1 Motivation 2.1.2 Seasonal changes in hydrologic records 2.1.3 Regional climate in Saxony 2.1.4 Objective and structure 2.2 Methods 2.2.1 Annual periodic signal extraction 2.2.2 The runoff ratio and its annual phase 2.2.3 Descriptive circular statistics 2.2.4 Detection of nonstationarities, trends and change points 2.3 Data 2.4.1 Estimation and variability of the timing of the runoff ratio 2.4.2 Temporal variability of the timing 2.4.3 Does temperature explain trends in seasonality of runoff ratio? 2.4.4 Trend analysis in snow dominated basins 2.4.5 Uncertainty and significance of the results 2.5 Conclusions 2.A Preparation of basin input data 2.A.1 Precipitation 2.A.2 Temperature and snow depth data 3 Evaluation of water-energy balance frameworks 3.1 Introduction 3.2 Theory 3.2.1 Coupled water and energy balance 3.2.2 The ecohydrologic framework for change attribution 3.2.3 Applying the climate change hypothesis to predict changes in basin evapo transpiration and streamflow 3.2.4 Derivation of climatic sensitivity using the CCUW hypothesis 3.2.5 The Budyko hypothesis and derived sensitivities 3.3 Sensitivity analysis 3.3.1 Mapping of the Budyko functions into UW space 3.3.2 Mapping CCUW into Budyko space 3.3.3 Climatic sensitivity of basin evapotranspiration and streamflow 3.3.4 Climate-vegetation feedback effects 3.4 Application: three case studies 3.4.1 Mississippi River Basin (MRB) 3.4.2 Headwaters of the Yellow River Basin (HYRB) 3.4.3 Murray-Darling River Basin (MDB) 3.5 Conclusions 3.5.1 Potentials and limitations 3.5.2 Insights on the catchment parameter 3.5.3 Validation 3.5.4 Perspectives 3.A Derivation of the climate change direction 4 Climate sensitivity of streamflow over the continental United States 4.1 Introduction 4.1.1 Motivation 4.1.2 Hydro-climate of the continental US 4.1.3 Aims and research questions 4.2 Methods 4.2.1 Ecohydrological concept to separate impacts of climate and basin changes 4.2.2 Streamflow change prediction based on a coupled water-energy balance framework 4.2.3 Streamflow change prediction based on the Budyko hypothesis 4.2.4 Statistical classification of potential climate and basin change impacts 4.3 Data 4.4 Results and discussion 4.4.1 Hydro-climate conditions in the US 4.4.2 Climate sensitivity of streamflow 4.4.3 Assessment of observed and predicted changes in streamflow 4.4.4 Uncertainty discussion 4.5 Conclusions 4.A Mathematical derivations for the Mezentsev function 5 Summary and conclusions 5.1 Shifting seasons in hydrology 5.1.1 Major findings 5.1.2 Socio-economic and political relevance 5.1.3 Limitations and possible directions for further research 5.2 Long-term annual changes in ET and streamflow 5.2.1 Major findings 5.2.2 Socio-economic and political relevance 5.2.3 Limitations and further research 5.3 General conclusions and outlook 5.3.1 Regional and temporal limits and validity 5.3.2 Hydrological records carry signals of climate and land use change 5.3.3 Statistical significance of past changes 5.3.4 Improvements in assessing ET 5.3.5 Remote sensing 5.3.6 Learning from the past to predict the future? Bibliography Danksagung Erklärung

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